共查询到14条相似文献,搜索用时 78 毫秒
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从芥酸出发,经臭氧化还原,乙酰化及四乙酸铅脱羧三步反应合成了茶长卷峨性信息素组分(4),再经CoCl2/Ph3P/NaBH4体系异构化合成桦广翅小卷峨、豆荚小卷娥等昆虫性信息素组份(5)。 相似文献
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The female-emitted pheromone ofGrapholitha molesta (Busck), the Oriental fruit moth, was collected by holding females in glass flasks during calling. Flask washes were found to contain four pheromone components: (Z)-8-dodecenyl acetate and (E)-8-dodecenyl acetate in a 1007 ratio, and (Z)-8-dodecen-1-ol and dodecanol in a 10020 ratio. The ratio of (Z)-8-acetate to (Z)-8-dodecen-1-ol was approx. 10030. Approximately 0.1–0.2 ng of pheromone was recovered per female per hour of calling.Published as Journal Article No. 8598 of the Michigan State University Agricultural Experiment Station. 相似文献
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The relative efficacy of disruptant blends comprised of different combinations of the Oriental fruit moth's pheromone components was determined in field tests. Disruption was evaluated by comparing male moth catch at synthetic and female-baited traps in disruptant and non-treatment areas. Three atmospheric dosages of a 8-dodecenyl acetate (93.5%Z6.5%E) blend, representing two successive 10-fold decreases in concentration (2.5 × 10–2 g/hectare/day to 2.5 × 10–4 g/hectare/day) were tested alone and in combination with an additional percentage of (Z)-8-dodecen-1-ol. Male moth orientation to traps was eliminated in plots exposed to the two highest binary acetate dosages. However, significantly more males were captured in synthetic-baited traps in the lowest acetate-alone treatment, indicating a diminution of disruption efficiency. In contrast, inclusion of (Z)-8-dodecen-1-ol in the disruptant blend effected essentially complete disruption of orientation at all concentrations tested. Mating success ofG. molesta pairs confined in small cages apparently was not affected by the presence of relatively high concentrations of the binary acetate and the acetate-alcohol blends. This suggests that habituation and/or adaptation of male response, at least for comparatively close-range behaviors, did not occur.Lepidoptera: Tortricidae.Published as Journal Article No. 9569 of the Michigan Agricultural Experiment Station. 相似文献
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The sex pheromone ofCryptophlebia leucotreta females is a mixture of (E)-8- and (Z)-8-dodecenyl acetate (dda). The compounds have been isolated from extracts ofC. leucotreta females and were identified by means of chromatography on a silver-impregnated column, and by combined GC-MS analysis and ozonolysis. Optimal catches of males were obtained with mixtures of (E)-8- and (Z)-8-dda in the range of 7030 to 3070. 相似文献
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Walter S. Leal J. Maurício S. Bento Yasuhiro Murata Miikio Ono José R. P. Parra Evaldo F. Vilela 《Journal of chemical ecology》2001,27(10):2041-2051
The sex pheromone of the citrus fruit borer Ecdytolopha aurantiana has been identified by gas chromatography coupled to an electroantennographic detector (GC-EAD). The electron impact mass spectral (EI-MS) fragmentation of the major EAD-active peak gave identifying features for a monounsaturated acetate. Further analyses by chemical ionization mass spectrometry (CI-MS), vapor-phase infrared spectroscopy (GC-IR), along with chemical derivatization (DMDS reaction), led to full characterization of the major component as (E)-8-dodecenyl acetate (E8–12 : Ac). The second constituent was identified as the related alcohol, (E)-8-dodecenol (E8–12 : OH). The two compounds were indistinguishable from the authentic synthetic standards in chemical and EAD analyses. Samples of the two compounds were obtained by a facile synthesis utilizing lithium chemistry. Field tests showed that captures in traps baited with a mixture of E8–12 : Ac and E8–12 : OH at 100 : 1 and 10 : 1 ratios were not significantly different from the catches in traps having two virgin females. Dosage tests showed better performance of traps baited with 1 mg than those with 0.1 mg of the pheromone blend, either in 100 : 1 or 10 : 1 ratio. 相似文献