共查询到20条相似文献,搜索用时 15 毫秒
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《分离科学与技术》2012,47(1-3):153-178
Abstract High-purity hydrogen is commercially produced by pressure swing adsorption from hydrogen-rich mixtures. In this work, a vacuum pressure swing adsorption cycle is used to produce high purity hydrogen from a hydrogen-lean binary mixture (20/80 H2/CO) using zeolite 5A as the sorbent. The effects of different process variables on separation performance have been studied. The purity of hydrogen product increases at low throughput, high feed pressure, high end pressure of cocurrent depressurization, low end pressure of countercurrent evacuation, and short cycle time. Also, it was found that for a H2-lean mixture, the separation is improved at higher ambient temperature. In addition, a new “vacuum purge” step was found to improve the separation and is therefore a promising step for commercial application. 相似文献
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《分离科学与技术》2012,47(10):1837-1847
Abstract A novel concentration-thermal swing adsorption process is described for separation of bulk binary liquid mixtures. The process is designed to produce essentially two pure products with high recoveries of both components. It is particularly suited for separation of azeotropic or close-boiling liquid mixtures which are difficult to separate by distillation. An example of the performance of the new process for separation of an azeotropic water-methyl acetate mixture is given. Experimental binary surface excess equilibrium isotherms, adsorptive mass transfer coefficients, and column dynamics for adsorption of water-methyl acetate mixtures on NaX zeolite are reported. 相似文献
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《分离科学与技术》2012,47(7):877-893
Abstract Adsorbent and cycle developments for the last 25 years have resulted in the advancement of vacuum swing adsorption processes for the production of oxygen from air, and in this review are traced and critically examined. The key criteria in the past developments and for future improvements are identified. 相似文献
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J. Sadeghzadeh Ahari S. Pakseresht M. Mahdyarfar S. Shokri Y. Zamani A. Nakhaei pour F. Naderi 《化学工程与技术》2006,29(1):50-58
A general dynamic model is developed for separation of air over a carbon molecular sieve and a zeolite adsorbent for production of nitrogen and oxygen. The proposed model is validated using experimental data from working laboratory scale N2–PSA and laboratory scale O2–PSA systems. Simulations studies are performed to investigate the effect of changing various process variables, such as the duration of PSA steps, bed length and feed inlet velocity. 相似文献
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变压吸附空分制氧的技术进展 总被引:9,自引:1,他引:8
介绍了近年来变压吸附空分制氧的技术进展情况,分别从空分制氧的工艺和吸附剂的改进状况进行了详细论述,并简单的描述了空分制氧的发展前景。 相似文献
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《分离科学与技术》2012,47(4-5):437-450
Abstract A simple pressure swing adsorption process for direct production of low to medium purity (23–50%) O2-enriched gas from ambient air is described. The process provides a high O2 production capacity per unit amount of the adsorbent and a high O2 recovery combined with a very low energy requirement for the separation. The performance of the process using three different air separation adsorbents is described. 相似文献
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《分离科学与技术》2012,47(9):1252-1259
We have evaluated the Vacuum Pressure Swing Adsorption (VPSA) technology to separate propane–propylene streams to produce polymer-grade propylene. Zeolite 4A is used as kinetic adsorbent since propylene diffuses much faster than propane. A single VPSA process is able to produce propylene with purity higher than 99.6%. However, propylene recovery is only 67% and therefore a second stage is used. In this VPSA unit, zeolite 4A with smaller crystal radius is employed to reduce kinetic limitations. The second VPSA (tail unit) produces purified propane and recovers propylene that is recycled to the feed of the first VPSA (front unit). Linking these two VPSA units allows us to produce polymer-grade propylene (PGP) recovering 95.9% of the propylene. Comparing the performance of this process with distillation, there is a significant decrease in the separation volume. However, further efforts are necessary to reduce the power consumption of VPSA which is still slightly higher than for distillation. 相似文献
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简述了变压吸附技术在分离净化方面的应用,及其在分离提纯高沸点组分中的研究进展,寻求进一步拓展变压吸附技术的应用领域,开发新型工业装置的途径 相似文献
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本文介绍了可以代替深冷法的新的制氮方法—变压吸附法,该法适合于70t/d以下规模。该法启动快,可根据需要随意开停车。产品氮气的纯度可达99.5%以上。 相似文献
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《分离科学与技术》2012,47(9-10):725-747
Abstract Bulk separation of a five-component mixture simulating coal gasification products was performed by pressure swing adsorption (PSA) using activated carbon. The PSA cycle consisted of four commercially used steps: (I) pressurization with H2, (II) adsorption, (III) blowdown, and (IV) evacuation. Using this cycle, four products were obtained with a single PSA unit: H2 (over 99.7% purity), CO, CH4, and acid gas (CO2 + H2S). The first three products contained less than 0.001% H2S, and the acid gas was suitable for sulfur recovery. A mathematical model incorporating equilibrium adsorption of mixture and mass transfer resistance (of CO2) was found capable of simulating all steps of the PSA cycle. The model simulation results were in fair agreement with the experimental data. A fundamental understanding of the dynamics of the cyclic process was gained through the model. 相似文献
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S. A. Al‐Muhtaseb 《化学工程与技术》2006,29(11):1323-1332
The effects of the adsorbent characteristics on the performance parameters and periodic state behavior of the vacuum swing adsorption (VSA) solvent vapor recovery (SVR) processes are examined and optimized. The adsorbent characteristics studied were the adsorbent particle's porosity, density, radius and heat capacity, the packed bed void fraction, the isosteric heat of adsorption, the monolayer saturation limit of the solvent molecules on the adsorbent, the adsorbent's affinity to adsorb the solvent molecules and the mass transfer coefficient for the adsorption of the solvent molecules. It was found that the best VSA‐SVR process performances can be obtained using adsorbents characterized by the minimum possible packed bed void fraction and particle porosity, with the maximum possible adsorbent heat capacity and density, adsorption monolayer saturation capacity and mass transfer coefficient, and at intermediate adsorption affinity and isosteric heat of adsorption of the solvent molecules. 相似文献
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变压吸附分离提纯CO_2技术的应用 总被引:3,自引:0,他引:3
本文叙述了变压吸附提纯CO2技术的基本原理和工艺过程,介绍了我国PSA-CO2的开发过程及发展前景,对已开发的PSA-CO2工业装置的生产成本和经济性进行了分析 相似文献
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《分离科学与技术》2012,47(6-7):519-529
Abstract Two pressure swing adsorption processes for separation of methane and carbon dioxide gas mixtures are described. One process simultaneously produces a high purity CH4 and a high purity CO2 product with high recoveries of both components from the feed gas. The other process only produces a high purity CH4 product with high recovery. Test data for these processes are reported and their relative advantages are discussed. 相似文献