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《分离科学与技术》2012,47(8):1055-1071
Abstract Heavy metals can be removed from dilute aqueous solutions in many ways. Among the innovative ones may be classified a process consisting of biosorption followed by flotation. A metal cation, cadmium, was examined; the metal was abstracted by microorganisms belonging to the Actinomycetes, i.e., Streptomyces clavuligerus and Streptomyces griseus, which have a filamentous morphology, and hence present a flocculent character. Dissolved-air flotation was the technique applied on a laboratory scale without the addition of any flotation surfactant. The parameters investigated in the batch mode were contact time, recycle ratio, solution pH, Cd concentration, biomass addition, and use of a frother (ethanol). Promising results were obtained; in certain cases an almost quantitative cadmium abstraction, followed by higher than 90% biomass recovery, was found. 相似文献
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《分离科学与技术》2012,47(6-7):719-729
Abstract The liquid hydrocarbons hexadecane and pseudocumene (1,2,4-trimethyl-benzene) were removed from their O/W-type emulsions by flotation. The effect of different inorganic salts (NaCl, Na2SO4, Na3PO4) on the removal efficiency was investigated. It was shown that the inorganic salt effect on flotation efficiency is connected with their influence on the double-layer thickness and on the adsorption of surface-active ions. 相似文献
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0 引言 磷化作为金属涂装前处理工艺,已经得到广泛的应用.磷化工艺以前主要以锌系、钙系、锰系或锌-钙、锌-锰系二元磷化体系为主.随着涂装对表面处理质量要求的提高,三元磷化开始在阴极电泳中广泛应用.它能显著提高涂层的附着力,改善磷化膜质量,增强涂层的耐蚀性能. 相似文献
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《分离科学与技术》2012,47(1-4):51-69
Abstract Copper biosorption from aqueous solutions by calcium alginate is reported in this paper. The experimental section includes potentiometric titrations of biosorbents, batch equilibrium and kinetic studies of copper biosorption, as well as fixed-bed biosorption experiments. The potentiometric titration results show that the surface charge increases with decreasing pH. The biosorption of copper strongly depends on solution pH; the metal ion binding increases from 0 to 90 percent in pH ranging from 1.5 to 5.0. In addition, a decrease in ionic strength results in an increase of copper ion removal. Kinetic studies indicate that mass transfer plays an important role in the biosorption rate. Furthermore, a fixed-bed biosorption experiment shows that calcium alginate has a significant capacity for copper ion removal. The two-pK Basic Stern model successfully represents the surface charge and equilibrium biosorption experimental data. The calculation results demonstrate that the copper removal may result from the binding of free copper and its hydroxide with surface functional groups of the biosorbents. 相似文献
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《分离科学与技术》2012,47(7):867-886
ABSTRACT The recovery of Co(II) ions from aqueous solutions under acidic conditions (pH 5) was investigated in flotation columns with inside diameters of 4.0 and 8.0 cm. Three surfactants, dodecylamine, cetyl pyridinium chloride, and sodium dodecyl sulfate, were used as collectors. Sodium dodecyl sulfate was found to be the most efficient; all three, however, produced hydrated froths, leading to rather low recoveries and separation efficiencies. The volumetric gas flow rate was found to affect the process in relation to the amount of surfactant added and the column diameter. The scale-up of the column should be done in terms of the same superficial gas velocity in order to maintain similar levels of metal ion recovery. 相似文献
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粉煤灰用于土壤聚合物固化重金属离子的研究 总被引:3,自引:1,他引:3
为了使土壤聚合物固化重金属离子比较理想效果,同时减少成本,本实验在土壤聚合物中掺加30%的粉煤灰固化重金属离子,结果表明:掺加 30% 粉煤灰的土壤聚合物对不同重金属离子有各自的理想固化量;综合抗压强度和浸出毒性两个方面,Cu2+、Zn2+ 和 Pb2+ 的理想固化量分别为2.O%、1.3%和1.4%;固化体具有良好的后期稳定性和抗酸性,可以满足我国酸雨比较严重的南方地区建材应用要求.总之,掺加 30% 粉煤灰的土壤聚合物固化重金属离子具有良好的经济效益和环境效益. 相似文献
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D. J. WILLIAMS 《Journal of the American Ceramic Society》1970,53(8):448-450
Certain optical transitions were calculated for the first-row transition metal ions Ti3+ , V3+ , Cr3+ , Fe2+ Co2+ , and Ni2+ in a silicate matrix. The calculations were performed at 7 inter-ionic distances for each ion because the metal-ion-to-oxygen interionic distances are unknown; the silicate oxygen charge was varied from 1.00 to 2.00 in each case because the true charge on silicate oxygens is also unknown. Integrals used in the calculations were calculated using Slater and self-consistent field wave functions, and computer programs were used to evaluate all integrals. Equations were derived for calculating all optical transitions for these ions in octahedral fields; the extension to fields of other symmetry is trivial. Several optical transitions were computed to obtain the calculated orders of magnitude for the optical transition. The results for self-consistent field wave functions are lower than expected; they indicate that the transition metal ion in glasses is situated in fields near the size of aquo complexes. 相似文献
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《分离科学与技术》2012,47(8):711-719
Abstract Cellulose acetate membranes obtained from Osmonics Inc. were characterized in terms of pure water permeability constant, solute transport parameter, and mass transfer coefficient with the reference system of aqueous sodium chloride solution. Reverse osmosis separation behavior of Ca, Mg, Zn, Mn, Cu, Al, and Fe as nitrate, chloride, and sulfate salts was studied. The effect of the addition of sodium sulfate to Mg(ClO4)2 and Mn(NO3)2 solutions on solute separation was also investigated. Acid mine-water obtained from New Brunswick was subjected to reverse osmosis, and separation of metal ions in the range of 95 to 99 % was obtained along with the recovery of product water of suitable quality for use in recycle operations. 相似文献
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《山东化工》2015,(22)
以三羟甲基丙烷三甲基丙烯酸酯(TRIM)作为交联剂,镉离子作为印迹分子,1,12-十二烷二醇-O,O'-二苯基磷酸(DDDPA)为功能单体,采用油包水,水包油(W/O/W)多重乳液聚合制备得到镉离子印迹微球。扫描电镜显示大约85%~95%Cd(III)的分子印迹微球颗粒的直径分布在20~40μm,平均直径约35μm。印迹微球膨胀率为25%,这说明了TRIM和DDDPA的组合导致识别位点规则的排布在聚合物表面。为了评价表面印迹技术的有效性,考察了这种镉离子印迹聚合物对镉离子和铜离子吸附性能。此外,将金属离子印迹微球应用于柱操作,通过填充有镉离子表面印迹微球的色谱柱进行金属离子分离和回收。与具有相似的磷酸基团商业螯合树脂相比,镉(II)印迹聚合物对镉离子显示出高选择性。 相似文献