首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 421 毫秒
1.
The aim of this work was to assess ultrafine particles (UFP) number concentrations in different microenvironments of Portuguese preschools and to estimate the respective exposure doses of UFP for 3–5‐year‐old children (in comparison with adults). UFP were sampled both indoors and outdoors in two urban (US1, US2) and one rural (RS1) preschool located in north of Portugal for 31 days. Total levels of indoor UFP were significantly higher at the urban preschools (mean of 1.82 × 104 and 1.32 × 104 particles/cm3 at US1 an US2, respectively) than at the rural one (1.15 × 104 particles/cm3). Canteens were the indoor microenvironment with the highest UFP (mean of 5.17 × 104, 3.28 × 104, and 4.09 × 104 particles/cm3 at US1, US2, and RS1), whereas the lowest concentrations were observed in classrooms (9.31 × 103, 11.3 × 103, and 7.14 × 103 particles/cm3 at US1, US2, and RS1). Mean indoor/outdoor ratios (I/O) of UFP at three preschools were lower than 1 (0.54–0.93), indicating that outdoor emissions significantly contributed to UFP indoors. Significant correlations were obtained between temperature, wind speed, relative humidity, solar radiation, and ambient UFP number concentrations. The estimated exposure doses were higher in children attending urban preschools; 3–5‐year‐old children were exposed to 4–6 times higher UFP doses than adults with similar daily schedules.  相似文献   

2.
J. Liu  D. Fung  J. Jiang  Y. Zhu 《Indoor air》2014,24(3):327-335
Ultrafine particle (UFP) emissions from three essential‐oil‐based mosquito repellent products (lemon eucalyptus (LE), natural insects (NI), and bite shield (BS)) were tested in a 386 l chamber at a high air exchange rate of 24/h with filtered laboratory air. Total particle number concentration and size distribution were monitored by a condensation particle counter and a scanning mobility particle sizer, respectively. UFPs were emitted from all three products under indoor relevant ozone concentrations (~ 17 ppb). LE showed a nucleation burst followed by a relatively stable and continuous emission while the other two products (NI and BS) showed episodic emissions. The estimated maximum particle emission rate varied from 5.4 × 109 to 1.2 × 1012 particles/min and was directly related to the dose of mosquito repellent used. These rates are comparable to those due to other indoor activities such as cooking and printing. The emission duration for LE lasted for 8–78 min depending on the dose applied while the emission duration for NI and BS lasted for 2–3 h.  相似文献   

3.
Children in preschools were studied as an exceptionally vulnerable group to lung diseases due to their immature immune system. Few data are available in the literature addressing the exposure of children in preschools to ultrafine (>10 nm) particles. Exposure of children to fine, ultrafine (10 nm–1 µm) particles and black carbon particles present inside and near two preschools in Nur-Sultan, Kazakhstan, during Fall 2019 was investigated. For Preschool I, the average daily (6 h) indoor (outdoor) PM1, PM2.5, and PM10 concentrations over three-week measurements were 15.0 (SD 12.5) µg/m3, 34.6 (SD 35.1) µg/m3, and 47.2 (SD 45.2) µg/m3, respectively. Average indoor UFP concentrations (>10.0 nm) including candle burning events were 5.20 × 103 (SD 8.80 × 103) particles/cm3, with the background UFP concentration to be 3.30 × 103 (SD 1.80 × 103) particles/cm3. In Preschool II, the average UFP concentration (>30.0 nm) in the morning and afternoon was 3.94 × 103 (SD 5.34 × 102) and 3.36 × 103 (SD 1.90 × 103) particles/cm3, respectively. Indoor black carbon (BC) concentrations were correlated with the outdoor smoking activity. The major sources of the indoor particles in the preschools were dust resuspension, candle burning, and infiltrated outdoor particles.  相似文献   

4.
Q. Zhang  J. Avalos  Y. Zhu 《Indoor air》2014,24(2):190-198
This study characterized fine (PM2.5) and ultrafine particle (UFP, diameter < 100 nm) emissions from microwave popcorn and analyzed influential factors. Each pre‐packed popcorn bag was cooked in a microwave oven enclosed in a stainless steel chamber for 3 min. The number concentration and size distribution of UFPs and PM2.5 mass concentration were measured inside the chamber repeatedly for five different flavors under four increasing power settings using either the foil‐lined original package or a brown paper bag. UFPs and PM2.5 generated by microwaving popcorn were 150–560 and 350–800 times higher than the emissions from microwaving water, respectively. About 90% of the total particles emitted were in the ultrafine size range. The emitted PM concentrations varied significantly with flavor. Replacing the foil‐lined original package with a brown paper bag significantly reduced the peak concentration by 24–87% for total particle number and 36–70% for PM2.5. A positive relationship was observed between both UFP number and PM2.5 mass and power setting. The emission rates of microwave popcorn ranged from 1.9 × 1010 to 8.0 × 1010 No./min for total particle number and from 134 to 249 μg/min for PM2.5.  相似文献   

5.
Although many studies have reported the health effects of biomass fuels in developing countries, relatively few have quantitatively characterized emissions from biomass stoves during cooking and heating. The aim of this pilot study was to characterize the emission characteristics of different biomass stoves in four rural houses in Bhutan during heating (metal chimney stove), rice cooking (traditional mud stove), fodder preparation (stone tripod stove), and liquor distillation (traditional mud stove). Three stage measurements (before, during, and after the activity had ceased) were conducted for PM2.5, particle number (PN), CO, and CO2. When stoves were operated, the pollutant concentrations were significantly elevated above background levels, by an average of 40 and 18 times for PM2.5 and CO, respectively. Emission rates (mg/min) ranged from 1.07 × 102 (PM2.5) and 3.50 × 102 (CO) for the stone tripod stove during fodder preparation to 6.20 × 102 (PM2.5) and 2.22 × 103 (CO) for the traditional mud stove during liquor distillation. Usable PN data were only available for one house, during heating using a metal chimney stove, which presented an emission rate of 3.24 × 1013 particles/min. Interventions to control household air pollution in Bhutan, in order to reduce the health risks associated with cooking and heating, are recommended.  相似文献   

6.
Taxi drivers’ exposure to traffic-related air pollutants inside their vehicles has been reported in different countries but not yet in Lebanon. Thus, we conducted a cross-sectional study on 20 Lebanese taxi drivers to (1) assess their exposure to ultrafine particles (UFP) and black carbon (BC) inside their vehicles and (2) identify determinants of this exposure. UFP and BC were measured using Diffusion Size Classifier Miniature® and microAeth ® Model AE51, respectively, for 5 hours. Data on characteristics of vehicles and trips were collected by face-to-face interviews. Associations between pollutant levels and their determinants were analyzed by multiple linear regression. The mean of UFP count (35.2 ± 17.6 x 103 particles cm-3) and BC (5.2 ± 1.9 μg m-3) concentrations in-taxis was higher in the morning measurements compared with those in the afternoon measurements. UFP count increased in-taxis by 60% for every 10 minutes spent in blocked traffic and by 84% starting from two trips with smokers compared to trips without smokers. Conversely, UFP count decreased by 30% for every 10 minutes under both air-conditioning and air recirculation mode with windows closed. BC was not affected by any of these factors. Our findings suggest easy ways to reduce UFP exposure inside vehicles for all commuters.  相似文献   

7.
M. Zaatari  J. Siegel 《Indoor air》2014,24(4):350-361
Particles in retail environments can have consequences for the occupational exposures of retail workers and customers, as well as the energy costs associated with ventilation and filtration. Little is known about particle characteristics in retail environments. We measured indoor and outdoor mass concentrations of PM10 and PM2.5, number concentrations of submicron particles (0.02–1 μm), size‐resolved 0.3–10 μm particles, as well as ventilation rates in 14 retail stores during 24 site visits in Pennsylvania and Texas. Overall, the results were generally suggestive of relatively clean environments when compared to investigations of other building types and ambient/occupational regulatory limits. PM10 and PM2.5 concentrations (mean ± s.d.) were 20 ± 14 and 11 ± 10 μg/m3, respectively, with indoor‐to‐outdoor ratios of 1.0 ± 0.7 and 0.88 ± 1.0. Mean submicron particle concentrations were 7220 ± 7500 particles/cm3 with an indoor‐to‐outdoor ratio of 1.18 ± 1.30. The median contribution to PM10 and PM2.5 concentrations from indoor sources (vs. outdoors) was 83% and 53%, respectively. There were no significant correlations between measured ventilation rates and particle concentrations of any size. When examining options to lower PM2.5 concentrations below regulatory limits, the required changes to ventilation and filtration efficiency were site specific and depended on the indoor and outdoor concentration, emission rate, and infiltration level.  相似文献   

8.
This study describes the size distribution and concentration of particles expelled by a portable, 3‐L ultrasonic humidifier. The ultrasonic humidifier was filled with waters of varying mineral content and hardness. Aerosol size distributions were measured during 8 hours of humidifier operation in a typical bedroom. Humidifiers produced approximately 1.22 × 1010‐2.50 × 1010 airborne particles per milliliter of water consumed, resulting in airborne particle concentrations of 3.01‐5.91 × 104 #/cm3, with modes ranging between 109 and 322 nm in diameter. The emission rate of particles varied by water type from 1.02 × 109 to 2.27 × 109 #/s. Lower mineral waters produced fewer, smaller particles when compared to higher mineral waters. Chemical analyses of particles collected with a cascade impactor indicated that the minerals in emitted particles had the same relative mineral concentrations as the fill water. Our results demonstrate that ultrasonic humidifiers should be considered a source of inhalation exposure to minerals dissolved in water, and that the magnitude of exposure to inhalable particles will vary with water quality.  相似文献   

9.
Concentrations and emission rates of sixteen trace elements in emitted PM during heating soybean oil using three types of pans, including Teflon, granitium, and cast-iron, were investigated. Statistically significant decreases in Mn and Co emission rates were observed when the oil was heated in the cast-iron pan compared to Teflon and granitium pans. Among the released trace elements, Ni, Ba, Zn, and Cr had more contribution to the emission rate. The concentrations of Fe in the emitted PM1 were found to be higher when cast-iron pan (8.49 ± 3.35 µg/m3) was utilized compared to Teflon (8.05 ± 2.27 µg/m3) and granitium (7.45 ± 1.38 µg/m3). However, these increases were statistically insignificant. The results of our study support the hypothesis that the trace elements translocate from cooking pans into the heated oil and subsequently to the particulate phase. This translocation creates a new inhalation exposure route to trace elements in indoor environments.  相似文献   

10.
Hotel housekeepers represent a large, low-income, predominantly minority, and high-risk workforce. Little is known about their exposure to chemicals, including volatile organic compounds (VOCs). This study evaluates VOC exposures of housekeepers, sources and factors affecting VOC levels, and provides preliminary estimates of VOC-related health risks. We utilized indoor and personal sampling at two hotels, assessed ventilation, and characterized the VOC composition of cleaning agents. Personal sampling of hotel staff showed a total target VOC concentration of 57 ± 36 µg/m3 (mean ± SD), about twice that of indoor samples. VOCs of greatest health significance included chloroform and formaldehyde. Several workers had exposure to alkanes that could cause non-cancer effects. VOC levels were negatively correlated with estimated air change rates. The composition and concentrations of the tested products and air samples helped identify possible emission sources, which included building sources (for formaldehyde), disinfection by-products in the laundry room, and cleaning products. VOC levels and the derived health risks in this study were at the lower range found in the US buildings. The excess lifetime cancer risk (average of 4.1 × 10−5) still indicates a need to lower exposure by reducing or removing toxic constituents, especially formaldehyde, or by increasing ventilation rates.  相似文献   

11.
In full-scale wastewater treatment systems, phosphorus removal typically occurs together with nitrogen removal. Nitrite, an intermediate of both the nitrification and denitrification processes, can accumulate in the reactor. The inhibitory effect of nitrite/free nitrous acid (FNA) on the aerobic metabolism of poly-phosphate accumulating organisms (PAOs) is investigated. A culture highly enriched (90 ± 5%) in Candidatus “Accummulibacter phosphatis”, a well-known PAO, was used to perform a series of batch experiments at various nitrite and pH levels. FNA was found to inhibit all key aerobic metabolic processes performed by PAOs, namely PHA oxidation, phosphate uptake, glycogen replenishment and growth. The inhibitory effect on the anabolic processes (growth, phosphate uptake and glycogen production) was much stronger than that on the catabolic processes (PHA oxidation). 50% inhibition on all anabolic processes occurred at FNA concentrations of approximately 0.5 × 10?3 mg HNO2–N/L (equivalent to 2.0 mg NO2?–N/L at pH 7.0), while full inhibition occurred at FNA concentrations of approximately 6.0 × 10?3 mg HNO2–N. These concentrations could be found in full-scale wastewater treatment systems that achieve nitrogen removal via the nitrite pathway. In comparison, PHA oxidation remained at 40–50% of the highest rate at FNA concentrations in the range 2.0 × 10?3–10.0 × 10?3 mg HNO2–N/L. Interestingly, PAOs were able to reduce nitrite under aerobic conditions (DO ≈ 3 mg/L), with the rate increasing substantially with the FNA concentration. The inhibition on phosphate uptake was found to be reversible.  相似文献   

12.
This study is the pioneer assessment of the PCBs in indoor dust particles (from air conditioners) of an urbanized megacity from South Asian. The ∑35 PCB concentration ranged from 0.27 to 152.9 ng/g (mean: 24.84 ± 22.10 ng/g). The tri- and tetra-PCBs were dominant homologues, contributing 57.36% of the total PCB concentrations. The mean levels of Σ8-dioxin-like (DL), Σ6-indicator PCBs and WHO2005-TEQ for DL-PCBs were 2.22 ± 2.55 ng/g, 9.49 ± 8.04 ng/g and 4.77 ± 4.89 pg/g, respectively. The multiple linear regression indicated a significant correlation of dusting frequency (p = 1.06 × 10–04) and age of the house (p = 1.02 × 10–06) with PCB concentrations in indoor environment. The spatial variation of PCB profile revealed relatively higher concentrations from sites near to illegal waste burning spots, electrical locomotive workshops, and grid stations. Human health risk assessment of PCBs for adults and toddlers through all three exposure routes (ie, inhalation, ingestion, and dermal contact) demonstrated that toddlers were vulnerable to high cancer risk (4.32 × 10−04), while adults were susceptible from low to moderate levels of risk (3.16 × 10−05). Therefore, comprehensive investigations for PCBs in the indoor settings, focusing particularly on the sensitive populations with relationship to the electronic devices, transformers, and illegal waste burning sites, are recommended.  相似文献   

13.
Water and wastewater filtration systems often house pathogenic bacteria, which must be removed to ensure clean, safe water. Here, we determine the persistence of the model bacterium Pseudomonas aeruginosa in two types of filtration systems, and use P. aeruginosa bacteriophages to determine their ability to selectively remove P. aeruginosa. These systems used beds of either anthracite or granular activated carbon (GAC), which were operated at an empty bed contact time (EBCT) of 45 min. The clean bed filtration systems were loaded with an instantaneous dose of P. aeruginosa at a total cell number of 2.3 (±0.1 [standard deviation]) × 107 cells. An immediate dose of P. aeruginosa phages (1 mL of phage stock at the concentration of 2.7 × 107 PFU (Plaque Forming Units)/mL) resulted in a reduction of 50% (±9%) and >99.9% in the effluent P. aeruginosa concentrations in the clean anthracite and GAC filters, respectively. To further evaluate the effects of P. aeruginosa phages, synthetic stormwater was run through anthracite and GAC biofilters where mixed-culture biofilms were present. Eighty five days after an instantaneous dose of P. aeruginosa (2.3 × 107 cells per filter) on day 1, 7.5 (±2.8) × 107 and 1.1 (±0.5) × 107 P. aeruginosa cells/g filter media were detected in the top layer (close to the influent port) of the anthracite and GAC biofilters, respectively, demonstrating the growth and persistence of pathogenic bacteria in the biofilters. A subsequent 1-h dose of phages, at the concentration of 5.1 × 106 PFU/mL and flow rate of 1.6 mL/min, removed the P. aeruginosa inside the GAC biofilters and the anthracite biofilters by 70% (±5%) and 56% (±1%), respectively, with no P. aeruginosa detected in the effluent, while not affecting ammonia oxidation or the ammonia-oxidizing bacterial community inside the biofilters. These results suggest that phage treatment can selectively remove pathogenic bacteria with minimal impact on beneficial organisms from attached growth systems for effluent quality improvement.  相似文献   

14.
There is increasing evidence of SARS-CoV-2 transmission via aerosol; the number of cases of transmission via this route reported in the literature remains however limited. This study examines a case of clustering that occurred in a courtroom, in which 5 of the 10 participants were tested positive within days of the hearing. Ventilation loss rates and dispersion of fine aerosols were measured through CO2 injections and lactose aerosol generation. Emission rate and influencing parameters were then computed using a well-mixed dispersion model. The emission rate from the index case was estimated at 130 quanta h−1 (interquartile (97–155 quanta h−1). Measured lactose concentrations in the room were found relatively homogenous (n = 8, mean 336 µg m−3, SD = 39 µg m−3). Air renewal was found to play an important role for event durations greater than 0.5 h and loss rate below 2–3 h−1. The estimated emission rate suggests a high viral load in the index case and/or a high SARS-CoV-2 infection coefficient. High probabilities of infection in similar indoor situations are related to unfavorable conditions of ventilation, emission rate, and event durations. Source emission control appears essential to reduce aerosolized infection in events lasting longer than 0.5 h.  相似文献   

15.
Baseline information on size‐resolved bacterial, fungal, and particulate matter (PM) indoor air concentrations and emission rates is presented for six school classrooms sampled in four countries. Human occupancy resulted in significantly elevated airborne bacterial (81 times on average), fungal (15 times), and PM mass (nine times) concentrations as compared to vacant conditions. Occupied indoor/outdoor (I/O) ratios consistently exceeded vacant I/O ratios. Regarding size distributions, average room‐occupied bacterial, fungal, and PM geometric mean particle sizes were similar to one another while geometric means estimated for bacteria, fungi, and PM mass during vacant sampling were consistently lower than when occupied. Occupancy also resulted in elevated indoor bacterial‐to‐PM mass‐based and number‐based ratios above corresponding outdoor levels. Mean emission rates due to human occupancy were 14 million cells/person/h for bacteria, 14 million spore equivalents/person/h for fungi, and 22 mg/person/h for PM mass. Across all locations, indoor emissions contributed 83 ± 27% (bacteria), 66 ± 19% (fungi), and 83 ± 24% (PM mass) of the average indoor air concentrations during occupied times.  相似文献   

16.
A major source of human exposure to ultrafine particles is candle use. Candles produce ultrafine particles in the size range under 10 nm, with perhaps half of the particles less than 5 nm. For these small particles at typically high concentrations, coagulation and deposition are two dominant mechanisms in aerosol size dynamics. We present an updated coagulation model capable of characterizing the relative contributions of coagulation, deposition, and air exchange rates. Size‐resolved coagulation and decay rates are estimated for three types of candles. Number, area, and mass distributions are provided for 93 particle sizes from 2.33 to 64 nm. Total particle production was in the range of 1013 min?1. Peak number, area, and mass concentrations occurred at particle sizes of <3, 20, and 40 nm, respectively. Both the number and area concentrations greatly exceeded background concentrations in the residence studied. Contributions of coagulation, deposition, and air exchange rates to particle losses were 65%, 34%, and 0.3% at high concentrations (106 cm?3), while they are 17%, 81%, and 1.7% at lower concentrations (3 × 104 cm?3), respectively. The increased particle production for the very smallest particles (2.33‐2.50 nm) suggests that even smaller particles may be important to study.  相似文献   

17.
Particle mass and number concentrations were measured in a mechanically ventilated classroom as part of a study of ventilation strategies for energy conservation. The ventilation system was operated either continuously, intermittently, or shut down during nights while it was on during workdays. It appears that the nighttime ventilation scheme is not important for indoor particle concentrations the following day if fans are operated to give five air exchanges in advance of the workday. The highest concentrations of PM10 were found during and after workdays and were due to human activity in the classroom. The average workday PM10 concentration was 14 μg/m3, well below the WHO guideline values. The number concentration of particles with diameter <0.750 μm was typically between 0.5 × 103 and 3.5 × 103 particle/cm3. These concentrations were largely independent of the occupants. Transient formation of small particles was observed when ventilation was shut down. Then remaining ozone reacted with terpenes emitted by indoor sources and gave up to 8 × 103 particle/cm3 before formation stopped due to lack of ozone. The intermittent ventilation regime was found least favorable for the indoor air quality in the classroom.  相似文献   

18.
Humans are a prominent source of airborne biological particles in occupied indoor spaces, but few studies have quantified human bioaerosol emissions. The chamber investigation reported here employs a fluorescence‐based technique to evaluate bioaerosols with high temporal and particle size resolution. In a 75‐m3 chamber, occupant emission rates of coarse (2.5–10 μm) fluorescent biological aerosol particles (FBAPs) under seated, simulated office‐work conditions averaged 0.9 ± 0.3 million particles per person‐h. Walking was associated with a 5–6× increase in the emission rate. During both walking and sitting, 60–70% or more of emissions originated from the floor. The increase in emissions during walking (vs. while sitting) was mainly attributable to release of particles from the floor; the associated increased vigor of upper body movements also contributed. Clothing, or its frictional interaction with human skin, was demonstrated to be a source of coarse particles, and especially of the highly fluorescent fraction. Emission rates of FBAPs previously reported for lecture classes were well bounded by the experimental results obtained in this chamber study. In both settings, the size distribution of occupant FBAP emissions had a dominant mode in the 3–5 μm diameter range.  相似文献   

19.
Emissions from indoor biomass burning are a major public health concern in developing areas of the world. Less is known about indoor air quality, particularly airborne endotoxin, in homes burning biomass fuel in residential wood stoves in higher income countries. A filter‐based sampler was used to evaluate wintertime indoor coarse particulate matter (PM10‐2.5) and airborne endotoxin (EU/m3, EU/mg) concentrations in 50 homes using wood stoves as their primary source of heat in western Montana. We investigated number of residents, number of pets, dampness (humidity), and frequency of wood stove usage as potential predictors of indoor airborne endotoxin concentrations. Two 48‐h sampling events per home revealed a mean winter PM10‐2.5 concentration (± s.d.) of 12.9 (± 8.6) μg/m3, while PM2.5 concentrations averaged 32.3 (± 32.6) μg/m3. Endotoxin concentrations measured from PM10‐2.5 filter samples were 9.2 (± 12.4) EU/m3 and 1010 (± 1524) EU/mg. PM10‐2.5 and PM2.5 were significantly correlated in wood stove homes (r = 0.36, P < 0.05). The presence of pets in the homes was associated with PM10‐2.5 but not with endotoxin concentrations. Importantly, none of the other measured home characteristics was a strong predictor of airborne endotoxin, including frequency of residential wood stove usage.  相似文献   

20.
The new particle formation due to the use of cleaning products containing volatile organic compounds (VOCs) in indoor environments is well documented in the scientific literature. Indeed, the physical-chemical process occurring in particle nucleation due to VOC-ozone reactions was deepened as well as the effect of the main influencing parameters (ie, temperature, ozone). Nonetheless, proper quantification of the emission under actual meteo-climatic conditions and ozone concentrations is not available. To this end, in the present paper the emission factors of newly generated ultrafine particles due to the use of different floor cleaning products under actual temperature and relative humidity conditions and ozone concentrations typical of the summer periods were evaluated. Tests in a chamber and in an actual indoor environment were performed measuring continuously particle number concentrations and size distributions during cleaning activities. The tests revealed that a significant particle emission in the nucleation mode was present for half of the products under investigation with emission factors up to 1.1 × 1011 part./m2 (8.8 × 1010 part./mLproduct), then leading to an overall particle emission comparable to other well-known indoor sources when cleaning wide surfaces.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号