Thermodynamic evaluations of solar cooling cogeneration cycle using NaSCN–NH<Subscript>3</Subscript> mixture

The commercial refrigeration and air conditioning consumes more electric power for its operation. The solar vapor absorption refrigeration helps to minimize the electric power usage and it is renewable. Large size of solar collector area is required for producing the standalone power as well as cooling cycle. The integration of power and cooling cycle minimizes the number of components such as heat exchanger, separator and collector area. The main objective of the work is to integrate power and cooling for two outputs with single cycle using NaSCN–NH₃ as working fluid. The advantages of NaSCN–NH₃ are having high pressure and pure ammonia vapor at the exit of the generator. The integrated cycle is made by providing the turbine at the exit of the generator along with superheater. It has three pressures of generator, condensing and sink pressure, which is depending on separator and ambient temperature. At the separator temperature of 150°C with weak solution concentration of 0.30, it produces the cogeneration output of 284.80 kW with cycle and plant thermal efficiency of 0.49 and 0.20 respectively.     

Thermodynamic study of multistage absorption cycles using low‐temperature heat

The use of low‐temperature heat (between 50 and 90°C) is studied to drive absorption systems in two different applications: refrigeration and heat pump cycles. Double‐ and triple‐stage absorption systems are modelled and simulated, allowing a comparison between the absorbent–refrigerant solutions H₂O–NH₃, LiNO₃–NH₃ and NaSCN–NH₃. The results obtained for the double‐stage cycle show that in the refrigeration cycle the LiNO₃–NH₃ solution operates with a COP of 0.32, the H₂O–NH₃ pair with a COP of 0.29 and the NaSCN–NH₃ solution with a COP of 0.27, when it evaporates at ?15°C, condenses and absorbs refrigerant at 40°C and generates vapour at 90°C. The results are presented for double‐ and triple‐stage absorption systems with evaporation temperatures ranging between ?40 and 0°C and condensation temperatures ranging from 15°C to 45°C. The results obtained for the double‐stage heat pump cycle show that the LiNO₃–NH₃ solution reaches a COP of 1.32, the NaSCN–NH₃ pair a COP of 1.30 and the H₂O–NH₃ mixture a COP of 1.24, when it condenses and absorbs refrigerant at 50°C, evaporates at 0°C and generates vapour at 90°C. For the double‐ and triple‐stage cycles, the results are presented for evaporation temperatures ranging between 0 and 15°C. The minimum temperature required in the generators to operate the refrigeration and heat pump cycles are also presented. Copyright © 2002 John Wiley & Sons, Ltd.     

Properties of some salt hydrates for latent heat storage

For the utilization of low-grade heat the latent storage of thermal energy is of great advantage because the heat can be preserved at a constant temperature perfectly matched to the special purpose of application. Investigations on the heat capacities, enthalpies of fusion, densities, crystallization behaviour and other chemical and physical properties have shown that the following salt hydrates are especially suitable media for storing low-grade heat. The eutectic mixture of water and 3.92% by weight of sodium fluoride, melting point (MP) = - 3.5°C, is extremely convenient and cheap for refrigerating or other cooling purposes. Lithium chlorate trihydrate, LiClO₃. 3H₂O, MP = +8.1°C has an extremely high storage capacity and other advantageous properties as a storage medium in cooling systems, but a very high price will limit its application. Calcium chloride hexahydrate, CaCl₂. 6H₂O, MP = + 29.2°C, is a suitable and cheap storage medium for heating purposes. For the same application disodium hydrogen phosphate dodecahydrate, Na₂HPO₄. 12H₂O, MP = + 35.2°C, is even better because of the larger storage capacity per unit volume and other advantages which largely compensate the higher material cost. the unique properties of potassium fluoride tetrahydrate, KF. 4H₂O, MP = +18.5°C, make it especially suitable for storing low-grade heat. It can directly function as an energy sink and as an energy reservoir in heat collecting and consuming systems. Examples of the practical applicability for residential heating, temperature levelling and cooling are described.     

Pre-adsorption of low-grade waste steam for high-temperature steam generation by using composite zeolite and long-term heat storage salt of MgSO4

Adsorptive heat transformer is a promising technology for waster heat recovery and global energy conservation. A novel cyclic adsorption heating system based on direct contact heat exchange method has been established for the purpose of high-temperature steam generation from hot water. Pre-adsorption is originally proposed before generation phase to enhance the system performance with composite zeolite 13X and MgSO₄ in the open-loop adsorption heating system. Composite zeolite is prepared by impregnation method. Experimental results show steam with temperature higher than 200°C is generated from inlet water at 72.0°C. During regeneration phase, dry air at 130°C and relative humidity of 7.37% is employed. Gross temperature lift is 95.0°C to 103°C for different pre-adsorption conditions. The effective steam generation time with pre-adsorption temperature at 90.0°C is prolonged by 27.4%. Meanwhile, the mass of steam is elevated by 16.2% compared with the cycle without pre-adsorption. Exergy coefficient of performance is upgraded by 14.7% and specific heating power for steam generation is increased by 16.0%. The pre-adsorption operation achieved the goal of recovery of low-grade waste steam on adsorbents to enhance the subsequent high-temperature steam generation. After pre-adsorption operation, the packed bed reaches adsorption and thermal equilibrium more quickly during generation phase. Thus, dynamic steam generation is significantly intensified and then system performance is improved correspondingly.     

Experimental investigation on heat recovery from condensation of thermal power plant exhaust steam by a CO2 vapor compression cycle

In this paper, a method that utilizes CO₂ vapor compression thermodynamic cycle to recover low‐temperature heat from exhausted water steam of fossil fuel thermal power plants is reported. Experimental investigation was carried out to study the characteristics of low‐temperature heat recovery by liquid CO₂ evaporation process from vacuum exhausted steam condensation occurring at the turbine exit. Furthermore, measured heat recovery performances over one whole year are presented and discussed. Experimental results show that the present heat recovery process by CO₂ vapor compression cycle is able to operate stably. The yearly averaged water temperature at the CO₂ condenser outlet was measured at 87.5 °C with a COP value above 5.0. This high energy efficiency ratio is found to be mainly due to two factors: the transcritical CO₂ vapor compression and steam condensation phase change occurring on the CO₂ evaporator. The findings from this paper provide helpful guidelines for low‐temperature heat recovery system design and improving fossil fuel utilization efficiency. Copyright © 2013 John Wiley & Sons, Ltd.     

Performance analysis of two combined cycle power plants with different steam injection system design

A thermal analysis of two combined cycle power plants is performed. The steam injection system in the combustion chamber constitutes the main difference between the two designs. For the first power plant (design 1) the injected steam is generated in the HRSG. While for second power plant (design 2) this steam is provided using a heat recovery system installed at the compressor outlet. The steam turbine cycle engenders two pressure extraction levels connected to open feed-water heaters. The steam injection in the combustion chamber improves the overall combined cycle efficiency if this steam is generated outside the HRSG.The increase of the ambient temperature affects the overall cycle efficiency.The optimum thermal efficiency, for any temperature value during the year, may be obtained for suitable margin of steam injection ratio. The second design presents better overall efficiency then the first one. In winter season (T_am = 15 °C), the overall cycle efficiency is about 54.45% for a range of steam injection ratio within 11.8 and 14%. While in summer season (T_am = 35 °C) and for the same cycle efficiency, the required range of steam injection ratio is between 18.5 and 18.8%.     

Thermal and Exergy Analysis of an Organic Rankine Cycle Power Generation System with Refrigerant R245fa

Abstract

In this paper, the performance of an organic Rankine cycle (ORC) power generating system operating with refrigerant R245fa was investigated when heat source temperature was below 200?°C. It was found the system thermal efficiency increased but the exergy efficiency of the evaporator decreased with the increase of the heat source temperature. It was also obtained that the exergy efficiency of the evaporator could reach70% when the heat source temperature was 80?°C, which was high enough to prove that the transformation efficiency between the waste heat and the electricity power was ideal. In the simulation model, the area of different parts of the heat exchanger were considered to be varied, flow rate of the waste heat and working medium, the system thermal and exergy efficiency of the evaporator were respectively calculated, the different parameter change regarding the performance influences of the ORC system were simulated. The results can be considered as a reference to research on the design of ORC power generating systems and heat exchangers.     

The Experimental Study on Regenerative Heat Transfer in High Temperature Air Combustion

For the purpose of decomposing the processing gases CF4 from semiconductor manufacturers, ceramic honeycomb regenerative burner system is suggested by using the principle of HTAC. A simulated high temperature air combustion furnace has been used to determine the features of HTAC flames and the results of the decomposition of CF4. The preheat air temperature of it is above 900℃. The exhaust gas released into the atmosphere is lower than 150℃. Moreover, the efficiency of recovery of waste heat is higher than 80%, the NOx level in exhaust gas is less than 198 mg/m3 and the distribution of temperature in the furnace is nearly uniform. The factors influencing on heat transfer, temperature profile in chamber and NOX emission were discussed. Also some CF4 can be decomposed in this system.     

Supercritical water gasification of sewage sludge and combined cycle for H2 and power production – A thermodynamic study

An integrated system of supercritical water gasification (SCWG) and combined cycle has been developed for H₂ production and power generation. Sewage sludge and lignite coal were selected as raw material in this simulation. The effects of feed concentration (10–30 wt%) and lignite coal addition (0–50 wt%) on syngas yield and H₂ yield were also investigated in the temperature range of 500 °C–700 °C. Several heat exchangers were considered in the proposed integrated system to minimize energy loss. High pressure syngas was expanded by using turbo-expander to produce electricity, resulting in the improvement of the total efficiency. The results showed that the minimum feed concentrations of 14.25 wt%, 18.75 wt%, and 25.50 wt% were required to achieve self-sufficient energy at 500 °C, 600 °C, and 700 °C, respectively. However, the lower feed concentration and higher temperature were preferable for syngas production. The highest syngas and H₂ yield were obtained at 700 °C and 10 wt% feed concentration. The SCWG could produce 178.08 kg syngas from 100 kg feed and 9.06 kg H₂ were obtained after H₂ separation. The total power generation from turbo-expander and combined cycle module was 48.37 kW. By combining SCWG and combined cycle, the total efficiency could reach 63.48%. It worth mentioning that the addition of lignite coal could help reduce the minimum feed concentration to achieve autothermal condition, but did not have significant improvement on H₂ production.     

A new power/cooling cogeneration system using R1234ze(E)/ionic liquid working fluid

A novel power/cooling system integrated with organic Rankine cycle and absorption-compression refrigeration cycle was proposed in order to realize the cascade utilization of low-grade energy. In the proposed system, R1234ze(E) (trans-1,3,3,3-tetrafluoropropene) is used as the working fluid for the organic Rankine cycle subsystem and the binary mixtures of R1234ze(E) with three ionic liquids [HMIM][BF₄], [EMIM][BF₄] and [OMIM][BF₄] are used as working fluid for absorption-compression refrigeration cycle subsystem due to their superior environmental protection property and physicochemical property. Moreover, in order to recover the heat of the exhaust gas from turbine in organic Rankine cycle subsystem, the exhaust gas is mixed with R1234ze(E)/ionic liquid solution directly in desorber, while the heat of refrigerant from desorber is recovered to reduce the heat load of condenser. The proposed system has much higher energy and exergy efficiency and lower heat load of condenser than reference system. Under specific conditions, increases of 0.24 and 0.07 in thermal efficiency and exergy efficiency of reference system can be achieved. The effect of distribution ratio, expansion ratio, heat source temperature, condensation temperature, generation temperature, evaporation temperature and compression ratio were analyzed for better design in actual application.     

Temperature–enthalpy/entropy charts of combined ejector–absorption cycle using NH3–H2O

This paper describes the performance of an ammonia–water combine ejector–absorption cycle as refrigerator and heat pump. This combination brings together the advantages of absorption and ejector systems. Also, thermodynamic cycles on the temperature–enthalpy and temperature–entropy charts are shown. The thermodynamics of the combined ejector–absorption cycles are simulated by a suitable method and a corresponding computer code, based on analytic functions describing the behaviour of the binary mixture NH₃–H₂O. It is found that in the case of the refrigerator and heat pump, the theoretical coefficient of performance (COP) or the theoretical heat gain factor (HGF) vary from 1.6 to 90.4 per cent and 0.7 to 37.6 per cent, greater than those of the conventional absorption system, respectively. The operation conditions were: generator temperature (205.5 to 237.1°C), condenser temperature (25.9 to 37.4°C) and evaporator temperature (−8.4 to 5°C). Copyright © 2000 John Wiley & Sons, Ltd.     

Exergy analysis on combustion and energy conversion processes

When we consider exergy analysis on combustion and thermodynamic processes, we introduce another concept against energy analysis, which is supported by an evaluation of its temperature level. When a higher temperature energy than that an ambient level is taken into consideration, it can be put for some domestic or industrial purpose. A medium temperature energy of 30–60 °C is used for domestic heating, and a high temperature of 200 °C and above is suitable for power generation or process heating. Therefore, we study exergy concept supported by temperature level. When we discuss power generation, a high temperature energy of 1500 °C and above in combined cycle has a higher conversion efficiency than that of 500–600 °C in steam cycle. If we try to apply high temperature air combustion, a preheated air temperature of 1000 °C and above can be produced by exhaust heat recovery from stack gas, which has been developed as a new technology of energy conservation. In this study, the authors present an exergy analysis on combustion and energy conversion processes, which is based on the above-mentioned concept of exergy and energy supported by temperature level. When we discuss high temperature air combustion in furnace, this process shows a higher performance than that of the ambient air combustion. Furthermore, when we discuss the power generation and heat pump processes, the minimum ambient temperature would already be known for each season, and the conversion performance can be estimated by the maximum operating temperature in their cycles. So, the authors attempt to calculate the exergy and energy values for combustion, power generation and heat pump processes.     

A comparative study of the carbon dioxide transcritical power cycle compared with an organic rankine cycle with R123 as working fluid in waste heat recovery

The organic rankine cycle (ORC) as a bottoming cycle¹ to convert low-grade waste heat into useful work has been widely investigated for many years. The CO₂ transcritical power cycle, on the other hand, is scarcely treated in the open literature. A CO₂ transcritical power cycle (CO₂ TPC) shows a higher potential than an ORC when taking the behavior of the heat source and the heat transfer between heat source and working fluid in the main heat exchanger into account. This is mainly due to better temperature glide matching between heat source and working fluid. The CO₂ cycle also shows no pinch limitation in the heat exchanger. This study treats the performance of the CO₂ transcritical power cycle utilizing energy from low-grade waste heat to produce useful work in comparison to an ORC using R123 as working fluid.Due to the temperature gradients for the heat source and heat sink the thermodynamic mean temperature has been used as a reference temperature when comparing both cycles. The thermodynamic models have been developed in EES² The relative efficiencies have been calculated for both cycles. The results obtained show that when utilizing the low-grade waste heat with the same thermodynamic mean heat rejection temperature, a transcritical carbon dioxide power system gives a slightly higher power output than the organic rankine cycle.     

Assessment of hydrogen production from waste heat using hybrid systems of Rankine cycle with proton exchange membrane/solid oxide electrolyzer

A techno-economic assessment of hydrogen production from waste heat using a proton exchange membrane (PEM) electrolyzer and solid oxide electrolyzer cell (SOEC) integrated separately with the Rankine cycle via two different hybrid systems is investigated. The two systems run via three available cement waste heats of temperatures 360 °C, 432 °C, and 780 °C with the same energy input. The waste heat is used to run the Rankine cycle for the power production required for the PEM electrolyzer system, while in the case of SOEC, a portion of waste heat energy is used to supply the electrolyzer with the necessary steam. Firstly, the best parameters; Rankine working fluid for the two systems and inlet water flow rate and bleeding ratio for the SOEC system are selected. Then, the performance of the two systems (Rankine efficiency, total system efficiency, hydrogen production rate, and economic and CO₂ reduction) is investigated and compared. The results reveal that the two systems' performance is higher in the case of steam Rankine than organic, while a bleeding ratio of 1% is the best condition for the SOEC system. Rankine output power, total system efficiency, and hydrogen production rate rose with increasing waste heat temperature having the same energy. SOEC system produces higher hydrogen production and efficiency than the PEM system for all input waste heat conditions. SOEC can produce 36.9 kg/h of hydrogen with a total system efficiency of 23.8% at 780 °C compared with 27.4 kg/h and 14.45%, respectively, for the PEM system. The minimum hydrogen production cost of SOEC and PEM systems is 0.88 $/kg and 1.55 $/kg, respectively. The introduced systems reduce CO₂ emissions annually by about 3077 tons.     

Performance of a high temperature hydrate solid/gas sorption heat pump used as topping cycle for cascaded sorption chillers

The purpose of this paper is to study and analyse the experimental performances of a solid/gas sorption heat pump using a new working pair such as MnCl₂ hydrate reacting reversibly with water. The aim of this heat pump device is to produce heat at a temperature level suitable for industrial purposes (typically 160 °C), from waste heat at 90 °C or from environment at 35 °C. Moreover, this kind of process can be efficiently used as a high-temperature topping cycle to drive by means of efficient heat pipes a lower temperature double effect absorption cycle in order to increase the cooling performances by achieving a quadri-effect cascaded chiller. This paper presents the experimental results of the water/hydrate reaction topping cycle and demonstrates the feasibility of a cascading cooling device with high cooling performance: a COP of 1.35 should effectively be attainable.     

Experimental investigation on a MnCl2–CaCl2–NH3 thermal energy storage system

Thermal energy storage (TES) is regarded as one promising technology for renewable energy and waste heat recovery. Among TES technologies, sorption thermal energy storage (STES) has drawn burgeoning attention due to high energy storage density, long-term heat storage capability and flexible working modes. Originating from STES system, resorption thermal energy storage (RTES) system is established and investigated for recovering the heat in this paper. The system is mainly composed of three high temperature salt (HTS) unit beds; three low temperature salt (LTS) unit beds, valves and heat exchange pipes. Working pair of MnCl₂–CaCl₂–NH₃ is selected for the RTES system. 4.8 kg and 3.9 kg MnCl₂ and CaCl₂ composite adsorbents are filled in the adsorption bed. Results indicate that the highest thermal storage density is about 1836 kJ/kg when the heat charging and discharging temperature is 155 °C and 55 °C, respectively. Volume density of heat storage ranges from 144 to 304 kWh/m³. The highest ratio of latent heat to sensible heat is about 1.145 when the discharging temperature is 55 °C. The energy efficiency decreases from 97% to 73% when the discharging temperature increases from 55 to 75 °C.     

Pseudo-stable transitions and instability in chemical heat pumps: the NH3–CoCl2 system

Research in our laboratory has been directed toward the development of a chemical heat pump, based on the NH₃–CoCl₂ system, to provide both refrigeration and heat for the agribusiness industry. In this work the stability of the salt in an inert atmosphere (nitrogen) and in the presence of ammonia was examined experimentally. For a given pressure, the stable composition of the CoCl₂·xNH₃ salt was found to vary with temperature, when the gaseous atmosphere alternated between ammonia and nitrogen. Specifically the salt changed from CoCl₂·6NH₃ to CoCl₂·2NH₃ (140°C, 260 kPa), from CoCl₂·6NH₃ to CoCl₂ (148°C, 260 kPa), and from CoCl₂·2NH₃ to CoCl₂ (170°C, 260 kPa). During the conversion of the salt from one phase to another, pseudo-stable transitions occurred at some processing conditions. In each case they were stable for several minutes, but always less than 1 h. In a nitrogen atmosphere CoCl₂ was found to be unstable above 300°C for pressures from 100 to 600 kPa. In ammonia CoCl₂·2NH₃ stability was found to be a function of temperature and pressure. An explanation for its decomposition, which could lead to the formation of solid NH₄Cl has been suggested. In summary, the CoCl₂·2NH₃ salt was stable at processing conditions close to the phase diagram equilibrium line for 100% decomposition to CoCl₂·2NH₃ and unstable at large departures from it. If commercial chemical heat pumps are to be technically viable, the salt used must be stable for many cycles of synthesis and decomposition. Regions of stability can be defined by plotting experimental results at different processing conditions on phase diagrams of the type developed here.     

Flue gas waste heat affects algal liquid temperature for microalgal production in column photobioreactors

To explore the effects of waste heat (50–170°C) from steel plant flue gas on the column photobioreactor algal liquid temperature for microalgal production, a flue gas-microalgal liquid heat transfer model was developed that simulated the microalgal growth environment for flue-gas carbon dioxide (CO₂) fixation. The simulation results showed that the influence of high-temperature flue gas weakened with the increasing microalgal liquid temperature due to enhanced evaporation and heat dissipation. Increasing the flue gas temperature and aeration rate resulted in a higher microalgal liquid temperature up to a maximum increase of 4.16°C at an ambient temperature of 25°C, an aeration rate of 2 L/min, and a flue gas temperature of 170°C. In an experiment on the effect of incubation temperature on the growth rate of microalgae, at an optimal temperature of 35°C, the Chlorella sp. PY-ZU1 growth rate exhibited a remarkable increase of 104.7% compared to that at 42.5°C. Therefore, modulating the flue gas conditions can significantly increase the microalgal growth rate for CO₂ fixation, making it a promising approach to increase biomass production for efficient carbon utilization.     

Comparative analysis of a solar‐driven novel salt‐based absorption chiller with the implementation of nanoparticles

The present study exemplifies the comprehensive thermal analysis to compare and contrast ammonia‐lithium nitrate (NH₃‐LiNO₃) and ammonia‐sodiumthiocynate (NH₃‐NaSCN) absorption systems with and without incorporation of nanoparticles. A well‐mixed solution of copper oxide/water (CuO/H₂O) nanofluid is considered inside a flat‐plate collector linked to an absorption chiller to produce 15‐kW refrigeration at ?5°C evaporator temperature. Enhancements in heat transfer coefficient, thermal efficiency, and useful heat gain of the collector are evaluated, and the effect of these achievements on the performance of both absorption chillers have been determined for different source temperatures. A maximum 121.7% enhancement is found in the heat transfer coefficient with the application of the nanofluid at 2% nanoparticle concentration. The maximum coefficient of performance observed for the NH₃‐NaSCN chiller is 0.12% higher than that for the NH₃‐LiNO₃ chiller at 0°C evaporator temperature. Contradictory to this, the average system coefficient of performance of the NH₃‐LiNO₃ absorption system has been found 5.51% higher than that of the NH₃‐NaSCN system at the same evaporator temperature. Moreover, the application of the nanofluid enhanced the performance of the NH₃‐NaSCN and NH₃‐LiNO₃ systems by 2.70% and 1.50%, respectively, for lower generator temperature and becomes almost the same at higher temperatures, which altogether recommends the flat‐plate collector–coupled NH₃‐LiNO₃ absorption system be integrated with a nanofluid.     

High-efficiency thermoelectrochemical conversion system based on H+-ion concentration cell stack

In fossil energy utilization processes, only about one-third of fuels is used effectively upon conversion, while the rest becomes waste heat. Therefore, making full use of waste heat is an effective way to save energy. Nowadays, the moderate-high temperature heat utilization systems continue to mature and develop. However, existing heat-to-electricity energy conversion technologies are not very efficient for utilization of low-grade waste heat. Herein, based on our previous finding in H⁺-ion concentration power generator, we design a cell stack structure in series to optimize and improve its thermal-to-electric performance with temperatures ranging from 50 °C to 170 °C. This experiment reveals that the thermal-to-electric conversion efficiency of 3-cell stack can reach up to 17.86%, which is more than twice as likely to a single-cell (8.39%). The electrochemical kinetic analysis and temperature distribution thermoanalysis results convince us that this tandem device is beneficial to the development for low-level heat recovery.