Investigation on Phase Change Behavior of Paraffin Phase Change Material in a Spherical Capsule for Solar Thermal Storage Units

In this work, the melting and solidification behaviour of paraffin phase change material encapsulated in a stainless steel spherical container has been studied experimentally. A computational fluid dynamics analysis has also been performed for the encapsulated phase change material (PCM) during phase change process. In the melting process, the hot air, used as the heat transfer fluid enters the test section and flows over the spherical capsule resulting in the melting of phase change material. In the solidification process, the ambient air flows over the capsule and received heat from phase change material resulting in the solidification of phase change material. In the computational fluid dynamics, the constant wall boundary condition is employed for both melting (75°C) and solidification (36°C) processes since the internal conductive resistance offered by the PCM is much higher compared to the outer surface convective resistance. The time required for complete solidification and melting of the phase change material obtained from the computational fluid dynamics analysis are validated with the experimental results and a reasonable agreement is achieved. The reason for the deviation between the results are analyzed and reported.     

Experimental investigation on melting characteristics of ethanolamine–water binary mixture used as PCM

An experimental investigation of the melting process of ethanolamine–water binary mixture used as PCM (phase change material) in a rectangular enclosure with a heated vertical wall is reported in this work. The liquid–solid interfaces were captured and the instantaneous liquid fraction was presented. The effect of natural convection was studied in terms of the molten fraction and the shape of the solid–liquid interface. The correlations of molten fraction and time-averaged Nusselt number are obtained so that the time of the melting process can be predicted. The results indicate that natural convection enhances the rate of melting compared with the pure conduction model and that pure conduction mechanism only occurs at the initial stage of melting. Conduction–convection coupled model is necessary for predicting melting process exactly.     

A new model of phase change process for thermal energy storage

Thermal energy can be converted into mechanical energy through the melting process of a phase change material (PCM). A PCM mixed with an insoluble liquid has higher energy converting efficiency during the whole melting process, where the massive microvacuum formed during the freezing process is filled by the insoluble liquid, which increases utilization of the volume change. The traditional theoretical model of the phase change process is unable to sufficiently describe the mixed PCM; therefore, a new model aimed at analyzing the characteristics of the volumetric change rate, as well as the freezing and melting times of the mixed PCM, is theoretically constructed. In this paper, the effective heat capacity method is used, and the effects of porosity are considered when the PCM is in the solid state. Comparisons of this model with the traditional model are carried out using both simulations and experiments for different pressures and geometric structures. Our results indicate that the introduced model has better accuracy when describing the phase change process of the pure PCM mixed with an insoluble liquid.     

Phase change and heat transfer characteristics of a eutectic mixture of palmitic and stearic acids as PCM in a latent heat storage system

The phase change and heat transfer characteristics of a eutectic mixture of palmitic and stearic acids as phase change material (PCM) during the melting and solidification processes were determined experimentally in a vertical two concentric pipes energy storage system. This study deals with three important subjects. First is determination of the eutectic composition ratio of the palmitic acid (PA) and stearic acid (SA) binary system and measurement of its thermophysical properties by differential scanning calorimetry (DSC). Second is establishment of the phase transition characteristics of the mixture, such as the total melting and solidification temperatures and times, the heat transfer modes in the melted and solidified PCM and the effect of Reynolds and Stefan numbers as initial heat transfer fluid (HTF) conditions on the phase transition behaviors. Third is calculation of the heat transfer coefficients between the outside wall of the HTF pipe and the PCM, the heat recovery rates and heat fractions during the phase change processes of the mixture and also discussion of the effect of the inlet HTF parameters on these characteristics. The DSC results showed that the PA–SA binary system in the mixture ratio of 64.2:35.8 wt% forms a eutectic, which melts at 52.3 °C and has a latent heat of 181.7 J g⁻¹, and thus, these properties make it a suitable PCM for passive solar space heating and domestic water heating applications with respect to climate conditions. The experimental results also indicated that the eutectic mixture of PA–SA encapsulated in the annulus of concentric double pipes has good phase change and heat transfer characteristics during the melting and solidification processes, and it is an attractive candidate as a potential PCM for heat storage in latent heat thermal energy storage systems.     

Thermal performance of a eutectic mixture of lauric and stearic acids as PCM encapsulated in the annulus of two concentric pipes

Thermal performance characteristics of a eutectic mixture of lauric and stearic acids as phase change material (PCM) during the melting and solidification processes were determined experimentally in a vertical two concentric pipe-energy storage system. This study deals with three important subjects: The first one is to determine the eutectic composition ratio of the lauric acid (LA) and stearic acid (SA) binary system, and to measure its thermophysical properties by DSC. The second one is to establish the thermal characteristics of the mixture such as total melting and solidification times, the heat transfer modes in melted and solidified PCM, and the effect of Reynolds and Stefan numbers as inlet heat transfer fluid (HTF) conditions on the phase transition behaviors. The final one includes the calculations of the heat transfer coefficients between the outside wall of the HTF pipe and the PCM, and heat fractions during the melting and solidification processes of the mixture, and also the discussion of the effect of inlet HTF parameters on these characteristics. The LA–SA binary system in the mixture ratio of 75.5:24.5 wt % forms a eutectic, which melts at 37°C and has a latent heat of 182.7 J g⁻¹, and, thus, these properties make it an attractive phase change material used for passive solar space heating applications such as building and greenhouse heating with respect to the climate conditions. The experimental results indicated that the mixture encapsulated in the annulus of two concentric pipes has good thermal and heat transfer characteristics during the melting and solidification processes, and it has potential for heat storage in passive solar space heating systems.     

相变过程体积变化率的实验研究

建立了一套实验装置研究相变过程中的体积变化规律及其影响因素.以正十六烷为相变材料,在不同的初始温度和边界温度下,对凝同过程和熔解过程的体积变化率进行测量分析.研究表明:在相变初始阶段,体积变化速率较大.体积变化速率的大小与相变速率的大小有关,所有影响相变速率的因素将影响体积变化速率.在压力的作用下,熔解过程的总体积变化率小于凝固过程的总体积变化率.对同体积的液态正十六烷,在相同的外界压力下,较小的体积膨胀率可获得较大的输出功率.     

Enhancement of PCM melting in enclosures with horizontally-finned internal surfaces

A numerical model for simulating the melting of a phase change material (PCM) housed within an internally-finned metal enclosure is developed. A finite volume approach, utilizing the temperature-transforming model for phase change, is used to predict the conjugate heat transfer in the cavity walls and fins, as well as within the molten PCM. The influence of the number of fins, the fin length and thickness, and the hot wall temperature on the melting process is reported. With horizontal fins, rapid melting occurs during the early stages of the phase change, followed by a second, slow melting regime. Analytical correlations are developed that can be used to quickly estimate melting rates during both melting regimes, and it is shown that the predictions of the correlations are in good agreement with those of the detailed model.     

Latent heat thermal energy storage using cylindrical capsule: Numerical and experimental investigations

This paper is aimed at analyzing the melting behavior of paraffin wax as a phase change material (PCM) encapsulated in a cylindrical capsule, used in a latent heat thermal energy storage system with a solar water heating collector. The heat for melting of PCM in the capsule is provided by hot water surrounding it. Since it is observed experimentally that the phase change occurs in a range of temperature, the present analysis considers this range instead of constant phase change temperature and the deviation between the results of these two is presented. The numerical analysis has been carried out by using enthalpy method and the results are verified with the experimental data. The experiments have been done by visualization technique without disturbing the actual process of melting. Three distinct stages of melting process have been identified as revealed by visualization studies. Results indicate that the melting process is chiefly governed by the magnitude of the Stefan number, Ste, phase change temperature range and the capsule radius. The analysis shows that the agreement between analytical and experimental results is significantly improved when the results are obtained considering phase change temperature range and the natural convection in the liquid phase instead of considering the process to be conduction dominated only.     

Effect of internal void placement on the heat transfer performance – Encapsulated phase change material for energy storage

The effect of an internal air void on the heat transfer phenomenon within encapsulated phase change material (EPCM) is examined. Heat transfer simulations are conducted on a two dimensional cylindrical capsule using sodium nitrate as the high temperature phase change material (PCM). The effects of thermal expansion of the PCM and the buoyancy driven convection within the fluid media are considered in the present thermal analysis. The melting time of three different initial locations of an internal 20% air void within the EPCM capsule are compared. Latent heat is stored within an EPCM capsule, in addition to sensible heat storage. In general, the solid/liquid interface propagates radially inward during the melting process. The shape of the solid liquid interface as well as the rate at which it moves is affected by the location of the internal air void. The case of an initial void located at the center of the EPCM capsule has the highest heat transfer rate and thus fastest melting time. An EPCM capsule with a void located at the top has the longest melting time. Since the inclusion of a void space is necessary to accommodate the thermal expansion of a PCM upon melting, understanding its effect on the heat transfer within an EPCM capsule is necessary.     

Thermal performance analysis of a flat slab phase change thermal storage unit with liquid-based heat transfer fluid for cooling applications

This paper presents the results of a thermal performance analysis of a phase change thermal storage unit. The unit consists of several parallel flat slabs of phase change material (PCM) with a liquid heat transfer fluid (HTF) flowing along the passages between the slabs. A validated numerical model developed previously to solve the phase change problem in flat slabs was used. An insight is gained into the melting process by examining the temperatures of the HTF nodes, wall nodes and PCM nodes and the heat transfer rates at four phases during melting. The duration of the melting process is defined based on the level of melting completion. The effects of several parameters on the HTF outlet temperature, heat transfer rate and melting time are evaluated through a parametric study to evaluate the effects of the HTF mass flow rate, HTF inlet temperature, gap between slabs, slab dimensions, PCM initial temperature and thermal conductivity of the container on the thermal performance. The results are used to design a phase change thermal storage unit for a refrigerated truck.     

Performance enhancement of high temperature latent heat thermal storage systems using heat pipes with and without fins for concentrating solar thermal power plants

A key drawback of using latent heat thermal storage systems for concentrating solar thermal power plants is the low thermal conductivity of the phase change material during the melting and solidification processes. This paper investigates an approach for reducing the thermal resistance by utilising axially finned heat pipes. A numerical model simulating the phase change material melting and solidification processes has been developed. This paper also includes the models of the evaporation and condensation of the heat pipe working fluid. The results show that by adding four axial fins and including the evaporation and condensation, the overall thermal performance of the storage system is enhanced significantly compared to having bare heat pipes. After 3 h a total of 106% increase in energy storage is obtained during the charging process. The results also show that the combined effect of incorporating the evaporation/condensation process and adding the fins leads to a threefold increase in the heat storage during the first 3 h. During the discharge process, there was a 79% increase in energy discharged and also the combined effect of incorporating the evaporation/condensation as well as adding the fins results in an almost four fold increase in the heat extracted within the first 3 h. A parametric analysis has also been carried out to analyse the effect of the finned heat pipe parameters after incorporating evaporation and condensation of the heat pipe working fluid.     

Melting of nano-enhanced phase change material in a cavity heated sinusoidal from below: Numerical study using lattice Boltzmann method

Natural convection and melting of ice as a phase change material dispersed with copper nanoparticles are numerically investigated. Square cavity filled with nano-mixture (Cu−ice) subjected to sinusoidal temperature distributions from the hot bottom boundary. The phase change process and heat transfer are formulated and solved using the enthalpy-based lattice Boltzmann method. Home-built numerical code is developed and validated. The effect of Rayleigh number (Ra = 10⁴, 10⁵, and 10⁶) and copper nanoparticle concentration (ϕ = 0%, 1%, 3%, and 5%) on the flow characteristics and thermal performance of NePCM during the melting process is examined. According to the numerical results, the melting and charging times decrease by increasing the Rayleigh number. It is also observed that increasing the volume fraction of nanoparticle decrease melting time by up to 10%.     

Modeling Yin—Yang Balance in Tai—Chi Diagram with a Melting—Freezing Rotating Device

InttoductionTai-chi diW is a symboI of wisdom in theChinese history, and is a very influential diagram in theWhole Chinese civilization. However, there is littlescientific research wOrk available in the literatUre thatprovides a physical model that can describe and interprethe yin-yang balance in the tai-chi diagram.The Presen stUdy is in an atteInPt to interpret theyin-yang balance in the tai--chi dign with a stwleNcal 1angUage through the Physical Processes ofmelhng and freezing in a r…     

铝/石蜡复合相变材料蓄热性能的数值模拟

相变储能材料由于其具有周期性储存和释放能量的特点,在电池热管理、太阳能发电等领域应用广泛,然而由于导热系数低的原因限制了其进一步的应用.高导热率泡沫材料的添加为解决这一不足提供了一种有效的方法.采用三周期性极小曲面(triply periodic minimal surface,TPMS)生成泡沫铝骨架,基于孔隙尺度数...     

Analysis of contact melting of phase change materials inside a heated rectangular capsule

Close-contact melting processes of phase change material (PCM) inside a horizontal rectangular capsule are studied. The PCM is heated by the capsule at constant heat flux at the top and isothermally at the bottom, and the sides are adiabatic. The theoretical formulas of the dimensionless melting rate and the thickness of the liquid layer during the heat transfer process are obtained by analysing, which is convenient for engineering predictions. Finally, the influences on the melting process are discussed, and conclusions are drawn.     

Numerical Study of Convection Melting Inside Ice Storage Systems by the Lattice Boltzmann Model

Abstract

The internal melt ice-on-coil tank with horizontal pipes is widely used in ice storage systems. The tank’s discharge process is greatly affected by the natural convection process that is caused by melting of the phase change material outside the pipes. To achieve an optimal arrangement of the pipes, a double-population lattice Boltzmann model was developed to simulate the transient solid-liquid phase change behavior in a section of an internal-melt ice-on-coil thermal storage tank with nine aligned built-in horizontal pipes. The evolutions in the phase change interface and melting rate was illustrated with different pipe shapes and pipe connections. Based on the melting rate, the whole melting process was divided into three stages: sharp decrease stage, continuous decrease stage, and snail-melting stage. The numerical results showed that a high melting rate was obtained by preferentially assigning the high-temperature pipes to the upper part of the tank, while a stable melting rate could be obtained when high-temperature pipes were preferentially assigned to the bottom part of the tank.     

TIM–PCM external wall system for solar space heating and daylighting

An external wall system for solar space heating and daylighting composed of transparent insulation material (TIM) and translucent phase change material (PCM) is presented. This system enables selective optical transmittance of solar radiation. Visible light is mainly transmitted and invisible radiation is mainly absorbed and converted to heat, causing in particular phase change. The storage medium is also the absorber. The concept of the system is presented in detail together with the investigations carried out, including a brief outline of modeling, optical experiments on PCM samples and long-term experiments on a prototype wall as well as numerical simulations. The results indicate a promising thermal–optical behavior of the system. For instance in a Swiss lowland climate (Zurich-airport) a mean energy flux of 13 W m⁻² (system efficiency 0.27) was calculated through a south facing TIM–PCM wall into the building during the month with the lowest irradiation (December). The parameters of the prototype wall with a mean melting temperature of the PCM of 26.5°C were assumed. When considering the percentage of time in which the building does not lose energy through the south facing TIM–PCM wall, a maximum can be reached with a mean melting temperature of approximately 20 to 21°C. In this case energy losses through the façade occur only during 1% of the time. With regard to the practical application of the system in buildings, aspects of reliability and durability have to be further investigated.     

Does nanoparticles dispersed in a phase change material improve melting characteristics?

Nanoparticles dispersed in a phase change material alter the thermo-physical properties of the base material, such as thermal conductivity, viscosity, and specific heat capacity. These properties combined with the configuration of the cavity, and the location of the heat source, influence the melting characteristics of the phase change material. In this paper, an assessment of the influence of the nanoparticles in the base material subjected to a heat generating source located in the center of an insulated square cavity, which is a common configuration in thermal capacitors for temporal heat storage is investigated. The interplay between heat conduction enhanced due to an increase in thermal conduction and buoyancy driven heat convection damped by the increase in viscosity of nanoparticles dispersed in the phase change materials is studied with the calculated streamlines and isotherms. We observed three regimes during the melting process, first at an early time duration dominated by heat conduction, later by buoyancy driven convection till the melting front levels with the center of the cavity, and lastly once again heat conduction in the bottom portion of the cavity. During the first two regimes, addition of nanoparticles have no significant performance gain on the heat storage cavity, quantified by maximum temperature of the heat source and average Nusselt number at the faces of the heat source. In the late regime, nanoparticles provide a slight performance gain and this is attributed to the increase in the specific heat of the melt due to the nanoparticles.     

Thermal performance of a water-phase change material solar collector

A new type of solar collector was developed and its short term thermal performance was investigated. The solar collector, which exhibited a net solar aperture area of 1.44 m², consisted of two adjoining sections one filled with water and the other with a phase change material with a melting and freezing range of about 45–50°C, i.e. paraffin wax in this study. The phase change material functioned both as an energy storage material for the stabilisation, theoretically, of the water temperature and as an insulation material due to its low thermal conductivity value. The results of the study indicated that the water temperature exceeded 55°C during a typical day of high solar radiation and it was kept over 30°C during the whole night. Covering the collector surface with an insulation blanket at a time when the water temperature was at its maximum improved the energy conservation of the water significantly. The instantaneous thermal efficiency values were between about 22% and 80%. The present solar collector was much advantageous over the traditional solar hot water collectors in Turkey in terms of total system weight and the cost in particular.     

Thermal Performance of a Phase Change Material‐Based Latent Heat Thermal Storage Unit

An experimental analysis is presented to establish the thermal performance of a latent heat thermal storage (LHTS) unit. Paraffin is used as the phase change material (PCM) on the shell side of the shell and tube‐type LHTS unit while water is used as the heat transfer fluid (HTF) flowing through the inner tube. The fluid inlet temperature and the mass flow rate of HTF are varied and the temperature distribution of paraffin in the shell side is measured along the radial and axial direction during melting and solidification process. The total melting time is established for different mass flow rates and fluid inlet temperature of HTF. The motion of the solid–liquid interface of the PCM with time along axial and radial direction of the test unit is critically evaluated. The experimental results indicate that the melting front moves from top to bottom along the axial direction while the solidification front moves only in the radial direction. The total melting time of PCM increases as the mass flow rate and inlet temperature of HTF decreases. A correlation is proposed for the dimensionless melting time in terms of Reynolds number and Stefan number of HTF. © 2013 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21120