超声波对微流道中聚合物流动性能的影响研究

为了研究超声波作用下的聚合物材料流动性能及其影响因素,利用自主开发的聚合物超声波辅助挤出测试系统,进行了超声波作用下聚合物熔体在微流道管壁的剪切力、剪切速率和表观黏度的测试,并在与传统稳态挤出相比较基础上,分析了超声波对微流道中聚合物熔体流动性能的影响。实验结果表明,引入超声振动后,微流道的入口压力降有明显降低,并且随着熔体剪切速率的增加而增大;超声振动作用下聚合物熔体剪切速率存在临界值,当剪切速率小于临界值时,超声下聚合物黏度小于传统稳态挤出聚合物黏度,反之,超声聚合物黏度大于传统挤出聚合物黏度。     

聚合物熔体超声挤出技术研究综述

综述了超声对聚合物挤出加工性能、化学反应、聚合物共混物相形态、结晶性聚合物的结晶行为、聚合物共混物力学性能等的影响。提出超声挤出技术实现工业化需解决的问题,展望了超声挤出技术在聚合物熔体反应挤出中的研究及应用前景。     

TekFlow聚合物熔体振动挤出成型技术

论述了一种新型聚合物熔体振动挤出成型技术TekFlow,该振动技术为一种旋转剪切与纵向振动的复合式机械振动,对该技术的理论依据、振动设备、振动设备中熔体的流变行为及振动挤出成品的性能方面展开了论述。该振动技术改善了聚合物的加工流变性能和力学性能,降低了成型温度与压力,提高了挤出产量,适用于热敏感性助剂或难分散性填料的共混挤出。     

聚合物熔体窄缝脉动挤出行为的光散射研究

利用聚合物熔体的双折射性质,对振动力场作用下窄缝挤出模头中的聚合物熔体脉动挤出行为进行光散射研究,用光弹性图像和光强度矩阵来表征聚合物熔体受到的剪切应力。振动力场的引入使光弹性图像和光强度矩阵发生了规律性变化。结果表明,振动力场使聚合物熔体剪切应力减小、表观粘度降低,最终使得挤出压力降低、产量提高。     

超声振动对PS熔体流变及黏弹行为的影响

采用Bagley入口校正等理论计算方法与实验结果相结合，讨论了超声振动对PS熔体流变及黏弹行为的影响。在口模入口处施加超声振动，降低了聚合物熔体的非牛顿性，改变其黏弹行为，使其在毛细管口模中流动时弹性形变及储能减小，形变松弛加快，黏度降低，从而使挤出加工中流动阻力变小，挤出效率得到提高。     

振动技术在塑料挤出成型中的应用

介绍了振动技术在塑料挤出加工中的应用,分析了振动力场在挤出过程中的作用及其机理,并讨论了振动力场对聚合物挤出成型制品力学性能的影响。     

辅助挤出技术在聚合物挤出加工中的应用

针对聚合物常规挤出加工时挤出速率低的缺点,介绍振动挤出技术、润滑挤出技术、气体辅助挤出技术等辅助挤出技术在聚合物挤出加工中的应用。这些辅助挤出技术对提高挤出速率和挤出物质量、降低能耗具有重要意义。     

基于电磁动态塑化挤出的模头挤出特性的研究

本文以塑料电磁动态塑化挤出机上的圆截面模头为对象,研究了将振动力场引入聚合物塑化挤出全过程条件下圆截面模头的挤出特性,建立了圆截面模头脉动挤出特性的数学模型,并进行了实验研究,理论分析与实验结果趋向一致,从而揭示了振动力场引入聚合物塑化挤出全过程对圆截面模头挤出特性的影响规律。     

振动力场下聚合物熔体流变行为的响应与分析 Ⅱ．毛细管挤出胀大比和第一法向应力差

在自行设计的恒速型毛细管动态流变装置上，对聚合物熔体进行动态挤出实验。实时采集毛细管的挤出胀大值，借助已建立的振动力场下聚合物熔体弹性行为的表征公式，计算振动力场下聚合物熔体在毛细管壁处的第一法向应力差。通过对比分析有无振动场下以及不同振动强度下聚合物熔体的流变性能，找到聚合物熔体弹性行为对振动力场的响应规律。     

动态挤出对聚合物不稳定流动力为的影响

与稳态挤出相比,在振动场作用下毛细管动态挤出聚合物熔体时,发生不稳定流动的临界流率得到提高。研究结果表明,振动条件下挤出聚合物能有效地改善挤出时的不流动现象,从而提高挤出时产量和质量,为聚合物的成型国呀带来巨大在的益处。     

Influence of ultrasound on the processing and structure of polypropylene during extrusion

The effects of ultrasonic irradiation on extrusion processing and crystallization behavior of polypropylene (PP) are examined. The results show that appropriate irradiation intensity can prominently decrease die pressure and apparent viscosity, increase output, reduce extrudate swell, and improve apparent quality of PP. DSC and WAXD analysis demonstrate that the crystalline structure of PP is changed and the content of the β crystalline increases through ultrasonic vibration. Special effects can be induced by ultrasound, such as strong stress, shatter and vibration, which alter the growth of PP crystals and may favor a special crystal transformation (α → β).     

Improvement in processability of metallocene polyethylene by ultrasound and binary processing aid

The effect of ultrasonic vibration and binary processing aid in improving the processability of metallocene linear low‐density polyethylene (mLLDPE) was investigated. During extrusion, ultrasonic vibration clearly reduced the die pressure and apparent viscosity of mLLDPE but had only a slight effect on its melt fracture. The effect of diatomite/PEG binary processing aid (BPA) was excellent in reducing the viscosity and eliminating the sharkskin fracture of mLLDPE. The effect of ultrasonic vibration and binary processing aid in improving the processability of mLLDPE was synergetic. With a combination of ultrasonic vibration and a small amount of processing aid, the flowability of mLLDPE was further improved, and the critical shear rate for the onset of sharkskin fracture was increased. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 1927–1935, 2007     

低密度聚乙烯毛细管动态挤出时的挤出胀大研究

在振动场的作用下，ＬＤＰＥ熔体于毛细管中动态挤出与稳态挤出时相比，挤出物的挤出胀大比减小，减小程度与施加的振动强度有关。在相同流率时于一定振幅条件下，挤出物胀大比变化与频率成非线性变化。结果表明，动态挤出时挤出物弹性效应得到改善，从而为聚合物的挤出成型加工带来巨大的益处。     

Extrusion Characteristics of Round-Section Dies with VFF

A vibration force field was applied to the whole process of polymer plasticating extrusion by periodical vibration of the screw. It observably affected both the extruder screw extrusion characteristics and the round-section die extrusion characteristics. It also affected the polymer plasticating extrusion process and the quality of the extrudates. An analytical model of typical dynamic extrusion of round-section dies was created. The results showed that a vibration force field can improve extrusion output.     

螺杆轴向振动对PVC/木粉复合材料挤出片材力学性能的影响

介绍了使用聚合物动态塑化单螺杆挤出机对聚氯乙烯(PVC)/术粉复合材料进行加工时,螺杆轴向振动对其挤出片材的拉伸性能的影响。将在振动频率为5-25Hz,振幅为40~200μm下挤出的PVC/木粉复合材料的拉伸性能和稳态状况下挤出的复合材料拉伸性能进行对比,从中找出最佳的振动参数范围。结果表明,振动频率为20 Hz,振幅为120μm时,复合材料的整体拉伸性能最佳,其拉伸强度、拉伸弹性模量、断裂伸长率和稳态相比都有较大的提高。     

动态挤出对聚合物不稳定流动行为的影响

与稳态挤出相比,在振动力场作用下毛细管动态挤出聚合物熔体时,发生不稳定流动的临界流率得到提高。研究结果表明,振动条件下挤出聚合物能有效地改善挤出时的不稳定流动现象,从而提高挤出时产量和质量,为聚合物的成型加工带来巨大的益处。     

超声微注塑机超声单元的设计与分析

提出一种基于超声驱动技术实现聚合物塑化和注射的超声微注射成型机。首先分析超声微注塑机整体结构及工作原理,然后进行超声注塑单元和超声振动模块结构设计,最后利用ANSYS软件进行超声振动模块模态分析和静力学分析,获得超声振动模块的振动频率及相应的纵向振型和超声振动模块的应力应变分布,针对分析结果进行材料强度刚度校核。结果表明,该超声电动微注塑机的超声振动模块能够获得满足需要的纵向振动,且其强度、刚度满足材料性能要求。     

Effects of ultrasonic oscillations on rheological behavior and mechanical properties of novel propylene‐based plastomers

The effects of ultrasonic oscillations on the die pressure, productivity of extrusion, melt apparent viscosity, melt surface appearance, and die swell of novel propylene‐based plastomers were studied in a specially designed ultrasonic oscillations extrusion system developed in our laboratory. The effects of ultrasonic oscillations on molecular weights, tensile strength, and dynamic mechanical properties of extrudates were also studied. The experimental results showed that the presence of ultrasonic oscillations during extrusion could significantly increase the productivity of plastomers at the same die pressure, and reduce die swell and melt fracture such as sharkskin at a given screw rotation speed. The die pressure and apparent viscosity of plastomers remarkably decreased with increasing ultrasonic intensity. Introduction of ultrasonic oscillations into plastomer melts can improve their processibility. The possible mechanism for ultrasonic improvement of rheological behavior was also proposed in this article. Under certain conditions, ultrasound‐assisted extrusion could slightly decrease the glass transition temperature (T_g) and storage modulus of plastomers due to the minor reduction in molecular weights, but showed no significant impact on yield strength and strength at break. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007