共查询到18条相似文献,搜索用时 62 毫秒
1.
2.
碲酸盐玻璃由于独特的光学性质在光通讯领域具有潜在的应用价值,如掺铒光纤放大器和非线性光学器件,因而得到广泛的关注。近几年,国内外为了提高碲酸盐玻璃的机械性质和光学性能而采取了玻璃的微晶化处理,希望得到碲酸盐玻璃陶瓷。对几种碲酸盐玻璃系统进行了热力学分析,研究比较了其析晶性能,并结合已见报道的文献论证了有望做出玻璃陶瓷的碲酸盐玻璃系统。 相似文献
3.
4.
ZnO对碲铌基重金属氧化物玻璃的结构和光学性能的影响 总被引:4,自引:0,他引:4
TeO2 Nb2O5系统重金属氧化物玻璃是一种新型的重金属氧化物玻璃材料,具有优良的非线性光学性能。本文研究了ZnO对碲铌基玻璃的结构、非线性光学性能和光学透过率的影响,研究表明:碲铌基玻璃的非线性光学效应源于电子云畸变效应,掺杂少量ZnO有利于玻璃非线性光学性能的提高,增加ZnO至2.5%(质量分数)时用四波混频法测得的玻璃三阶非线性极化率χ(3)可达9.2×10-13esu,然后随ZnO含量增至10%(质量分数)时χ(3)减至6.0×10-13esu。ZnO含量在10%~15%(质量分数)时χ(3)则无明显变化。同时,加入15%(质量分数)的ZnO有利于玻璃透过率的提高。Raman光谱研究表明,掺入过多的ZnO(>5%(质量分数))时,网络间隙中的Nb5+可被Zn2+取代而进入网络,同时提供更多的桥氧,从而使玻璃网络中的[TeO4]4-基团向[TeO3]2-转化。 相似文献
5.
碲酸盐氧卤玻璃具有低声子能以及较好的稳定性和析晶性能等优秀的综合品质,是一类很有前途的光学玻璃材料。采用熔融法制备了不同组成的TeO2-Nb2O5-BaO-BaCl2系统玻璃,研究了网络结构变化和组成对该系统玻璃的成玻璃性能和析晶性能的影响,同时探讨了向玻璃基体内引入银纳米晶体的可能性。结果表明,BaCl2的引入使得玻璃网络结构中键合及基团种类增多,碲氧链间的连接加强,网络结构更加紧密,并且成玻璃区域有所扩展。TeO2-Nb2O5-BaO-BaCl2系统玻璃基体在保持自身结构稳定性的同时,更有利于AgCl纳米晶体析出,是一种适合金属纳米晶掺杂的优良光学玻璃基体材料。 相似文献
6.
7.
不同铒离子掺杂浓度下碲酸盐玻璃荧光特性研究 总被引:2,自引:0,他引:2
测试了掺铒碲酸盐玻璃的荧光特性,研究了。^4I13/2能级上Er^3+离子的荧光谱、荧光强度和荧光寿命.研究显示,掺铒碲酸盐玻璃中存在着强烈的荧光俘获效应和浓度猝灭效应.荧光俘获效应使得荧光谱中的各谱线成分相对强度随着Er^3+离子掺杂浓度的增加发生改变,从而导致荧光谱主峰的变迁和荧光谱的展宽.Er^3+离子间的协作上转换引起的能量转移,使得荧光强度在较高掺杂浓度下发生猝灭.同时,荧光俘获效应和浓度猝灭效应的相互作用,导致荧光寿命随着Er^3+离子掺杂浓度的增加呈现出先增大后减小的变化趋势. 相似文献
8.
9.
10.
机械化学合成铁酸盐纳米晶的新进展 总被引:2,自引:0,他引:2
铁酸盐是一种重要的功能材料。本文介绍了纳米铁酸盐性质、应用及合成方法的特点。着重论述了机械化学法合成铁酸盐纳米晶的机制,并展望了该领域的发展趋势。 相似文献
11.
利用电场诱导热转印技术,通过电场诱导热扩散和后续热处理分别在硅酸盐玻璃内部获得了银离子与银纳米晶图形.借助XPS、FT-IR、UV-vis研究了银的扩散、析晶机制.结果发现,在直流电场作用下,图形膜中金属银通过电化学反应被氧化为银离子,并沿电力线扩散进入玻璃基体,分别以Ag+和Ag0形式占据Na+空位和填充到玻璃网络间隙.后续热处理过程中部分Ag+还原为Ag,银离子通过扩散、成核、析晶为银纳米晶.EPA和HRTEM等分析表明,玻璃内部获得的金属银离子及银纳米晶图形清晰,银含量最高可达24.5%(质量分数),扩散深度>200μm,银纳米晶体呈面心立方结构,直径为7~15nm. 相似文献
12.
W.A. CapanemaK. Yukimitu J.C.S. Moraes F.A. SantosM.S. Figueiredo S.M. SidelV.C.S. Reynoso O.A. SakaiA.N. Medina 《Optical Materials》2011,33(11):1569-1572
The structure and optical properties of a 80TeO2-(20−x)Li2O-xTiO2 glass system where x = 0, 5, 10, and 15 mol% has been investigated using FTIR spectroscopy and Brewster angle measurements. The sample preparation, linear refractive index and density measurements, and infrared spectroscopic analysis are described. The refractive index and density of the studied tellurite glass samples increase when the amount of Ti in the glass is increased. The dispersion of the phase refractive index was analyzed using Wemple’s model. The dispersion energy Ed is significantly affected by the addition of Ti to TeO2-based glass. The analysis of FTIR spectra indicate a Te coordination change that is in agreement with the increase of the Te coordination number determined from dispersion data using Wemple’s equation. 相似文献
13.
14.
15.
Sandra Balan Mendoza Jaime Sylvio Alves Ortiz Tiago Bassani Dantas Cristiano Ferreira Damasceno 《Packaging Technology and Science》2002,15(4):225-230
The mechanical performance of lightweight glass packages produced by the NNPB (narrow neck press and blow) process was evaluated by comparison with the same glass packages (regular weight) produced by the conventional process (blow and blow). The temper number (annealing process evaluation), thickness distribution behaviour and mechanical performance (impact, vertical load and thermal shock strength) were analysed before and after line simulation, applied in optimized conditions in the laboratory. The performance of lightweight glass packages under transport simulation (truck envelope) in relation to the regular weight bottles was also evaluated. Both bottles presented residual stress values within the specified limits. The lightweight glass bottles had a more homogenous thickness distribution in comparison with the regular weight bottles and a better performance (about 33% improvement) in relation to the impact strength, especially in the heel, even when evaluated after line simulation. As to the vertical load strength, the lightweight glass bottle also indicated a superior performance to the regular weight bottle, both before and after line simulation. Both bottles withstood the temperature difference of 42°C that such packages are supposed to resist according to thermal shock specification. Due to the better thickness distribution of lightweight glass packages, they withstood a maximum temperature difference (progressive thermal shock) of 5–10°C higher than the regular weight bottles. No restrictions of the lightweight glass packages submitted to the transport simulation were found. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
16.
17.
18.
大型LNG储罐底部泡沫玻璃绝热层保冷性能 总被引:1,自引:0,他引:1
通过理论分析和工程实例对比计算,得出泡沫玻璃绝热保冷层厚度与储罐底部冷损失、蒸发量、蒸发率关系式和关系曲线,证明在绝热层一定厚度范围内,冷损失、蒸发量、蒸发率均随绝热层厚度呈双曲线关系,降低较快,此后保冷性能趋于稳定。计算表明实际工程中所采用的绝热层普遍偏厚,如实例中绝热层厚度减少53.3%,冷损失仅为最大冷损失的7.58%,仅比实际值增加3.82%;日蒸发率为0.04%,仅比实际值增大0.02%,表明实际工程中大型LNG储罐底部绝热层厚度优化大有空间。 相似文献