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1.
A unipolar charger with multiple discharging wires has been developed and investigated to enhance the extrinsic charging efficiency of nanoparticles by using sheath air near the wall of the charger. The applied voltage of the charger ranged from +4.0 to +10 kV, corresponding to corona current from 0.02 to 119.63 μA. Monodisperse NaCl particles of 10 ~ 50 nm and Ag particles of 2.5 ~ 10 nm in diameter were produced to test the performance of the charger with multiple discharging wires and to investigate the particle loss at different sheath flow rates, corona voltages and sheath air velocities. Results showed that the optimal efficiency in the charger was obtained at +9 kV applied voltage, 10 L/min aerosol flow rate and 20 L/min sheath air flow rate. The extrinsic charging efficiency increased from 2.86% to 86.3% in the charger as the particle diameter increasing from 2.5 to 50 nm. The TDMA (tandem-differential mobility analyzer) technique was used to investigate the charge distribution, and the charge distributions in the exit were obtained at the optimal operating condition.  相似文献   

2.
A single-wire corona unipolar charger with radial sheath air was proposed to enhance the nanoparticle charging efficiency. The charger consists of an insulated Teflon tube (inner diameter = 6.35 mm) with a 6 mm-long grounded porous metal tube placed at its center from which radial sheath air is introduced, and a discharge gold wire of 50 μm in the outer diameter and 6 mm in the effective length. The performance of the charger was evaluated and optimized numerically. The effect of the position of the sheath air opening on reducing charged particle loss was found to be important and two designs were studied. In design 1, both ends of the 6 mm wide sheath air opening are aligned with the ends of the 6 mm-long discharge wire, while in design 2 the sheath air opening is shifted 2 mm toward the left of the leading edge of the wire. At the same operating condition, design 2 was found to have less electrostatic loss than design 1 because of its smaller deposition region for charged particles. Compared to two unipolar chargers with the highest extrinsic charging efficiency for particles smaller than 10 nm in diameter, design 2 operated at the applied voltage of +3.5 kV, aerosol flow rate of 0.5 L/min, and sheath airflow rate of 0.7 L/min has a comparable extrinsic charging efficiency of 17.2%–70.5% based on particle number for particles ranging from 2.5 to 10 nm in diameter.

Copyright 2013 American Association for Aerosol Research  相似文献   

3.
Aerosol instrument characterization and verification for nanometer-sized particles requires well-established generation and classification instruments. A precise size selection of sub-3-nm charged aerosol particles requires a differential mobility analyzer (DMA), specially designed for the sub-3-nm size range. In this study, a Herrmann-type high-resolution DMA developed at Yale University was characterized in various operation conditions. A relation between sheath flow rate and tetraheptylammonium ion (C28H60N+, THA+, 1.47 nm, mobility equivalent diameter) was established. The maximum particle size that the DMA was able to classify was 2.9 nm with the highest sheath flow rate of 1427 liters per minute (Lpm), and 6.5 nm with the lowest stable sheath flow rate of 215 Lpm, restricted by the maximum and minimum flow rates provided by our blower. Resolution and transmission of DMA are reported for tetrapropylammonium (C12H28N+, TPA+, 1.16 nm), THA+, and THA2Br+ (1.78 nm) ions measured with two different central electrodes and five different sheath flow rates. The transmission varied between 0.01 and 0.22, and the resolution varied between 10.8 and 51.9, depending on the operation conditions.

Copyright © 2016 American Association for Aerosol Research  相似文献   


4.
A butanol-type ultrafine condensation particle counter (UCPC, Model 3776, TSI, Inc., Shoreview, MN, USA), which can achieve a 50% detection efficiency diameter (d50) of 2.5 nm using a capillary-sheath structure, was modified and tested in the laboratory for airborne measurements. The aerosol flow rate through the capillary is a key factor affecting the quantification of aerosol particle number concentrations. A pressure-dependent correction factor for the aerosol flow rate was determined using a newly added mass flow meter for the sheath flow and the external calibration system. The effect of particle coincidence in the optical sensing volume was evaluated using an aerosol electrometer (AE, Model 3068B, TSI, Inc.) as a reference. An additional correction factor for the coincidence effect was derived to improve the quantification accuracy at higher concentrations. The particle detection efficiency relative to the AE was measured for mobility diameters of 3.1–50 nm and inlet absolute pressures of 101–40 kPa. The pressure dependence of the d50 value, asymptotic detection efficiency, and shape of the particle detection efficiency curve is discussed, along with simple theoretical calculations for the diffusion loss of particles and the butanol saturation ratio in the condenser.

© 2017 American Association for Aerosol Science  相似文献   


5.
Presented is a laminar-flow, water-based condensation particle counter capable of particle detection near 1 nm. This instrument employs a three-stage, laminar-flow growth tube with a “moderator” stage that reduces the temperature and water content of the output flow without reducing the peak supersaturation, and makes feasible operation at the large temperature differences necessary for achieving high supersaturations. The instrument has an aerosol flow of 0.3 L/min, and does not use a filtered sheath flow. It is referred to as a “versatile” water condensation particle counter, or vWCPC, as operating temperatures can be adjusted in accordance with the cut-point desired. When operated with wall temperatures of ~2°C, >90°C, and ~22°C for the three stages, respectively, the vWCPC detects particles generated from a heated nichrome wire with a 50% efficiency cut-point near 1.6 nm mobility diameter. At these operating temperatures, it also detects 10–20% of large molecular ions formed from passing filtered ambient air through a bipolar ion source. Decreasing the temperature difference between the first two stages, with the first and second stages operated at 10 and 90°C, respectively, essentially eliminates the response to charger ions, and raises the 50% efficiency cut-point for the nichrome wire particles to 1.9 nm mobility diameter. The time response, as measured by rapid removal of an inlet filter, yields a characteristic time constant of 195 ms.

Copyright © 2017 American Association for Aerosol Research  相似文献   


6.
Electroaerodynamic (EAD) jet printing, where aerodynamic force is coupled with electrostatic force in order to obtain a wide range of controlled pattern sizes, is introduced. Charged and sheathed aerosol particles yield a high deposition rate even at low velocity owing to the force of their electrostatic attraction to the substrate. In this study, two coaxial nozzles (inner diameters of 6 mm and 100 μm) were designed and tested theoretically and experimentally in order to observe the effects of electrostatic force, particle size, and air flow rate on particle trajectory and dot pattern size. A higher sheath air flow rate (higher Stokes number) caused the aerosol jet stream to be focused. For Stokes numbers higher than 1, the effect of applied voltage on pattern size was less than that of the sheath air flow rate. However, for Stokes number lower than 1, the pattern size was affected by both the applied voltage and the sheath air flow rate. After incorporating all data, the diameter of the particle deposition area (Wp) was expressed as a function of nozzle diameter (W), sheath air flow rate (Qsheath), aerosol flow rate (Qaerosol), Stokes number (Stk), and Electrostatic number (Es). Three different equations were obtained for Stk < 1, for 1 ≤ Stk < 5, and for Stk ≥ 5, respectively. These equations would be used to predict pattern width for given conditions of aerosol and sheath flow rates, particle size, electric field, and nozzle size.

Copyright 2013 American Association for Aerosol Research  相似文献   

7.
A single-wire corona unipolar aerosol charger with a sheath air to avoid particle loss was designed and experimental charging efficiencies were obtained at a fixed aerosol flow rate of 1 L/min using monodisperse silver nanoparticles of 2.5 to 20 nm in diameter. The charger has a cylindrical casing of 30 mm in inner diameter in which a gold wire of 50 μm in diameter and 2 mm in length is used as the discharge electrode. A two-dimensional (2-D) numerical model was developed to predict nanoparticle charging efficiency in the unipolar charger. Laminar flow field was solved by using the Semi-Implicit Method for Pressure Linked Equations (SIMPLER method), while electric potential and ion concentration fields were solved on the basis of Poisson and convection–diffusion equations, respectively. The charged particle concentration fields and charging efficiencies were then calculated on the basis of the convection–diffusion equation in which ion–particle combination coefficient was calculated by Fuchs diffusion charging theory (Fuchs, N. A. (1963 Fuchs, N. A. 1963. On the Stationary Charge Distribution on Aerosol Particles in a Bipolar Ionic Atmosphere. Geophys. Pura. Appl., 56: 185193. [Crossref] [Google Scholar]). On the Stationary Charge Distribution on Aerosol Particles in a Bipolar Ionic Atmosphere. Geophys. Pura. Appl., 56:185–193). Good agreement between predicted and experimental extrinsic charging efficiencies was obtained. Numerical results showed the advantage of using sheath air to minimize charged particle loss and indicated the location where major charged particle loss occurred. It is expected that the present model can be used to facilitate the design of more efficient corona-wire unipolar charger in the future.  相似文献   

8.
The AIST-inkjet aerosol generator (IAG) can generate highly monodisperse solid or liquid aerosol particles in the particle diameter range from 0.3 to 20 μm at precisely known particle generation rates. The device has been developed for evaluating the counting efficiencies of optical and condensation particle counters. Particle generation efficiency of the IAG is defined as the number of aerosol particles generated by one voltage pulse sent to an inkjet head. The 95% confidence interval of the efficiency were 0.998 ± 0.006 within the 0.4 to 10 μm particle diameter range. The efficiencies remained close to unity when the droplet generation rates were within 20–500 s?1 and 100–900 s?1 using ultrapure-water and isopropyl alcohol (IPA) as the solvent of the inkjet solution, respectively. The operating aerosol flowrate range of the IAG is currently 0.5 and 1.0 L/min. The coefficients of variations (C.V.) of the size distributions were 2 to 3% indicating the generated particles were highly monodisperse. The generated particle sizes were defined as the volume equivalent diameter, Dve. The uncertainty analysis on the factors affecting Dve indicated that 95% confidence interval of the Dve is expected to be ±5%. The uncertainty of Dve was entirely caused by the uncertainty of the average mass of a droplet. The reproducibility of particle sizes within 0.5 to 10 μm was evaluated using an aerodynamic particle sizer. The C.V. of the measured particle sizes were less than 6% and 4% when NaCl particles and ionic liquid droplets were generated, respectively.

Copyright 2014 American Association for Aerosol Research  相似文献   

9.
A postplasma neutralizer for submicron particles size measurements by mobility analysis has been evaluated. Bipolar ion currents have been measured downstream a dielectric barrier discharge (DBD) to estimate the ion fluxes at the inlet of charging volume and the ni·τ product that define the theoretical maximal concentration that can be neutralized. Charge distributions were measured versus DBD voltage, aerosol diameter and concentration for monodisperse aerosols. It is confirmed that the charge distribution of particles depends on the ratio of initial positive and negative ion currents controlled by the DBD voltage leading to a tuneable mean charge of aerosol in this post-DBD bipolar charger. As expected from Gunn's law, the mean charge and the variance are proportional to particle diameter above 50 nm and independent of the aerosol concentration. The size distributions measured with 85Kr and post-DBD neutralizer present the same modal diameters and a maximal overestimation of the total concentration of 10%, for aerosol from 15 to 730 nm with concentrations up to 6 × 1012 m?3. This post-DBD bipolar charger can be used for submicron aerosol neutralization and thus for scanning mobility particle sizer size distribution measurements in air as well as in nitrogen to suppress ozone downstream DBD.

Copyright © 2017 American Association for Aerosol Research  相似文献   

10.
Here, we present a concept of a personal electrostatic bioaerosol sampler (PEBS), which is an open channel collector consisting of a novel wire-to-wire particle charger and a collection section housing a double-sided and removable metal collection plate and two quarter-cylinder ground electrodes. The charger consists of a tungsten wire (25.4 mm long and 0.076 mm in diameter) connected to high voltage and positioned in the center of the charging section (a cylinder 50.8 mm long and 25.4 mm in diameter); a ring of stainless steel wire 0.381 mm in diameter surrounds the hot electrode at its midpoint and is grounded. The newly designed wire-to-wire charger produces lower ozone concentrations compared to traditional wire-to-plate or wire-to-cylinder charger designs. The particles captured on the collection plate are easily eluted using water or other fluids. The sampler was iteratively optimized for optimum charging and collection voltages, and collection electrode geometry. When tested with polystyrene latex particles ranging from 0.026 µm to 3.1 µm in diameter and 10 L/min collection flow rate, the sampler's collection efficiency was approximately 70%–80% at charging and collection voltages of +5.5 kV and ?7 kV, respectively. The PEBS showed this collection efficiency at sampling times ranging from 10 min to 4 h. Preliminary tests with Bacillus atrophaeus bacterial cells and fungal spores of Penicillium chrysogenum showed similar collection efficiency. The use of a unique wire-to-wire charger resulted in ozone production below 10 ppb. Due to low ozone emissions, this sampler will allow maintaining desirable physiological characteristics of the collected bioaerosols, leading to a more accurate sample analysis.

© 2017 American Association for Aerosol Research  相似文献   

11.
Abstract

Charged particles can be classified according to their electrical mobility using electrical methods. These particles are often transported against an adverse electric field from a region of high electric potential to a grounded region, e.g., in the aerosol sample outlet of a differential mobility analyzer (DMA). Electrostatic losses due to the adverse electric field can be reduced using a tube made of electrostatic dissipative (ESD) materials. The transmission of charged particles through an adverse axial electric field inside the ESD tube is studied considering particle losses due to electrostatic migration and Brownian motion. The electric field inside the ESD tube is solved analytically. Assuming Hagen-Poiseuille flow, plug flow, or turbulent flow, the transmission efficiency of the charged particles is evaluated using both a simplified analytical model and Monte-Carlo simulation. Transmission efficiencies of 1.48-nm ions are measured at various flow rates and for various tube lengths. The measured transmission efficiencies agree with the results from both the analytical model and Monte-Carlo simulation. The ideal tube length for relatively high transmission efficiencies is discussed. Both the analytical model and Monte-Carlo simulation show that the recommended tube length for the test DMA is longer than a threshold value corresponding to an adverse particle electrostatic migration velocity of less than ~20% of the average air flow velocity. Based on these findings, the sample outlet of a miniature cylindrical DMA is improved using an ESD tube. The measured penetration efficiency of 1.48-nm ions at a sheath flow rate of 25?L min?1 and an aerosol flow rate of 1.5?L min?1 is improved by 50%.

Copyright © 2019 American Association for Aerosol Research  相似文献   

12.
A corona-based unipolar aerosol charger has been constructed, and its performance has been systematically evaluated. The prototype consists of completely separated corona ionization and charging chambers. With this configuration the electrostatic loss of charged particles is eliminated, and particle loss by diffusion and the space charge effect is minimized by the angular injection of the ionizer flow and the rapid exit of charged particles. The charger performance was optimized by varying different operational parameters, i.e., total and ionizer flowrates, and ion concentration. It was found that operation with one corona ionizer gave higher extrinsic charging efficiency than operation with two ionizers. The corona-discharge current has negligible effect on the charging performance. Operating the charger at a total flowrate of 5 lpm, with 1.0 lpm flow in each of the two ionizers, gave the highest extrinsic charging efficiency. Further, the performance of prototype charger was not compromised even at a total flowrate of 10 lpm. The charger provides higher extrinsic charging efficiency than other corona-based unipolar chargers. Extrinsic charge distributions for particles of different sizes were at last measured by the tandem-DMA technique.  相似文献   

13.
Classifying sub-3?nm particles effectively with relatively high penetration efficiencies and sizing resolutions is important for atmospheric new particle formation studies. A high-resolution supercritical differential mobility analyzer (half-mini DMA) was recently improved to classify aerosols at a sheath flow rate less than 100?L/min. In this study, we characterized the transfer functions, the penetration efficiencies, and the sizing resolution of the new half-mini DMA at the aerosol flow rate of 2.5–10?L/min and the sheath flow rate of 25–250?L/min using tetra-alkyl ammonium ions and tungsten oxide particles. The transfer functions of the new half-mini DMA at an aerosol flow rate lower than 5?L/min and a sheath flow rate lower than 150?L/min agree well with predictions using a theoretical diffusing transfer function. The penetration efficiencies can be approximated using an empirical formula. When classifying 1.48?nm molecular ions at an aerosol-to-sheath flow ratio of 5/50?L/min, the penetration efficiency, the sizing resolution, and the multiplicative broadening factor of the new half-mini DMA are 0.18, 6.8, and 1.11, respectively. Compared to other sub-3?nm DMAs applied in atmospheric measurements (e.g. the mini-cyDMA, the TSI DMA 3086, the TSI nanoDMA 3085, and the Grimm S-DMA), the new half-mini DMA characterized in this study is able to classify particles at higher aerosol and sheath flow rates, leading to a higher sizing resolution at the same aerosol-to-sheath flow ratio. Accordingly, the new half-mini DMA can reduce the uncertainties in atmospheric new particle formation measurement if coupled with an aerosol detector that could work at the corresponding high aerosol flow rate.

© 2018 American Association for Aerosol Research  相似文献   

14.
We have developed a miniature disk electrostatic aerosol classifier (mini-disk EAC) for use in electrical mobility-based personal nanoparticle instrumentation for measurement of personal exposures to nanoaerosols. The prototype consists of two parallel disk electrodes separated by an electrically insulating spacer, to create the particle classification zone. The aerosol enters and exits the classification zone along the bottom disk electrode. An additional, particle-free sheath flow is used to improve the measurement resolution. The transmission measurement of the mini-disk EAC for DMA-classified particles shows that particle losses due to diffusion and electrical image forces were low. The particle penetration at 10 nm diameter (the designed lower size limit for the classifier) was 67% when the prototype was operated at the aerosol and sheath flow rates of 0.5 and 1.0 l min?1, respectively. The performance of the mini-disk EAC was experimentally characterized using the particle cutoff curves that describe their penetration through the classifier as a function of applied voltage across the two disk electrodes. Based on the measurement of particle penetration at different aerosol and sheath flows, it was found that the aerosol and sheath flow rates of 0.5 and 1.5 l min?1 were optimal for classifier operation. Finally, a semi-empirical model was also developed to describe the transfer function of the mini-disk EAC for non-diffusive particles.  相似文献   

15.
The objective of this work is to understand the charging dynamics of metal nanoparticles under wavelength-selected UV irradiation, with a particular focus on the effect of particle structure on the quantum yield. We employed an ion mobility analysis technique to measure the size-resolved single charging efficiency of structure-controlled silver nanoparticles (spheres vs. aggregates) in the mobility diameter (D m) range of 10 ~ 100 nm. We found that the measured particle charging efficiency follows D 2 m dependence for both spherical and aggregate particles. Based on the measured charging efficiency and calculated particle photon absorption cross section, we are also able to determine the mobility size dependence of photoelectric quantum yield for both spheres and aggregates. The quantum yield of spheres is a constant for larger particles (50 nm or larger) but significantly enhanced as particle size decreases. The quantum yield of aggregates is shown to be particle structure dependent and does not behave as a simple summation of individual primary particles. The aggregate particles have higher quantum yield compared with spheres of the same mobility size but is offset by the lower photon absorption cross section, and thus overall charging efficiency of aggregates is lower than spheres of the same mobility size.

© 2013 American Association for Aerosol Research  相似文献   

16.
We developed an improved particle measurement spectroscopic technique, real-time laser transmission spectroscopy (RTLTS), to detect the number-weighted distribution of particles in real time. The measurement system used a deuterium–tungsten lamp for the light source and a spectrometer as the detector. The operating wavelength range was 300–810 nm. To obtain a physically reasonable number concentration from the experimental results, a sequential regularization method was used during the calculations. To verify the feasibility and reliability of RTLTS, the number-weighted distribution of polystyrene particle suspensions was determined over diameters ranging from 0.005 to 2.000 μm in 0.005-μm increments. The measured concentration error was 0.67–32.67%. A mean diameter of the smallest particle we had detected was 0.09 μm, with a 16% oversizing. The measurable concentration range was ~108 #/cc to ~1011 #/cc for 0.895-μm-diameter particles. The measurable concentration range could be adjusted simply by changing the system configuration. This technique is available for both waterborne and airborne particles.

Copyright 2013 American Association for Aerosol Research  相似文献   

17.
A modified version of the previously developed tubular particle-removal device based on the UV/photoelectron method (Shimada et al. (1997) J. Aerosol Sci. 28, 649) is manufactured to investigate removal efficiency of aerosol particles suspended in air at a reduced pressure down to 20 torr. The present measurements with monodisperse particles of 0.458 μm in diameter show the dependence of the removal efficiency on pressure, flow rate and electric field in the electrostatic precipitation device. To predict the removal efficiency, a theoretical analysis for the particle collection processes in the precipitator is made, in which particle charging by negative ions, and particle transport by air flow, diffusion and electrical migration are numerically calculated taking into account the effects of reduced pressure. The calculated results reproduce the measured removal efficiencies well. It is found in the calculation that the Fuchs’ approach to ionic particle charging needs modification to predict charging of highly charged particles by ions of the same polarity. It is also demonstrated that the removal efficiency is increased to 100% when the precipitator is equipped with an additional set of electrodes that collects charged particles.  相似文献   

18.
In this study we investigated the charging characteristics of a novel aerosol neutralizer (Surface-discharge Microplasma Aerosol Charger; SMAC) based on the dielectric barrier discharging. The surface discharge was induced by supplying positive and negative DC pulses with a pair of micro-structured electrodes. We confirmed the occurrence of the surface discharge by measuring the microdischarge current, and evaluated the charging performance of the SMAC as a particle neutralizer by measuring the penetration efficiency, neutralizing probability, and charge distribution for particles in the size range of 10–200 nm. The SMAC was found to obtain a particle penetration exceeding 90% for the whole particle size range. The neutral fraction obtained by the SMAC showed good agreement with a bipolar diffusion charging theory and the fraction obtained by an 241Am radioactive source when the SMAC was optimized for aerosol neutralization with the offset voltage control. The charge distributions of negatively and positively charged particles by the SMAC and the 241Am neutralizer were in good agreement also. The charge balance of positive and negative particles obtained by the SMAC was effectively controlled by adjusting the offset voltage on each electrode. This is the first study to demonstrate the successful use of dielectric barrier surface discharge to bring particles of 10–200 nm to an equilibrium charging state in a controllable manner.  相似文献   

19.
《分离科学与技术》2012,47(3):299-309
A numerical methodology based on the Lagrangian approach is outlined to study the performance of a select class of electrostatic aerosol separators. This modeling method is used to perform a parametric study on the efficiency of a wire-cylinder separator in separation of water aerosols from air. The geometry consists of an 80 µm diameter wire placed in the centerline of a 20 mm diameter cylinder. The work focuses on the effect of applied voltage (in the range of 4 to 8 kV), flow velocity (in the range of 0.3 to 1.5 m/s), flow temperature (in the range of 280 K to 320 K), and separator length (in the range of 0.05 to 0.15 m) on charging of water aerosols and on separator collection efficiency in laminar flow. The aerosols size ranges between 0.01–10 µm. The results of the study show that applied voltage, flow rate, and separator length affect the separation efficiency significantly, while the effect of flow temperature seems negligible.  相似文献   

20.
A low-flow miniature differential mobility analyzer (mDMA) has been developed for compact field-portable mobility spectrometers to classify the submicrometer aerosol. The mDMA was designed for an ultra-low aerosol flow rate of 0.05 L/min. At a sheath flow rate of 0.2 L/min, the mDMA's upper size limit was estimated to be about 921 nm. The mDMA has a classification zone of 2.54 cm long, an outer diameter of 2.54 cm, and an inner diameter of 1.778 cm. The design allows low-cost fabrication and easy assembly. Tandem DMA measurements were carried out to evaluate the performance of the mDMA. Its transfer function was described using Stolzenburg's model. The experimentally measured transfer function shows close agreement with the theory. The transmission efficiency was comparable to that of the Knutson–Whitby DMA for particles in the range of 10–1000 nm. The mobility resolution was comparable to that of the TSI 3085 nanoDMA at the same aerosol flow rate. The design features and performance of the mDMA make it suitable for compact field portable mobility size spectrometers for measurement of nanoparticles and submicrometer aerosol.  相似文献   

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