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1.
不同于覆膜防油纸和含氟防油纸,本研究通过调整环保防油剂的种类、涂布量,制备可降解、不含氟的环保防油纸。结果表明,环保丙烯酸类防油剂的涂布量对纸张的防油等级起决定性作用,防油等级随着涂布量的增加而增大。3种丙烯酸类防油剂都具有一定的防油效果,涂布后纸张的防油等级达到12级。综合考虑涂布量和成本等因素,丙2防油剂效果最优,其涂布量为5.5 g/m2时,涂布纸的抗张指数92.4 N·m/g,Cobb值10 g/m2,透气率0.034 mm/s。  相似文献   

2.
食品防油纸是食品包装纸中的一大类,食品防油纸要求具有防油性能,同时对物理强度、抗水性能、防黏性能、印刷适应性和卫生指标都有一定要求。不同于覆膜防油纸和含氟防油纸,本文通过研究不同种类的环保防油剂,制备出丙烯酸酯类复配环保防油剂,并将其应用到食品防油纸生产中。确定优选丙烯酸酯类环保防油剂(丙2)为防油涂层的主要原料,丙烯酸酯类环保防油剂(丙2)和淀粉的最优配比为1∶1,此时纸张的防油等级为12级。成功应用于中试生产,中试环保防油纸和含氟防油纸相比,防油等级和耐热油性能达到最高要求,抗张指数和撕裂指数优于含氟防油纸,吸水性、透气率、生产成本和含氟防油剂相近,证明了环保防油剂复配的可靠性。其性能指标:抗张指数(纵向)91.35 N.m/g,撕裂指数(横向)8.86 m N.m^(2)/g,平滑度(正面/反面)38 s/23 s,吸水性(正面)10.2 g/m^(2),透气率1.65 mm/s。  相似文献   

3.
本研究以未漂阔叶木浆为原料,在最适打浆度(70°SR)下制备定量为60 g/m2的防油原纸,通过表面涂布TEMPO氧化纳米纤维素(TCNF)和壳聚糖(CTS)的方法,提高纸张的防油性能,探究不同涂布量对纸张防油等级、耐热油性能、防溶剂性能、纸张物理性能的影响。结果表明,双层涂布TCNF和CTS,涂布量分别为2.5和1.4 g/m2时,纸张达到最高防油等级(12级),且纸张具有较好的耐热油和防溶剂性能,透气度0.003μm/(Pa·s),厚度为106μm。  相似文献   

4.
防油纸是食品包装领域常用的一种包装材料。随着人们健康和环保意识的增强,对无硅与无氟型防油纸的需求日益增加。采用阳离子淀粉(CS)、羧甲基纤维素(CMC)和环保防油剂复配,采用一次性涂布,开发了一种环保型防油纸。实验结果表明:CS/CMC复配液与环保防油剂按照质量比1∶1混合后,涂布量为2.5g/m 2的条件下,所制备的食品防油纸接触角达到99.6°,KIT防油等级达到8级。  相似文献   

5.
防水防油纸有广泛的应用前景,本文介绍了纸张防水防油的机理和纸张防油性能的测定,采用本色蔗渣浆,经过打浆和浆内添加防水剂、防油剂和助留剂,制备了本色蔗渣浆防水防油纸;探讨了纸浆卡伯值、打浆度、助留剂等因素对纸张防油防水性能的影响,结果表明,在含氟防油剂用量1.8%,防水剂用量5%,助留剂用量0.02%,纸浆游离度400ml时,纸张具有良好的防油性能。  相似文献   

6.
水性含氟丙烯酸酯共聚物防水防油剂的研究   总被引:3,自引:0,他引:3  
李小瑞  辛华 《上海造纸》2005,36(3):49-52,61
含氟化合物具有优异的防水防油性能,水性含氟丙烯酸酯共聚物聚合速度快、对环境污染小,乳状液产品可直接应用与生产中、制备和使用成本相对低,因而得到了迅速发展.该文介绍了水性含氟丙烯酸酯共聚物的制备方法,水性含氟丙烯酸酯共聚物作为纸张防水防油剂的作用机理和应用,并总结了有关纸张防水防油性的测定方法.  相似文献   

7.
含氟化合物具有优异的防水防油性能,水性含氟丙烯酸酯共聚物聚合速度快、对环境污染小,乳状液产品可直接应用与生产中,制备和使用成本低,因而得到了迅速发展。本文介绍了水性舍氟丙烯酸酯共聚物的制备方法,水性舍氟丙烯酸酯共聚物作为纸张防水防油剂的作用机理和应用。并总结了有关纸张防水防油性的测定方法。  相似文献   

8.
核壳型阳离子聚丙烯酸酯硬挺剂的合成及应用   总被引:1,自引:0,他引:1  
以丙烯酸酯类化合物为主要原料,采用种子乳液聚合法合成了核壳型(软核硬壳)阳离子型聚丙烯酸酯乳液.通过红外光谱仪(FT-IR),热重/差热综合热分析仪(DTA-TG)和Zeta电位仪分析了自制乳液的结构和性能,并测试了竹浆纤维织物经硬挺剂与氟系防水防油剂一浴法整理的效果.试验结果表明,该阳离子型聚丙烯酸酯乳液与氟系防水防油剂具有良好的相容性和稳定性,整理后织物可达到与二浴法整理相近的硬挺、防水与防油效果,且织物富有弹性.  相似文献   

9.
研究了聚乙烯醇(PVA)/纳米微纤丝(NFC)涂布对砂纸原纸防油性能及力学性能的影响。研究结果表明:PVA浓度5%涂布的砂纸原纸各项性能均弱于PVA10%浓度的涂布纸。5%PVA涂布(涂布量为2.61g/m~2)时,随着NFC用量增加,其防油性能得到了相应提高,但其防油等级均在6以下;10%PVA涂布(涂布量为8.27g/m~2)时,其涂布后砂纸原纸防油等级均在12左右。在PVA浓度为5%时,涂布纸的拉伸强度比砂纸原纸的提高了约100%;在相同5%NFC的添加量下,10%PVA涂布纸的拉伸强度比5%的提高了约67.37%。随着NFC添加量的增加,纸张的耐折度随之提升。当NFC的添加量在合适范围内,纸张的撕裂度也随NFC添加量的增加而提高。  相似文献   

10.
为开发外卖食品包装容器,以白卡纸为基材,通过涂覆羧甲基壳聚糖(CMCS)溶液和聚乳酸(PLA)溶液制备防水防油纸,从而赋予卡纸防水和耐油性能,力学性能相比原纸也有所改善.本文研究了CMCS和PLA涂布量以及风干时间对卡纸的阻隔性和力学性能的影响.结果表明:涂布5%(wt)、涂布量为3.06 g/m2的CMCS烘干后,再...  相似文献   

11.
Since grapevine ( Vitis spp .) rootstock material is being traded increasingly as disbudded woody material a lack of distinctive morphological features on such material necessitates an alternative and reliable means of identification. Methods described here were developed for rapid and efficient extraction of DNA from woody samples rich in phenolic compounds and polysaccharides, and for subsequent identification of varieties by RAPD PCR. Using these methods, and with the application of only one selected RAPD primer, we were able to differentiate sixteen rootstock varieties, including the seven varieties most commonly used in Germany. Problems commonly encountered with reproducibility of RAPD patterns were avoided by choosing primers with a dinucleotide sequence and a high G/C content that allowed a rather high annealing temperature of 45°C. Methods described here should also be useful for other horticultural crops, especially those with woody tissues rich in phenolic compounds and polysaccharides.  相似文献   

12.
An internet website (http://cpf.jrc.it/smt/) has been produced as a means of dissemination of methods of analysis and supporting spectroscopic information on monomers and additives used for food contact materials (principally packaging). The site which is aimed primarily at assisting food control laboratories in the European Union contains analytical information on monomers, starting substances and additives used in the manufacture of plastics materials. A searchable index is provided giving PM and CAS numbers for each of 255 substances. For each substance a data sheet gives regulatory information, chemical structures, physico-chemical information and background information on the use of the substance in particular plastics, and the food packaging applications. For monomers and starting substances (155 compounds) the infra-red and mass spectra are provided, and for additives (100 compounds); additionally proton NMR are available for about 50% of the entries. Where analytical methods have been developed for determining these substances as residual amounts in plastics or as trace amounts in food simulants these methods are also on the website. All information is provided in portable document file (PDF) format which means that high quality copies can be readily printed, using freely available Adobe Acrobat Reader software. The website will in future be maintained and up-dated by the European Commission's Joint Research Centre (JRC) as new substances are authorized for use by the European Commission (DG-ENTR formerly DGIII). Where analytical laboratories (food control or other) require reference substances these can be obtained free-ofcharge from a reference collection housed at the JRC and maintained in conjunction with this website compendium.  相似文献   

13.
The characterization of the aromatic profile of several apricot cultivars with molecular tracers in order to obtain objective data concerning the aromatic quality of this fruit was undertaken using headspace–solid phase microextraction (HS–SPME). Six apricot cultivars were selected according to their organoleptic characteristics: Iranien, Orangered, Goldrich, Hargrand, Rouge du Roussillon and A4025. The aromatic intensity of these varieties measured by HS–SPME–Olfactometry were defined and classified according to the presence and the intensity of grassy, fruity and apricot like notes. In the six varieties, 23 common volatile compounds were identified by HS–SPME–GC–MS. Finally, 10 compounds, ethyl acetate, hexyl acetate, limonene, β-cyclocitral, γ-decalactone, 6-methyl-5-hepten-2-one, linalool, β-ionone, menthone and (E)-hexen-2-al were recognized by HS–SPME–GC–O as responsible of the aromatic notes involved in apricot aroma and considered as molecular tracers of apricot aromatic quality which could be utilized to discriminate apricot varieties.  相似文献   

14.
The advent of the functional barrier concept in food packaging has brought with it a requirement for fast tests of permeation through potential barrier materials. In such tests it would be convenient for both foodstuffs and materials below the functional barrier (sub-barrier materials) to be represented by standard simulants. By means of inverse gas chromatography, liquid paraffin spiked with appropriate permeants was considered as a potential simulant of sub-barrier materials based on polypropylene (PP) or similar polyolefins. Experiments were performed to characterize the kinetics of the permeation of low molecular weight model permeants (octene, toluene and isopropanol) from liquid paraffin, through a surrogate potential functional barrier (25 μm-thick oriented PP) into the food simulants olive oil and 3% (w/v) acetic acid. These permeation results were interpreted in terms of three permeation kinetic models regarding the solubility of a particular model permeant in the post-barrier medium (i.e. the food simulant). The results obtained justify the development and evaluation of liquid sub-barrier simulants that would allow flexible yet rigorous testing of new laminated multilayer packaging materials.  相似文献   

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This paper describes the second part of a project undertaken to develop certified mussel reference materials for paralytic shellfish poisoning toxins. In the first part two interlaboratory studies were undertaken to investigate the performance of the analytical methodology for several PSP toxins, in particular saxitoxin and decarbamoyl-saxitoxin in lyophilized mussels, and to set criteria for the acceptance of results to be applied during the certification exercise. Fifteen laboratories participated in this certification study and were asked to measure saxitoxin and decarbamoyl-saxitoxin in rehydrated lyophilized mussel material and in a saxitoxin-enriched mussel material. The participants were allowed to use a method of their choice but with an extraction procedure to be strictly followed. The study included extra experiments to verify the detection limits for both saxitoxin and decarbamoyl-saxitoxin. Most participants (13 of 15) were able to meet all the criteria set for the certification study. Results for saxitoxin.2HCl yielded a certified mass fraction of <0.07 mg/kg in the rehydrated lyophilized mussels. Results obtained for decarbamoyl-saxitoxin.2HCl yielded a certified mass fraction of 1.59+/-0.20 mg/kg. The results for saxitoxin.2HCl in enriched blank mussel yielded a certified mass fraction of 0.48 +/- 0.06 mg/kg. These certified reference materials for paralytic shellfish poisoning toxins in lyophilized mussel material are the first available for laboratories to test their method for accuracy and performance.  相似文献   

18.
<正>We are pleased to announce the launch of a new international peer-reviewed journal-Food Science and Human Wellness,ISSN 2213-4530,which is an open access journal,produced and hosted by Elsevier B.V.on behalf of Beijing Academy of Food Sciences.Food Science and Human Wellness is an international peer-reviewed English journal that provides a forum for the dissemination of the  相似文献   

19.
《印刷工业》2014,(11):95-95
According to Printing and Printing Equipment Industries Association of China(PEIAC)'s statistics to the plate manufucturer in China, in 2013, the actual offset plate production has reached 346 million square meters in China. Among them, the CTP production volume was 245 million square meters, up by 11% than that of last year; the total sales of the CTP plate was 239 million square meters, up by 13%.  相似文献   

20.
《印刷工业》2014,(8):103-103
正Held at Guangdong Modern International Exhibition Center,Print China 2015 will cover 7exhibition halls,besides the original Hall No.3,4,5,6,7,the newly built F zone of Hall 3 will be used too.The total area will be140,000 square meters.Hall 3:Offset and large printing equipment,package printing equipment,post press  相似文献   

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