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聚醋酸乙烯酯(PVAc)经醇解反应制备了不同水解度的聚醋酸乙烯酯(PHPVAc),并探索了PHPVAc水解度、成膜技术、测试条件对膜渗透汽化性能影响的规律.实验发现,改变膜材料的水解度、铸膜溶剂组成、操作温度以及料液组成可以调节膜的分离性能,获得较佳的分离效果. 相似文献
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《分离科学与技术》2012,47(13):1955-1967
ABSTRACT In the present work, cobalt(III) acetylacetonate [Co(acac)3] was added to polycarbonate (PC) to improve its performance on pervaporation separation of water/ethanol mixtures. By adding 3 wt% of Co(acac)3 the resulting PC/Co(acac)3 complex membrane possessed a permeation rate similar to a pure polycarbonate membrane, but the separation factor (water/ethanol) was about three times higher. The stability of the complex membrane was tested, and it was found that, after being immersed in an aqueous ethanol solution for 72 hours, the complex membrane was still stable. In addition, the effects of the added amount of Co(acac)3 and the feed composition on pervaporation performance are presented in this work, and the mechanism of the improvement in pervaporation performance is briefly discussed. 相似文献
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Sorption and pervaporation of benzene/cyclohexane mixtures were studied by using poly(vinyl chloride) (PVC) polymer. The effects of composition of benzene/cyclohexane mixture and temperature on sorption and pervaporation characteristics were determined at 30, 40, and 50 °C for the membranes containing 8 wt% PVC polymer. Liquid feed composition effects on the flux and the selectivity were determined for two different membranes at 30 °C. The membranes that were prepared from the solutions containing 4 wt% and 8 wt% PVC polymer have thicknesses of 30 μm and 50 μm, respectively. Membrane thickness changes with polymer content as expected. Total sorption increased with increasing concentration of benzene. Increasing the concentration of benzene resulted in increasing flux as well as decreasing selectivity also. Fluxes were increased and selectivity decreased with increasing temperature. The selectivity was not affected significantly with varying amounts of polymer in the casting solution but the flux decreased with increasing amount of polymer in the casting solution. 相似文献
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《分离科学与技术》2012,47(16):2298-2307
Polyvinyl alcohol (PVOH) has been chemically modified by polymerizing hydroxyethylmethacrylate (HEMA) in aqueous solution of PVOH and finally crosslinking PVOH with glutaraldehyde to produce a semi-interpenetrating network (SIPN) membrane. Accordingly, three such SIPN membranes, namely SIPNI, SIPNII, and SIPNIII were synthesized with different weight ratio of PVOH: HEMA i.e., 1:0.25 (SIPNI), 1:0.50 (SIPNII), and 1:0.75 (SIPNIII). These SIPN membranes were used for pervaporative separation of methanol from its mixtures with toluene. The flux and methanol selectivity of these SIPN membranes were found to be much higher than conventional PVOH membrane crosslinked with glutaraldehyde. Among the three membranes, SIPNIII with 75 wt% HEMA incorporation shows optimum performance in terms of flux and methanol selectivity. The permeability of the membranes was also found to increase with increase in HEMA content in PVOH matrix. The novelty of the work lies in synthesis and characterization of a new kind of membrane and its potential for selective removal of methanol from its mixtures with toluene. 相似文献
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采用涂敷法制备了聚丙烯酸(PAA)-聚乙烯醇(PVA)共混膜,将其用于渗透汽化法分离甲醇(MeOH)-碳酸二甲酯(DMC)共沸物,考察了共混比例、热处理条件对甲醇分离性能的影响. 渗透汽化实验结果表明,随着热处理时间延长或热处理温度提高,分离因子先升高后降低,而渗透通量则逐渐减小;随着共混膜中PAA/PVA比例增加,分离因子先升高后降低,而渗透通量先减小后增大;当PAA/PVA质量比为7/3、热处理时间为60 min、热处理温度为150℃时,选择性最佳,在料液组成为70%(w) MeOH-30%(w) DMC及70℃的操作温度下,甲醇的分离因子为9.5(透过侧MeOH浓度为95.5%, w),渗透通量为360 g/(m2×h). 相似文献
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交联壳聚糖渗透蒸发膜的制备及其在偏二甲肼/水体系分离中的应用 总被引:1,自引:0,他引:1
采用壳聚糖为原料,聚酯无纺布为支撑层,用戊二醛交联制备了高选择性、高通量的交联壳聚糖渗透蒸发复合膜.考察了料液浓度、料液温度、膜厚等对偏二甲肼/水体系分离性能的影响.结果表明:在料液温度为10℃,膜厚度为25 μm,进料液中偏二甲肼的质量分数为50%时,改性复合膜的分离因子最高达到5.25,渗透通量可达167 g/(m... 相似文献
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Poly(vinyl alcohol)/polyacrylonitrile blend membranes were prepared to separate pyridine/water mixtures by pervaporation. The membranes were characterized by Fourier transform infrared spectroscopy and scanning electron microscopy. The effects of membrane composition, feed pyridine concentration, operating temperature, downstream pressure and ultrasound irradiation on the separation process were evaluated. The experimental results indicated that with increasing PVA mass ratio and operating temperature the permeate flux increased but the separation factor decreased, while with increasing feed concentration and downstream pressure the separation factor increased and the permeate flux decreased. It was observed that Ultrasound irradiation enhanced the permeate flux. 相似文献
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《分离科学与技术》2012,47(11):1699-1708
Hydroxy terminated polybutadiene (HTPB)-based polyurethaneurea membranes with and without cross-linkage were synthesized and first used as membrane material to separate p-/o-xylene mixtures by pervaporation. Compared with HTPB-PU (without cross-linkage) membranes, HTPB-DVB-PU (cross-linked HTPB-PU with divinyl benzene) membranes demonstrated a lower degree of swelling in xylene isomer solutions and noticeable improved separation factor of p-/o-xylene. On the other hand, the amount of p-xylene adsorbed in HTPB-DVB-PU membranes increased significantly rather than that of o-xylene. While the separation factor of p-/o-xylene increased but the total flux decreased with increasing DVB content, which can be ascribed to the improved chemical structure and more homogeneous chain structures of the HTPB-DVB-PU membranes. The p-xylene normalized permeation rate and separation factor of p-/o-xylene of HTPB-DVB-PU membrane reached 2.70 kgµm/m2h and 2.23, respectively, at a feed concentration of 10 wt% p-xylene at 30°C. 相似文献
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Mukund G. Mali Veeresh T. Magalad Gavisiddappa S. Gokavi Tejraj M. Aminabhavi K. V. S. N. Raju 《应用聚合物科学杂志》2011,121(2):711-719
Mixed matrix membranes of poly(vinyl alcohol) and poly(vinyl pyrrilidone) blends were prepared by loading with phosphomolybdic acid (PMA) and their pervaporation (PV) properties were investigated for the PV separation of isopropanol. Membrane performance shown a dependence on the extent of PMA loading. The 4 wt % PMA‐loaded blend membrane had the highest separation factor of 29991, which declined considerably at higher loading. The flux of 4 wt % PMA‐loaded membrane was lower than that of nascent blend membrane. Feed water composition and temperature influenced the PV performance. Solubility selectivity was higher than diffusion selectivity. Degree of swelling was smaller after PMA loading exhibiting better separation ability. The PV results were analyzed using the Flory‐Huggins theory and sorption was dominated by Langmuir's mode. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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《分离科学与技术》2012,47(11):2483-2499
Abstract The selective removal of water from ethanol through pervaporation was demonstrated in a microchannel device using a commercial membrane. Photolithography and dry etching techniques were employed for fabrication of the microseparator with hydraulic diameters of 30 µm to 80 µm. Experiments conducted at 90°C and 2–3 Torr, with Reynolds Numbers ranging from 8 to 91, resulted in an average water and ethanol permeance of 1.2×10?3 and 8×10?5 cm3/cm2 · s · cmHg respectively. A mass transfer analysis involving Sherwood correlations was used to calculate the theoretical boundary layer resistance. The comparison of overall mass transfer coefficient with the boundary layer coefficients suggests that the membrane was the dominant resistance for this system. 相似文献
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Several pervaporation membranes, cellulose acetate (CA), polyvinylbutyral (PVB), poly(MMA-co-AA), MMA-AA-BA, CA/PVB blend and CA/poly(MMA-co-AA) blend, were prepared, and their pervaporation properties were evaluated by separation of methanol/C5 or methanol/MTBE (methyl tert-butyl ether). The results shows that the CA composite membrane has a high separation performance (flux Jmenthanol =350g.m-2.h-1 and separation factor a > 400) for methanol/C5 mixtures, and the pervaporation characteristics of MMA-AA-BA copolymer membranes changes with the ratio of copolymer. For CA/poly(MMA-co-AA) blend membrane, the pervaporation performance is improved in comparison with CA or poly(MMA-co-AA) membrane. From the experiment of CA/PVB blend membranes for methanol/MTBE mixture, it is found that the compatibility of blends may affect the separation features of blend membrane. 相似文献
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Several pervaporation membranes, cellulose acetate (CA), polyvinylbutyral (PVB), poly(MMA-co-AA),MMA-AA-BA, CA/PVB blend and CA/poly(MMA-co-AA) blend, were prepared, and their pervaporation properties were evaluated by separation of methanol/C5 or methanol/MTBE (methyl tert-butyl ether). The results shows that the CA composite membrane has a high separation performance (flux Jmethanol = 350 g.m-2.h-1 and separation factor α>400) for methanol/C5 mixtures, and the pervaporation characteristics of MMA-AA-BA copolymer membranes changes with the ratio of copolymer. For CA/poly(MMA-co-AA) blend membrane, the pervaporation performance is improved in comparison with CA or poly(MMA-co-AA) membrane. From the experiment of CA/PVB blend membranes for methanol/MTBE mixture, it is found that the compatibility of blends may affect the separation features of blend membrane. 相似文献
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《分离科学与技术》2012,47(4):627-646
Abstract In this study permeation and separation characteristics of dimethylformamide (DMF)/water mixtures were investigated by pervaporation (PV), vapor permeation (VP), and vapor permeation with temperature difference (TDVP) methods using alginate membranes crosslinked with calcium chloride. The effects of membrane thickness (30–90 µm), feed composition (0–100 wt%), operating temperature (30–50°C) on the permeation rates and separation factors were investigated. The permeation rate was found to be inversely proportional to the membrane thickness whereas separation factor increased as the membrane thickness was increased. It was observed that the permeation rates in VP and TDVP were lower than in PV however the highest separation factors were obtained with TDVP method. Alginate membranes gave permeation rates of 0.97–1.2 kg/m2 h and separation factors of 17–63 depending on the operation conditions and the method. In addition, sorption‐diffusion properties of the alginate membranes were investigated at the operating temperature and the feed composition. It was found that the sorption selectivity was dominant factor for the separating of DMF/water mixtures. 相似文献
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《分离科学与技术》2012,47(3):429-437
Pervaporation and vapor permeation are membrane-based processes proposed as alternatives to conventional separation technologies. Applications range from organic solvent removal from water, ethanol, or butanol recovery from fermentation broths, solvent/biofuel dehydration to meet dryness specifications, and organic-organic separations such as the removal of sulfur compounds from gasoline. Unlike membrane filtration processes, which rely on an applied liquid pressure gradient and size sieving to accomplish a separation, pervaporation and vapor permeation separate compounds based on a chemical activity driving force and the sorption and diffusion of the compounds through the membrane. These properties enable the separation of even miscible liquid mixtures. 相似文献