Energy and exergy performance assessment of a novel solar-based integrated system with hydrogen production

In this study, a new solar power assisted multigeneration system designed and thermodynamically analyzed. In this system, it is designed to perform heating, cooling, drying, hydrogen and power generation with a single energy input. The proposed study consists of seven sub-parts which are namely parabolic dish solar collector, Rankine cycle, organic Rankine cycle, PEM-electrolyzer, double effect absorption cooling, dryer and heat pump. The effects of varying reference temperature, solar irradiation, input and output pressure of high-pressure turbine and pinch point temperature heat recovery steam generator are investigated on the energetic and exergetic performance of integration system. Thermodynamic analysis result outputs show that the energy and exergy performance of overall study are computed as 48.19% and 43.57%, respectively. Moreover, the highest rate of irreversibility has the parabolic dish collector with 24,750 kW, while the lowest rate of irreversibility is calculated as 5745 kW in dryer. In addition, the main contribution of this study is that the solar-assisted multi-generation systems have good potential in terms of energy and exergy efficiency.     

Development and thermodynamic assessment of a novel solar and biomass energy based integrated plant for liquid hydrogen production

In this paper, a combined power plant based on the dish collector and biomass gasifier has been designed to produce liquefied hydrogen and beneficial outputs. The proposed solar and biomass energy based combined power system consists of seven different subplants, such as solar power process, biomass gasification plant, gas turbine cycle, hydrogen generation and liquefaction system, Kalina cycle, organic Rankine cycle, and single-effect absorption plant with ejector. The main useful outputs from the combined plant include power, liquid hydrogen, heating-cooling, and hot water. To evaluate the efficiency of integrated solar energy plant, energetic and exergetic effectiveness of both the whole plant and the sub-plants are performed. For this solar and biomass gasification based combined plant, the generation rates for useful outputs covering the total electricity, cooling, heating and hydrogen, and hot water are obtained as nearly 3.9 MW, 6584 kW, 4206 kW, and 0.087 kg/s in the base design situations. The energy and exergy performances of the whole system are calculated as 51.93% and 47.14%. Also, the functional exergy of the whole system is calculated as 9.18% for the base working parameters. In addition to calculating thermodynamic efficiencies, a parametric plant is conducted to examine the impacts of reference temperature, solar radiation intensity, gasifier temperature, combustion temperature, compression ratio of Brayton cycle, inlet temperature of separator 2, organic Rankine cycle turbine and pump input temperature, and gas turbine input temperature on the combined plant performance.     

Comparative energy,exergy and exergo-economic analysis of solar driven supercritical carbon dioxide power and hydrogen generation cycle

Parabolic dish solar collector system has capability to gain higher efficiency by converting solar radiations to thermal heat due to its higher concentration ratio. This paper examines the exergo-economic analysis, net work and hydrogen production rate by integrating the parabolic dish solar collector with two high temperature supercritical carbon dioxide (s-CO₂) recompression Brayton cycles. Pressurized water (H₂O) is used as a working fluid in the solar collector loop. The various input parameters (direct normal irradiance, ambient temperature, inlet temperature, turbine inlet temperature and minimum cycle temperature) are varied to analyze the effect on net power output, hydrogen production rate, integrated system energetic and exergetic efficiencies. The simulations has been carried out using engineering equation solver (EES). The outputs demonstrate that the net power output of the integrated reheat recompression s-CO₂ Brayton system is 3177 kW, whereas, without reheat integrated system has almost 1800 kW net work output. The overall energetic and exergetic efficiencies of former system is 30.37% and 32.7%, respectively and almost 11.6% higher than the later system. The hydrogen production rate of the solarized reheat and without reheat integrated systems is 0.0125 g/sec and 0.007 g/sec, accordingly and it increases with rise in direct normal irradiance and ambient temperature. The receiver has the highest exergy destruction rate (nearly 44%) among the system components. The levelized electricity cost (LEC) of 0.2831 $/kWh with payback period of 9.5 years has proved the economic feasibility of the system design. The increase in plant life from 10 to 32 years with 8% interest rate will decrease the LEC from (0.434-0.266) $/kWh. Recuperators have more potential for improvement and their cost rate of exergy is higher as compared to the other components.     

Parametric analysis of a solar energy based multigeneration plant with SOFC for hydrogen generation

Renewable energy-based hydrogen production plants can offer potential solutions to both ensuring sustainability in energy generation systems and designing environmentally friendly systems. In this combined work, a novel solar energy supported plant is proposed that can generate hydrogen, electricity, heating, cooling and hot water. With the suggested integrated plant, the potential of solar energy usage is increased for energy generation systems. The modeled integrated system generally consists of the solar power cycle, solid oxide fuel cell plant, gas turbine process, supercritical power plant, organic Rankine cycle, cooling cycle, hydrogen production and liquefaction plant, and hot water production sub-system. To conduct a comprehensive thermodynamic performance analysis of the suggested plant, the combined plant is modeled according to thermodynamic equilibrium equations. A performance assessment is also conducted to evaluate the impact of several plant indicators on performance characteristics of integrated system and its sub-parts. Hydrogen production rate in the suggested plant according to the performance analysis performed is realized as 0.0642 kg/s. While maximum exergy destruction rate is seen in the solar power plant with 8279 kW, the cooling plant has the lowest exergy destruction rate as 1098 kW. Also, the highest power generation is obtained from gas turbine cycle with 7053 kW. In addition, energetic and exergetic efficiencies of solar power based combined cycle are found as 56.48% and 54.06%, respectively.     

Performance assessment of an integrated PV/T and triple effect cooling system for hydrogen and cooling production

In this paper we study an integrated PV/T absorption system for cooling and hydrogen production based on U.A.E weather data. Effect of average solar radiation for different months, operating time of the electrolyzer, air inlet temperature and area of the PV module on power and rate of heat production, energy and exergy efficiencies, hydrogen production and energetic and exergetic COPs are studied. It is found that the overall energy and exergy efficiency varies greatly from month to month because of the variation of solar radiation and the time for which it is available. The highest energy and exergy efficiencies are obtained for the month of March and their value is 15.6% and 7.9%, respectively. However, the hydrogen production is maximum for the month of August and its value is 9.7 kg because in august, the solar radiation is high and is available for almost 13 h daily. The maximum energetic and exergetic COPs are calculated to be 2.28 and 2.145, respectively and they are obtained in the month of June when solar radiation is high for the specified cooling load of 15 kW.     

Thermodynamic performance assessment of ocean thermal energy conversion based hydrogen production and liquefaction process

In the proposed study, the thermodynamic performance assessment of ocean thermal energy conversion (OTEC) based hydrogen generation and liquefaction system are evaluated. In this context, the energetic and exergetic analyses of integrated system are conducted for multigeneration. This integrated process is consisted of the heat exchangers, turbine, condenser, pumps, solar collector system, hot storage tank, cold storage tank and proton exchange membrane (PEM) electrolyzer. In addition to that, the impacts of different design indicators and reference ambient parameters on the exergetic performance and exergy destruction rate of OTEC based hydrogen production system are analyzed. The energetic and exergetic efficiencies of integrated system are founded as 43.49% and 36.49%, respectively.     

Exergy analysis and parametric study of concentrating type solar collectors

The exergetic performance of concentrating type solar collector is evaluated and the parametric study is made using hourly solar radiation. The exergy output is optimized with respect to the inlet fluid temperature and the corresponding efficiencies are computed. Although most of the performance parameters, such as, the exergy output, exergetic and thermal efficiencies, stagnations temperature, inlet temperature, ambient temperature etc. increase as the solar intensity increases but the exergy output, exergetic and thermal efficiencies are found to be the increasing function of the mass flow rate for a given value of the solar intensity. The performance parameters, mentioned above, are found to be the increasing functions of the concentration ratio but the optimal inlet temperature and exergetic efficiency at high solar intensity are found to be the decreasing functions of the concentration ration. On the other hand, for low value of the solar intensity, the exergetic efficiency first increases and then decreases as the concentration ratio is increased. This is because of the reason that the radiation losses increase as the collection temperature and hence, the concentration ratio increases. Hence, for lower value of solar intensity, there is an optimal value of concentration ratio for a given mass flow rate at which the exergetic efficiency is optimal. Again it is also observed that the mass flow rate is a critical parameter for a concentrating type solar collector and should be chosen carefully.     

A new integrated renewable energy system for clean electricity and hydrogen fuel production

In this paper, a new renewable energy-based cogeneration system for hydrogen and electricity production is developed. Three different methods for hydrogen production are integrated with Rankine cycle for electricity production using solar energy as an energy source. In addition, a simple Rankine cycle is utilized for producing electricity. This integrated system consists of solar steam reforming cycle using molten salt as a heat carrier, solar steam reforming cycle using a volumetric receiver reactor, and electrolysis of water combined with the Rankine cycle. These cycles are simulated numerically using the Engineering Equation Solver (EES) based on the thermodynamic analyses. The overall energetic and exergetic efficiencies of the proposed system are determined, and the exergy destruction and entropy generation rates of all subcomponents are evaluated. A comprehensive parametric study for evaluating various critical parameters on the overall performance of the system is performed. The study results show that both energetic and exergetic efficiencies of the system reach 28.9% and 31.1%, respectively. The highest exergy destruction rates are found for the steam reforming furnace and the volumetric receiver reforming reactor (each with about 20%). Furthermore, the highest entropy generation rates are obtained for the steam reforming furnace and the volumetric receiver reforming reactor, with values of 174.1 kW/K and 169.3 kW/K, respectively. Additional parametric studies are undertaken to investigate how operating conditions affect the overall system performance. The results report that 60.25% and 56.14% appear to be the highest exergy and energy efficiencies at the best operating conditions.     

Development of a sustainable multi-generation system with re-compression sCO2 Brayton cycle for hydrogen generation

Current research aims to develop, design, and analyze a novel solar-assisted multi-purpose energy generation system for hydrogen production, electricity generation, refrigeration, and hot water preparation. The suggested system comprises a solar dish for supplying the necessary heat demand, a re-compression carbon dioxide-based Brayton cycle, a PEM electrolyzer for hydrogen generation, an ejector refrigeration system working with ammonia, and a hot water preparation system. The first law and exergy analyses are implemented to determine the performance of the multi-generation plant with various outputs. Besides, the exergo-environmental evaluation of the plant is conducted for the environmental impacts of the plant. Furthermore, parametric analyses are executed for investigating the system outputs, exergy destruction rate, and system efficiencies. According to the results, the rate of hydrogen generated by means of the multi-generation power plant is determined to be 0.062 g/s which corresponds to an hourly production of 0.223 kg. Besides, with the utilization of the supercritical closed Brayton cycle, a power generation rate of 74.86 kW is achieved. Furthermore, the irreversibility of the overall plant is estimated as 535.7 kW in which the primary contributor of this amount is the solar system with a destruction rate of 365.5 kW.     

A novel combined biomass and solar energy conversion-based multigeneration system with hydrogen and ammonia generation

In the present study, an innovative multigeneration plant for hydrogen and ammonia generation based on solar and biomass power sources is suggested. The proposed integrated system is designed with the integration of different subsystems that enable different useful products such as power and hydrogen to be obtained. Performance evaluation of designed plant is carried out using different techniques. The energetic and exergetic analyses are applied to investigate and model the integrated plant. The plant consists of the parabolic dish collector, biomass gasifier, PEM electrolyzer and hydrogen compressor unit, ammonia reactor and ammonia storage tank unit, Rankine cycle, ORC cycle, ejector cooling unit, dryer unit and hot water production unit. The biomass gasifier unit is operated to convert biomass to synthesis gaseous, and the concentrating solar power plant is utilized to harness the free solar power. In the proposed plant, the electricity is obtained by using the gas, Rankine and ORC turbines. Additionally, the plant generates compressed hydrogen, ammonia, cooling effect and hot water with a PEM electrolyzer and compressed plant, ammonia reactor, ejector process and clean-water heater, respectively. The plant total electrical energy output is calculated as 20,125 kW, while the plant energetic and exergetic effectiveness are 58.76% and 55.64%. Furthermore, the hydrogen and ammonia generation are found to be 0.0855 kg/s and 0.3336 kg/s.     

Thermodynamic analysis of a novel integrated system operating with gas turbine,s-CO2 and t-CO2 power systems for hydrogen production and storage

In this paper, a proposal for a novel integrated Brayton cycle, supercritical plant, trans critical plant and organic Rankine cycle-based power systems for multi-generation applications are presented and analyzed thermodynamically. The plant can generate power, heating-cooling for residential applications, and hydrogen simultaneously from a single energy source. Both energetic and exergetic analyses are conducted on this multi-generation plant and its subsystems in order to evaluate and compare them thermodynamically, in terms of their useful product capabilities. The energetic and exergetic effectiveness of the multi-generation system are computed as 44.69% and 42.03%, respectively. After that, a parametric study on each of the subsystems of the proposed combined system is given in order to provide a deeper understanding of the working of these subsystems under different states. Lastly, environmental impact assessments are provided to raise environmental concerns for several operating conditions. For the base working condition, the results illustrate that the proposed plant has 0.5961, 0.0442, 0.6265 and 1.678 of exergo-environmental impact factor, exergy sustainability index, exergy stability factor and sustainability index, respectively.     

Application of the concept of a renewable energy based-polygeneration system for sustainable thermal desalination process—A thermodynamics' perspective

Fossil fuel-powered thermal desalination processes have many harmful environmental effects including greenhouse gas (GHG) emissions and high-salinity brine discharge resulting in biological damages, in addition to energy losses because of the high temperatures of the streams leaving the desalination unit. In this study, a solar energy-based polygeneration approach has been proposed to address these issues. In the proposed system, concentrated solar parabolic trough technology is used to drive a multi-stage flash (MSF) desalination unit for production of fresh water. To recover the waste heat carried by the produced clean water, an organic Rankine cycle is integrated to produce electricity. In addition, to recover the waste heat carried by brine, an absorption cooling system is employed to provide cooling. In order to mitigate the effects of high-salinity brine, a pressure retarded osmosis (PRO) unit is installed, which reduces the salinity of the discharge and produces additional electrical energy. To ensure stable nighttime operations, a thermal energy storage (TES) system is also added to the system. A comprehensive thermodynamic analysis is conducted through mass, energy, and entropy, as well as exergy balances along with energetic and exergetic efficiencies to assess the overall performance of the system. The attained results show that at reference conditions with an overall parabolic trough collectors (PTCs) area of 100 000 m², the system produces 583.3 kW of electricity, approximately 4284 kW of cooling, and 1140 m³ of freshwater daily. Furthermore, the effects of changing operational conditions on the overall performance of the system are investigated. At design conditions, the overall energetic and exergetic efficiencies of the system are found to be 34.54% and 14.55%, respectively.     

Introducing an integrated SOFC,linear Fresnel solar field,Stirling engine and steam turbine combined cooling,heating and power process

A new integrated combined cooling, heating and power system which includes a solid oxide fuel cell, Stirling engine, steam turbine, linear Fresnel solar field and double effect absorption chiller is introduced and investigated from energy, exergy and thermodynamic viewpoints. In this process, produced electrical power by the fuel cell and steam turbines is 6971.8 kW. Stirling engine uses fuel cell waste heat and produces 656 kW power. In addition, absorption chiller is driven by waste heat of the Stirling engine and generates 2118.8 kW of cooling load. Linear Fresnel solar field produces 961.7 kW of thermal power as a heat exchanger. The results indicate that, electrical, energy and exergy efficiencies and total exergy destruction of the proposed system are 49.7%, 67.5%, 55.6% and 12560 kW, respectively. Finally, sensitivity analysis to investigate effect of the different parameters such as flow rate of inputs, outlet pressure of the components and temperature changes of the solar system on the hybrid system performance is also done.     

Performance assessment of parabolic dish and parabolic trough solar thermal power plant using nanofluids and molten salts

The present study has been conducted using nanofluids and molten salts for energy and exergy analyses of two types of solar collectors incorporated with the steam power plant. Parabolic dish (PD) and parabolic trough (PT) solar collectors are used to harness solar energy using four different solar absorption fluids. The absorption fluids used are aluminum oxide (Al₂O₃) and ferric oxide (Fe₂O₃)‐based nanofluids and LiCl‐RbCl and NaNO₃‐KNO₃ molten salts. Parametric study is carried out to observe the effects of solar irradiation and ambient temperature on the parameters such as outlet temperature of the solar collector, heat rate produced, net power produced, energy efficiency, and exergy efficiency of the solar thermal power plant. The results obtained show that the outlet temperature of PD solar collector is higher in comparison to PT solar collector under identical operating conditions. The outlet temperature of PD and PT solar collectors is noticed to increase from 480.9 to 689.7 K and 468.9 to 624.7 K, respectively, with an increase in solar irradiation from\ 400 to 1000 W/m². The overall exergy efficiency of PD‐driven and PT‐driven solar thermal power plant varies between 20.33 to 23.25% and 19.29 to 23.09%, respectively, with rise in ambient temperature from 275 to 320 K. It is observed that the nanofluids have higher energetic and exergetic efficiencies in comparison to molten salts for the both operating parameters. The overall performance of PD solar collector is observed to be higher upon using nanofluids as the solar absorbers. Copyright © 2015 John Wiley & Sons, Ltd.     

Exergetic analysis and performance evaluation of parabolic dish Stirling engine solar power plant

In this communication, a 50 MW_e design capacity parabolic dish Stirling engine solar power plant (PDSSPP) has been modeled for analysis, where 2000 units of parabolic dish Stirling engine each having capacity of 25 kW_e were considered to get desired capacity. An attempt has been made to carry out the energetic and exergetic analysis of different components of a solar power plant system using parabolic dish collector/receiver and Stirling engine. The energetic and exergetic losses as well as efficiencies for typical PDSSPP under the typical operating conditions have been evaluated. Variations of the efficiency of Stirling engine solar power plant at the part‐load condition are considered for year‐round performance evaluation. The developed model is examined at location Jodhpur (26.29°N, 73.03°E) in India. It is found that year‐round energetic efficiency varies from 15.57% to 27.09%, and exergetic efficiency varies from 16.83% to 29.18%. The unit cost of electric energy generation (kW_eh) is about 8.76 Indian rupees (INR), with 30 years life span of the plant and 10% interest rate on investment. Copyright © 2012 John Wiley & Sons, Ltd.     

Energetic and exergetic performance evaluation of a combined heat and power system with the micro gas turbine (MGTCHP)

This study deals with the energetic and exergetic performance assessment of a combined heat and power system with micro gas turbine (MGTCHP). Quantitative energy and exergy balance for each component and the whole MGTCHP system was considered, while energy and exergy consumption within the system were determined. The performance characteristics of this MGTCHP system were evaluated using energy and exergy analyses methods. The energetic and exergetic efficiencies of the MGTCHP system are calculated as 75.99% with 254.55 kW (as 99.15 kW—electrical and 155.40 kW—hot water_{@363.15 K}) and 35.80% with 123.61 kW (as 99.15 kW—electrical and 24.46 kW—hot water_{@363.15 K}), respectively. The maximum energy loss and exergy consumption occur at 44.03 kW in the stack gas and 129.61 kW in the combustion chamber, respectively. Copyright © 2007 John Wiley & Sons, Ltd.     

Energy,exergy, exergo-economic and exergo-environmental analyses of solar based hydrogen generation system

The present study focuses on the energy, exergy, exergo-economic, and exergo-environmental analyses of the solar-assisted multi-generation system. The multi-generation system consists of parabolic trough solar collector, regenerative power plant, double-effect absorption chiller system, proton exchange membrane electrolyzer, and multi-stage flash desalination plant. In the regenerative power plant, liquid petroleum gas (LPG) based boiler is implemented. The propane (C₃H₈) is used as the fuel in the boiler combustion chamber. The thermal and exergetic efficiencies of the power cycle are observed to be 41.08% and 23.26%, respectively. The electrical power of 1.384 MW is produced by the low-pressure turbine. Whereas, the thermal COP and exergetic COP are observed and maintained in the range of 1.28 to 0.22, respectively. The liquid hydrogen is produced by the PEM electrolyzer with the thermal and exergetic efficiencies of 60.83% and 64.65%, respectively. Furthermore, the exergo-economics and exergo-environmental analyses have also been conducted and all the parameters have been analyzed and concluded through graphs and tables.     

Exergetic optimization of flat plate solar collectors

In this paper, an exergetic optimization of flat plate solar collectors is developed to determine the optimal performance and design parameters of these solar to thermal energy conversion systems. A detailed energy and exergy analysis is carried out for evaluating the thermal and optical performance, exergy flows and losses as well as exergetic efficiency for a typical flat plate solar collector under given operating conditions. In this analysis, the following geometric and operating parameters are considered as variables: the absorber plate area, dimensions of solar collector, pipes' diameter, mass flow rate, fluid inlet, outlet temperature, the overall loss coefficient, etc. A simulation program is developed for the thermal and exergetic calculations. The results of this computational program are in good agreement with the experimental measurements noted in the previous literature. Finally, the exergetic optimization has been carried out under given design and operating conditions and the optimum values of the mass flow rate, the absorber plate area and the maximum exergy efficiency have been found. Thus, more accurate results and beneficial applications of the exergy method in the design of solar collectors have been obtained.     

Energetic and exergetic assessments of a novel solar power tower based multigeneration system with hydrogen production and liquefaction

In this article, a thermodynamic investigation of solar power tower assisted multigeneration system with hydrogen production and liquefaction is presented for more environmentally-benign multigenerational outputs. The proposed multigeneration system is consisted of mainly eight sub-systems, such as a solar power tower, a high temperature solid oxide steam electrolyzer, a steam Rankine cycle with two turbines, a hydrogen generation and liquefaction cycle, a quadruple effect absorption cooling process, a drying process, a membrane distillation unit and a domestic hot water tank to supply hydrogen, electrical power, heating, cooling, dry products, fresh and hot water generation for a community. The energetic and exergetic efficiencies for the performance of the present multigeneration system are found as 65.17% and 62.35%, respectively. Also, numerous operating conditions and parameters of the systems and their effects on the respective energy and exergy efficiencies are investigated, evaluated and discussed in this study. A parametric study is carried out to analyze the impact of various system design indicators on the sub-systems, exergy destruction rates and exergetic efficiencies and COPs. In addition, the impacts of varying the ambient temperature and solar radiation intensity on the irreversibility and exergetic performance for the present multigeneration system and its components are investigated and evaluated comparatively. According to the modeling results, the solar irradiation intensity is found to be the most influential parameter among other conditions and factors on system performance.     

Thermodynamic investigation of a concentrating solar collector based combined plant for poly-generation

The detailed thermodynamic evaluation for combined system assisted on solar energy for poly-generation are studied in this paper. This poly-generation cycle is operated by the concentrating solar radiation by using the parabolic dish solar collector series. The beneficial exits of this integrated plant are the electricity, fresh-water, hot-water, heating-cooling, and hydrogen while there are different heat energy recovery processes within the plant for development performance. A Rankine cycle with three turbines is employed for electricity production. In addition to that, the desalination aim is performed by utilizing the waste heat of electricity production cycle in a membrane distillation unit for fresh-water generation. Also, a PEM electrolyzer sub-component is utilized for hydrogen generation aim in the case of excess power generation. Finally, the hot-water production cycle is performed via the exiting working fluid from the very high-temperature generator of the cooling cycle. Moreover, based on the thermodynamic assessment outputs, the whole energy and exergy efficiencies of 58.43% and 54.18% are computed for the investigated solar plant, respectively.