响应面法优化低脂甘薯脆片加工工艺

以红心甘薯为原料,优化低脂甘薯片生产过程中漂烫、热风干燥、油炸等关键工艺参数,以产品含油率和色差(L*值和b*值)为评价指标,并通过响应面优化确定最优的低脂甘薯片生产工艺。结果表明,较优漂烫工艺条件为:漂烫温度70 ℃,漂烫时间7 min;较优的热风干燥工艺条件为:热风干燥温度70 ℃,热风干燥时间40 min;最优油炸工艺条件为:预油炸温度149 ℃,预油炸时间98 s,二次油炸温度190 ℃,在该条件下测定含油率的平均值达(17.1±0.2)%。该工艺条件下制得的甘薯脆片含油率低于同类产品,外观亮黄,无焦糊现象。     

Physical and thermal properties of potato chips during vacuum frying

Vacuum frying (1.33 kPa), with the aid of a de-oiling mechanism, was used to produce low-fat potato chips.The kinetics of oil absorption and oil distribution in the potato chips was studied so that effectiveness of the de-oiling system could be established. Non-linear regression was used to fit the experimental data to the models used to describe oil absorption in potato chips with time.Moisture content, oil content, microstructure, diameter and thickness expansion, bulk density, true density, and porosity of chips fried at different temperatures (120, 130, and 140 °C) was performed to evaluate the effect of process temperature on the product. The convective heat transfer coefficient at the oil-chip interface was determined for the same temperature range.The final oil content of the potato chips was 0.072 ± 0.004, 0.062 ± 0.003, and 0.059 ± 0.003 g/g solid for frying temperatures of 120, 130, and 140 °C, respectively. These values are lower (80-87% less) than those found in the not de-oiled potato chips, which indicates that the de-oiling mechanism is crucial in vacuum frying processing. A significant difference (P < 0.05) was observed in oil content and oil distribution within temperatures. The rate of change in product quality attributes was greatly affected by temperature; however, the final values of moisture content, bulk density, true density, porosity, diameter shrinkage, and thickness expansion were not affected by temperature.During vacuum frying, the convective heat transfer coefficient changed considerably as frying progressed; moreover, it increased with temperature reaching a maximum between 2200 and 2650 W/m² K depending on frying temperature.     

Antioxidant efficiency of oregano during frying and storage of potato chips

The effect of oregano on the oxidative stability of cottonseed oil during frying of potato chips and on the storage stability of the produced chips was studied. The ground spice or an ethanol‐derived extract thereof was added to the oil at a concentration of 2 g l^?1 (dry basis) before frying. The results showed that both ground oregano and its ethanol‐derived extract decreased the rates of accumulation of conjugated dienes, polar compounds, polymerised triglycerides, dimeric triglycerides as well as p‐anisidine value (p‐AV) of the frying oil. The major decrease was observed in the accumulation of polymerised and dimeric triglycerides. The accumulation of oxidised triglycerides showed a low decrease with the addition of oregano, while the hydrolytic compounds formed during frying were not affected. No significant difference (at 95% significance level) between ground oregano and its ethanol‐derived extract was observed. The storage stability of potato chips removed from the fryer at various time intervals was estimated by the rates of increase in peroxide value and conjugated dienes of the oil absorbed in the chips. Both rates were depressed when oregano was added to the frying oil; the protective action of oregano extract was considerably greater (at 95% significance level) than that of ground oregano. Copyright © 2003 Society of Chemical Industry     

复合马铃薯片油炸工艺研究

以马铃薯淀粉和马铃薯全粉为主要原料,对复合马铃薯片的油炸工艺参数进行了研究。采用正交试验,确定了生产低含油量、低丙烯酰胺(AA)含量、高脆度复合薯片的最佳油炸工艺参数,即油炸前坯料的含水量控制在20%左右,含盐量2%左右,油温以160℃为佳,炸制时间为40 s,油炸薯片丙烯酰胺含量为0.28 mg/kg,在市售薯片基础上降低26.32%;含油量为23.36%,降低了1.47个百分点。     

马铃薯片煎炸条件对棕榈油品质的影响研究

通过一系列的实验及定量分析,探讨了不同的煎炸温度、煎炸棕榈油中杂质(薯渣)含量和单位质量棕榈油的煎炸薯片生产率对煎炸过程中棕榈油酸价变化的影响。实验结果表明:煎炸温度、单位质量棕榈油的煎炸薯片生产率和煎炸油中杂质的含量对于煎炸油的酸价变化均有着显著地影响(α≤0.1)。单位质量棕榈油的煎炸薯片生产率对煎炸油的酸价变化影响最为显著,其次为煎炸温度,煎炸油中杂质(薯渣)的含量影响相对最小。当煎炸温度为170℃,单位质量棕榈油的煎炸薯片生产率为80 g/(kg.h),杂质(薯渣)的含量为0.050%时,相同的煎炸时间内对煎炸棕榈油的酸价变化影响最小。     

Changes in oil and potato chips during frying

The effect of frying of potato chips (batch processing during 12 h) on the chemical characteristics and fatty acid composition of the used oil were determined. Samples of the fried oil and potato chips were taken at various time periods. The volatile carbonyl compounds of the aroma concentrate of each sample were isolated and their oxime derevatives were prepared and subsequently estimated by UV absorption for the total oximes and conjugated diene carbonyl oximes. The development of the volatile carbonyl compounds in both frying oil and fried potato chips was increased on continued frying. Concerning the frying oil this increase was found to be in coincident with the decrease in the linoleic and linolenic acid percent.     

Quality changes of edible oils during vacuum and atmospheric frying of potato chips

Demand for safe and nutritionally rich fried products is gaining a momentum among consumers, leading to the increased consumption of vacuum fried products. The impact of vacuum frying (VF)(110 °C, 40 kPa) on chemical composition of food, fatty acid profile, microstructure, oxidative stability and sensory attributes was assessed and differentiated with that of atmospheric frying(AF) (180 °C). The potato slices were fried in mustard and soyabean oil used repetitively for 25 h. The oil content of VF potato chips was lower (15.18%) than AF chips (18.98%), however water loss in AF chips was higher than VF chips by 1.63-fold. VF significantly prevented the PUFA degradation, minimizes transfatty acid (TFA) formation and maintain a low C18:2/C16:0 ratio as compared to AF. VF Chips fried in soyabean oil show an increase in TFA content from 2.15 to 2.63% and a decrease in PUFA from 51.57 to 45.16% as compared to AF chips where TFA content increased from 2.15 to 3.72% and PUFA shows a higher reduction from 51.57 to 37.69% at the end of 25 h of frying. This indicate that in AF, oil is safe for use upto 10 cycles of frying, while as in VF, the same oil can be used for upto 40 cycles of frying without quality deteoriation. Sensorial analysis revealed that VF chips retain a better colour, taste and flavour but were less crispy than that of AF chips. These findings validate the application of vacuum frying technology for the production of high-quality foods with lesser degradation of frying oil.Industrial relevanceFood manufacturers are now impelled by the health-conscious consumer base for the production of healthy food products. The toxic effect of foods fried in degraded oils on human health is now widely known and thus the production of safe fried foods is the need of hour globally. In this context, vacuum frying is the most feasible approach for the production of quality fried products retaining the natural colour, flavour, sensory and nutritional properties better than that of atmospheric frying. Vacuum frying causes the least degradation of fatty acid of the frying oil and the fried potatoes, producing healthy potato chips. Therefore, the oil used for vacuum frying have a greater shelf life and oxidative stability than atmospheric frying. However, the higher installation cost of vacuum fryer still limits its use in the street fried food market, where degradation of oil is more likely. Thus, for its widespread commercialisation in developing countries, steps should be taken both by government and manufacturing companies to reduce the installation costs.     

Effect of frying variables on French fry properties

This work focuses on the effect of frying variables (repeated frying, potato‐to‐oil ratio, potato distribution in the fryer, oil type and potato variety) on French fry properties (water content, oil content, crust thickness and shrinkage). Furthermore, the rate of change in French fry properties during a frying batch is investigated. The temperature was acquired in several positions within the oil and the potato. It was found that when repeated frying was conducted up to regulation limits for frying oil use, the examined French fry properties were not significantly affected. On the contrary, the potato‐to‐oil ratio, potato distribution and potato variety significantly affected the water content of French fries. The most significant changes occurred during the first 1–2 min of a frying batch. According to the temperature measurements, the crust‐core front continued to advance after this first frying period. However, there was no observable crust thickness increase; this was attributed to crust shrinkage.     

Vacuum frying of high-quality fruit and vegetable-based snacks

Sweet potato, green beans, Tommy Atkins mango, and blue potato were fried in a vacuum frying process at a temperature of 120-130 ± 1°C. Before frying, green beans and mango slices were soaked in a 50% maltodextrine 0.15% citric acid solution. The products were also fried in a traditional (atmospheric pressure) fryer at 160-165 ± 1°C for 4 min. A 30-member consumer panel rated the sensory quality of both types of fried snacks using a 1-9 hedonic scale. Compared with traditional frying, oil content of vacuum-fried sweet-potato chips and green beans was 24% and 16% lower, respectively. Blue potato and mango chips had 6% and 5% more oil, respectively, than the traditional-fried samples. Anthocyanin (mg/100 g d.b.) of vacuum-fried blue potato chips was 60% higher. Final total carotenoids (mg/g d.b.) were higher by 18% for green beans, 19% for mango chips, and by 51% for sweet-potato chips. Sensory panelists overwhelmingly preferred (p < 0.05) the vacuum-fried products for color, texture, taste, and overall quality. Most of the products retained or accentuated their original colors when fried under vacuum. The traditional-fried products showed excessive darkening and scorching. These results support the applicability of vacuum frying technology to provide high-quality fruit and vegetable snacks.     

Use of natural antioxidants in refined palm olein during repeated deep-fat frying

An optimization study on the use of oleoresin rosemary extract, sage extract and citric acid added into refined, bleached and deodorized (RBD) palm olein before deep-fat frying of potato chips was performed using a constrained mixture design. Results revealed that the use of these natural antioxidants could improve the sensory acceptability of potato chips during a 5-day repeated deep-fat frying. All three antioxidants significantly (P<0.05) improved the sensory characteristics, including appearance, taste, crispiness, odor and overall acceptability. After day 5 of frying, the most acceptable fried potato chips were those fried in oil containing a combination of 0.059% oleoresin rosemary extract, 0.063% sage extract and 0.028% citric acid. The natural antioxidants significantly (P<0.05) lowered the rate of oxidation of oil during deep-fat frying and contributed to measured sensory acceptability of fried potato chips.     

油炸马铃薯片中丙烯酰胺形成的影响因素的研究

丙烯酰胺是富含碳水化合物和氨基酸的食品经高温加热发生美拉德反应而产生的,但有关影响丙烯酰胺形成因素的研究却较少。探讨了油炸温度、原料中还原糖和氨基酸含量、鲜薯切片浸泡液的柠檬酸浓度、油炸前薯片的水分含量及抗氧化剂和油的使用时间对丙烯酰胺形成的影响。结果表明:原料中还原糖和氨基酸含量越高,产品中生成的丙烯酰胺就越多;油炸温度越高,产品中丙烯酰胺含量也相应越高;浸泡液柠檬酸浓度越大,产品中丙烯酰胺含量越低;而随着半成品中含水量的降低,产品中的丙烯酰胺含量也逐渐减少;在油中添加不同浓度的BHT和TBHQ以及采用使用时间不同的油,对加工出来的薯片之间丙烯酰胺含量没有显著的影响。     

Two-stage frying process for high-quality sweet-potato chips

Vacuum frying (1.33 kPa), with the aid of a de-oiling mechanism, was used to produce low-fat sweet potato chips. The kinetics of oil absorption and oil distribution in the chips (total, internal, and surface oil content) was studied so that effectiveness of the de-oiling system could be established. Product quality attributes (PQAs) such as moisture content, oil content, diameter shrinkage, and thickness expansion, as well as, color, texture, bulk density, true density, and porosity of chips fried at different temperatures (120, 130, and 140 °C) was performed to evaluate the effect of process temperature on the product.     

Mechanisms of oil uptake during deep frying and applications of predrying and hydrocolloids in reducing fat content of chips

Deep frying resulting in high-fat content is extensively used in the food industries and domestic households, and becoming an integral diet globally. The physical and chemical changes and oil uptake contributes to the unique taste and texture of fried food. Consumption of food high in fat is a health concern due to the increasing rate of obesity and cardiovascular diseases. Consumer awareness has led food industries to aim at fat reduction while maintaining the organoleptic properties of fried foods. This article reviews recent findings in reducing fat content emphasising on pretreatments. Modification of product surface was proven to lower fat content, reducing moisture content by 10% after predrying results in 54% fat reduction, while hydrocolloids coating in potato chips reduces fat content by 57% after deep frying. Although current technology, vacuum frying and air frying have a promising result in using less oil, but the initial cost is high.     

Oxidative stability of potato chips: effect of frying oil type,temperature and antioxidants

The effect of type of frying oil and temperature on the oxidative stability of potato chips during storage was studied. Cottonseed oil, soybean oil, olive kernel oil and palmolein were used as frying media. The chips were packaged in metallized cellophane bags and incubated at 63 °C. At definite time intervals the absorbed oil was extracted and analyzed for peroxide value, Totox number and conjugated diene content. Olive kernel oil and palmolein absorbed into the chips showed better stability, whereas soybean oil presented the higher oxidation rate. Frying temperature (170, 180 or 190 °C) did not affect the oxidation rate during storage, with the exception of conjugated diene formation which was greater for chips fried at 190 °C. Ground oregano or oregano extract, obtained by petroleum ether extraction, were added to the chips as antioxidants. Both retarded significantly the oxidation rate of the oil absorbed into the chips, with results comparable to tertiary butylhydroquinone (TBHQ) during storage at 63 °C for 7 days; however TBHQ proved significantly more effective after that time. © 1999 Society of Chemical Industry     

Comparative study of physical and sensory properties of pre-treated potato slices during vacuum and atmospheric frying

The objective of this research was to study the effect of different processing conditions on physical and sensory properties of potato chips. Potato slices of Desirée and Panda varieties (diameter: 30 mm; thickness: 3 mm) were pre-treated in the following ways: (i) control or unblanched slices without pre-drying; (ii) blanched slices in hot water at 85 °C for 3.5 min and air-dried at 60 °C until a final moisture content of ∼0.6 kg water/kg dry solid; (iii) control slices soaked in a 3.5 kg/m³ sodium metabisulphite solution at 20 °C for 3 min and pH adjusted to 3. Pre-treated slices were fried at 120 and 140 °C under vacuum conditions (5.37 kPa, absolute pressure) and under atmospheric pressure until they reached a final moisture content of ∼1.8 kg water/100 kg (wet basis). An experimental design (3 × 2³) was used to analyze the effect of pre-treatment, potato variety, type of frying and frying temperature over the following responses: oil content, instrumental color and texture and sensory evaluation. Vacuum frying increased significantly (p < 0.05) oil content and decreased instrumental color and textural parameters. Sensory attributes, flavor quality and overall quality, were significantly improved using vacuum frying. The higher frying temperature (140 °C) increased ΔE, maximum breaking force, hardness and crispness and decreased L^* and b^* values. On the other hand, Panda potato variety improved the color of the product. A great improvement on color parameters was obtained using sulphited potato slices instead of the other pre-treatments. Although, the better flavor was obtained for control potato chips, no significant differences were found for overall quality between control and sulphited potato chips. Significant correlations (p < 0.01) between sensory and instrumental responses were found.     

大豆油煎炸过程理化指标与煎炸时间相关性研究

针对食用植物油煎炸过程中理化指标是否可有效反映煎炸油品品质变化这一问题,以大豆油为煎炸油,薯条和鸡排为煎炸物质进行煎炸实验。随煎炸时间延长取不同程度煎炸油检测,研究酸值、羰基值、极性组分、p-茴香胺值、过氧化值和总氧化值等理化指标与煎炸时间相关性。结果表明:所研究理化指标中酸值、羰基值和极性组分3项指标与煎炸时间相关性较好,可有效反映油品变坏程度,p-茴香胺值、过氧化值和总氧化值相关性较差。     

The possibility of lowering oil content of potato chips by combining atmospheric frying with postfrying vacuum application

Four protocols involving the application of low pressures, either toward the end of frying or after frying, were investigated with the aim of lowering the oil content of potato chips. Protocol 1 involving frying at atmospheric pressure followed by a 3 min draining time constituted the control. Protocol 2 involved lowering of pressure to 13.33 kPa, 40 s before the end of frying, followed by draining for 3 min at the same pressure. Protocol 3 was the same as protocol 2, except that the pressure was lowered 3 s before the end of frying. Protocol 4 involved lowering the pressure to 13.33 kPa after the product was lifted from the oil and holding it at this value over the draining time of 3 min. Protocol 4 gave a product having the lowest oil content (37.12 g oil/100 g defatted dry matter), while protocol 2 gave the product with highest oil content (71.10 g oil/100 g defatted dry matter), followed by those obtained using protocols 1 and 3 (68.48 g oil/100 g defatted dry matter and 52.50 g oil/100 g defatted dry matter, respectively). Protocol 4 was further evaluated to study the effects of draining times and vacuum applied, and compared with the control. It was noted that over the modest range of pressures investigated, there was no significant effect of the vacuum applied on the oil content of the product. This study demonstrates that the oil content of potato chips can be lowered significantly by combining atmospheric frying with draining under vacuum.     

马铃薯片常压油炸工艺优化研究

对影响常压油炸马铃薯片品质的工艺参数进行了优化研究。结果表明,在柠檬酸溶液浓度为0.10%～0.25%、预干燥时间为10～40min和油炸温度为170～200℃的范围内,以薯片的丙烯酰胺含量、含油量和脆度为指标,常压油炸薯片的最佳工艺条件为:薯片切片采用柠檬酸溶液浓度为0.20%的柠檬酸水溶液浸泡后,于85℃预干燥30min,最后用180℃恒温油炸至熟。     

OPTICAL ASSESSMENT OF CORN OIL DETERIORATION DURING FRYING

The ultraviolet (UV), visible and near-infrared (NIR) absorption changes in corn oil were measured during processes simulating deep fat frying. Corn oil, maintained at 185C, was exposed to various treatments with nitrogen, air, water injection, air with water injection, and steam. Autoxidation due to a combination of air and high temperature in the simulated frying trials caused visible absorption changes between 400 and 580 nm as the oil deteriorated similar to those observed in potato frying experiments. These absorption changes were found to be associated with changes in an ultraviolet absorption band with a maximum near 270 nm. Second-derivative calibration equations developed at various visible and NIR absorption wavelengths successfully predicted the percentage of total polar materials (%TPM) which accumulated in the corn oil during simulated trials of autoxidation (R values from 0.93 to 0.98). Using spectral data from repetitive potato frying experiments, the predicted %TPM calculated with these equations correlated well with kinematic viscosity measurements (R values from 086 to 0.97).     

Modeling water loss and oil uptake during vacuum frying of pre-treated potato slices

The objective of this research was to determine the kinetics of water loss and oil uptake during frying of pre-treated potato slices under vacuum and atmospheric pressure. Potato slices (diameter: 30 mm; width: 3 mm) were pre-treated in the following ways: (i) raw potato slices “control”; (ii) control slices were blanched in hot water at 85 °C for 3.5 min; (iii) blanched slices were dried in hot air until reaching a moisture content of ∼0.6 g water/g dry basis. The slices were fried under vacuum (5.37 kPa, absolute pressure, at 120, 130 and 140 °C) and atmospheric conditions (at 180 °C). Two models based on the Fick's law were used to describe water loss: (i) with a constant effective diffusive coefficient; and (ii) with a variable effective diffusive coefficient. Oil uptake data were fitted to an empirical model, with a linear behavior for short times whereas the model was time independent for long times. The variable diffusivity model better fitted experimental water loss, giving values of effective diffusivity between 4.73 × 10⁻⁹ and 1.80 × 10⁻⁸ m²/s. The proposed model for the study of the kinetics of oil uptake fitted the experimental data properly. Control and blanched vacuum fried potato chips increased their final oil contents to 57.1% and 75.4% respectively, when compared with those fried at atmospheric pressure. However, the oil absorption of dried vacuum fried potato chips diminished by ∼30%.