一个用于精馏塔模拟的新模型

A new computational mass transfer model is proposed for simulating the distillation process by solving the fluctuating mass flux for the closure of turbulent mass transfer equation in order to obtain the concentration profile and the separation efficiency of distillation column. The feather of the proposed model is to abandon the conventional way of introducing the turbulent mass transfer diffusivity (dispersion coefficient) to the turbulent mass transfer equation. To verify the validity of the proposed model, a commercial scale packed column and a sieve tray column were simulated and compared with published experimental data. The simulated results were satisfactorily confirmed in both concentration distribution and separation efficiency.     

分壁精馏塔分离芳烃的稳态及动态研究

采用分壁精馏塔（DWC）严格稳态模型,对比苯、甲苯、二甲苯以及均三甲苯四组分混合物的常规分离和分壁精馏塔分离方法,稳态分析结果表明：直接序列分壁精馏塔流程较常规三塔分离序列可减小再沸器负荷18.9%,年度总成本TAC可降低13.0%,DWC有效避免了常规塔器分离过程中中间组分的返混现象。在Aspen Dynamic环境下对最优序列进行组分控制,结果表明组分控制可很好地应对进料流量和组分组成波动。     

用动态模拟技术进行油气田工艺处理系统开停工方案的研究

石油天然气开采过程中对于油气处理系统投产运行和系统关停过程的研究是系统设计过程中的重要组成部分。在设计过程中,油气生产工艺流程稳态模拟已得到广泛的应用,但对于非稳态工艺过程,如系统的开停工、控制系统的研究等,则必须借助动态模拟软件仿真模拟技术来进行研究。本文通过HYSYS软件的动态模拟系统对油气田处理工艺系统的开停工过程进行动态研究分析,以期通过开停工方案的研究,能对现场的实际生产起到有效的指导作用。     

醋酸甲酯侧反应精馏过程的多变量动态控制

侧反应器与精馏塔的耦合结构与物料交换方式的灵活性,造成系统的自由度高、设计变量多,增加了该过程的稳态优化模拟和动态控制的难度。针对侧反应精馏过程(SRC)的平滑操作和自动控制问题,以醋酸甲酯工业生产过程为例,采用基于独立反应量的稳态设计方法获取最佳的反应精馏集成结构和操作参数,在此基础上设计了以产品成分调节变比值控制为主的多变量控制方案,并通过在Aspen流程模拟软件建立醋酸甲酯侧反应精馏动态流程模拟系统,验证控制方案的有效性。     

拟稳态模型用于间歇萃取精馏的数值模拟

Batch extractive distillation (BED) is a special method used in the distillation process by adding a solvent into the batch distillation column to alter the relative volatility of the components and improve the separation. A comprehensive design and simulation method is required due to the complexity of BED. In this study, a quasi-steady-state model for BED is proposed, the derivation and solution of the model are presented. This shortcut model can be used to simulate the composition and temperature of the reboiler, the top and other plates of the column in a batch extractive distillation operation. The calculated values are in good agreement with the experi-mental data. The results show that the quasi-steady-state model is a practical method because of some advantages such as high precision and fast calculation.     

改进的信息流图及其在精馏塔建模与仿真中的应用

计算机动态建模与仿真中,人们最常用的用以辅助进行交流和讨论以及文档化相关成果与决策的分析、设计方法及表示法是信息流图（information flow diagram）。在前人研究的基础上,提出了一种改进的、更为完善的信息流图表示法。该表示法共包含三大类、九小类组成元素,基本能够完全覆盖计算机动态建模与仿真中所有种类的数学公式及其他模型表达方式。最后,以精馏塔的动态建模与仿真为例,详细说明了改进的信息流图的具体应用情况。事实证明,改进的信息流图不仅为相关工作人员提供了良好的沟通媒介,还使人们能够更加容易地从先前的仿真模型构建项目中复用需求和设计组件等,从而提高了仿真模型构建的效率和质量。     

乙烯装置开停车过程节能减排技术进展

随着我国乙烯装置的大型化、原料价格的增长以及环保要求的日益严格,乙烯装置开停车过程的节能减排研究逐渐受到乙烯企业和国内外研究者的重视。综述了国内外关于乙烯装置开停车过程中的节能减排技术,并对动态模拟在开停车节能减排中的应用进展进行了介绍。     

Application of iterative dynamic programming to optimal control of a distiltation column

Iterative Dynamic Programming (IDP) is proven to be a useful technique for solving constrained dynamic optimisation problems. A high purity binary distillation column model has been chosen to investigate some of the IDP properties as well as its applicability. The investigated problems cover transitions from one steady state to another with the minimization of a quadratic cost function with associated terminal constraints.     

规整填料精馏塔的设计计算

通过大量的文献调研，比较了规整填料精馏塔和板式塔的优缺点，对规整填料精馏塔内压降、传质及液泛时压降的计算公式进行了比较，总结出设计计算规整填料精馏塔的步骤与方法，为规整填料精馏塔的应用提供了基础。     

内部热耦合精馏塔的操作性能与模拟

对同轴式内部热耦合精馏塔的操作性能和节能效果进行了研究,考察了全回流操作条件下,压缩比对回流量、冷凝器负荷和再沸器负荷的影响。结果表明,随着压缩比的增大,回流量、冷凝器负荷和再沸器负荷均降低。通过实验数据计算得到了该塔的理论板数和两塔间的传热量,精馏段为9块理论板,提馏段为4块理论板,当压缩比为2.2:1时,两塔间传热量为9.98kW。连续操作条件下,对内部热耦合精馏塔的节能效果进行了分析,通过与常规精馏塔的比较,内部热耦合精馏塔可节约52.3%的冷量,输入的再沸器和压缩机总负荷可节约20.34%。另外,基于实验数据,对该内部热耦合精馏塔进行了动态模拟,经连续操作下的实验验证,该内部热耦合精馏塔可在2h后达到稳定操作。     

香茅油间歇精馏塔的工艺计算

对300t/a香茅油间歇精馏塔进行物料衡算,根据物料衡算的结果对精馏塔的操作温度、最小理论板数、理论板数、最小回流比、操作回流比和塔径等进行计算,获得塔体的工艺和设备参数。     

Modeling,simulation, and optimization of multiproduct cryogenic air separation unit startup

The startup of multiproduct cryogenic air separation plants takes several hours, during which time limited revenue is generated with high costs incurred due to the highly energy-intensive nature of these operations. This motivates the development of high-fidelity dynamic models to capture the complexity of the startup process to aid decision-making. This article focuses on the development of a startup model for a multiproduct air separation unit (ASU), and its use in dynamic simulation and optimization. To accomplish this, a first-principles based dynamic ASU model is extended by including various discontinuities using smooth approximations, adding dynamics to the primary heat exchanger, and extending the handling phase change within process streams. Dynamic simulations demonstrate plant response behavior during startup, including a failed startup resulting from an injudicious choice of input trajectory. In addition, improvement of startup operation is demonstrated through the incorporation of the model within a dynamic optimization framework.     

安庆石化Ⅰ套常减压装置流程模拟及优化

安庆石化应用ASPEN PLUS软件,建立Ⅰ套常减压装置模型,运用灵敏度分析工具,对装置进行模拟优化,将优化结果应用于生产,取得较好的应用效果.     

动态模拟用于加压汽提塔控制优化

带侧线加压单塔是煤气化废水工艺中的关键设备之一.但现有控制方案,存在操作难以稳定等问题.在对汽提塔动态模型讨论基础上,借助Aspen Dynamics动态模拟工具,对该汽提塔的动态特性、控制方案抗扰动能力以及对异常情况的响应情况等进行了深入讨论,在模拟基础上分析了现有控制方案的不足,并提出了改进方案.模拟和工业运行的结...     

A three-phase nonequilibrium dynamic model for catalytic distillation

A detailed three-phase nonequilibrium (NEQ) dynamic model for simulating batch and continuous catalytic distillation (CD) processes has been developed. In this model, both molar and energy holdups in liquid and vapour phases are taken into account. Multicomponent mass transfer and heat transfer between vapour and liquid phases as well as between liquid and solid (catalyst) phases are described by the Maxwell-Stefan equations. The resulting differential and algebra equations in this model are implemented in gPROMS and C++. The simulation results are in good agreement with the experimental data obtained from the batch and continuous CD processes for the production of diacetone alcohol (DAA) using Amberlite IRA-900 as a catalyst. Sensitivity analysis on the mass transfer and kinetics using the three-phase NEQ dynamic model indicates that the formation of DAA is controlled by solid-liquid mass transfer, whereas the formation of mesityl oxide is kinetically controlled under the simulation conditions.     

一种模拟气液相变过程的相变模型

提出了一种基于VOF（volume of fluid）方法的相变模型,用于计算气液相变过程的控制方程中的传热传质源项。在单位时间步长上相界面附近发生的传热以瞬态热扩散来考虑,并假设该传热导致了相变的发生。相变模型能够通过相界面单元的温度、流体热物性以及时间步长来计算传热传质源项。通过一维Stefan问题和二维水平膜沸腾问题对该相变模型进行验证,对比了相界面位置以及温度分布,结果与理论解吻合良好。进一步探讨了相变模型中的时间步长对计算精度的影响。结果表明时间步长越小,本相变模型模拟得到的结果与理论解的偏差越小。     

Minimum reflux calculation for multicomponent distillation in multi-feed,multi-product columns: Mathematical model

Multi-feed, multi-product distillation columns are ubiquitous in multicomponent distillation systems. The minimum reflux ratio of a distillation column is directly related to its energy consumption and capital cost. Thus, it is a key parameter for distillation systems design, operation, and comparison. In this series, we present the first accurate shortcut based algorithmic method to determine the minimum reflux condition for any general multi-feed, multi-product (MFMP) distillation column separating any ideal multicomponent mixture. The classic McCabe-Thiele or Underwood method is a special case of this general approach. Compared with existing techniques, this method does not involve any rigorous tray-by-tray calculation, nor does it require guessing of key components. In this first part of the series, we present the mathematical model for a general MFMP column, derive constraints for feasible separation and minimum reflux condition, discuss their geometric interpretations, and present an illustrative example to demonstrate the effectiveness of our approach.     

规整填料塔多元蒸馏过程混合型模型的模拟

填料塔精馏过程的模拟设计大多采用平衡级模型,但由于单一板效率值的难以确定,很多场合模拟很不成功;而新提出的非平衡级模型认为塔内传质传热均处于非平衡状态,由于方程数和经验性参数多,模型求解非常困难。文章针对规整填料的特点,建立了规整填料塔蒸馏过程的一种混合型模型,模型的主要特征是认为气液二相传质处于不平衡状态,而传热处于平衡状态。模型建立在实际填料基础上,既舍去传统的平衡级模型不确定性,又省略了非平衡级模型中复杂的经验性传热系数和液相传质系数的计算。模型计算值和实验值符合较好,也证实混合型模型既反映实际,又使模型求解变得相对容易。