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Sebisty effect describes the unusual fact that the thickness of the hot-dip galvanizing coating on the steel containing 0.12%-0.25% silicon decreases with increasing temperature of zinc bath. The microstructures of hot-dip galvanized coatings on silicon-containing steels (0.14%Si) immersed in zinc bath at 723K and 753K were analyzed. It is found that the thickness of η and ζ layer decreases with the increase of temperature of zinc bath and Г layer changes from discontinuous layer (at 723K) to relatively continuous layer (at 753K). The improvement of the fluidity of zinc bath due to the rising temperature of zinc bath makes η layer thinner. Moreover, the existence of relatively continuous Г layer and the acceleration of the dissolution of ζ layer to zinc bath co-lead to the decrease of the thickness of ζ layer with increasing temperature. 相似文献
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热浸镀锌合金技术的发展与应用 总被引:3,自引:0,他引:3
综述了国内外关于热浸镀锌合金技术的最新发展.研究表明,锌浴中同时加入Ni和Bi的热镀锌效果较常规锌浴及Zn-Ni合金浴更佳;锌浴中加入适量的Sn可抑制高含硅量(大于0.25%Si)的钢材镀层的异常生长,其抑制机理是由于Sn在Fe-Zn合金相层生长前沿会形成一层连续层,从而阻碍了Fe-Zn相层生长。文中还介绍了Zn-Sn-Ni-Bi、Zn-Sn-V(Ni)以及Al-Sn-Bi合金技术的实际应用情况.
相似文献
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分析了42CrMo钢多节拉杆在热处理和热浸镀锌后出现裂纹的原因.结果表明,热加工过程中产生的过大残余应力是导致出现裂纹的原因.在满足拉杆力学性能的前提下,调质时适当提高回火温度,延长回火时间,并降低热浸镀锌温度,缩短在10% NH4Cl水溶液中的"爆光"时间,采用13%的水溶性有机介质冷却,可有效降低残余应力.通过上述工艺改进,可避免多节拉杆裂纹的产生. 相似文献
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从耐腐蚀性能的角度讨论了地锚拉杆镶嵌锻造的必要性。拉伸试验表明,地锚拉杆镶嵌锻造后,实用强度达不到设计要求的28.8 kN,断裂部位发生在拉杆镶嵌锻造部分,且靠近锁紧扣孔口。对拉杆镶嵌锻造部分的前后组织进行了金相观察,结果显示,拉杆冷变形后的细长晶粒经镶嵌锻造后重新转变成了等轴晶粒,产生了再结晶,冷变形强化效果消失是导致其实用强度下降的根源。进一步研究表明,拉杆产生再结晶是由高温锁紧扣锻坯热传导致其温度升高造成的。故镶嵌锻造前,在拉杆镶嵌锻造部分浸涂一定比例的混合液,使拉杆镶嵌锻造后的温度低至再结晶温度以下。采用此方法后的拉伸实验结果表明,地锚拉杆镶嵌锻造后实用强度未明显下降,金相分析也表明未产生再结晶。 相似文献
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超声波对热浸镀锌的影响 总被引:1,自引:0,他引:1
研究了超声波介入对热浸镀锌的镀层组织和性能的影响。结果表明大功率超声使镀层中不出现脆性的Fe-Zn金属间化合物层,镀层组织致密表面光滑,可显著地提高镀层的粘附性,变形性和耐蚀性。 相似文献
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The modified zinc phosphate conversion coatings(ZPC) were formed on hot-dip galvanized(HDG) steel when 1.0 g/L sodium molybdate were added in a traditional zinc phosphate solution. The growth performance and corrosion resistance of the modified ZPC were investigated by SEM, open circuit potential(OCP), mass gain, potentiodynamic polarization and electrochemical impedance spectroscopy(EIS) measurements and compared with those of the traditional ZPC. The results show that if sodium molybdate is added in a traditional zinc phosphate solution, the nucleation of zinc phosphate crystals is increased obviously; zinc phosphate crystals are changed from bulky acicular to fine flake and a more compact ZPC is obtained. Moreover, the mass gain and coverage of the modified ZPC are also boosted. The corrosion resistance of ZPC is increased with an increase in coverage, and thus the corrosion protection ability of the modified ZPC for HDG steel is more outstanding than that of the traditional ZPC. 相似文献
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笔者通过具体工程实例,详细分析了影响索道钢支架支柱热浸镀锌质量的各种因素,着重阐述了热浸镀锌过程中的各阶段动态控制的方法,可供类似工程借鉴、参考。 相似文献
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通过对变形量50%的20钢不同温度及时间的镀层层深的测定,根据公式ρ~2=k_0τe~(-Q/RT)计算出铝的扩散激活能。 相似文献
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测试了30钢经50%强形变后在不同温度下再结晶形核的时间,根据公式G=G。e^-QIRT计算了再结晶晶核的激活能。 相似文献
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