Combined Henyey-Greenstein and Rayleigh phase function

The phase function is an important parameter that affects the distribution of scattered radiation. In Rayleigh scattering, a scatterer is approximated by a dipole, and its phase function is analytically related to the scattering angle. For the Henyey-Greenstein (HG) approximation, the phase function preserves only the correct asymmetry factor (i.e., the first moment), which is essentially important for anisotropic scattering. When the HG function is applied to small particles, it produces a significant error in radiance. In addition, the HG function is applied only for an intensity radiative transfer. We develop a combined HG and Rayleigh (HG-Rayleigh) phase function. The HG phase function plays the role of modulator extending the application of the Rayleigh phase function for small asymmetry scattering. The HG-Rayleigh phase function guarantees the correct asymmetry factor and is valid for a polarization radiative transfer. It approaches the Rayleigh phase function for small particles. Thus the HG-Rayleigh phase function has wider applications for both intensity and polarimetric radiative transfers. For microwave radiative transfer modeling in this study, the largest errors in the brightness temperature calculations for weak asymmetry scattering are generally below 0.02 K by using the HG-Rayleigh phase function. The errors can be much larger, in the 1-3 K range, if the Rayleigh and HG functions are applied separately.     

Thermal radiation of nanoparticles occurring at a heated flat surface in vacuum

The most general expression for the rate of radiative heating (cooling) of an electrically neutral nanoparticle occurring in vacuum near a flat surface of a homogeneous polarizable medium is obtained for the first time. The magnetic polarizability of a conducting nanoparticle radically influences the rate of heat exchange between this particle and a metal surface. The rate of radiative cooling is several orders of magnitude higher than the power density of thermal radiation from a blackbody of the same size. This ratio is retained for micron size particles occurring at a distance of several hundred microns from the surface.     

Relationship between asymmetry parameter and hemispheric backscatter ratio: implications for climate forcing by aerosols

Calculations of direct climate forcing by anthropogenic aerosols commonly use radiative transfer parameters, including asymmetry parameter g. One method of obtaining the asymmetry parameter of a particle population is to convert measured values of the hemispheric-to-total-scatter ratio (backscatter ratio b) into their corresponding g values. We compare a conversion derived from Mie calculations with one derived from the Henyey-Greenstein (HG) phase function to show that the HG method systematically overestimates g for typical size distributions of accumulation-mode aerosols. A delta-Eddington radiative transfer calculation is used to show that a 10% overestimation of g can systematically reduce climate forcing as a result of aerosols by 12% or more. Mie computations are used to derive an empirical relationship between backscatter ratio and asymmetry parameter for log-normal accumulation-mode aerosols. This relationship can be used to convert the backscatter ratio to the asymmetry parameter, independent of geometric mean diameter D(gv) or complex refractive index m, but the conversion requires knowledge of the breadth σ(g) of the size distribution.     

Modeling of thermal barrier coating temperature due to transmissive radiative heating

Thermal barrier coatings are generally designed to possess very low thermal conductivity to reduce the conduction heat transfer from the coating surface to the metal turbine blade beneath the coating. In high-temperature power generation systems, however, a considerable amount of radiative heat is produced during the combustion of fuels. This radiative heat can propagate through the coating and heat up the metal blade, and thereby reduce the effectiveness of the coating in lowering the thermal load on the blade. Therefore, radiative properties are essential parameters to design radiative barrier coatings. This article presents a combined radiation and conduction heat transfer model for the steady-state temperature distribution in semitransparent yttria-stabilized zirconia (YSZ) coatings. The results of the model show a temperature reduction up to 45 K for YSZ of high reflectance (80%) compared to the YSZ of low reflectance (20%). The reflectivities of YSZ and metal blade affect the temperature distribution significantly. Additionally, the absorption and scattering coefficients of YSZ, the thickness of the coating, and the thermal conductivities of YSZ and metal blade affect the temperature distribution.     

Optical filters consisting of metallic waveguide arrays

We demonstrate high-pass optical filters with cutoffs in the 0.3-10-micron spectral region. These filters consist of uniform arrays of hollow metallic waveguides, obtained by coating wafers of the previously developed channel-glass (CG) materials with a thin metal film. In these filters the channel diameter controls the cutoff frequency, the channel length controls the sharpness of the cutoff, and the channel density determines the transmission efficiency at cutoff. All of these parameters can be controlled in the CG starting material. The properties of the metal coatings that influence the filter properties are also discussed. Cutoff wavelengths near 300 nm have been achieved to date by using CG materials with submicrometer channel diameters. At all channel diameters, the transmission spectra include a peak just above the cutoff wavelength, where the transmission value can exceed that expected on the basis of the geometrical open area of the CG structure.     

Phase-function normalization for accurate analysis of ultrafast collimated radiative transfer

The scattering of radiation from collimated irradiation is accurately treated via normalization of phase function. This approach is applicable to any numerical method with directional discretization. In this study it is applied to the transient discrete-ordinates method for ultrafast collimated radiative transfer analysis in turbid media. A technique recently developed by the authors, which conserves a phase-function asymmetry factor as well as scattered energy for the Henyey-Greenstein phase function in steady-state diffuse radiative transfer analysis, is applied to the general Legendre scattering phase function in ultrafast collimated radiative transfer. Heat flux profiles in a model tissue cylinder are generated for various phase functions and compared to those generated when normalization of the collimated phase function is neglected. Energy deposition in the medium is also investigated. Lack of conservation of scattered energy and the asymmetry factor for the collimated scattering phase function causes overpredictions in both heat flux and energy deposition for highly anisotropic scattering media. In addition, a discussion is presented to clarify the time-dependent formulation of divergence of radiative heat flux.     

The optical properties of porous silicon produced by metal-assisted anodic etching

Porous silicon (PS) was obtained from n-type (100) mono-crystalline silicon wafers with different metal using two different illumination conditions. The visible photoluminescence (PL) may come from defect-related radiative centers on PS surface and adsorbed hydrogen atoms may be associated to the elimination of irradiative centers on PS surface, which can be proved by the infrared absorption spectra. The metal can be used as catalytic role to increase the etching rate under back illumination, but under front illumination, the metal can cancel light-generated carrier leading to the decrease of etching rate during anodic etching. Furthermore, the change of minority carrier lifetime is opposite to the change of PL efficiency of PS, which can be Confirmed by the results of μ-PCD measurements.     

Scanning Probe Lithography Patterning of Monolayer Semiconductors and Application in Quantifying Edge Recombination

Scanning probe lithography is used to directly pattern monolayer transition metal dichalcogenides (TMDs) without the use of a sacrificial resist. Using an atomic‐force microscope, a negatively biased tip is brought close to the TMD surface. By inducing a water bridge between the tip and the TMD surface, controllable oxidation is achieved at the sub‐100 nm resolution. The oxidized flake is then submerged into water for selective oxide removal which leads to controllable patterning. In addition, by changing the oxidation time, thickness tunable patterning of multilayer TMDs is demonstrated. This resist‐less process results in exposed edges, overcoming a barrier in traditional resist‐based lithography and dry etch where polymeric byproduct layers are often formed at the edges. By patterning monolayers into geometric patterns of different dimensions and measuring the effective carrier lifetime, the non‐radiative recombination velocity due to edge defects is extracted. Using this patterning technique, it is shown that selenide TMDs exhibit lower edge recombination velocity as compared to sulfide TMDs. The utility of scanning probe lithography towards understanding material‐dependent edge recombination losses without significantly normalizing edge behaviors due to heavy defect generation, while allowing for eventual exploration of edge passivation schemes is highlighted, which is of profound interest for nanoscale electronics and optoelectronics.     

Enhancement of bonding strength by graded structure at interface between apatite layer and bioactive tantalum metal

Tantalum metal is a candidate for use as an implant material in high load-bearing bony defects, due to its attractive features such as high fracture toughness and high workability. This metal, however, does not have bone-bonding ability, i.e. bioactivity, and therefore the development of bioactive tantalum metal is highly desirable. It is known that the essential prerequisite for an artificial material to show bioactivity is to form a bonelike apatite layer on its surface in the body environment. The same type of apatite layer is formed in a simulated body fluid (SBF) with inorganic ion concentrations nearly equal to those of human blood plasma. The present authors previously showed that the apatite formation on tantalum metal in SBF was remarkably accelerated by treatment with 0.5 M-NaOH aqueous solution and subsequent firing at 300 °C, while untreated tantalum metal spontaneously formed the same apatite after a long soaking period. In the present study, the bonding strength of the apatite layer to the substrate was quantitatively evaluated in comparison with that to the untreated tantalum metal. Adhesive strength was measured as an estimation of bonding strength, and the surface microstructure of both the substrates was characterized in order to discuss the difference in the bonding strength in terms of surface structure. The apatite layer formed on the NaOH- and heat-treated tantalum metal shows higher adhesive strength than that formed on the untreated metal. The amorphous sodium tantalate layer formed on the tantalum metal by NaOH and heat treatments, has a smooth graded structure where its concentration gradually changes from the surface into the interior metal. Smooth graded structure with complex of apatite is constructed after soaking in SBF. The higher bonding strength of the apatite layer formed on the treated metal is attributed to its smooth graded structure.     

Optical-fiber surface-plasmon resonance sensor with multiple resonance peaks

We report on an optical fiber surface plasmon resonance sensor that exhibits multiple resonance peaks. The sensor is based on a uniform-waist single-mode tapered fiber coated on one side with a thin metal layer. Owing to the asymmetry of the sensor structure, the different hybrid surface plasmon modes supported by the semicircular layer can be excited by the fundamental fiber mode. As a result, the sensor transmission spectrum exhibits several dips that depend on the taper waist diameter. The advantages of a plasmon resonance sensor with multiple dips are discussed.     

Plasmon line shaping using nanocrosses for high sensitivity localized surface plasmon resonance sensing

The detection of small changes in the wavelength position of localized surface plasmon resonances in metal nanostructures has been used successfully in applications such as label-free detection of biomarkers. Practical implementations, however, often suffer from the large spectral width of the plasmon resonances induced by large radiative damping in the metal nanocavities. By means of a tailored design and using a reproducible nanofabrication process, high quality planar gold plasmonic nanocavities are fabricated with strongly reduced radiative damping. Moreover, additional substrate etching results in a large enhancement of the sensing volume and a subsequent increase of the sensitivity. Coherent coupling of bright and dark plasmon modes in a nanocross and nanobar is used to generate high quality factor subradiant Fano resonances. Experimental sensitivities for these modes exceeding 1000 nm/RIU with a Figure of Merit reaching 5 are demonstrated in microfluidic ensemble spectroscopy.     

复合材料螺栓联接螺纹载荷分布规律研究

基于Abaqus有限元分析软件建立了复合材料螺栓联接的三维有限元模型,以预测复合材料螺栓联接的螺纹载荷分布,为使模型符合真实情况,将螺母支承在弹性地基上并通过Abaqus USDFLD子程序考虑了C基或SiC基复合材料拉压不对称特性。此外,本文对预测金属螺纹的载荷分布的Yamamoto方法进行了经验性的推广,使其可以反映C基或SiC基复合材料的各向异性和拉压不对称性。通过对比多组材料及几何参数下推广的Yamamoto方法（EYM）和有限元法（FEM）预测的螺纹载荷分布验证了推广的Yamamoto方法的有效性。研究结果表明：复合材料螺栓联接的载荷分布通常比金属联接的载荷分布更均匀;随着螺距与直径之比的增加,螺纹载荷分布不均程度有所增加;复合材料螺栓绕其轴线相对于螺母的转动对载荷分布几乎没有影响。     

Laboratory studies of alkali metal filter deposition, ultraviolet transmission, and visible blocking

Far-ultraviolet alkali metal or Wood's filters have been produced and tested supporting the production of a flight filter for the Wide Field Planetary Camera 2 on the Hubble Space Telescope. Sodium layers 0.5-1-mum thick transmit up to 40% in the ultraviolet while efficiently blocking visible wavelengths. The prevention of visible pinholes is assisted by a clean, sleek-free surface and a cooled substrate during deposition. The coatings are stabilized efficiently by a bismuth overcoating whose transmission spectrum is presented. We also report for the first time, to our knowledge, the first demonstrated long-wavelength cutoff from a lithium filter, with a shorter cutoff wavelength than sodium and potentially higher stability for astronomical imaging.     

Apparent texture symmetry deviations in aluminum sheet

An ultrasonic texture measurement system for sheet metal is being developed using rotating electromagnetic acoustic transducers (EMATs). We report on further investigations of deviation from theoretically predicted symmetries in the elastic constants (as measured ultrasonically using the aforementioned system) of cold-rolled aluminum sheet reported in earlier publications. A study of the effects of annealing and deliberate deformation (both elastic and plastic) are used to develop an explanation of the nature and likely origin of this asymmetry. These deviations from symmetry cannot be detected by ultrasonic Lamb wave measurement in three directions alone. Texture asymmetry is relevant to the sheet metal manufacturer as it affects formability and may indicate processing problems. Results indicate that the asymmetry in the measured ultrasonic Lamb wave velocities on either side of the rolling direction is due to a stress effect rather than crystallographic     

Diffusive-to-ballistic transition in dynamic light transmission through thin scattering slabs: a radiative transfer approach

We study the deviation from diffusion theory that occurs in the dynamic transport of light through thin scattering slabs. Solving numerically the time-dependent radiative transfer equation, we obtain the decay time and the effective diffusion coefficient Deff. We observe a nondiffusive behavior for systems whose thickness L is smaller than 8l(tr), where l(tr) is the transport mean free path. We introduce a simple model that yields the position of the transition between the diffusive and the nondiffusive regimes. The size dependence of Deff in the nondiffusive region is strongly affected by internal reflections. We show that the reduction of approximately 50% of Deff that was observed experimentally [Phys. Rev. Lett. 79, 4369 (1997)] can be reproduced by the radiative transfer approach. We demonstrate that the radiative transfer equation is an appropriate tool for studying dynamic light transport in thin scattering systems when coherent effects play no significant role.     

Modulation of Cathodoluminescence by Surface Plasmons in Silver Nanowires

The waveguide modes in chemically-grown silver nanowires on silicon nitride substrates are observed using spectrally- and spatially-resolved cathodoluminescence (CL) excited by high-energy electrons in a scanning electron microscope. The presence of a long-range, travelling surface plasmon mode modulates the coupling efficiency of the incident electron energy into the nanowires, which is observed as oscillations in the measured CL with the point of excitation by the focused electron beam. The experimental data are modeled using the theory of surface plasmon polariton modes in cylindrical metal waveguides, enabling the complex mode wavenumbers and excitation strength of the long-range surface plasmon mode to be extracted. The experiments yield insight into the energy transfer mechanisms between fast electrons and coherent oscillations in surface charge density in metal nanowires and the relative amplitudes of the radiative processes excited in the wire by the electron.     

Multiple-scattering transmission and an effective average photon path length of a plane-parallel beam in a homogeneous medium

A two-stream radiative transfer model is used to derive expressions for the multiple-scattered transmitted flux (including single-scattering contributions) and the total effective average photon path length on transmission of a normally incident plane-parallel beam on a homogeneous layer characterized by the optical depth, the single-scattering albedo, and the asymmetry parameter of the scatterers. The results are simple analytical expressions that are useful for modifying the Beer-Lambert transmission law for a thick scattering medium in which the multiple-scattering contribution to the transmission is not negligible.     

Electrical Excitation of Long-Range Surface Plasmons in PC/OLED Structure with Two Metal Nanolayers

A current-driven source of long-range surface plasmons(LRSPs)on a duplex metal nanolayer is reported.Electrical excitation of LRSPs was experimentally observed in a planar structure,where an organic light-emitting film was sandwiched between two metal nanolayers that served as electrodes.To achieve the LRSP propagation in these metal nanolayers at the interface with air,the light-emitting structure was bordered by a one-dimensional photonic crystal(PC)on the other side.The dispersion of the light emitted by such a hybrid PC/organic-light-emitting-diode structure(PC/OLED)comprising two thin metal electrodes was obtained,with a clearly identified LRSP resonance peak.     

Grating-coupling of surface plasmons onto metallic tips: a nanoconfined light source

We describe and demonstrate a new nanometer-scale broadband light source. It is based on the grating-coupled excitation of surface plasmon polaritons (SPPs) on the shaft of a sharp conical metal taper with a tip radius of few tens of nanometers. Far-field excitation of linear nanoslit gratings results in the resonant generation of SPPs traveling over more than 10 mum to the tip apex and converging to an intense radiative local light spot. Such nanofabricated tips are expected to find various applications in nanospectroscopy, overcoming problems with background illumination in apertureless microscopy.     

Highly contrasting effects of different climate forcing agents on terrestrial ecosystem services

Many atmospheric constituents besides carbon dioxide (CO(2)) contribute to global warming, and it is common to compare their influence on climate in terms of radiative forcing, which measures their impact on the planetary energy budget. A number of recent studies have shown that many radiatively active constituents also have important impacts on the physiological functioning of ecosystems, and thus the 'ecosystem services' that humankind relies upon. CO(2) increases have most probably increased river runoff and had generally positive impacts on plant growth where nutrients are non-limiting, whereas increases in near-surface ozone (O(3)) are very detrimental to plant productivity. Atmospheric aerosols increase the fraction of surface diffuse light, which is beneficial for plant growth. To illustrate these differences, we present the impact on net primary productivity and runoff of higher CO(2), higher near-surface O(3), and lower sulphate aerosols, and for equivalent changes in radiative forcing. We compare this with the impact of climate change alone, arising, for example, from a physiologically inactive gas such as methane (CH(4)). For equivalent levels of change in radiative forcing, we show that the combined climate and physiological impacts of these individual agents vary markedly and in some cases actually differ in sign. This study highlights the need to develop more informative metrics of the impact of changing atmospheric constituents that go beyond simple radiative forcing.