结构弛豫对Cu36Zr48Ag8Al8块状非晶合金组织结构和力学性能的影响

利用铜模吸铸法在不同电压下制备出成分为Cu36Zr48Ag8Al8大块非晶合金。并将不同制备态的Cu36Zr48Ag8Al8大块非晶合金分别在低于玻璃转化温度以下进行低温（150℃）和高温（300℃）退火。利用X射线衍射（xRD）、扫描电子显微镜（sEM）和万能试验机等技术手段研究了低温和高温弛豫退火对不同制备态的Cu36Zr48Ag8Al8大块非晶合金的组织结构和力学性能的影响,并应用结构弛豫理论对其变化机制进行了分析。     

Mg-Cu-Ni-Gd非晶合金结构弛豫及力学性能

采用差示扫描热分析仪(DSC/DTA),X射线衍射(XRD)和透射电镜(TEM)研究了Mg-Cu-Ni-Gd系非晶合金的结构弛豫以及力学性能,分析了Ni元素对Mg基非晶合金的结构弛豫和力学性能的影响.结果表明, Mg65Cu25 Gd10非晶合金在305 K下保温180 s发生结构弛豫后,出现约1-2 nm的中程有序畴.采用Ni元素部分取代Cu元素,可提高合金抗结构弛豫能力和力学性能.     

Cu46Zr46Al8非晶合金电子束焊接特性分析

对Cu₄₆Zr₄₆Al₈非晶合金进行了电子束焊接,并分析了接头微观组织转变、显微硬度分布及拉伸性能.结果表明,Cu₄₆Zr₄₆Al₈非晶合金电子束焊接接头熔化区组织大部分仍为非晶态,过冷液相区内发生晶化形成Cu-Zr金属间化合物.焊接接头熔化区与母材硬度相当,过冷液相区硬度值显著降低.接头抗拉强度及韧性相比母材都明显降低,拉伸断裂于过冷液相区内的脆性化合物层,呈现典型的沿晶脆性断裂特征.     

Cu44.25Ag14.75Zr36Ti5非晶合金的晶化行为

采用铜模铸造法制备了直径为3mm的柱状Cu44.25Ag14.75Zr36Ti5块体非晶合金,X射线衍射证明试样为完全非晶态。利用差示扫描热分析仪(DSC)、X射线衍射,研究了该非晶合金的晶化行为。利用Kissinger和Ozawa方程求得Cu44.25Ag14.75Zr36Ti5第一晶化峰和第二晶化峰的晶化激活能。结果表明,该大块非晶合金具有良好的热稳定性,在10K/min的加热速率下,析出相主要是Cu8Zr3和Cu10Zr7。     

退火工艺对Ce69Al10Cu20Co1非晶合金热稳定性与力学性能的影响

利用X射线衍射分析、差热扫描热分析仪和纳米压痕仪研究退火保温时间对Ce69Al10Cu20Co1非晶热稳定性和力学性能的影响。结果表明:在低于玻璃转变温度以下长时间等温退火,材料仍保持非晶结构,随退火时间的延长,合金的自由体积和缺陷浓度逐渐减少,合金玻璃转化温度逐渐升高,而晶化温度逐渐降低。纳米压痕结果表明,铸态和弛豫态非晶合金在压痕保载曲线均出现明显的蠕变平台,随退火时间延长,由于形成更加致密的堆垛结构,蠕变平台宽度不断减小,而合金的模量和硬度均有提高。     

Zr含量对非晶合金非晶形成能力及力学性能的影响

采用铜模吸铸法制备出直径为3 mm的[Zr0.72+x(Cu0.59Ni0.41)0.28-x]88Al12(x=0,0.05,0.1)棒状非晶合金。通过X射线衍射(XRD)、差示扫描热量法(DSC)、微机控制电子式万能力学试验机和扫描电镜(SEM)研究其非晶形成能力与压缩力学性能的变化规律。结果表明:随着Zr含量的提高,合金的过冷液相区宽度ΔTx减小,热稳定性下降;约化玻璃转变温度Trg和参数γ均随着Zr含量的提高而下降,非晶形成能力下降;在x=0时,断裂强度、塑性应变和抗压强度均达到最大值,分别为1 531 MPa、14.61%和1 838 MPa;而在x=0.1时,塑性应变和抗压强度则分别达到最小值5.06%和1 495 MPa;试样的室温准静态压缩力学性能随Zr含量的增加而下降。     

高温变形对(Cu50Zr50)92Al8等温晶化行为及其力学性能的影响

研究了(Cu50Zr50)92Al8非晶合金在过冷液相区中,经过牛顿流变和非牛顿流变后的等温晶化行为及其对该合金力学性能的影响。结果表明,牛顿型流变对(Cu50Zr50)92Al8非晶合金的结构没有明显的影响;而非牛顿流变对该非晶的显微结构及其等温晶化行为有显著影响:非牛顿流变促进了(Cu50Zr50)92Al8非晶合金的晶化,其主要晶化相为体心立方结构的CuZr相(B2相)和CuZr马氏体相;经非牛顿流变及真空热处理试样,在室温压缩过程中,应力诱发了部分B2相的马氏体相变,从而使其在室温下表现出超弹性,当预塑性应变量为8%时,其总可回复应变为5%左右。     

过冷液态Zr48Cu36Ag8Al8块体非晶合金的相分离及组织演变

本文通过x射线衍射(XRD)、差示扫描量热法(DSC)和透射电子显微镜(TEM)研究了退火温度对Zr₄₈Cu₃₆Ag₈Al₈金属玻璃微观结构演化的影响。结果表明,快速凝固获得的样品为典型的非晶态结构。当样品在703K保温20分钟时,均一的非晶基体相分离成两种非晶合金,即,发生相分离。由于相分离结构与非晶基体在等温退火过程是竞争的关系,这个结构很容易向晶化态进行转变,形成AlZr₂ AlAg₃相。Zr₄₈Cu₃₆Ag₈Al₈金属玻璃的微观结构在过冷液相区等温退火过程中经历了的局部结构转变,相分离以及纳米晶转变,这个过程意味着Zr₄₈Cu₃₆Ag₈Al₈金属玻璃的微观结构对退火温度十分敏感。此外,相分离的形成可以加速纳米晶的形成。     

具有高非晶形成能力的高熵合金Cu29Zr32Ti15Al5Ni19

用铜模吸铸法成功地合成了由两个固溶体相构成的高熵合金(HEA) Cu₂₉Zr₃₂Ti₁₅Al₅Ni₁₉和相同成分的非晶态合金(HE-BMG)。实验结果表明该成分的高熵合金具有高的非晶形成能力。铸态高熵合金Cu₂₉Zr₃₂Ti₁₅Al₅Ni₁₉的抗压强度为1127MPa。在750℃保温2小时后的Cu₂₉Zr₃₂Ti₁₅Al₅Ni₁₉高熵合金的硬度仍高达826HV。     

Ti20Zr20Hf20Cu20Be20高熵非晶合金应力弛豫行为研究

高熵非晶合金力学弛豫行为的研究,对于理解玻璃转变、塑性变形、弛豫机理等科学问题和拓展其工程应用极为关键。本文采用应力分析方法对Ti20Zr20Hf20Cu20Be20高熵非晶合金条带进行了研究,旨在揭示高熵非晶合金应力弛豫行为。通过分析其在恒定应变下较宽时间窗口和温度窗口内的应力衰减过程,发现在低于Tg的玻璃态下,高熵非晶合金中存在着弛豫解耦现象,分别是慢弛豫和快弛豫过程。其中慢弛豫呈现扩展指数衰减模式,弛豫时间存在对温度的Arrhenius动力学依赖关系,与长程原子重排运动有关,快弛豫过程对应于微观局部内应力的逐步消散过程。不论该高熵非晶合金变形处于弹性阶段还是发生了屈服,应力弛豫过程受应变的影响都较小。本研究揭示了高熵非晶合金中新的弛豫解耦现象和与之相关的独特动力学机制,拓宽了我们对高熵非晶合金弛豫动力学过程以及其本征特性的认知。     

Small scale resistance spot welding of Cu47Ti34Zr11Ni8 (Vitreloy 101) bulk metallic glass

The resistance spot welding of Vitreloy 101 (Cu₄₇Ti₃₄Zr₁₁Ni₈) metallic glass ribbons was studied by mechanical testing, scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and X-ray diffraction (XRD). Material was expelled along the weld interface and around the electrode contact points on the alloy surface. There were no significant changes in composition between the melted and native alloy although minor (∼8%) crystallization was observed in DSC data. Failure during peel and tensile-shear tests of the welds was observed to occur at the periphery of the weld (pullout failure), where slower melting and cooling occurred away from the heat sink effects of the welding electrodes. Measurements of lap welds indicated a maximum shear strength of 810 ± 77 MPa, about 75% of the predicted shear strength of the monolithic alloy. Embrittlement and crystallization around the weld likely contributed to failure. A finite element analysis (FEA) model was developed to explore the temperature–time relation inside the metallic glass during and following welding and it confirmed the main features observed experimentally. The model indicated rapid melting as temperatures reached ∼2000 K followed by cooling of the center of the weld nugget at rates up to ∼48,000 K s⁻¹, greatly exceeding the critical cooling rate for this material of 250 K s⁻¹. A torus of material around the weld nugget remained molten for longer and cooled more slowly than the center of the weld nugget.     

玻璃态Cu29Zr32Ti15Al5Ni19在纳米压入过程中的压痕尺寸效应及应变硬化现象

利用纳米压痕技术对高熵非晶合金Cu₂₉Zr₃₂Ti₁₅Al₅Ni₁₉分别在载荷控制模式、连续刚度模式和循环加载模式下进行了研究。该合金在纳米压入过程中会发生Pop-in现象,且载荷大小比加载速率对Pop-in现象的影响更大。当载荷超过40mN时,即使采用高达5mN/s的加载速率仍然可以观察到Pop-in现象。该合金存在压痕尺寸效应,其测试纳米硬度随载荷的增大而下降,其Meyer指数(n)小于2。压入过程中的能量耗散分数(E_d)在54%-60%之间变化。循环加载测试结果显示该合金加工硬化效应明显。     

Nanocrystallization-induced large room-temperature compressive plastic strain of Ti40Zr25Ni8Cu9Be18 BMG

By combining neutron diffraction, high-resolution transmission electron microscopy and thermal analysis measurements, the microstructure of as-cast Ti₄₀Zr₂₅Ni₈Cu₉Be₁₈ BMG with diameter of 2 mm was identified to be quenched-in nuclei/amorphous matrix. The quenched-in nuclei transform to (Ti,Zr)Be₂ nanocrystals with the average size of 4 nm homogeneously distributed into the amorphous matrix during deformation, which could be responsible for the large room-temperature compressive plastic strain, up to 8.0% at a constant strain rate of 5 × 10⁻⁴ s⁻¹.     

温度和应变速率对Mg61Cu20.3Ag8.7Er10非晶合金力学行为的影响

采用XRD、SEM等技术分析了Mg61Cu20.3Ag8.7Er10合金的结构和断口形貌,研究了Mg61Cu20.3Ag8.7Er10非晶合金在不同温度和不同应变速率条件下的力学行为。结果表明,室温下非晶合金的断裂强度随应变速率的增加而降低。-100℃时,非晶合金不仅具有较高的强度,同时还表现出一定的塑性行为,此时,应变速率对于非晶合金的强度和塑性几乎没有影响。     

Mechanical relaxations of a (Zr77.5Ti22.5)55(Ni48Cu52)21.25Be23.75 amorphous alloy studied using dynamic mechanical analysis

The dynamic mechanical properties of a (Zr_77.5Ti_22.5)₅₅(Ni₄₈Cu₅₂)_21.25Be_23.75 amorphous alloy were investigated by frequency-dependent elastic moduli and isothermal multi-frequency measurements. The frequency-dependent loss modulus showed a relaxation behavior resulting from a glass transition, and the variation of the peak frequency was related to the Arrhenius equation. Isothermal multi-frequency measurement data were used to construct the master curves of the elastic moduli and tan δ by applying the time-temperature superposition principle. The temperature dependence of the shift factor was found to follow the Arrhenius relationship, and the activation energies for the low temperature relaxation and glass transition were approximately 156.6kJ/mol and 554kJ/mol, respectively. The glass transition temperature (T _g) was manifested by the crossover region of the shift factor dependence, and from the relationship between the shift factors and the temperature aboveT _g), the fragility index of this alloy was estimated.     

二次重熔工艺对触变成形Al—Pb合金力学性能的影响

研究了二次重熔工艺对触变成形Al—20％Pb合金性能的影响,结果表明：在半固态温度615℃热不同时间时,加热150min时初生相球化程度最高,成形合金的力学性能最好;在不同温度加热150min时,620℃时的初生相颗粒圆整度最高,合金的力学性能最好。初生相球化程度越高,合金越致密且变形协调能力越好,合金的力学性能越好。