Application assessment of high throughput flip chip assembly for ahigh lead-eutectic solder cap interconnect system using no-flowunderfill materials

Flip chip on board (FCOB) is one of the most quickly growing segments in advanced electronic packaging. In many cases, assembly processes are not capable of providing the high throughputs needed for integrated surface mount technology (SMT) processing (Tummala et al, 1997). A new high throughput process using no-flow underfill materials has been developed that has the potential to significantly increase flip chip assembly throughput. Previous research has demonstrated the feasibility and reliability of the high throughput process required for FCOB assemblies. The goal of this research was to integrate the high throughput flip chip process on commercial flip chip packages that consisted of high lead solder balls on a polyimide passivated silicon die bonded with eutectic solder bumped pads on the laminate substrate interface (Qi, 1999). This involved extensive parametric experimentation that focused on the following elements: no-flow process evaluation and implementation on the commercial packages, reflow profile parameter effects on eutectic solder wetting of high lead solder bumps, interactions between the no-flow underfill materials and the package solder interconnect and tented via features, void capture and void formation during processing, and material set compatibility and the effects on long term reliability performance     

Effects of substrate design on underfill voiding using the low cost, high throughput flip chip assembly process and no-flow underfill materials

The formation of underfill voids is an area of concern in the low cost, high throughput, or "no-flow" flip chip assembly process. This assembly process involves placement of a flip chip device directly onto the substrate pad site covered with pre-dispensed no-flow underfill. The forced motion of chip placement causes a convex flow front to pass over pad and solder mask-opening features promoting void capture. This paper determines the effects of substrate design on the phenomena of underfill voiding using the no-flow process. A full-factorial design experiment analyzes several empirically determined factors that can affect void capture in no-flow processing. The substrate design parameters included pad height, solder mask opening height, pad/solder mask opening separation, and pad pitch. The process parameters include chip placement velocity and underfill viscosity. The process robustness is measured in terms of the number of voids created during chip placement, and is further analyzed for the location and any visible modes of void formation. The goal of the work is to determine improved substrate designs to minimize voiding in flip chip processing using no flow underfills.     

Void Formation Study of Flip Chip in Package Using No-Flow Underfill

The advanced flip chip in package (FCIP) process using no-flow underfill material for high I/O density and fine-pitch interconnect applications presents challenges for an assembly process that must achieve high electrical interconnect yield and high reliability performance. With respect to high reliability, the voids formed in the underfill between solder bumps or inside the solder bumps during the no-flow underfill assembly process of FCIP devices have been typically considered one of the critical concerns affecting assembly yield and reliability performance. In this paper, the plausible causes of underfill void formation in FCIP using no-flow underfill were investigated through systematic experimentation with different types of test vehicles. For instance, the effects of process conditions, material properties, and chemical reaction between the solder bumps and no-flow underfill materials on the void formation behaviors were investigated in advanced FCIP assemblies. In this investigation, the chemical reaction between solder and underfill during the solder wetting and underfill cure process has been found to be one of the most significant factors for void formation in high I/O and fine-pitch FCIP assembly using no-flow underfill materials.     

No-flow underfill flip chip assembly––an experimental and modeling analysis

In the flip-chip assembly process, no-flow underfill materials have a particular advantage over traditional underfill: the application and curing of the former can be undertaken before and during the reflow process. This advantage can be exploited to increase the flip-chip manufacturing throughput. However, adopting a no-flow underfill process may introduce reliability issues such as underfill entrapment, delamination at interfaces between underfill and other materials, and lower solder joint fatigue life. This paper presents an analysis on the assembly and the reliability of flip-chips with no-flow underfill. The methodology adopted in the work is a combination of experimental and computer-modeling methods. Two types of no-flow underfill materials have been used for the flip chips. The samples have been inspected with X-ray and scanning acoustic microscope inspection systems to find voids and other defects. Eleven samples for each type of underfill material have been subjected to thermal shock test and the number of cycles to failure for these flip chips have been found. In the computer modeling part of the work, a comprehensive parametric study has provided details on the relationship between the material properties and reliability, and on how underfill entrapment may affect the thermal–mechanical fatigue life of flip chips with no-flow underfill.     

No-flow underfill process modeling and analysis for low cost, high throughput flip chip assembly

A new defect in which a chip "floats" over the board surface after chip placement is appearing in the low-cost, high-throughput flip chip on board (FCOB) assembly that is based on no-flow underfill. This defect has the potential to significantly lower process yield when process variables are not properly controlled. In fact, it was found that much of the yield loss observed post reflow is attributable to "chip floating." A process model has been developed that will allow an understanding of the underlying physics of the floating phenomena and identification of process variables so that this process defect can be eliminated. The critical process variables include chip placement speed, chip placement force, dwell time, deposited underfill mass and underfill material properties such as viscosity, density, surface tension, wetting speed on the board, etc. A test chip and board was specially designed so that chip floating over the board can be easily detected. To validate the model, the effects of the critical process variables on chip floating were investigated by a series of experiments, and the results were compared to the theoretical model's predictions.     

Rotational solder self-alignment mechanics modeling for a flip chip in the presence of a viscous fluid

Advent of 2.5/3Dimensional (2.5/3D) integration using through-silicon vias (TSVs) enables the formation of high signal bandwidth, fine pitch, and short-distance interconnections in stacked dies but the new package configuration poses technical challenges in package assembly process. To pace industry demands, a new alternative, Thermal Compression Bonding (TCB), to the conventional Flip Chip on Board (FCOB) process has been being developed for the 3D stacking. Among process materials, epoxy flux (or no-flow underfill) draws high attention again due to its technical advantages in both TCB and mass reflow process. The conventional mass reflow with epoxy flux could provide outstanding benefits to 2.5D package assembly process. The new Low Cost High Throughput Flip Chip Assembly process is one such process requiring fewer processing steps, lower cycle times, and lower cost. In this new process, underfill is dispensed prior to chip placement, and solder reflow and underfill cure occur simultaneously. This reduces the cycle time required for manufacture; however, the presence of a viscous underfill affects the chips' capacity for self-alignment. In a companion study, self-alignment for a flip chip undergoing rectilinear translation was analyzed. This paper applies an equivalent analysis process to a flip chip undergoing rotation in the presence of a viscous underfill. Details of the modeling process are presented along with parametric studies and contrasted against pure translation case. Conditions and process parameters which are more conducive to realignment and those hampering realignment are presented.     

Solder wetting in a wafer-level flip chip assembly

Wafer-level flip chips provide an innovative solution in establishing flip chip as a standard surface mount process. In this paper, the wetting of solder bumps within confining underfill during the reflow of a wafer-level flip chip assembly is addressed. For real time monitoring of an assembly during the reflow process, a system using a high-speed camera is utilized. The collapse of solder bumps on the chip in the vertical direction is found to be a prerequisite of solder wetting. Underfill voids and outgassing are found to cause chip drift and tilt during the reflow process. In addition, symmetry of the underfill flow and fillet formation is identified as a critical factor in maintaining chip to substrate alignment. During solder wetting of the metallization pads on the substrate, the underfill needs to maintain a low viscosity. With the selection of a thermally stable underfill and corresponding process development, wafer-level flip chip assemblies with good solder interconnects are demonstrated     

FEM modeling of temperature distribution of a flip-chip no-flow underfill package during solder reflow process

Flip chip on organic substrate has relied on underfill to redistribute the thermomechanical stress and to enhance the solder joint reliability. However, the conventional flip-chip underfill process involves multiple process steps and has become the bottleneck of the flip-chip process. The no-flow underfill is invented to simplify the flip-chip underfill process and to reduce the packaging cost. The no-flow underfill process requires the underfill to possess high curing latency to avoid gelation before solder reflow so to ensure the solder interconnect. Therefore, the temperature distribution of a no-flow flip-chip package during the solder reflow process is important for high assembly yield. This paper uses the finite-element method (FEM) to model the temperature distribution of a flip-chip no-flow underfill package during the solder reflow process. The kinetics of underfill curing is established using an autocatalytic reaction model obtained by DSC studies. Two approaches are developed in order to incorporate the curing kinetics of the underfill into the FEM model using iteration and a loop program. The temperature distribution across the package and across the underfill layer is studied. The effect of the presence of the underfill fillet and the influence of the chip dimension on the temperature difference in the underfill layer is discussed. The influence of the underfill curing kinetics on the modeling results is also evaluated.     

Assembly of lead-free bumped flip-chip with no-flow underfills

Lead-free solder reflow process has presented challenges to no-flow underfill material and assembly. The currently available no-flow underfill materials are mainly designed for eutectic Sn-Pb solders. This paper presents the assembly of lead-free bumped flip-chip with developed no-flow underfill materials. Epoxy resin/HMPA/metal AcAc/Flux G system is developed as no-flow underfills for Sn/Ag/Cu alloy bumped flip-chips. The solder wetting test is conducted to demonstrate the fluxing capability of the underfills for lead-free solders. A 100% solder joint yield has been achieved using Sn/Ag/Cu bumped flip-chips in a no-flow process. A scanning acoustic microscope is used to observe the underfill voiding. The out-gassing of HMPA at high curing temperatures causes severe voiding inside the package. A differential scanning calorimeter (DSC) used to study the curing degree of the underfill after reflow with or without post-cure. The post-curing profiles indicate that the out-gassing of HMPA would destroy the stoichiometric balance between the epoxy and hardener, and result in a need for high temperature post-cure. The material properties of the underfills are characterized and the influence of underfill out-gassing on the assembly and material properties is investigated. The impact of lead-free reflow on the material design and process conditions of no-flow underfill is discussed.     

Study of the self-alignment of no-flow underfill for micro-BGA assembly

As a concept to achieve high throughput low cost flip-chip assembly, a process development activity is underway, implementing next generation flip-chip processing based on large area underfill printing/dispensing, IC placement, and simultaneous solder interconnect reflow and underfill cure. The self-alignment of micro-BGA (ball grid array, BGA) package using flux and two types of no-flow underfill is discussed in this paper. A “rapid ramp” temperature profile is optimized for reflow of micro-BGA using no-flow underfill for self-aligning and soldering. The effect of bonding force on the self-alignment is also described. A SOFTEX real time X-ray inspection system was used to inspect samples to ensure the correct misalignment before reflow, and determine the residual displacement of solder joints after reflow. Cross-sections of the micro-BGA samples are taken using scanning electronic microscope. Our experimental results show that the self-alignment of micro-BGA using flux is very good even though the initial misalignment was greater than 50% from the pad center. When using no-flow underfill, the self-alignment is inferior to that of using flux. However, for a misalignment of no larger than 25% from the pad center, the package is also able to self-align with S1 no-flow underfill. However, when the misalignment is 37.5–50% from the pad center, there are 10–14% residual displacement after reflow. The reason is the underfill resistant force inhibiting the self-alignment of the package due to rapid increment of underfill viscosity during reflow. The self-alignment of micro-BGA package using no-flow underfill allows only <25% misalignment prior to the soldering. During assembling, although the bonding force does not influence on the self-alignment of no-flow underfill, a threshold bonding force is necessary to make all solder balls contact with PCB pads, for good soldering. The no-flow underfill is necessary to modify the fluxing/curing chemistry for overcoming the effect of tin metal salt produced during soldering on underfill curing, and for maintaining the low viscosity during soldering to help self-alignment.     

Processing of fluxing underfills for flip chip-on-laminate assembly

Fluxing underfill eliminates process steps in the assembly of flip chip-on-laminate (FCOL) when compared to conventional capillary flow underfill processing. In the fluxing underfill process, the underfill is dispensed onto the board prior to die placement. During placement, the underfill flows in a "squeeze flow" process until the solder balls contact the pads on the board. The material properties, the dispense pattern and resulting shape, solder mask design pattern, placement force, placement speed, and hold time all impact the placement process and the potential for void formation. A design of experiments was used to optimize the placement process to minimize placement-induced voids. The major factor identified was board design, followed by placement acceleration. During the reflow cycle, the fluxing underfill provides the fluxing action required for good wetting and then cures by the end of the reflow cycle. With small, homogeneous circuit boards it is relatively easy to develop a reflow profile to achieve good solder wetting. However, with complex SMT assemblies involving components with significant thermal mass this is more challenging.     

Mechanical loading of flip chip joints before underfill: the impact on yield and reliability

The underfill-facilitated migration from ceramic to lower cost laminate substrates has become a powerful enabler of direct chip attach by offering lower cost, greater electrical functionality, and a smaller system footprint over comparable packaging technologies. Once underfilled, flip chip on laminate has proven extremely reliable even in severe automotive environments. However, between the process steps of reflow and underfill cure, unprotected flip chip solder joints assembled to laminate boards are susceptible to damage and breakage if mishandled. Here, the survivability and long-term reliability of flip chip joints was studied over a range of applied strains. Mechanical loading of joints was applied via beam deflections of populated, but nonunderfilled, laminate boards. Electrical continuity was monitored before and after testing to determine when the load applied to the flip chip exceeded the joint fracture strength. The propensity for solder joint fracture was then calculated as a function of solder bump size and also as a function of strain rate. Analysis of the mechanical properties of solder revealed assembly strategies which reduce bump damage and eliminate yield loss during the process steps leading up to underfill cure. Both strained and unstrained units were then underfilled and cycled between −50 and +150 °C. While mechanical damage was evident in bump cross-sections of strained flip chip assemblies, the fatigue lives of underfilled solder joints were found to be independent of the size of mechanical loads applied before underfill.     

Adhesion issues in flip-chip on organic modules

Flip chip attach on organic carriers is a novel electronic packaging assembly method which provides advantages of high input/output (I/O) counts, electrical performance and thermal dissipation. In this structure, the flip chip device is attached to organic laminate with predeposited eutectic solder. Mechanical coupling of the chip and the laminate is done via underfill encapsulant materials. As the chip size increases, the thermal mismatch between silicon and its organic carrier becomes greater. Adhesion becomes an important factor since the C4 joints fail quickly if delamination of the underfill from either chip or the solder mask interface occurs. Newly developed underfills have been studied to examine their properties, including interfacial adhesion strength, flow characteristics, void formation and cure kinetics. This paper will describe basic investigations into the properties of these underfills and also how these properties related to the overall development process. In addition, experiments were performed to determine the effects on adhesion degradation of flip chip assembly processes and materials such as IR reflow profile, flux quantity and residues. Surface treatment of both the chip and the laminate prior to encapsulation were studied to enhance underfill adhesion. Accelerated thermal cycling and highly accelerated stress testing (HAST) were conducted to compare various underfill properties and reliability responses     

Double bump flip-chip assembly

Capillary underfill remains the dominate process for underfilling Hip-chip die both in packages and for direct chip attach (DCA) on printed circuit board (PCB) assemblies. Capillary underfill requires a post reflow dispense and cure operation, and the underflow time increases with increasing die area and decreasing die-to-substrate spacing. Fluxing or no-How underfills are dispensed prior to die placement and cure during the solder reflow cycle. Since filler particles in the fluxing underfill can be trapped between the solder ball and the substrate pad during placement, the filler content of fluxing underfills is typically limited to <20% or assembly yield drops dramatically. At 20% filler concentration, the coefficient of thermal expansion (CTE) of the underfill is near that of the bulk resin (50-80 ppm//spl deg/C). In this paper, a double bump Hip-chip process is described. A filled capillary underfill is coated onto a wafer and cured. The wafer is then polished to expose the solder bumps. A second solder bump is formed over the original bump by stencil printing solder paste. After dicing, the die is assembled to the PCB using unfilled fluxing underfill. In the resulting structure, the low CTE underfill is near the low CTE Si die, and the higher CTE underfill is in contact with the PCB. In addition, the standoff height is increased compared to a conventional single bump assembly. In air-to-air thermal shock tests, the double bump assembly was /spl sim/ 1.5 X more reliable than the conventional single bump construction with fluxing underfill. Modeling results are also presented.     

Correlation of flip chip underfill process parameters and materialproperties with in-process stress generation

Electronic packaging designs are moving toward fewer levels of packaging to enable miniaturization and to increase performance of electronic products. One such package design is flip chip on board (FCOB). In this method, the chip is attached face down directly to a printed wiring board (PWB). Since the package is comprised of dissimilar materials, the mechanical integrity of the flip chip during assembly and operation becomes an issue due to the coefficient of thermal expansion (CTE) mismatch between the chip, PWB, and interconnect materials. To overcome this problem, a rigid encapsulant (underfill) is introduced between the chip and the substrate. This reduces the effective CTE mismatch and reduces the effective stresses experienced by the solder interconnects. The presence of the underfill significantly improves long term reliability. The underfill material, however, does introduce a high level of mechanical stress in the silicon die. The stress in the assembly is a function of the assembly process, the underfill material, and the underfill cure process. Therefore, selection and processing of underfill material is critical to achieving the desired performance and reliability. The effect of underfill material on the mechanical stress induced in a flip chip assembly during cure was presented in previous publications. This paper studies the effect of the cure parameters on a selected commercial underfill and correlates these properties with the stress induced in flip chip assemblies during processing     

Modeling of the curing kinetics of no-flow underfill in flip-chip applications

No-flow underfill has greatly improved the production efficiency of flip-chip process. Due to its unique characteristics, including reaction latency, curing under solder reflow conditions and the desire for no post-cure, there is a need for a fundamental understanding of the curing process of no-flow underfill. Starting with a promising no-flow underfill formulation, this paper seeks to develop a systematic methodology to study and model the curing behavior of this underfill. A differential scanning calorimeter (DSC) is used to characterize the heat flow during curing under isothermal and temperature ramp conditions. A modified autocatalytic model is developed with temperature-dependent parameters. The degree of cure (DOC) is calculated; compared with DSC experiments, the model gives a good prediction of DOC under different curing conditions. The temperature of the printed wiring board (PWB) during solder reflow is measured using thermocouples and the evolution of DOC of the no-flow underfill during the reflow process is calculated. A stress rheometer is used to study the gelation of the underfill at different heating rates. Results show that at high curing temperature, the underfill gels at a lower DOC. Based on the kinetic model and the gelation study, the solder wetting behavior during the eutectic SnPb and lead-free SnAgCu reflow processes is predicted and confirmed by the solder wetting tests.     

Adhesion characterization of no-flow underfills used in flip chipassemblies and correlation with reliability

Adhesion is one of the key properties of underfills used in flip chip assemblies. This paper characterizes the adhesion strengths of no-flow underfill materials to various die passivations using the shear test techniques. A novel shear test vehicle with planner underfill layers between the die and substrate is presented. The adhesion strengths and failure modes of the no-flow underfill materials during shear testing correlate well with their thermal shock reliability test results. Underfill adhesion related failures such as delamination and crack are investigated and correlated between flip chip assemblies and shear test vehicle assemblies without solder joint interconnects     

Near Void-Free Assembly Development of Flip Chip Using No-Flow Underfill

The advanced flip-chip-in-package (FCIP) process technology, using no-flow underfill material for high I/O density (over 3000 I/O) and fine-pitch (down to 150 mum) interconnect applications, presents challenges for flip chip processing because underfill void formation during reflow drives interconnect yield down and degrades reliability. In spite of such challenges, a high yield, reliable assembly process (>99.99%) has been achieved using commercial no-flow underfill material with a high I/O, fine-pitch FCIP. This has been obtained using design of experiments with physical interpretation techniques. Statistical analysis determined what assembly conditions should be used in order to achieve robust interconnects without disrupting the FCIP interconnect structure. However, the resulting high yield process had the side effect of causing a large number of voids in the FCIP assemblies. Parametric studies were conducted to develop assembly process conditions that would minimize the number of voids in the FCIP induced by thermal effects. This work has resulted in a significant reduction in the number of underfill voids. This paper presents systematic studies into yield characterization, void formation characterization, and void reduction through the use of structured experimentation which was designed to improve assembly yield and to minimize the number of voids, respectively, in FCIP assemblies.     

Study of the fluxing agent effects on the properties of no-flowunderfill materials for flip-chip applications

As one of the key requirements of the no-flow underfill materials for flip-chip applications, a proper self-fluxing agent must be incorporated in the developed no-flow underfill materials to provide proper fluxing activity during the simultaneous solder reflow and underfill material curing. However, most fluxing agents have some adverse effects on the no-flow underfill material properties and assembly reliability. In this paper, we have extensively investigated the effects of the concentration of the selected fluxing agent on the material properties, interconnect integrity and assembly reliability. Through this work, an optimum concentration window of the fluxing agent is obtained and a routine procedure of evaluating fluxing agents is established     

Lead-free solder flip chip-on-laminate assembly and reliability

This paper examines the assembly process for flip chip die with SnAgCu solder bumps and the results of liquid-to-liquid thermal shock testing. The SnAgCu alloy required a thicker dip layer of flux to achieve good wetting compared to the SnPb eutectic alloy. A liquid spray flux yielded more consistent solder wetting with the SnAgCu alloy. With both fluxes, a nitrogen reflow atmosphere was necessary with the SnAgCu alloy. A peak reflow temperature of 246°C was used for the assembly of the SnAgCu thermal shock test vehicles. A lower peak temperature of 235°C did not yield sufficient solder wetting. Liquid-to-liquid thermal shock testing was performed from -40°C to +125°C. The SnPb alloy performed slightly better than the SnAgCu and the dip flux was better that the spray flux. The degree of delamination with the SnAgCu alloy was significantly higher than with the SnPb alloy. Cracks in the underfill between adjacent solder balls were observed. The SnPb alloy extruded into these cracks more readily than the SnAgCu and created electrical shorts