共查询到20条相似文献,搜索用时 15 毫秒
1.
Jimmy Wei Ping Lye Norasikin Saman Ahmad Mujahid Md Noor Safia Syazana Mohtar Nurul Sakinah Othman Siti Shilatul Najwa Sharuddin Helen Kong Hanapi Mat 《化学工程与技术》2020,43(7):1285-1296
Immobilized nanoscale zero-valent iron on natural zeolite (NI-NZ) was synthesized for remediation of antibiotics-contaminated wastewater. A series of characterization methods confirmed the success of preventing the agglomeration of nanoscale zero-valent iron particles, using natural zeolite as supporting media. The equilibrium data fitted well with the Langmuir and Temkin models, whereas the pseudo-second-order and Elovich kinetic models were suitable to describe the kinetic data. The versatility of NI-NZ was also tested in a coagulation-flocculation process which increased the removal of tetracycline from 10 to 75 %. 相似文献
2.
《分离科学与技术》2012,47(8):2117-2143
Abstract The aim of this work is to study the effectiveness of regional, low-cost natural clinoptilolitic zeolite tuff in heavy metal ions removal from aqueous solution, through comparative study with commercial granulated activated carbon. The equilibrium of adsorption of Cd2+, Pb2+, and Zn2+ on both adsorbents have been determined at 25, 35, and 45°C in batch mode. The granulated activated carbon has shown around three times higher adsorption capacity for Cd2+ and Zn2+ than natural zeolite, and almost the same adsorption capacity for Pb2+ as the natural zeolite. The metal ion selectivity series Pb2+ > Cd2+ > Zn2+, on a mass basis, has been obtained on both adsorbents. The Langmuir and Freundlich model have been used to describe the adsorption equilibrium. The thermodynamic parameters were calculated from the adsorption isotherm data obtained at different temperatures. The study of the influence of the acidity of the metal ion aqueous solution has shown an increase of metal ion uptake with increase of the pH. The sorption mechanism of Cd2+, Pb2+, and Zn2+ on natural zeolite changes from ion-exchange to ion-exchange and adsorption of metal-hydroxide with increase of the pH from 2 to 6 (and 7 for Zn2+). The preliminary cost calculation, based on adsorbents maximum adsorption capacity and their price, have revealed the potential of natural zeolite as an economic alternative to the granulated activated carbon in the treatment of heavy metal polluted wastewater. 相似文献
3.
S. N. Hussain H. M. A Asghar H. Sattar N. W. Brown E. P. L Roberts 《Chemical Engineering Communications》2013,200(10):1280-1288
An innovative process has been developed at University of the Manchester in order to remove organic contaminants from wastewater using graphite intercalation compounds (GICs) as adsorbents with electrochemical regeneration. The present study has demonstrated the removal of tartrazine, from water by adsorption and electrochemical regeneration. The adsorption of tartrazine onto GIC adsorbent was shown to be a quick process, however, with extremely low adsorption capacity compared to porous adsorbents. Low adsorption capacity of the adsorbent is being compensated by rapid electrochemical regeneration associated with low energy consumption that makes the process cost-effective. Regeneration efficiency of around 100% could be obtained in an electrochemical cell by passing a charge of 18 C g?1 for 18 min through a 10-mm thick adsorbent bed. A series of adsorption and regeneration cycles showed that there was little loss in adsorbent capacity, demonstrating that tartrazine loaded GIC adsorbent could be effectively regenerated electrochemically. 相似文献
4.
5.
改性粉煤灰对二甲酚橙的吸附研究 总被引:4,自引:0,他引:4
研究了改性粉煤灰对二甲酚橙的吸附性能。探讨了吸附时间、溶液初始浓度、吸附剂用量及溶液初始pH对二甲酚橙去除率的影响。结果表明:在pH=11及常温条件下,改性粉煤灰用量为8g/L时对浓度为7.6mg/L二甲酚橙的去除率为85%。 相似文献
6.
Removal of ammonium ions from aqueous solutions with coal-based activated carbons modified by oxidation 总被引:3,自引:0,他引:3
The main purpose of this work is to study the possibilities for removal of ammonium ions from aqueous solutions by the two coal-based activated carbons (one obtained from Bulgarian lignite from the Chukurovo deposit, and the second, available as commercial product) and their oxidized modifications. The porous texture and surface chemistry of the adsorbents were characterized. Adsorption of ions was investigated using solutions with different concentrations in the range 35-280 mg l−1 in a static mode. Equilibrium modeling data were fitted to linear Langmuir’s and Freundlich’s equations and maximum adsorption capacities were calculated. 相似文献
7.
8.
9.
The effects of ozonation, granular (GAC) and biological activated carbon (BAC) in the removal of natural organic matter and precursors of disinfection byproducts from drinking water were studied on pilot scale. Ozonation was determined to be the best method to reduce concentrations of the precursors of AOX, chloroform and mutagenicity, whereas BAC removed organic matter the most effectively. Reductions in TA100 mutagenicity were an average 40%, 4%, 26% in ozonated, GAC and BAC filtered water, respectively. Average reductions of AOX levels were similar at 48%, 7% and 35%, respectively. The chloroform formation potential always increased after GAC filtration. 相似文献
10.
11.
含氟废水排放量逐年增长,氟污染日益受到人们的关注.因此,含氟废水处理方法与技术研究一直是国内外环保领域的重要课题.本文阐述了目前国内外电视电脑显示器(CRT)玻璃清洗过程中对含氟废水处理的方法,重点介绍了常用的化学沉淀法、混凝沉淀法、中和沉淀和混凝沉淀配合使用,并对除氟机理进行了讨论. 相似文献
12.
13.
Michihiro Miyake Chikashi Tamura Motohide Matsuda 《Journal of the American Ceramic Society》2002,85(7):1873-1875
The conversion of waste incineration fly ash to zeolitic compounds by hydrothermal treatment in the presence of NaOH solution has been investigated. An acid pretreatment of fly ash in addition to water washing and heating at 800°C was found to be an important process to prepare reproducible zeolitic compounds. Treatment with a low-concentration NaOH solution at 60°C and 100°–120°C successfully produced zeolites A and P, respectively, as major products. At increased concentrations of NaOH, sodalite was generated. The hydrothermal products showed uptake behavior for NH4 + ions. 相似文献
14.
新生MnO2对茜素红吸附脱色的研究 总被引:2,自引:0,他引:2
以新生MnO2为吸附剂,对水中茜素红染料进行了脱色研究,探讨了影响吸附的因素。结果表明,降低pH值、增加吸附剂投加量,有利于新生水合二氧化锰对茜素红染料的脱色。当新生态水合MnO2浓度为300 mg/L,茜素红浓度为400 mg/L,pH=2,反应时间为60 min时,茜素红脱色率达90%以上。实验还发现对茜素红染料吸附较好符合Freundich吸附等温式,吸附速率较快。 相似文献
15.
The purpose of this study was to point out processes that can provide triazine oxidation via hydroxyl radical production in a water treatment line. We focus our attention on:
- oxido-flocculation, using Fe2+, H2O2
- inter-oxidation, using O3, H2O2 and eventually an heterogeneous catalyst.
- disinfection, using UV, O3 and H2O2 combinations.
Results show that triazines can be removed by all these processes with different efficiencies. At full scale, the O3/H2O2 process presents the best performances from an economical and technical point of view. 相似文献
16.
聚磷酸铵阻燃聚丙烯的研究 总被引:14,自引:1,他引:14
采用聚磷酸铵(APP)对聚丙烯(PP)进行了填充改性,研究了APP对PP阻燃性能和力学性能的影响,还研究了200℃下APP对PP阻燃复合材料的流变行为及结晶性能的影响。结果表明:在PP中加入适量的APP,可改善体系的阻燃性能,同时对材料的力学性能会产生影响,使复合体系的弯曲强度与弯曲模量明显提高,却使断裂伸长率,特别是冲击强度降低;在200℃时,较低剪切速率范围内,APP的加入有利于复合材料流动性能的改善,但在高剪切速率范围内对复合材料的流动性能影响不大;APP在PP中具有成核剂作用,可使PP的结晶过程在较高温度下进行,结晶速率也大大提高,但对PP的结晶度和熔点影响不大。 相似文献
17.
18.
Performance data for GAC columns treating surface water are analyzed to determine the relative importance of physical adsorption and biological activity, with and without pre-ozonation. Kinetic and equilibrium adsorption parameters for the source water are used in the Homogeneous Surface Diffusion model to predict GAC performance over 83 weeks. The model underestimates removal of TOC for ozonated and unozonated streams by 46% and 28%, respectively, which is attributed to omission of biological removal in the model. 相似文献
19.
20.
缔合法磷酸二铵氨化反应特征的研究 总被引:1,自引:0,他引:1
研究了氨和磷酸缔合物生成磷酸一铵的化学反应特征。其反应式为:(R3NH)H2PO4+NH3→R3N+(NH4)H2PO4获得了两个温度范围的反应速率方程:20~50℃:-γA=8.678×103·exp(-1.9564×103·1/T·C0.3A50~80℃:-γA=0.4203×102·exp(-0.9780×103·1/T·C0.3A方程计算与实测在相同与不同温度时的平均误差分别为-4.29%和-0.32%。研究结论:反应级数n=0.3;反应为受液膜控制的快速反应;生成磷酸二铵的反应有一慢速区,反应分为两段进行较为经济。 相似文献