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对丁腈橡胶(NBR)和丁腈酯橡胶(BNBR)热氧老化前后的物理机械性能和动态力学性能进行对比研究,并分析了分子结构对材料热氧老化和动态力学性能的影响。结果表明,NBR和BNBR的物理机械性能相当,热氧老化后BNBR的力学性能更优异,其原因可能是BNBR中酯基热稳定性好。NBR的腈基极性强于BNBR的酯基,侧基极性愈强,其相互作用力愈大,单键内旋转愈困难,链的柔顺性愈差,同时,BNBR的柔性酯基可起到增塑剂的作用,这2个因素导致BNBR在低温下的动态力学性能优于NBR。 相似文献
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高腈基含量无规羧基丁腈液体橡胶的合成 总被引:2,自引:0,他引:2
阐述了以Bd、AN和AA为聚合单体,过硫酸盐B为引发剂,硫醇C为分子质量调节剂的自由基乳液无规羧基丁腈液体橡胶的合成方法。研究了聚合配方及其工艺条件、后处理工艺对聚合物性能的影响。结果表明,过硫酸盐B0.2~0.3份,硫醇C5~6份,乳化剂A3~3.5份,聚合反应温度为(25±2)℃;洗涤剂为不低于90℃的自来水,用量为胶浆的1.5倍,干燥温度为110~130℃时,可以得到Mn为1400±200、结合丙烯腈质量分数为30%-35%、羧基值为0.5~10mmol/g的无规羧基丁腈液体橡胶。 相似文献
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通过对一种高温固化的单组分丁腈一酚醛型胶粘剂的研究,讨论了酚醛树脂用量、硫化压力对胶粘剂粘接性能的影响;考核了胶粘剂的综合性能。结果表明,丁腈橡胶和酚醛树脂的用量比例在一定范围内有最佳值;剥离强度随硫化压力的增大而提高,但当硫化压力大于40MPa时,再增大压力剥离强度增加趋势不显著。 相似文献
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A. M. Motawie M. M. Abdel‐Aziz A. M. Rabia A. M. Mazrous M. M. Badr E. M. Sadek 《应用聚合物科学杂志》2010,118(4):2056-2061
Blends of polypropylene (PP) and acrylonitrile butadiene rubber (NBR) were prepared with different weight compositions with a plasticorder at 180°C at a rotor speed of 60 rpm for 8 min. The physicomechanical properties and mass swell of the prepared blends were investigated with special reference to the effects of the blend ratio. The prepared epoxidized linseed oil (EL) (i.e., E0.5L, E1L, E1.5L, and E2L using 0.5, 1, 1.5, and 2 mol H2O2/mole of unsaturation in linseed oil) and maleic acid anhydride (MAH) were melt mixed in various contents (i.e., 1, 5, 10, and 15 wt %) with a PP/NBR blend with a weight ratio of 70/30 and used as compatibilizers. The effect of the compatibilizer contents on the physicomechanical properties and mass swell of the binary blend was investigated. With an increase in the compatibilizer content up to 10 wt %, the blend showed an improvement in the physicomechanical properties and reduced mass swell in comparison with the uncompatibilized one. The addition of a compatibilizer beyond 10 wt % did not improve the blend properties any further. The efficiency of the compatibilizers (10 wt %) was also evaluated by studies of phase morphology (scanning electron microscopy). © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
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Chrome‐tanned leather waste generated in huge amount from leather industry causing environmental problem; this leather waste was used as filler in acrylonitrile butadiene rubber before treatment and after treatment with ammonia solution and sodium formate. Different formulations of acrylonitrile butadiene rubber/leather waste (untreated–treated with ammonia solution—treated with sodium formate) composites are prepared. The formed composites exhibit a considerable improvement in some of their properties such as rheometric characteristics especially with composites loaded with treated leather waste. Tensile strength, modulus at 100% elongation, hardness, and Young's modulus were improved for composite loaded with treated leather. Crosslinking density in toluene was increased by the incorporation of leather wastes treated or untreated resulting in decreases in swelling equilibrium. Distinct increase in the ageing coefficient and the thermal stability for composites loaded with both treated and untreated leather. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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Blends based on ethylene–propylene–diene monomer rubber (EPDM) and acrylonitrile butadiene rubber (NBR) was prepared. Sulfur was used as the vulcanizing agent. The effects of blend ratio on the cure characteristics and mechanical properties, such as stress–strain behavior, tensile strength, elongation at break, hardness, rebound resilience, and abrasion resistance have been investigated. Tensile and tear strength showed synergism for the blend containing 30% of NBR, which has been explained in terms of morphology of the blends attested by scanning electron micrographs. A relatively cocontinuous morphology was observed for 70 : 30, EPDM/NBR blend system. The experimental results have been compared with the relevant theoretical models. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
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Chavakorn Samthong Nappaphan Kunanusont Chutimar Deetuam Tanchanok Wongkhan Thanapat Supannasud Anongnat Somwangthanaroj 《Polymer International》2019,68(12):2004-2016
We report here the morphology, thermal and tensile properties of poly(lactic acid) (PLA) blends composed of acrylonitrile butadiene rubber (NBR) with different acrylonitrile contents with/without dynamic vulcanization by dicumyl peroxide (DCP). The interfacial tension of PLA and NBR measured by contact angle measurement decreased as the acrylonitrile content of NBR decreased. Likewise, SEM images showed that the rubber particle size reduced with decreasing acrylonitrile content owing to the stronger interfacial adhesion between the PLA matrix and NBR domains. Incorporation of DCP at 1.0 phr for dynamic vulcanization led to higher crosslink density and, in turn, optimal tensile strength and tensile toughness as a result of the action of PLA‐NBR copolymer as a reactive compatibilizer. The dynamic vulcanization of the blends containing low acrylonitrile NBR gave the most improved tensile properties because the free radicals from DCP decomposition preferentially attacked the allylic hydrogen atoms or double bonds of the butadiene backbone. Accordingly, more NBR macroradicals were generated and probably more PLA‐NBR copolymers were produced. Moreover, further addition of DCP at 2.0 phr provided a large amount of crosslinked NBR gel, which significantly degraded the tensile properties. From the DSC results, dynamic vulcanization lowered the cold crystallization temperature, implying an improvement of cold crystallization. Finally, TGA results showed a higher degradation temperature as a function of DCP content, which suggested that thermal stability increased due to stronger interfacial adhesion as well as higher gel content. © 2019 Society of Chemical Industry 相似文献
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李愿鹏 《化学工业与工程技术》2012,33(3):50-54
乳聚丁苯橡胶生产中,后处理单元是决定产品质量的关键环节。针对后处理单元非计划停车频繁、运行周期短的状况,从工艺、设备、现场管理等方面进行了分析,找出影响后处理单元稳定运行的主要因素并进行了改进。 相似文献
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用改性沥青作相容剂,研究溴化丁基橡胶(BIIR)/丁腈橡胶(NBR)并用胶的微观结构和性能。结果表明:与未添加改性沥青CJ-100的BIIR/NBR并用胶相比,添加改性沥青CJ-100的BIIR/NBR并用胶的相容性较好,加工性能改善,气密性、耐屈挠和耐臭氧性能提高;添加5份改性沥青CJ-100的BIIR/NBR(并用比为80/20)并用胶物理性能、气密性、耐屈挠和耐臭氧性能较好,气密性接近全BIIR胶料,有望用于全钢载重子午线轮胎气密层。 相似文献
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In this research, water-swellable rubbers (WSRs) were prepared by the blending of acrylonitrile butadiene rubber (NBR) with epoxidized acrylonitrile butadiene rubber (ENBR), precipitated silica, vulcanizing agents, and polyacrylic acid sodium (PAAS) as superabsorbent polymers (SAPs). ENBR was prepared with a molybdenum trioxide catalyst and a tert-butyl hydroperoxide oxidant through a free-radical reaction under specific conditions and was used as a compatibilizer to improve the interfacial adhesion of the NBR matrix and hydrophilic components of the WSRs. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy were used to analyze the structure and properties of ENBR. The dispersion of silica and SAPs in the rubber matrix was investigated by transmission electron microscopy. The presence of ENBR enhanced the water-absorption properties of the WSRs. The NBR–ENBR composites exhibited a higher mechanical performance after water absorption than that without ENBR. Both the swelling ratio and the absorption rate increased with the ENBR content. When the weight ratio of NBR–ENBR was 25/75, an equilibrium swelling ratio of 172% (13% higher than that of the sample without ENBR) was obtained. Scanning electron microscopy analysis revealed that the addition of ENBR improved the compatibility between the SAPs and the NBR matrix. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47694. 相似文献
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Nadeem Iqbal Sadia Sagar Mohammad Bilal Khan Mohamed Ismail Bassyouni Zaffar M. Khan 《应用聚合物科学杂志》2013,130(6):4392-4400
Variant concentrations of ceramic fibers (CerFs) were incorporated into acrylonitrile butadiene rubber (NBR) to fabricate elastomeric ablative composites for ultrahigh temperature applications. The CerFs introduction into the polymer matrix has enhanced the ablation resistance up to 59% and successfully reduced the backface temperature of the polymer composite up to 110oC during the ultrahigh temperature ablation investigation. Thermal decomposition of the polymer composites was diminished up to 10% with increasing fiber concentration in the rubber matrix. Thermal conductivity was reduced equal to 63% while thermal impedance was enhanced up to 84% with the utmost fiber incorporation into the NBR matrix. The CerFs have adversely affected the mechanical properties of NBR matrix due to their brittle/inert nature and weak interface bonding with the host matrix. Scanning electron microscopy along with the energy dispersive x‐ray spectroscopy was used to examine the ablated specimens and the fiber dispersion within the host matrix. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 4392–4400, 2013 相似文献