Ink‐jet‐printable phosphorescent organic light‐emitting‐diode devices

Abstract— A novel method for the fabrication of ink‐jet‐printed organic light‐emitting‐diode devices is discussed. Unlike previously reported solution‐processed OLED devices, the emissive layer of OLED devices reported here does not contain polymeric materials. The emission of the ink‐jet‐printed P²OLED (IJ‐P²OLED) device is demonstrated for the first time. It shows good color and uniform emission although it uses small‐molecule solution. Ink‐jet‐printed green P²OLED devices possess a high luminous efficiency of 22 cd/A at 2000 cd/m² and is based on phosphorescent emission. The latest solution‐processed phosphorescent OLED performance by spin‐coating is disclosed. The red P²OLED exhibits a projected LT50 of >53,000 hours with a luminous efficiency of 9 cd/A at 500 cd/m². The green P²OLED shows a projected LT50 of >52,000 hours with a luminous efficiency of 35 cd/A at 1000 cd/m². Also discussed is a newly developed sky‐blue P²OLED with a projected LT50 of >3000 hour and a luminous efficiency of 18 cd/A at 500 cd/m².     

Advanced compensation technologies for large‐sized UHD OLED TVs

In this paper, we present novel organic light‐emitting diode (OLED) display panel compensation technologies for large‐sized ultra‐high‐definition OLED TVs considering variations of threshold voltage, mobility, channel size, OLED efficiency, and OLED uniformity. Using these technologies, we have successfully launched 55‐, 65‐ and 77‐in. ultra‐high‐definition OLED TVs.     

Fluorescent‐based tandem white OLEDs designed for display and solid‐state‐lighting applications

Abstract— Highly efficient tandem white OLEDs based on fluorescent materials were developed for display and solid‐state‐lighting (SSL) applications. In both cases, the white OLED must have high power efficiency and long lifetime, but there are a number of attributes unique to each application that also must be considered. Tandem OLED technology has been demonstrated as an effective approach to increase luminance, extend OLED lifetime, and allow for use of different emitters in the individual stacks for tuning the emission spectrum to achieve desired performance. Here, examples of bottom‐emission tandem white OLEDs based on small‐molecule fluorescent emitters designed for displays and for SSL applications are reported. A two‐stack tandem white OLED designed for display applications achieved 36.5‐cd/A luminance efficiency, 8500K color temperature, and lifetime estimated to exceed 50,000 hours at 1000 cd/m². This performance is expected to meet the specifications for large AMOLED displays. A two‐stack tandem white OLED designed for SSL applications achieved 20‐lm/W power efficiency, 38‐cd/A luminance efficiency, 3500K color temperature, and lifetime estimated to exceed 140,000 hours at 1000 cd/m². With the use of proven light‐extraction techniques, it is estimated that this tandem device will exceed 40 lm/W with more than 500,000‐hour lifetime, performance that should be sufficient for first‐generation lighting products.     

Development of a phosphorescent white OLED with extremely high power efficiency and long lifetime

Abstract— A white OLED device with extremely high power efficiency and long lifetime was developed, in which blue, yellow‐green, and red phosphorescent emitters were used. The performances achieved were 64 lm/W and 10,000 hours of lifetime at an initial luminance of 1000 cd/m² by using a light outcoupling technique. The device also exhibited the good durability important for practical usage. New technologies, such as blue phosphorescent materials and a sophisticated organic layer structure, were applied to the device. Hopefully, these technologies will open the door to the practical use of OLEDs as light sources.     

Printable phosphorescent organic light‐emitting devices

Abstract— A new approach to full‐color printable phosphorescent organic light‐emitting devices (P²OLEDs) is reported. Unlike conventional solution‐processed OLEDs that contain conjugated polymers in the emissive layer, the P²OLED's emissive layer consists of small‐molecule materials. A red P²OLED that exhibits a luminous efficiency of 11.6 cd/A and a projected lifetime of 100,000 hours from an initial luminance of 500 cd/m², a green P²OLED with a luminous efficiency of 34 cd/A and a projected lifetime of 63,000 hours from an initial luminance of 1000 cd/m², a light‐blue P²OLED with a luminous efficiency of 19 cd/A and a projected lifetime 6000 hours from an initial luminance of 500 cd/m², and a blue P²OLED with a luminous efficiency of 6.2 cd/A and a projected lifetime of 1000 hours from an initial luminance of 500 cd/m² is presented.     

The effect of transmittance and luminous efficiency with the application of cathode mesh mask in transparent organic light‐emitting devices

With the development of organic light‐emitting devices (OLEDs), the transparent OLED is also restricted by its efficiency and stability. Thus, in order to improve the transmittance and luminous efficiency of transparent OLED, the cathode mesh mask combined with Al:Ag alloy is adopted to prepare the cathode of transparent OLED, which would enhanced the luminance, efficiency, and transmittance of the device. With the same driving voltage, the device has the highest brightness, when the cathode thickness is 85 nm. At the voltage of 13 and 14 V, the luminance, for bottom‐emission and top‐emission, is 9501 cd/m² and 1840 cd/m², respectively. The entire transmittance of the device has achieved about 78% at a 480 nm wavelength.     

Red‐phosphorescent OLEDs employing bis(8‐quinolinolato)phenolato‐aluminum(III) complexes as emission‐layer hosts

Abstract— We have used bis(8‐quinolinolato)phenolato‐aluminum complexes as emission‐layer hosts in red‐phosphorescent OLED devices. This enabled high‐efficiency long‐lived OLED devices with a simple device structure that does not require a hole‐blocking layer. Devices with a red‐phosphorescent dopant introduced into a noble bis(8‐quinolinolato)phenolato‐aluminum complex exhibited a high efficiency of 12 cd/A at CIE color coordinates (0.65, 035) and a long operating lifetime of 30,000 hours or more at an initial luminance of 700 cd/m². Moreover, triplet‐triplet annihilation was reduced in the devices because of the wide emission zone enabled by the complex and the short phosphorescent lifetime of the red‐phosphorescent dopant. We have successfully incorporated these red‐phosphorescent devices into commercial OLED displays.     

Flexible active‐matrix OLED displays: Challenges and progress

Abstract— Organic light‐emitting‐device (OLED) devices are very promising candidates for flexible‐display applications because of their organic thin‐film configuration and excellent optical and video performance. Recent progress of flexible‐OLED technologies for high‐performance full‐color active‐matrix OLED (AMOLED) displays will be presented and future challenges will be discussed. Specific focus is placed on technology components, including high‐efficiency phosphorescent OLED technology, substrates and backplanes for flexible displays, transparent compound cathode technology, conformal packaging, and the flexibility testing of these devices. Finally, the latest prototype in collaboration with LG. Phillips LCD, a flexible 4‐in. QVGA full‐color AMOLED built on amorphous‐silicon backplane, will be described.     

Development of 8‐in. oxide‐TFT‐driven flexible AMOLED display using high‐performance red phosphorescent OLED

An 8‐in. flexible active‐matrix organic light‐emitting diode (AMOLED) display driven by oxide thin‐film transistors (TFTs) has been developed. In‐Ga‐Zn‐O (IGZO)‐TFTs used as driving devices were fabricated directly on a plastic film at a low temperature below 200 °C. To form a SiO_x layer for use as the gate insulator of the TFTs, direct current pulse sputtering was used for the deposition at a low temperature. The fabricated TFT shows a good transfer characteristic and enough carrier mobility to drive OLED displays with Video Graphic Array pixels. A solution‐processable photo‐sensitive polymer was also used as a passivation layer of the TFTs. Furthermore, a high‐performance phosphorescent OLED was developed as a red‐light‐emitting device. Both lower power consumption and longer lifetime were achieved in the OLED, which used an efficient energy transfer from the host material to the guest material in the emission layer. By assembling these technologies, a flexible AMOLED display was fabricated on the plastic film. We obtained a clear and uniform moving color image on the display.     

Development of a color‐tunable polychromatic organic‐light‐emitting‐diode device for roll‐to‐roll manufacturing

A flexible vertically stacked flexible polychromatic color‐tunable OLED has been developed by means of low resistive intermediate electrode technology. The polychromatic OLED has a capability to show 16 million colors with 105% National Television Committee Standard (NTSC) color reproduction. The device can produce arbitrary shape with arbitrary colors, suitable for artistic expressions, just as many as those used in information displays. Independently controlled red, green, and blue light‐emitting layers are stacked vertically. With conventional indium tin oxide technology, because of the temperature restriction, it was quite difficult to achieve low resistance on plastic substrate. The reported numbers were all more than 80 Ω/□. According to the surface mobility control using Fick's law analysis, low sheet resistance 7.34 Ω/□ on plastic film was developed. At first, flexible 7.17 cm² transparent OLED was fabricated for the performance confirmation of transparent electrode. And then polychromatic color‐tunable OLED with the same size were successfully fabricated on plastic. With optical length optimization for each color stack of polychromatic OLED, more than 100% color reproduction in National Television Committee Standard was achieved by stack design. The polychromatic device can be used for colored illumination, as well as for organic‐light‐emitting display pixels for three times emission than conventional pixel design. The device is fabricated on plastic substrate so that the polychromatic organic‐light‐emitting‐diode device is manufacturable with roll‐to‐roll production line.     

Enhancement of emission efficiency in white OLED device by highly efficient narrow spectrum red‐emission material

Newly developed red‐emission material with a narrow spectrum enhanced the current efficiency of a red OLED 1.3 times greater than a conventional material while maintaining chromaticity of red. This material also increased the power efficiency of a white OLED 1.2 times greater than the conventional material without impairing color rendering.     

Flexible high‐resolution full‐color top‐emitting active‐matrix organic light‐emitting diode display

We developed a high‐performance 3.4‐in. flexible active‐matrix organic light‐emitting diode (AMOLED) display with remarkably high resolution using an oxide semiconductor in a backplane, by applying our transfer technology that utilizes metal separation layers. Using this panel, we also fabricated a prototype of a side‐roll display for mobile uses. In these AMOLED displays, a white OLED combined with a color filter was used in order to achieve remarkably high resolution. For the white OLED, a tandem structure in which a phosphorescent emission unit and a fluorescent emission unit are serially connected with an intermediate layer sandwiched between the emission units was employed. Furthermore, revolutionary technologies that enable a reduction in power consumption in both the phosphorescent and fluorescent emission units were introduced to the white tandem OLED.     

Repeatedly foldable AMOLED display

In this study, a 5.9‐inch foldable active‐matrix organic light emitting diode (AMOLED) display was developed. A folding test was performed repeatedly. The display survived the folding test (100,000 folds) with a curvature radius of 2 mm. To protect an organic light emitting diode (OLED) against moisture, inorganic passivation layers are provided on the upper and lower sides of the flexible display. Using our transfer technology, high density passivation layers can be obtained. The measured water vapor transmission rate of the layer is 7 × 10^?6 g/m²?day or less, which improves OLED reliability. With these techniques, we have developed a book‐type display, which is repeatedly foldable like a book, and a tri‐fold display including a display area, which is foldable in three.     

OLED‐based pico‐projection system

Abstract— Two pico‐projection systems, a monochrome green and a full‐color system, based on high‐efficiency OLED microdisplays (VGA; pixel size, 12 μm) are presented. Both optical systems are described by a numerical aperture of about 0.3, a magnification of 15x, and a working distance of 300–360 mm. The frequency limit of both systems is 42 cycles/mm at an image contrast of about 60%. The monochrome projection system with a volume smaller than 10 cm³ consists of one green OLED and a projection lens with five elements. The measured luminance in the image plane is about 0.061 lm. The image has a diagonal of 150 mm with a working distance of about 300 mm and has a considerable image contrast of 396:1. The second system combines three high‐brightness OLEDs, red, green, and blue colored, together with a projection lens and an image‐combining element, and an X‐Cube to achieve full‐color projection. The estimated luminance value for the three‐panel projection unit with an OLED luminance of 10,000 cd/m² for each display will be about Φcalculated = 0.147 lm. In this paper, the system concepts, the optical designs, and the realized prototypes of the monochrome and full‐color projection system are presented.     

World's first large size 77‐inch transparent flexible OLED display

Large flexible organic light‐emitting diode (OLED) display provides various electronic applications such as curved, bendable, rollable, and commercial display, because of its thinness, light weight, and design freedom. In this work, the process flow and key technologies to fabricate the world's first large size 77‐inch transparent flexible OLED display are introduced. “White OLED on TFT + color filter” method is used to fabricate the aforementioned display. On both thin‐film transistor and color filter substrates, transparent polyimide (PI) was used as plastic substrate with multi‐barrier. In case of a transparent flexible display, the multi‐barrier is required for the additional consideration to overcome the decrease of transmittance due to the difference in refractive index of the conventional multi‐barrier. We developed the special multi‐barrier to increase transparency with superior water vapor transition rate characteristic. The optimized amorphous indium gallium zinc oxide thin‐film transistors were employed on the multi‐barrier, and it shows the highly uniform electrical performance and reliability on plastic substrate. Also, the typical panel failure mechanism during laser lift‐off process caused by a particle in PI is studied, and a sacrificial layer was suggested between PI and a carrier glass to reduce the panel failure. Finally, we successfully realized the world's first 77‐inch transparent flexible OLED display with ultra‐high‐definition resolution, which can be rolled up to a radius of 80 mm with a transmittance of 40%.     

Advanced technologies for UHD curved OLED TV

Ultra‐high definition (UHD) curved organic light‐emitting diode (OLED) TV requires advanced technologies to realize mass production. White, red, green, and blue (WRGB) OLED TV based on stripe WRGB sub‐pixel structure has distinct advantages in luminance of white, faster response time, wider viewing angle, and potential higher resolution. In this paper, we will introduce technological progress for commercializing large‐sized and UHD curved OLED TV. Those technologies including oxide thin film transistors, white OLEDs, compensation circuit, and solid phase encapsulation enable panel size scalability as well as mass production with lifetime reliability.     

Characterization and compensation of OLED aging in a digital AMOLED system

Organic light‐emitting diode (OLED) aging is the root cause for image sticking artifact and considered as the toughest problem besides the low yield problem of active‐matrix organic light‐emitting diode (AMOLED) displays. Digital driving can eliminate Mura artifact and allow a similar yield like LCD. However, it is more prone to OLED aging than analog driving, so that the lifetime will become shorter. In this paper, we pursue the approach to measure the pixel current and compensate OLED I–V drift. Information gained from electrical measurements during the lifetime of the display may be correlated to electro‐optical drift, particularly the current efficiency. The aging model has to consider the dependence of I–V drift and efficiency loss on the operation point/voltage for each subframe. Specific compensation algorithms have been developed. Two AMOLED prototypes (1.5 and 2.8 in.) were validated. Burned‐in pattern can be compensated, so the concept has been proven as effective. With the method described in this paper, digital AMOLED may reach a similar and even significantly higher lifetime than an analog AMOLED.     

High‐resolution OLED display with remarkably low power consumption using blue/yellow tandem structure and RGBY subpixels

A top‐emission organic light‐emitting diode (OLED) with a microcavity structure combined with a blue/yellow tandem structure was developed. A high‐resolution active‐matrix OLED display with the world's lowest level of power consumption using the tandem OLED with red, green, blue, and yellow subpixels was fabricated.     

Highly efficient deep‐blue organic light‐emitting devices

Abstract— A highly efficient deep‐blue organic light‐emitting device (OLED) incorporating a novel composite hole‐transport layer (c‐HTL) and an emitter based on the new non‐symmetrical mono(styryl)amine fluorescent dopant in the stable host MADN, which achieved a luminance efficiency of 5.4 cd/A with a Commission Internationale d'Eclairage (CIEx,y) of (0.14, 0.13) and an external quantum efficiency of 5.1% at 20 mA/cm² and 6.8 V, is reported. The increased device efficiency is attributed to an improved balance between hole and electron currents in the recombination zone.     

Solution‐processable double‐layered ionic p‐i‐n organic light‐emitting diodes

Abstract— Solution‐processed double‐layered ionic p‐i‐n organic light‐emitting diodes (OLEDs), comprised of an emitting material layer doped with an organometallic green phosphor and a photo‐cross‐linked hole‐transporting layer doped with photo‐initiator is reported. The fabricated OLEDs were annealed using simultaneous thermal and electrical treatments to form a double‐layered ionic p‐i‐n structure. As a result, an annealed double‐layered OLED with a peak brightness over 20,000 cd/m² (20 V, 390 mA/cm²) and a peak efficiency of 15 cd/A (6 V, 210 cd/m²) was achieved.