共查询到20条相似文献,搜索用时 31 毫秒
1.
H. Khelifi A. Aydi N. Abdelmoula A. Simon A. Maalej H. Khemakhem M. Maglione 《Journal of Materials Science》2012,47(4):1943-1949
Lead-free (1 − x)NaNbO3/xBa(Ti0.5Sn0.5)O3 (x = 0.1, 0.125, 0.15, 0.175, 0.2, and 0.3) ceramics were elaborated by the conventional ceramic technique. Sintering has been
made at 1523 K for 2 h. The crystal structure was investigated by X-ray diffraction with CuKα radiation at room temperature.
As a function of composition, these compounds crystallize with tetragonal or cubic symmetry. Dielectric measurements show
that the materials have a classical ferroelectric behavior for compositions in the range 0.10 ≤ x ≤ 0.15 and relaxor one for compositions in the range 0.15 < x ≤ 0.30. Temperatures T
C or T
m decrease as x content increases. The ferroelectric behavior has been confirmed by hysteresis characterization. For x = 0.1, a piezoelectric coefficient d
31 of 42.146 pC N−1 was obtained at room temperature. The evolution of the Raman spectra was studied as a function of temperature for x = 0.1. 相似文献
2.
M. Y. Lin Y. F. Wang D. C. Ling H. S. Sheu H.-C. I. Kao 《Journal of Superconductivity and Novel Magnetism》2010,23(5):721-724
A series of single phase (La1−x
Sr1+x
) (Mn0.5Co0.5)O4 (0≤x≤0.40) materials with a tetragonal K2NiF4 structure was prepared by a solid state reaction method at 1400 or 1450 °C with a short period of heating time. Powder X-ray
diffraction (XRD) and the Rietveld refinement method were employed for the structural analysis. Unit cell a- and c-axes decrease with increasing amount of Sr substitution. A discrepancy between the zero-field-cooled and the field-cooled
magnetization is observed in all samples investigated below a characteristic temperature, T
*, which likely arises from the canted nature of spins or the random freezing of spins. It appears that T
* decreases with increasing amount of Sr substitution, which is possibly due to the enhancement of chemical pressure induced
by Sr and a corresponding increases of the valence of Mn and/or Co. 相似文献
3.
James T. Joseph Shyla Joseph Annamma John J. K. Thomas V. S. Prasad Sam Solomon 《Journal of Materials Science: Materials in Electronics》2011,22(3):228-232
Microwave dielectric ceramics of the type (Sm0.5Y0.5)Ti(Nb1−x
Ta
x
)O6 were prepared for x = 0, 0.2, 0.4, 0.6, 0.8 and 1 through the conventional solid state ceramic route. The ball-milled compositions were calcined
at 1,250 °C. The cylindrical pellets were sintered at temperatures between 1,385 and 1,450 °C. The densities were determined
by Archimedes method. The structure was analyzed using X-ray diffraction method. The microwave dielectric properties of the
polished pellets were measured using cavity resonator method. The morphological studies were done using Scanning Electron
Microscopy and Transmission Electron Microscopy. The Raman spectra were recorded and analyzed to confirm the structural change.
The photoluminescence spectra were also taken and the emission lines were identified. A correlation study was done among the
measured properties and parameters. Most of the samples have high dielectric constant, high quality factor and low temperature
coefficient of resonant frequency and hence suitable for microwave applications. 相似文献
4.
Hiroyuki Sasakura Yoshiya Akagi Masashi Tanaka Shigeki Tsukui Motoaki Adachi 《Journal of Superconductivity and Novel Magnetism》2010,23(7):1381-1384
New Pb-based layered cuprates containing boron with the 1232 structure have been synthesized in the (Pb0.5B0.5)Sr2(Er3−x−y
Ce
x
Sr
y
)Cu2O
z
system. Nearly the single 1232 phase samples are obtained for the nominal composition of 1.6≤x≤1.9 and y=0.2. A sample with the composition of (Pb0.5B0.5)Sr2(Er1.2Ce1.6Sr0.2)Cu2O
z
shows resistivity-dropping phenomenon below 10 K and it shows a diamagnetic signal at about 9.0 K, though the superconducting
volume fraction is very small. From these results, the sample may well be a new Pb-based superconductor with the 1232 structure. 相似文献
5.
A. Younis A. Hussain M. Asghar A. Manzoor S. Javed 《Journal of Superconductivity and Novel Magnetism》2011,24(4):1327-1332
The dielectric properties of Cu0.5Tl0.5Ba2Ca2−q
Mg
q
Cu3O10−δ
(q=0, 0.5, 1.0 1.5) superconductor samples were studied at two temperatures of 80 and 290 K by capacitance (C) and conductance (G) measurements with the test frequency (f) in the range of 10 KHz to 10 MHz. We have presented the measurements of the dielectric constants (ε′ and ε″), dielectric loss factor (tan δ) and ac-conductivity (σ
ac) as a function of frequency and temperature. A negative capacitance (NC) experience has been observed, which is most likely
due to different contact electrodes and superconductor samples’ Fermi levels. Since metals have their Fermi levels higher
than ceramics, there is a flow of the carriers from the ceramic samples towards the metal electrodes. The dielectric polarization
phenomenon is observed, which is due to dislodgment of mobile charges from their equilibrium position relative to fixed charges
of the reservoir layer. The improved inter plane coupling promoted by Mg substitution at Ca site would change the dielectric
response of Cu0.5Tl0.5Ba2Ca2−q
Mg
q
Cu3O10−δ
superconductors. To observe such effects in Mg doped Cu0.5Tl0.5Ba2Ca2−q
Mg
q
Cu3O10−δ
superconductors, di- electric measurements were carried out both at room temperature (290 K) and in the superconducting state
closer to the boiling point of liquid nitrogen (80 K). The excess conductivity arising due to superconducting state of material
has been determined, and its role in the mechanism of superconductivity is suggested. The negative dielectric constant (ε′) and dielectric loss factor (tan δ) show strong dispersion at low frequencies. The lower thermal agitation at 80 K may enhance the polarizability and hence
the dielectric constants (ε′ and ε″). 相似文献
6.
M. A. A. Moussa N. M. Al-Hosiny 《Journal of Superconductivity and Novel Magnetism》2011,24(4):1309-1314
The chemical solution nitrate route was used to prepare Y0.5[Yb1−x
Nd
x
]0.5Ba2Cu3O
z
superconducting phase with x=0.1, 0.2 and 0.3. Different calcination temperatures from 870 to 900 °C were used. Both XRD and DSC techniques were utilized
in monitoring the Y0.5[Yb1−x
Nd
x
]0.5Ba2Cu3O
z
superconducting phase and the non-superconducting impurity phases such as BaCuO5, CuO and RE2BaCuO5. These two techniques were used to study the effect of impurity phases on the decomposition temperature of Y0.5[Yb1−x
Nd
x
]0.5Ba2Cu3O
z
superconducting phase. The value of x, the Nd amount, and the calcination temperature both influenced the type and number of impurity phases, which resulted in
changing the eutectic and peritectic reaction temperatures. 相似文献
7.
I. V. Belen’kaya O. A. Savinskaya M. A. Neklyudova A. P. Nemudry 《Inorganic Materials》2011,47(12):1347-1355
We have synthesized Sr1 − x
Pb
x
FeO3 − δ (x = 0, 0.05, 0.1, 0.15, 0.2, 0.3, 0.5) perovskite-like materials and studied their structure by X-ray diffraction, M?ssbauer
spectroscopy, and electron microscopy. According to the X-ray diffraction data, the Pb solubility limit in the perovskite
structure is x ≈ 0.15. The materials with x = 0.05 and 0.1 contained Pb1.33Sr0.67Fe2O5 inclusions 10–30 nm in size. Using chronopotentiometry and temperature-programmed desorption, we have estimated oxygen mobility
in the materials with x = 0.05 and 0.1. The results demonstrate that Pb doping increases oxygen mobility in the strontium-ferrite-based materials. 相似文献
8.
Li Jianhua 《Journal of Materials Science》2011,46(19):6364-6370
(Na0.5K0.5)1−x
Li
x
NbO3 powders and ceramics were prepared by molten salt synthesis method. Pure perovskite-phase powder was obtained at a low temperature
of 740 °C with a grain size of below 800 nm. The effects of the LiNbO3 on phase transition, microstructure, electrical properties, and temperature stability were investigated. A morphotropic phase
boundary was identified. The scanning electron microscopy indicated that the (Na0.5K0.5)1−x
Li
x
NbO3 powders and ceramics obtained by the molten salt synthesis method have a relatively uniform particle size and microstructure.
The results indicate that these materials are promising candidates for lead-free piezoelectric ceramics for practical applications. 相似文献
9.
The effect of Pb doping on the superconducting properties of (Cu0.5−x
Pb
x
Tl0.5)Ba2Ca2Cu3O10−δ
(x=0.0, 0.15, 0.25, 0.35) samples has been investigated. Lead is doped in Cu0.5Tl0.5Ba2O4−δ
charge reservoir layer and at the CuO2 planar sites. A multiphase material is achieved with the doping of Pb at the CuO2 planar sites; however, a predominant single-phase (Cu0.5−x
Pb
x
Tl0.5)Ba2Ca2Cu3O10−δ
(x=0.0, 0.15, 0.25, 0.35) material is synthesized with the doping of Pb at the charge reservoir layers. Formation of multiphase
material with the doping of lead at the planar sites showed that its substitution at the planar site is not possible and the
formation of PbO2 planes is less likely. In the samples doped at the charge reservoir layer, the zero critical temperature [T
c
(R=0)] is systematically depressed with the increased concentration of lead. The T
c
(R=0) and magnitude of the diamagnetism are enhanced after post-annealing the samples in oxygen atmosphere. An apical oxygen
mode is observed around 438 cm−1 in undoped samples, which is shifted to 457–461 cm−1 in the Pb-doped samples. This shift in the peak position is most likely associated with the connectivity of apical oxygen
atoms with Pb atoms of (Cu0.5−x
Pb
x
Tl0.5)Ba2O4−δ
(x=0.0, 0.15, 0.25, 0.35) charge reservoir layers. The presence of Pb in the charge reservoir layer and its increased concentration,
somehow, stops the flow of mobile carriers to the conducting CuO2 planes. The decreased density of mobile carriers diminishes the critical temperature and magnitude of diamagnetism in the
final compound. The increased oxygen diffusion in the unit cell achieved by post-annealing in oxygen replenishes the concentration
of carriers in conducting CuO2 planes, which increases the T
c
(R=0) and the magnitude of diamagnetism. These experiments have shown that the density of mobile carriers plays a vital role
in the mechanism of superconductivity and their depressed density suppresses the superconductivity parameters. 相似文献
10.
Tayyba Firdoss A. A. Khurram Nawazish A. Khan 《Journal of Superconductivity and Novel Magnetism》2010,23(3):325-328
We have studied the ac response of Sn doped Cu0.5Tl0.5Ba2Ca2Cu3−x
Sn
x
O10−δ
superconductor samples from their ac-susceptibility measurements under different magnitudes of ac magnetic fields; H
ac=0.4, 4, 16 A/m. The samples with x=0.5 and 1.0 have shown strong flux pinning and intergrain coupling. However, the sample with Sn doping of x=1.5 has shown very poor flux pinning characteristics. 相似文献
11.
M. Mumtaz Nawazish A. Khan S. M. Hasnain Adnan Younis 《Journal of Superconductivity and Novel Magnetism》2011,24(6):1939-1945
The main role played by mobile carriers and fluctuation induced conductivity (FIC) in (Cu0.5Tl0.5−x
K
x
)Ba2Ca3Cu1Zn3O12−δ
(x=0, 0.25) superconductor samples are analyzed in the light of the Aslamazov–Larken (AL) theory. The enhancement of three-dimensional
(3D) conductivity and grain size is achieved with K-doping at Tl sites in the (Cu0.5Tl0.5−x
K
x
)Ba2O4−δ
charge reservoir layer, which are further improved by post-annealing the samples in oxygen. The improvement of these factors
causes the increase in cross-over temperature (T
o), zero resistivity critical temperature {T
c(R=0)} and T
c(onset) of diamagnetism to their higher values. We have also evaluated the exponents (λ
2D and λ
3D), zero temperature coherence lengths ξ
c(0), and interlayer coupling (J) for these samples and tried to correlate them to the superconductivity order parameters. 相似文献
12.
Hengwei Liu Aimin Sun Yanzhong Lu Yaotong Ma Jinyuan Ma Guidan Wei Long Zheng 《Journal of Superconductivity and Novel Magnetism》2010,23(8):1525-1528
A series of polycrystalline samples of Mg1−x
Zn
x
(B1−x
C
x
)2 (x=0.00, 0.02, 0.04, 0.06, 0.08, and 0.10) were synthesized by a conventional solid-state reaction method under a background
pressure about 10−3 Pa. Phase identification, crystal structure and superconducting transition temperature (T
c) were studied by means of X-ray diffraction (XRD) and resistivity measurements. The results indicated that the lattice parameters
a and c show no clear trend in their changes with increasing doping level, and it turned out that the dopants had a marked effect
on the crystal-lattice parameters and changed the crystal structure of the samples. The T
c for Mg1−x
Zn
x
(B1−x
C
x
)2 decreased with C and Zn doping, but the rate of decrease was slower than single C-doped. We propose that the suppression
of T
c by doping originates largely from the structural change. 相似文献
13.
S. L. Young T. C. Wu L. Horng C. H. Lin H. Z. Chen M. C. Kao C. R. Ou N. F. Shih J. B. Shi 《Journal of Superconductivity and Novel Magnetism》2010,23(6):953-956
The ceramic composites, (La0.7Pb0.3MnO3)1−x
(SiO2)
x
, with diluted magnetic properties are prepared using solid-sate sintering route. Magnetization processes of (La0.7Pb0.3MnO3)1−x
(SiO2)
x
composites are explored in this study. Ferromagnetism is gradually attenuated due to the magnetic dilution induced by the
increase of SiO2 content. Clearly, irreversible behavior is observed in the zero-field cooling and the field cooling (ZFC–FC) curves at a
low field of 100 Oe. Saturation magnetization decreases as x increases while ferromagnetic transition temperature remains around 346 K for all composites. All the composites exhibit
ferromagnetic hysteresis behavior which can be modeled by the law of the approach to saturation in the form M=M
S(1−a/H). The term a/H expresses the deviation of magnetization from saturation. The smaller factor a for La0.7Pb0.3MnO3-rich samples results in sharper square curve which should be associated with the long-range spin order of ferromagnetic coupling. 相似文献
14.
New lead-free ceramics (Bi0.5Na0.5)1−x−yBax(Yb0.5Na0.5)yTiO3 (x = 0.02–0.10 and y = 0–0.04) have been prepared by an ordinary sintering technique and their structure and piezoelectric properties have been
studied. X-ray diffraction shows that Ba2+ and Yb3+ diffuse into the Bi0.5Na0.5TiO3 lattices to form a solid solution with a pure perovskite structure and a morphotropic phase boundary (MPB) between rhombohedral
and tetragonal phases is formed at 0.04 < x < 0.10. The partial substitutions of Ba2+ and Yb3+ for A-site ions of Bi0.5Na0.5TiO3 decrease effectively the coercive field E
c and improve significantly the remanent polarization P
r. The ceramics with x = 0.06 and y = 0–0.02 situate within the MPB and possess the lower E
c and larger P
r, and thus exhibit optimum piezoelectric properties: d
33 = 155–171 pC/N and k
p = 29.2–36.7%. The temperature dependences of the dielectric and ferroelectric properties suggest that the ceramics may contain
both the polar and non-polar regions at temperatures near/above T
d. 相似文献
15.
Preparation and properties of ceramics based on (Na0.5Bi0.5)1 ? xAxTiO3 (A = Sr, Cd) solid solutions
This paper describes the preparation and properties of (Na0.5Bi0.5)1 − x
A
x
TiO3 (A = Sr, Cd) lead-free ferroelectric ceramics. The (0.63–0.66)Na0.5Bi0.5TiO3 · (0.37–0.34)Sr0.7Bi0.2TiO3 ceramics are shown to have the best dielectric and piezoelectric properties: tanδ = 0.013–0.009, ɛRT = 1200–1500, d
31 = (370–400) × 10−12 C/N, and k
ρ = 0.4–0.58. The cadmium-containing ceramics offer low dielectric losses and high dielectric permittivity at room temperature. 相似文献
16.
The electrical conductivity, band gap, dielectric permittivity, and molar polarizability of Zn2(Ti
a
Sn
b
)1 − x
Zr
x
O4 solid solutions have been determined. All of the synthesized samples are dielectrics with semiconducting behavior of conductivity.
The phase diagram of the Zn2TiO4-Zn2SnO4-Zn2ZrO4 system is presented. 相似文献
17.
M. Mumtaz Nawazish A. Khan Faheem Ashraf 《Journal of Superconductivity and Novel Magnetism》2011,24(6):1985-1989
The relatively higher electronegative elements (M = Pd, Nb, Bi, Hg) have been partially doped at Tl sites in Cu0.5Tl0.5−x
M
x
Ba2O4−δ
(x=0,0.25) charge reservoir layer of Cu0.5Tl0.5−x
M
x
Ba2Ca2Cu3O10−δ
superconductor. These elements may retain more oxygen in the charge reservoir layer due to their higher electronegativity
as compared to Tl, and the higher population of oxygen in the charge reservoir layer can optimize the charge carriers’ density
in the conducting CuO2 planes. The optimum density of mobile charge carriers in the conducting CuO2 increases Fermi wave-vector K
F and Fermi velocity v
F of the carriers, which results in the improvement of superconducting properties of the material. 相似文献
18.
Nawazish A. Khan Rehana Begum Mazhar Mehmood 《Journal of Superconductivity and Novel Magnetism》2010,23(3):351-359
A reproducible synthesis and characterization of Zn-doped Cu0.5Tl0.5Ba2Ca2Cu3−y
Zn
y
O12−δ
(y=0, 0.5, 1.0, 1.5) superconductors at a relatively lower synthesis temperature of 840°C are studied by using X-ray diffraction,
resistivity, ac-susceptibility and FTIR absorption measurements. The X-ray diffraction (XRD) studies of these samples have
shown a tetragonal structure in which the c-axis length has been found to decrease with increased Zn doping. The critical temperature and magnitude of diamagnetism have
not been significantly affected with the doping of Zn at this synthesis temperature. The magnitude of diamagnetism in the
as-prepared undoped samples is decreased, whereas it remains stable (unchanged) in oxygen post-annealed samples. The apical
oxygen phonon’s modes of type Tl–OA–M(2) and Cu(1)–OA–M(2) {where M=Cu/Zn} and the planar oxygen phonon modes of type M(2)–OP–M(2) are also softened with the increase of Zn doping. We interpreted the softening of these oxygen related phonon modes
linked with the decreased c-axis length, reduced John–Teller distortions and increased mass of Zn (65.38 amu) as compared to that of Cu (63.54 amu) (Kaplan
et al., Phys. Rev. B 65, 214509, 2002). 相似文献
19.
Kandasami Asokan Jae Young Park Sunwoo Choi Changhwan Chang Sang Sub Kim 《Nano Research》2010,3(4):256-263
We experimentally investigate the stabilization of the anatase phase of Ti1−x
Sn
x
O2 (x < 0.5) nanofibers when synthesized by an electrospinning method. The as-spun nanofibers became nano-grained, polycrystalline
nanofibers after calcination and the diameters of the nanofibers depend on Sn content. Stabilization of the anatase phase
in Ti-rich compositions and incorporation of Sn ions were confirmed by X-ray diffraction, Raman, X-ray absorption near-edge
structure, and photoluminescence (PL) spectroscopies. Results from the PL study also demonstrated the tunable nature of the
optical properties, with the emission maximum shifting towards higher wavelength with increasing Sn concentration.
相似文献
20.
Superconducting properties of cadmium doped Cu0.5Tl0.5Ba2Ca2Cu3−y
Cd
y
O10−δ
(y=0,0.5,1.0,1.5,2.0) samples have been studied using X-ray diffraction, resistivity, ac-susceptibility and FTIR absorption
measurements. In X-ray diffraction studies these samples have shown to have tetragonal structure. The zero resistivity critical
temperature and magnitude of diamagnetism are suppressed with the increased incorporation of Cd in the final compound. A change
in the shape of FTIR absorption spectra, after doping, has shown the incorporation of Cd in the unit cell. A systematic hardening
of the apical oxygen modes and softening of the CuO2 planar modes of vibration with increased Cd doping have shown that it is incorporated in the unit cell of Cu0.5Tl0.5Ba2Ca2Cu3−y
Cd
y
O10−δ
(y=0,0.5,1.0,1.5,2.0) superconductors. The FTIR absorption measurements of these samples have shown that hardening of the apical
oxygen modes of types Cu(1)–O(2)–Tl and Cu(1)–O(2)–Cu(2)/Cd
y
(y=0,0.5,1.0,1.5,2.0) increases with the increase of Cd doping in the samples. A softening of the CuO2 planar oxygen mode Cu(2)–O–Cu(2) is also observed with the increased Cd doping in the final compound. It is most likely that
hardening of the apical oxygen modes and the softening of the planar modes of vibration are associated damped harmonic oscillations
produced by heavier Cd atoms in the CuO2 planes, which suppress the phonon population from a desired level, reducing the magnitude of superconductivity in the final
compound. 相似文献