盐梯度太阳池Kalina循环发电系统性能研究

Kalina循环发电系统是一种典型的低温热源发电系统,具有广阔的应用前景。盐梯度太阳池能够实现连续聚热和跨季节蓄热,可广泛应用于光热发电系统和光热供热系统。文章提出了一种以太阳池储热量为热源的盐梯度太阳池Kalina循环发电系统,并利用Aspen Hysys软件对该系统进行建模。而后根据模拟结果,研究了提热温度、运行压力和氨水浓度对该系统各项性能的影响。此外,还分析了典型工况下,该系统的热力性能。分析结果表明:随着提热温度逐渐升高,盐梯度太阳池Kalina循环发电系统的发电功率、热效率和效率均逐渐增加;随着运行压力逐渐升高,该系统的热效率和效率逐渐升高,并且存在最佳的运行压力1.75 MPa,使得该系统获得最大发电功率;随着氨水浓度逐渐增大,该系统的发电功率也会逐渐增大,但热效率和效率却逐渐降低;当氨水浓度为85%、运行压力为1.75 MPa、提热温度为90℃时,该系统的热效率和效率分别为7.93%,57.59%。     

Application of modified Kalina cycle in biomass chp plants

This paper presents alternatives to Kalina cycles typically used in place of the organic Rankine cycle in biomass power plants. Overviews of both Rankine and Kalina cycles are given alongside the possibilities of using biomass as a viable energy source and recommended guidelines from the engineering practice for selection and management of these cycles. Benefits of Kalina novel bottoming cycle (and the alternative cycles presented herewith) over the Rankine cycle are the higher thermodynamic cycle efficiency and lower capital expenditures combined with the possibility of using low-grade heat sources, such as biomass or waste heat from exhaust gases. Analysis of ammonia-water binary system under various operating conditions has been performed for all the proposed cycles based on the published references and it has been shown that the proposed alternative models prove to be simpler and to have similar or even greater thermodynamic efficiency compared with the Kalina novel bottoming cycle.     

Experimental investigation of a scroll expander for an organic Rankine cycle

This paper presents experimental investigation of the performance of an organic Rankine cycle (ORC) with scroll expander which utilizes renewable, process and waste heats. An ORC test bench is built with a scroll expander‐generator unit modified from a refrigeration compressor‐electrical drive unit. A detailed experimental investigation within the test bench is performed with the organic working fluid R134a. The results show that scroll expander can effectively be used in low‐power ORC to generate mechanical work or electricity from low‐temperature thermal sources (e.g. 80–200 °C, respectively). The experiments are performed under fixed intake conditions into the expander. The pressure ratio and the load connected to the expander‐generator unit were varied. It is found that an optimum pressure ratio and an optimum angular speed co‐exist. When operating optimally, the expander's isentropic efficiency is the highest. The optimum angular speed is around 171 rad/s which corresponds to a generated voltage of 18.6 V. The optimum pressure ratio is about 4. The isentropic efficiency at optimum operation is found in the range of 0.5 to 0.64, depending on the intake conditions. The volumetric efficiency overpasses 0.9 at optimum operation and degrades significantly if the load is increased over the optimum load. A regenerative ORC equipped with the studied expender‐generator unit that operates under 120 °C heat source and has an air cooled condenser generates 920 W net power with efficiencies of 8.5% energetically and 35% exergetically. Copyright © 2014 John Wiley & Sons, Ltd.     

Exergy analysis of a 1.2 MW waste heat power generation project

According to systematic features, analysis method based on exergy balance is established. Basic indicators in the system, the subsystem, and facilities are put forward in this paper. By using this method to analyze the generation system of megawatt‐scale in one chemical enterprise, it is found that the objective exergy efficiency of the system is 35.67%, and exergy loss of organic Rankine cycle (ORC) is the highest. The thermal efficiency of the total system is 9.61%. For the condenser, the thermal efficiency is 91.18%, and the exergy efficiency is only 23.44%. The objective exergy efficiency of the evaporator is 74.04%. The influence coefficient of exergy loss of condenser is higher than that of pump and expander, but input exergy of the condenser is lower than that of the expander. It is revealed that ORC subsystem is the part which needs to be focused on, and the condenser is the most important component of ORC subsystem which should be optimized firstly.     

Technological and economic analyses on power generation from the waste heat in a modified aluminum smeltingpot

Current pot ventilation system is designed in a conservative manner to prevent hazardous gases from escaping aluminum smelting pots. Reduction of pot draft is an initiative of both efficiently using waste heat in the exhaust gas and significantly reducing fan power of the ventilation system. This work presents a systematic analysis on the reduction of pot draft and the consequent problem, ie, fugitive emissions from the smelting pot. Numerical models with different length scales are developed to simulate the fluid flow and heat transfer in pots and potroom. The superstructure of a typical aluminum smelting pot is successfully modified to maintain the pot tightness in the reducing pot draft. The results show that the current pot draft could be reduced by 50% at least using the developed technology. The techno-economic analysis of power generation from the waste heat in aluminum smelting pot is made based on organic Rankine cycle (ORC), and the potential benefits of using the pot exhaust gas of both normal and 50% reduced flow rates are estimated. It is found that the levelized energy cost of the optimized ORC system using 50% reduced exhaust gas is 0.048 $/kWh with a system's lifespan of 10 years and 0.038 $/kWh with a lifespan of 15 years while the payback time of investment is 5.2 years.     

Parametric optimisation of the organic Rankine cycle for power generation from low-grade waste heat

This research work deals with the optimisation of controllable parameters of the organic Rankine cycle (ORC) run by waste heat. Performance measures have been evaluated for different waste heat temperatures, condenser temperatures, refrigerants and mass flow rate. The design of experiment was performed on the L9 orthogonal array of Taguchi's method. Three performance measures such as thermal efficiency, exergy destruction rate and the work output were used for the assessment and optimisation of the cycle. An optimum combination of parameters obtained by Taguchi's method is compared with analytical results. The comparison suggests that the variance of results is within the desired level of confidence. Individual effect of parameters on the performance of ORC is also estimated using analysis of variance. Turbine inlet temperature has large effects on efficiency and work output. Mass flow rate of the refrigerant has the largest effect on the exergy destruction rate.     

Thermodynamic analysis and optimization of a geothermal Kalina cycle system using Artificial Bee Colony algorithm

In this paper, thermodynamic analysis is carried out for a geothermal Kalina cycle employed in Husavic power plant. Afterwards, the optimum operating conditions in which the cycle is at its best performance are calculated. In order to reach the optimum thermal and exergy efficiencies of the cycle, Artificial Bee Colony (ABC) algorithm, a new powerful multi-objective and multi-modal optimization algorithm, is conducted. Regarding the mechanism of ABC algorithm, convergence speed and precision of solutions have been remarkably improved when compared to those of GA, PSO and DE algorithms. Such a relative improvement is indicated by a limit parameter and declining probability of premature convergence. In this research, exergy efficiency including chemical and physical exergies and thermal efficiency are chosen as the objective functions of ABC algorithm where optimum values of the efficiencies for the Kalina cycle are found to be 48.18 and 20.36%, respectively, while the empirical thermal efficiency of the cycle is about 14%. At the optimum thermal and exergy efficiencies, total exergy destruction rates are respectively 4.17 and 3.48 MW. Finally, effects of the separator inlet pressure, temperature, basic ammonia mass fraction and mass flow rate on the first and second law efficiencies are investigated.     

Exergy analysis of a 420 MW combined cycle power plant

Combined cycle power plants (CCPPs) have an important role in power generation. The objective of this paper is to evaluate irreversibility of each part of Neka CCPP using the exergy analysis. The results show that the combustion chamber, gas turbine, duct burner and heat recovery steam generator (HRSG) are the main sources of irreversibility representing more than 83% of the overall exergy losses. The results show that the greatest exergy loss in the gas turbine occurs in the combustion chamber due to its high irreversibility. As the second major exergy loss is in HRSG, the optimization of HRSG has an important role in reducing the exergy loss of total combined cycle. In this case, LP‐SH has the worst heat transfer process. The first law efficiency and the exergy efficiency of CCPP are calculated. Thermal and exergy efficiencies of Neka CCPP are 47 and 45.5% without duct burner, respectively. The results show that if the duct burner is added to HRSG, these efficiencies are reduced to 46 and 44%. Nevertheless, the results show that the CCPP output power increases by 7.38% when the duct burner is used. Copyright © 2007 John Wiley & Sons, Ltd.     

Cascaded waste‐heat recovery as a green technology for energy sustainability in power generation

In this work, the Cascaded waste‐heat recovery (WHR) is analyzed from the thermodynamic point of view. Typically, WHR is most effective with small gas turbines and old machines which have a relatively higher design mass flow per kW and higher exhaust temperatures than new designs. The working fluid used in the WHR technology is propane, which vaporizes and condenses at low temperatures. The temperature of the heat source, the outlet pressure of the two expanders, and the mass flow rate of the working fluid are assumed as working variables of the technology. The effect of these variables on the thermal efficiency and power output is evaluated. The obtained results are analyzed and discussed. The results of the calculation are also compared with similar published studies. The overall efficiency considering the gas turbine upstream ranges from about 35% up to 39%. The highest efficiency and power output of the WHR alone at 900 K heat source temperature, 800 kPa condenser pressure, and 100 kg/s mass‐flow rate are 30% and 18 MW, respectively, for two‐expander WHR, and 18% and 9 MW, respectively, for single expander WHR. Copyright © 2014 John Wiley & Sons, Ltd.     

Performance analysis of an industrial waste heat‐based trigeneration system

The thermodynamic performance of an industrial waste heat recovery‐based trigeneration system is studied through energy and exergy efficiency parameters. The effects of exhaust gas inlet temperature, process heat pressure, and ambient temperature on both energy and exergy efficiencies, and electrical to thermal energy ratio of the system are investigated. The energy efficiency increases while electrical to thermal energy ratio and exergy efficiency decrease with increasing exhaust gas inlet temperature. On the other hand, with the increase in process heat pressure, energy efficiency decreases but exergy efficiency and electrical to thermal energy ratio increase. The effect of ambient temperature is also observed due to the fact that with an increase in ambient temperature, energy and exergy efficiencies, and electrical to thermal energy ratio decrease slightly. These results clearly show that performance evaluation of trigeneration system based on energy analysis is not adequate and hence more meaningful evaluation must include exergy analysis. The present analysis contributes to further information on the role of exhaust gas inlet temperature, process heat pressure, ambient temperature influence on the performance of waste heat recovery‐based trigeneration from a thermodynamic point of view. Copyright © 2009 John Wiley & Sons, Ltd.     

Thermodynamic analysis and optimization of power cycles using a finite low‐temperature heat source

The analysis of a subcritical Rankine cycle with superheating, operating between a constant flowrate low‐temperature heat source and a fixed temperature sink, according to the principles of classical and finite size thermodynamics, is presented. The results show the existence of two optimum evaporation pressures: one minimizes the total thermal conductance of the two heat exchangers, whereas the other maximizes the net power output. A comparison of such results for five working fluids leads to the selection of R141b for a system generating 10% of a reference power which depends on the specified source and sink characteristics; for the conditions under consideration this reference power is 6861 kW. The results for this particular system show that the minimum total thermal conductance of the two heat exchangers is 1581 kW K^?1; the corresponding thermal efficiency is 12.6% and the total exergy losses are 13.8% of the source's exergy. Slightly more than 50% of the exergy destruction occurs in the vapor generator. Copyright © 2011 John Wiley & Sons, Ltd.     

Analysis of a combined power and refrigeration cycle by the exergy method

The exergy analysis method was applied in order to evaluate the new combined cycle proposed by Goswami [Solar thermal technology: present status and ideas for the future. Energy Sources 1998;20:137–45], using Hasan–Goswami–Vijayaraghavan parameters. This new combined cycle was proposed to produce both power and cooling simultaneously with only one heat source and using ammonia–water mixture as the working fluid. The simulation of the cycle was carried out in the process simulator ASPEN Plus. The Redlich–Kwong–Soave equation of state was used to calculate the thermodynamic properties. The cycle was simulated as a reversible as well as an irreversible process to clearly show the effect of the irreversibilities in each component of the cycle. At the irreversible process two cases were considered, changing the environmental temperature. However, in order to know the performance of the new cycle at different conditions of operation, the second irreversible case was analyzed varying the rectification temperatures, the isentropic efficiency of the turbine and the return temperature of the chilled water. Exergy effectiveness values of 53% and 51% were obtained for the irreversible cycles; with heat input requirements at temperatures of 125 and 150 °C. Solar collectors or waste heat are suggested as heat sources to operate the cycle.     

Optimal power generation from low concentration coal bed methane in Iran

Development of a model for optimal power generation from the thermal oxidation of a low concentration coal bed mine has been considered as the main objective of this investigation. The model has been applied to identify the optimal thermodynamic characteristics of the power generation system through using a mixture with 1.6% methane concentration in a recuperative lean-burn gas turbine and coupling a gas engine to the system for more power generation from the remaining coal bed methane. The implementation of the model based on the real site condition would lead to the generation of 6.97 MW electricity in Tabas coal mine of Iran.     

Study on waste heat recovery from exhaust smoke in cogeneration system using woody biomass fuels

In recent years, fossil fuels such as petroleum, coal, and natural gas have become limited resources. In addition, bad effects caused by excessive carbon dioxide (CO₂) emissions have now begun destroying our global environment seriously. Since current living and economical standards depend strongly on the fossil fuels, it is necessary to realize a new society that utilizes biomass as one of major sources of energy. In this background, we manufactured a practical Stirling engine using woody biomass fuels for the first time in Japan in 2005. Further we proposed a unique cogeneration system with the Stirling engine that uses woody biomass fuels such as sawdust, firewood, and wood pellets. In this cogeneration system, 43% of the input energy is wasted as heat loss from the exhaust smoke into the atmosphere. Therefore we tried to recover the waste heat by using a thermoelectric conversion module in this study. In this report, the results of basic performance test and demonstration experiment as a cogeneration system combined the waste heat recovery with a power generating system are reported. © 2011 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.20390     

Heat exchanger network design of an organic Rankine cycle integrated waste heat recovery system of a marine vessel using pinch point analysis

The coexistence of different kinds of waste heat sources on marine vessels with various temperature ranges increases the need for an optimal heat exchanger network (HEN) design for the heat collection process to reduce the unutilizable heat that needs to be discharged to overboard. The optimal HEN design has not been taken into consideration by using pinch point analysis in previous studies of marine organic Rankine cycle (ORC) systems that utilize from different kinds of waste heat sources. The objective of the study is to determine the optimal HEN design for an ORC integrated waste heat recovery system of a marine vessel by utilizing the pinch point analysis to improve the overall energy efficiency. Lubricating oil, high-temperature cooling water and scavenge air of the main engine, and the exhaust gas emitted from the boiler plant were identified as the major waste heat sources of a reference container ship. A heat collection stream, in which thermal oil is used as the heat transfer fluid that transfers the collected heat to an ORC system, was proposed. The pinch point analysis showed that the optimum waste heat recovery could be gained by separating the scavenge air cooler into three stages and the lubricating oil cooler into two stages. The results of the parametric study for the varying evaporator inlet pressure between 1000 and 3000 kPa showed that R1234ze(Z) yields the best performance among nine different organic working fluids with the thermal efficiency and exergy efficiency of 15.24% and 86.47% for the ORC system, respectively. For the proposed configuration, the unavailable waste heat that cannot be transferred to thermal oil was found as 23.71%, 16.56%, 13.17%, and 7.81% of the total waste heat produced by the heat sources, and also 8.24%, 9.80%, 11.55%, and 12.93% of the net power output produced by the main engine can be recovered for 25%, 50%, 76%, and 100% maximum continuous rating (MCR), respectively.     

Performance investigation of salt gradient cylindrical solar pond integrated and nonintegrated with evacuated tube solar collectors

In this study, the energetic and exergetic efficiencies of a salt gradient cylindrical solar pond (SGCSP) that integrated and nonintegrated evacuated tube solar collectors (ETSCs) are investigated to improve daily heat preservation performance of the heat storage zone (HSZ). The integrated system is consisted of an SGCSP and four ETSCs. The SGCSP has a surface area of 2 m², a depth of 1.65 m, salty water layers at different densities, and HSZ in which the cylindrical serpentine type heat exchanger (CSHE) is located. Thus, the daily effects of the heat storage performance of both the ETSCs and the SGCSP in the winter season was determined experimentally. The analysis of the data regarding the efficiencies of the system is investigated separately by means of experimental studies where the SGCSP is integrated and nonintegrated with the ETSCs. The number of ETSCs integrated with SGCSP is increased to 1, 2, 3, and 4, respectively, and each of the five different experimental systems is performed separately. The temperature distributions of the integrated system are measured by a data acquisition system on 11 different points per hour. The efficiencies are calculated using the data obtained from these studies. Consequently, the energetic and exergetic efficiencies of the SGCSP are obtained without collectors as 10.4% and 4.3% and with one collector as 12.83% and 6.15%, with two collectors 14.88% and 8.25%, with three collectors 16% and 9.35%, and finally with four collectors 16.94% and 10.3%, respectively. Furthermore, the theoretical efficiencies are found to be consistent with the experimental results obtained by increasing the collector numbers.     

Performance investigation of the heat pump and power generation integration system

A novel heat pump and power generation integration system (HPPGIS) using solar energy as a low temperature heat source was presented in this study. This system could be operated in both an organic Rankine cycle power generation (ORC‐PG) mode and a reverse Carnot cycle heat pump (RCC‐HP) mode. Compared with a single heat pump and power generation system, this system improved the utilization efficiency of solar energy, thus showing potential for the generation of economic benefits. Contrastive analyses of different working fluids using ORC‐PG and RCC‐HP systems were conducted first, leading to the selection of R142b and R245fa as optimal fluids. Then, an experimental investigation of the system was carried out under different conditions. A heat pump and ORC system model was proposed and validated by comparing experimental and simulated values. The experimental results indicated that the HPPGIS had good feasibility and stability in both modes. In the ORC‐PG mode, HPPGIS had a power output of 1.29 kW and a thermal efficiency of 4.71% when the water inlet temperature of the evaporator was 90.03°C. In the RCC‐HP mode, HPPGIS had a COP of 3.16 and a heat capacity of 33.24 kW when the water outlet temperature of the condenser was 106.23°C.     

Thermodynamic analysis of an LNG fuelled combined cycle power plant with waste heat recovery and utilization system

This paper has proposed an improved liquefied natural gas (LNG) fuelled combined cycle power plant with a waste heat recovery and utilization system. The proposed combined cycle, which provides power outputs and thermal energy, consists of the gas/steam combined cycle, the subsystem utilizing the latent heat of spent steam from the steam turbine to vaporize LNG, the subsystem that recovers both the sensible heat and the latent heat of water vapour in the exhaust gas from the heat recovery steam generator (HRSG) by installing a condensing heat exchanger, and the HRSG waste heat utilization subsystem. The conventional combined cycle and the proposed combined cycle are modelled, considering mass, energy and exergy balances for every component and both energy and exergy analyses are conducted. Parametric analyses are performed for the proposed combined cycle to evaluate the effects of several factors, such as the gas turbine inlet temperature (TIT), the condenser pressure, the pinch point temperature difference of the condensing heat exchanger and the fuel gas heating temperature on the performance of the proposed combined cycle through simulation calculations. The results show that the net electrical efficiency and the exergy efficiency of the proposed combined cycle can be increased by 1.6 and 2.84% than those of the conventional combined cycle, respectively. The heat recovery per kg of flue gas is equal to 86.27 kJ s^?1. One MW of electric power for operating sea water pumps can be saved. The net electrical efficiency and the heat recovery ratio increase as the condenser pressure decreases. The higher heat recovery from the HRSG exit flue gas is achieved at higher gas TIT and at lower pinch point temperature of the condensing heat exchanger. Copyright © 2006 John Wiley & Sons, Ltd.     

Performance assessment of steam Rankine cycle and sCO2 Brayton cycle for waste heat recovery in a cement plant: A comparative study for supercritical fluids

The main objective of this study is to investigate the feasibility of a waste heat recovery (WHR) closed Brayton cycle (BC) working with supercritical carbon dioxide (sCO₂). For this aim, an actual WHR steam Rankine cycle (RC) in a cement plant was evaluated thermodynamically. After, a sCO₂-BC was theoretically adapted to the actual WHR system for the performance assessment. Both systems were analyzed comparatively in terms of energy and exergy. According to the results, the sCO₂-BC showed higher performance than the actual steam RC with a net electricity generation of 9363 kW where it was calculated as 8275 kW for the actual cycle. In addition, the energy efficiencies were found to be 27.6% and 24.18% where the exergy efficiencies were calculated as 58.22% and 51.39% for sCO₂-BC and steam RC, respectively. In the following part of the study, the closed BC was examined for different supercritical working fluids, namely, CO₂, pentafluoroethane (R125), fluoromethane (R41), and sulfur hexafluoride (SF6). Parametrical analyses were conducted to determine the effects of the system parameters such as turbine inlet temperature, compressor inlet temperature, and pressure ratio on the cycle performance. The simulation results of the comparative study showed that, among the supercritical fluids, the CO₂ demonstrated a higher performance for the closed BC with an energy efficiency of 27.9% followed by R41, SF6, and R125. As a result, the utilization of sCO₂-BC for WHR can be sustainably adapted and extended for environmentally friendly energy generation.     

结合ORC和VCR的中温余热回收系统性能分析

为了利用丰富的中低温余热进行制冷,本文提出了一种结合ORC(有机朗肯循环)和VCR(蒸汽压缩制冷循环)的制冷系统,并对新系统进行了热力学分析和火用损失分析。此外,对比分析了Cyclohexane、D4、n-octane及R141b四种工质的热力学性能与ORC蒸发温度、制冷剂蒸发温度及透平效率等参数对系统制冷性能的影响。结果表明:以Cyclohexane为ORC工质时,系统总制冷COP(性能系数)最高为1.262;ORC蒸发温度对制冷工质与有机工质的质量流量比有显著的影响;制冷剂蒸发温度对系统的制冷COP有显著的影响;制冷剂冷凝温度对系统制冷COP的影响比ORC冷凝温度大;ORC蒸发器、VCR冷凝器以及ORC冷凝器的火用损失占系统总火用损失的57.28%。