Comparison of double layer in argon helicon plasma and magnetized DC discharge plasma

We present in this paper the comparison of an electric double layer (DL) in argon helicon plasma and magnetized direct current (DC) discharge plasma. DL in high-density argon helicon plasma of 13.56 MHz RF discharge was investigated experimentally by a floating electrostatic probe and local optical emission spectroscopy (LOES). The DL characteristics at different operating parameters, including RF power (300–1500 W), tube diameter (8–60 mm), and external magnetic field (0–300 G), were measured. For comparison, DL in magnetized plasma channel of a DC discharge under different conditions was also measured experimentally. The results show that in both cases, DL appears in a divergent magnetic field where the magnetic field gradient is the largest and when the plasma density is sufficiently high. DL strength (or potential drop of DL) increases with the magnetic field in two different structures. It is suggested that the electric DL should be a common phenomenon in dense plasma under a gradient external magnetic field. DL in magnetized plasmas can be controlled properly by magnetic field structure and discharge mode (hence the plasma density).     

Axial profiles of argon helicon plasma by optical emission spectroscope and Langmuir probe

We present the axial profiles of argon helicon plasma measured by a local optical emission spectroscope (OES) and Langmuir RF-compensated probe. The results show that the emission intensity of the argon atom lines (750 nm, 811 nm) is proportional to the plasma density determined by the Langmuir probe. The axial profile of helicon plasma depends on the discharge mode which changes with the RF power. Excited by helical antenna, the axial distribution of plasma density is similar to that of the external magnetic field in the capacitive coupled mode (E-mode). As the discharge mode changes into the inductively coupled mode (H-mode), the axial distribution of plasma density in the downstream can still be similar to that of the external magnetic field, but becomes more uniform in the upstream. When the discharge entered wave coupled mode (W-mode), the plasma becomes nearly uniform along the axis, showing a completely different profile from the magnetic field. The W-mode is expected to be a mixed pattern of helicon (H) and Trivelpiece-Gould (TG) waves.     

Simulation of a helicon plasma source in a magnetoplasma rocket engine

The helicon plasma source, which generates high thrust and high impulse, is of vital importance for magnetoplasma rocket engines. In this work, a multi-component, two-dimensional, axisymmetric fluid model coupled with an electromagnetic field was developed to model the helicon discharge. The simulation results demonstrate that: (i) the discharge mode changes twice—each conversion is accompanied by a plasma density jump and an electron temperature peak in the discharge; (ii) when the input current increases, the plasma density increases, and ionization occurs faster; (iii) the background magnetic field clearly enhances the discharge; (iv) the plasma density may be smaller if the discharge has not entered the wave mode.     

Effects of magnetic field on electron power absorption in helicon fluid simulation

In this study, a code, named Peking University Helicon Discharge(PHD), which can simulate helicon discharge processes under both a background magnetic field greater than 500 G and a pressure less than 1 Pa, is developed. In the code, two fluid equations are used. The PHD simulations led to two important findings:(1) the temporal evolution of plasma density with the background magnetic field exhibits a second rapid increase(termed as the second density jump),similar to the transition of modes in helicon plasmas;(2) in the presence of a magnetic field, the peak positions of electron power absorption appeared near the central axis, unlike in the case of no magnetic field. These results may lead to an enhanced understanding of the discharge mechanism.     

Modification of exposure conditions by the magnetic field configuration in helicon antenna-excited helium plasma

Modification of exposure conditions downstream in the diffusion chamber has been performed in helicon antenna-excited helium plasma by adjusting the magnetic field(intensity and geometry).In the inductively coupled mode(H mode), a reduction in ion and heat fluxes is found with increasing magnetic field intensity, which is further explained by the more highly magnetized ions off-axis around the last magnetic field lines(LMFL). However, in helicon wave mode(W mode), the increase in magnetic field intensity can dramatically increase the ion and heat fluxes.Moreover, the effect of LMFL geometry on exposure conditions is investigated. In H mode with contracting LMFL, off-axis peaks of both plasma density and electron temperature profiles shift radially inwards, bringing about a beam with better radial uniformity and higher ion and heat fluxes. In W mode, although higher ion and heat fluxes can be achieved with suppressed plasma cross-field diffusion under converging LMFL, the poor radial uniformity and a small beam diameter will limit the size of samples suitable for plasma irradiation experiments.     

The application of a helicon plasma source in reactive sputter deposition of tungsten nitride thin films

A reactive helicon wave plasma (HWP) sputtering method is used for the deposition of tungsten nitride (WNx) thin films. N2 is introduced downstream in the diffusion chamber. The impacts of N2 on the Ar-HWP parameters, such as ion energy distribution functions (IEDFs), electron energy probability functions (EEPFs), electron temperature (Te) and density (ne), are investigated. With the addition of N2, a decrease in electron density is observed due to the dissociative recombination of electrons with ${{\rm{N}}}_{2}^{+}.$ The similar IEDF curves of Ar+ and N2+ indicate that the majority of ${{\rm{N}}}_{2}^{+}$ stems from the charge transfer in the collision between Ar+ and N2. Moreover, due to the collisions between electrons and N2 ions, EEPFs show a relatively lower Te with a depletion in the high-energy tail. With increasing negative bias from 50 to 200 V, a phase transition from hexagonal WN to fcc-WN0.5 is observed, together with an increase in the deposition rate and roughness     

Axial uniformity diagnosis of coaxial surface wave linear plasma by optical emission spectroscopy

The coaxial surface wave linear plasma with preeminent axial uniformity is developed with the 2.45 GHz microwave generator. By optical emission spectroscopy, parameters of the argon linear plasma with a length over 600 mm are diagnosed under gas pressure of 30 and 50 Pa and different microwave powers. The spectral lines of argon and Hβ (486.1 nm) atoms in excited state are observed for estimating electron excitation temperature and electron density. Spectrum bands in 305–310 nm of diatomic OH (${{\rm{A}}}^{2}{{\rm{\Sigma }}}^{+}-{{\rm{X}}}^{2}{{\rm{\Pi }}}_{{\rm{i}}}$) radicals are used to determine the molecule rotational temperature. Finally, the axial uniformity of electron density and electron excitation temperature are analyzed emphatically under various conditions. The results prove the distinct optimization of compensation from dual powers input, which can narrow the uniform coefficient of electron density and electron excitation temperature by around 40% and 22% respectively. With the microwave power increasing, the axial uniformity of both electron density and electron excitation temperature performs better. Nevertheless, the fluctuation of electron density along the axial direction appeared with higher gas pressure. The axial uniformity of coaxial surface wave linear plasma could be controlled by pressure and power for a better utilization in material processing.     

Development of a compact high-density blue core helicon plasma device under 2000 G magnetic field of ring permanent magnets

A helicon wave plasma source in a tube of ring permanent magnets (PMs) has been constructed to study the effect of the configuration of the magnetic field with zero magnetic points on plasma parameters. This device also serves as an exploration platform for a simple, compact helicon wave plasma source adaptable to engineering applications. A small-diameter (26 mm) high-density (∼1018 m−3) blue core plasma is produced in ∼1 Pa argon by helicon RF (radio-frequency) discharge using a Nagoya III antenna under magnetic field (∼2 kG) of compact ring PMs (length ∼204 mm). Operational parameters, i.e. RF power and neutral gas pressure are scanned and plasma density is measured by an RF compensated probe to explore the operating characteristics of the device. Iconic feature of a helicon discharge, such as blue core plasmas and E-H-W mode transitions are well observed in the device, despite the wavelength calculated using the conventional dispersion relation of a bounded whistler waves (Chen 1991 Plasma Phys. Control. Fusion 33 339) is order of magnitudes longer than the length of the plasma in this device which seems to suggest that such helicon device is impossible. Surprisingly, the wavelength calculated by the unbounded whistle wave dispersion formula in turn suggests the occurrence of a half wavelength resonance.     

Reversal of radial glow distribution in helicon plasma induced by reversed magnetic field

In this work,the reversal of radial glow distribution induced by reversed magnetic field is reported.Based on the Boswell antenna which is symmetric and insensitive to the magnetic field direction,it seems such a phenomenon in theory appears impossible.However,according to the diagnostic of the helicon waves by magnetic probe,it is found that the direction of magnetic field significantly affects the propagation characteristic of helicon waves,i.e.,the interchange of the helicon waves at the upper and the lower half of tube was caused by reversing the direction of magnetic field.It is suggested that the variation of helicon wave against the direction of magnetic field causes the reversed radial glow distribution.The appearance of the traveling wave does not only improve the discharge strength,but also determines the transition of the discharge mode.     

Characteristics of inductively coupled plasma(ICP) and helicon plasma in a singleloop antenna

Large area uniform plasma sources, such as high-density magnetized inductively coupled plasma(ICP) and helicon plasma, have broad applications in industry. A comprehensive comparison of ICP and helicon plasma, excited by a single-loop antenna, is presented in this paper from the perspectives of mode transition, hysteresis behavior, and density distribution. The E-H mode transition in ICP and the E-H-W mode transition in helicon plasma are clearly observed in the experiments. Besides, the considerable variation of hysteresis behavior from inverse hysteresis to normal hysteresis by the influence of the magnetic field is explored. The bi-Maxwellian and Maxwellian electron energy distribution functions in each discharge are used to explain this phenomenon, which is essentially related to the transition from a nonlocal kinetic property to a local kinetic property of electrons. In addition, we notice that the plasma density, in the radial direction, is peaked in the center of the tube in ICP, but a complicated distribution is formed in helicon plasma. In the axial direction, the maximum plasma density is still in the center of the antenna in ICP, whereas the highest plasma density is located downstream, far away from the antenna, in helicon plasma. It is believed that the reflected electrons in the sheath and pre-sheath by the upper metallic endplate and downstream propagated helicon wave will be responsible for this plasma density profile in helicon plasma. Due to the constrained electron motion in the magnetic field, an extremely uniform density distribution will be obtained with an appropriate axial magnetic field in the wave discharge mode.     

Directional power absorption in helicon plasma sources excited by a half-helix antenna

This paper deals with the investigation of the power absorption in helicon plasma excited through a half-helix antenna driven at 13.56 MHz. The simulations were carried out by means of a code,HELIC. They were carried out by taking into account different inhomogeneous radial density profiles and for a wide range of plasma densities, from 10~(11) cm~(-3) to 10~(13) cm~(-3). The magnetic field was 200, 400, 600 and 1000 G. A three-parameter function was used for generating various density profiles with different volume gradients, edge gradients and density widths. The density profile had a large effect on the efficient Trivelpiece–Gould(TG) and helicon mode excitation and antenna coupling to the plasma. The fraction of power deposition via the TG mode was extremely dependent on the plasma density near the plasma boundary. Interestingly, the obtained efficient parallel helicon wavelength was close to the anticipated value for Gaussian radial density profile.Power deposition was considerably asymmetric when the n/B_0 ratio was more than a specific value for a determined density width. The longitudinal power absorption was symmetric at approximately n_0 =10~(11) cm~(-3), irrespective of the magnetic field supposed. The asymmetry became more pronounced when the plasma density was 10~(12) cm~(-3). The ratio of density width to the magnetic field was an important parameter in the power coupling. At high magnetic fields, the maximum of the power absorption was reached at higher plasma density widths. There was at least one combination of the plasma density, magnetic field and density width for which the RF power deposition at both side of the tube reached its maximum value.     

Electron population properties with different energies in a helicon plasma source

The characteristics of electrons play a dominant role in determining the ionization and acceleration processes of plasmas. Compared with electrostatic diagnostics, the optical method is independent of the radio frequency(RF) noise, magnetic field, and electric field. In this paper, an optical emission spectroscope was used to determine the plasma emission spectra, electron excitation energy population distributions(EEEPDs), growth rates of low-energy and highenergy electrons, and their intensity jumps with input powers. The 56 emission lines with the highest signal-to-noise ratio and their corresponding electron excitation energy were used for the translation of the spectrum into EEEPD. One discrete EEEPD has two clear different regions,namely the low-energy electron excitation region(neutral lines with threshold energy of13–15 eV) and the high-energy electron excitation region(ionic lines with threshold energy?19 e V). The EEEPD variations with different diameters of discharge tubes(20 mm, 40 mm,and 60 mm) and different input RF powers(200–1800 W) were investigated. By normalized intensity comparison of the ionic and neutral lines, the growth rate of the ionic population was higher than the neutral one, especially when the tube diameter was less than 40 mm and the input power was higher than 1000 W. Moreover, we found that the intensities of low-energy electrons and high-energy electrons jump at different input powers from inductively coupled(H) mode to helicon(W) mode; therefore, the determination of W mode needs to be carefully considered.     

Relationship of mode transitions and standing waves in helicon plasmas

Helicon wave plasma sources have the well-known advantages of high efficiency and high plasma density, with broad applications in many areas. The crucial mechanism lies with mode transitions, which has been an outstanding issue for years. We have built a fluid simulation model and further developed the Peking University Helicon Discharge code. The mode transitions, also known as density jumps, of a single-loop antenna discharge are reproduced in simulations for the first time. It is found that large-amplitude standing helicon waves (SHWs) are responsible for the mode transitions, similar to those of a resonant cavity for laser generation. This paper intends to give a complete and quantitative SHW resonance theory to explain the relationship of the mode transitions and the SHWs. The SHW resonance theory reasonably explains several key questions in helicon plasmas, such as mode transition and efficient power absorption, and helps to improve future plasma generation methods.     

The properties of N-doped diamond-like carbon films prepared by helicon wave plasma chemical vapor deposition

In this paper, N-doped diamond-like carbon(DLC) films were deposited on silicon substrates by using helicon wave plasma chemical vapor deposition(HWP-CVD) with the Ar/CH_4/N_2 mixed gas. The surface morphology, structural and mechanical properties of the N-doped DLC films were investigated in detail by scanning electron microscopy(SEM), x-ray photoelectron spectroscopy(XPS), Raman spectra, and atomic force microscopy(AFM). It can be observed from SEM images that surface morphology of the films become compact and uniform due to the incorporation of N. The maximum of the deposition rate of the films is 143 nm min~(-1), which is related to the high plasma density. The results of XPS show that the N incorporates in the films and the C-C sp~3 bond content increases firstly up to the maximum(20%) at 10 sccm of N_2 flow rate, and then decreases with further increase in the N_2 flow rate. The maximum Young's modulus of the films is obtained by the doping of N and reaches 80 GPa at 10 sccm of N_2 flow rate, which is measured by AFM in the scanning probe microscope mode. Meanwhile, friction characteristic of the N-doped DLC films reaches a minimum value of 0.010.     

Mechanism of high growth rate for diamond-like carbon films synthesized by helicon wave plasma chemical vapor deposition

A high growth rate fabrication of diamond-like carbon(DLC)films at room temperature was achieved by helicon wave plasma chemical vapor deposition(HWP-CVD)using Ar/CH_4gas mixtures.The microstructure and morphology of the films were characterized by Raman spectroscopy and scanning electron microscopy.The diagnosis of plasma excited by a helicon wave was measured by optical emission spectroscopy and a Langmuir probe.The mechanism of high growth rate fabrication for DLC films by HWP-CVD has been discussed.The growth rate of the DLC films reaches a maximum value of 54μm h~(-1)at the CH_4flow rate of 85 sccm,which is attributed to the higher plasma density during the helicon wave plasma discharge.The CH and H_αradicals play an important role in the growth of DLC films.The results show that the H_αradicals are beneficial to the formation and stabilization of C=C bond from sp~2to sp~3.     

The effect of nitrogen concentration on the properties of N-DLC prepared by helicon wave plasma chemical vapor deposition

Nitrogen-doped diamond-like carbon (N-DLC) films were synthesized by helicon wave plasma chemical vapor deposition (HWP-CVD). The mechanism of the plasma influence on the N-DLC structure and properties was revealed by the diagnosis of plasma. The effects of nitrogen doping on the mechanical and hydrophobicity properties of DLC films were studied. The change in the ratio of precursor gas flow reduces the concentration of film-forming groups, resulting in a decrease of growth rate with increasing nitrogen flow rate. The morphology and structure of N-DLC films were characterized by scanning probe microscopy, Raman spectroscopy, and X-ray photoemission spectroscopy. The mechanical properties and wettability of N-DLC were analyzed by an ultra-micro hardness tester and JC2000DM system. The results show that the content ratio of N+ and ${{\rm{N}}}_{2}^{+}$ is positively correlated with the mechanical properties and wettability of N-DLC films. The enhancement hardness and elastic modulus of N-DLC are attributed to the increase in sp3 carbon–nitrogen bond content in the film, reaching 26.5 GPa and 160 GPa respectively. Water contact measurement shows that the increase in the nitrogen-bond structure in N-DLC gives the film excellent hydrophobic properties, and the optimal water contact angle reaches 111.2°. It is shown that HWP technology has unique advantages in the modulation of functional nanomaterials.     

Investigation on plasma characteristics in a laser ablation pulsed plasma thruster by optical emission spectroscopy

In order to further improve the propulsion performance of pulsed plasma thrusters for space micro propulsion, a novel laser ablation pulsed plasma thruster is proposed, which separated the laser ablation and electromagnetic acceleration. Optical emission spectroscopy is utilized to investigate the plasma characteristics in the thruster. The spectral lines at different times,positions and discharge intensities are experimentally recorded, and the plasma characteristics in the discharge channel are concluded through analyzing the variation of spectral lines. With the discharge energy of 24 J, laser energy of 0.6 J and the use of aluminum propellant, the specific impulse and thrust efficiency reach 6808 s and 70.6%, respectively.     

Characteristics of temporal evolution of particle density and electron temperature in helicon discharge

On the basis of considering electrochemical reactions and collision relations in detail,a direct numerical simulation model of a helicon plasma discharge with three-dimensional two-fluid equations was employed to study the characteristics of the temporal evolution of particle density and electron temperature.With the assumption of weak ionization,the Maxwell equations coupled with the plasma parameters were directly solved in the whole computational domain.All of the partial differential equations were solved by the finite element solver in COMSOL MultiphysicsTM with a fully coupled method.In this work,the numerical cases were calculated with an Ar working medium and a Shoji-type antenna.The numerical results indicate that there exist two distinct modes of temporal evolution of the electron and ground atom density,which can be explained by the ion pumping effect.The evolution of the electron temperature is controlled by two schemes:electromagnetic wave heating and particle collision cooling.The high RF power results in a high peak electron temperature while the high gas pressure leads to a low steady temperature.In addition,an OES experiment using nine Ar I lines was conducted using a modified CR model to verify the validity of the results by simulation,showing that the trends of temporal evolution of electron density and temperature are well consistent with the numerically simulated ones.     

Power absorption,plasma parameters and wave structure in inductive RF plasma source with low value external magnetic field

The efficiency of radio-frequency (RF) power absorption, RF magnetic field structure and plasma parameters were measured in cylindrical inductive RF plasma sources 20 cm in diameter and 22, 32, 53 cm in length with a low value external magnetic field. The experiments were carried out in argon at pressures of 13–140 mPa. The RF power supply changed from 200 W to 800 W. The spiral antenna was used for sustaining the discharge. It was shown that efficiency of RF power absorption depended nonlinearly on the external magnetic field values. At maximal values of the RF power absorption efficiency, the axial distributions of longitudinal B_z and azimuthalBcomponents of RF magnetic field manifested the formation of the partially standing wave with a half wavelength close to 8 cm. At the same conditions, the axial dependence of the radial RF magnetic field component B_r differed drastically. It was concluded that the B_z and Bamplitudes were largely determined by the RF field of Trivelpiece-Gould wave, while B_r amplitude represented the radial RF field of the helicon wave.     

Preliminary Study of a Hybrid Helicon-ECR Plasma Source

A new type of hybrid discharge is experimentally investigated in this work. A helicon source and an electron cyclotron resonance(ECR) source were combined to produce plasma. As a preliminary study of this type of plasma, the optical emission spectroscopy(OES) method was used to obtain values of electron temperature and density under a series of typical conditions. Generally,it was observed that the electron temperature decreases and the electron density increases as the pressure increased. When increasing the applied power at a certain pressure, the average electron density at certain positions in the discharge does not increase significantly possibly due to the high degree of neutral depletion. Electron temperature increased with power in the hybrid mode.Possible mechanisms of these preliminary observations are discussed.