共查询到20条相似文献,搜索用时 31 毫秒
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本文通过一体积较小而内腔结构复杂的汽车铰链罩注射模复杂部位的结构设计实例,突出说明了斜滑块抽芯机构和斜导柱抽芯机构在注射模中的重要作用。 相似文献
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Jingxiang Ma Marc Vollmann Henning Menzel Sven Pohle Holger Butenschön 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(1):41-50
Conventional molecular wires of the oligophenyleneethynylene (OPE) type are two-dimensional rigid molecules of fixed length.
Possible problems concerning π,π stacking and device geometry associated therewith might be overcome by replacement of some
of the 1,4-phenylene moieties by 1,1′-disubstituted ferrocene units. These make the wire three-dimensional thereby reducing
the likelihood of intermolecular π,π interactions and serve in addition as hinges as a result of the almost free rotation
around the Cp-Fe-Cp axis. This feature provides a limited conformational flexibility with the possibility of a length adjustment
comparable to a foldable ruler. Here the syntheses and some physical properties of molecular wires containing two ferrocene
hinges are described. In a number of cases the Sonogashira coupling reactions used for the coupling of the respective building
blocks proceed much faster under microwave irradiation as compared to conventional heating.
This paper is dedicated to Professor Didier Astruc in honor of his pioneering research efforts and accomplishments in the
field of organometallic materials. 相似文献
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Comparison of Glass Vessels and Plastic Bags for Enclosing Living Plant Parts for Headspace Analysis
Plants release volatile chemicals into their surrounding air space that can affect the physiology of neighboring plants and influence the behavior of insects. In studying these interactions, it is desirable to collect volatiles from plants that have not been excised and are growing under as natural conditions as possible. We compared a vessel of borosilicate glass and Nylon-6 or polyester [poly(ethyleneterephthalate) or PET] cooking bags for enclosing plants during collection of volatiles. A push–pull airflow system was used, and volatiles were trapped on Tenax TA and analyzed by gas chromatography after thermal desorption. Low levels of impurities were found for the glass vessel and polyester bags. Nylon bags contained higher levels and more impurities. Recoveries of standards of 10 plant volatiles were measured in static and dynamic systems. In a static air system, there was good recovery only from the glass vessel. In a dynamic system, there was generally good recovery from both the glass vessel and polyester bags. Recoveries of α-pinene and (Z)-jasmone were poor throughout. The former was shown to have a very low breakthrough volume on the Tenax TA adsorbent, and the latter may be strongly adsorbed on glass. All three materials were essentially transparent in the IR and visible (photosynthetic) range but with significantly different absorptions in the UV range. In a simulated dynamic entrainment in full sunlight, internal vessel temperatures were higher than ambient by up to 9.5°C in the glass vessel and 7.5°C in the polyester bag. Lower increases in temperature relative to ambient (<1°C) were recorded when entrainments were conducted in the shade. In a field trial, the profiles of volatiles collected from an apple tree infested with rosy apple aphid using a glass vessel and a polyester bag were similar. Polyester bags are recommended as more convenient than glass vessels for the enclosure of plants during the collection of volatiles. 相似文献
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Dr. Helmus van de Langemheen Valerijs Korotkovs Joachim Bijl Dr. Claire Wilson Dr. Sangram S. Kale Prof. Christian Heinis Prof. Rob M. J. Liskamp 《Chembiochem : a European journal of chemical biology》2017,18(4):387-395
Two polar hinges for cyclization of peptides have been developed, leading to bicyclic peptides and cyclized peptides with improved solubility and biological activity. Increasingly, we note that a good aqueous solubility of peptides is an absolute prerequisite, not only to allow handling and purification of our target peptides but also being crucial for biological activity characteristics. Compared to earlier hinges, the 1,1′,1“‐(1,3,5‐triazinane‐1,3,5‐triyl)tris(2‐bromoethanone) (TATB) and 2,4,6‐tris(bromomethyl)‐s‐triazine (TBMT), each containing three nitrogen atoms are structurally similar but chemically very different. Both were accessible in a one‐step fashion from bromoacetonitrile. TATB and TBMT are very suitable for the preparation of more soluble bicyclic peptides. Azide‐modified TATB and TBMT derivatives provide hinges for the preparation of cyclized peptides for incorporation on scaffolds to afford protein mimics. 相似文献
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