Biogas production from catch crops: Increased yield by combined harvest of catch crops and straw and preservation by ensiling

The combination of catch crop cultivation with its use for biogas production would increase renewable energy production in the form of methane, without interfering with the production of food and fodder crops. The low biomass yield of catch crops has been shown as the main limiting factor for using these crops as co-substrate in biogas plants, since the profit obtained from the sale of methane barely compensates the harvest costs. Therefore, a new agricultural strategy to harvest catch crops together with the residual straw of the main crop was investigated, in order to increase the biomass and the methane yield per hectare. Seven catch crops harvested together with stubble from the previous main crop were evaluated. The effects of stubble height, harvest time and ensiling as a storage method for the different catch crops/straw blends were studied. Biomass yields as TS ranged between 3.2 and 3.6 t ha⁻¹ y⁻¹of which the catch crop constituted around 10% of the total biomass yield. Leaving the straw on the field until harvest of the catch crop in the autumn could benefit methane production from the straw both due to increased biomass yield and an increased organic matter bioavailability of the straw taking place on the field during the autumn months. Ensiling as a storage method could be feasible in terms of energy storage and guaranteeing the feedstock availability for the whole year. This new agricultural strategy may be a good alternative for economically feasible supply of catch crops and straw for biogas production.     

Modeling & optimization of renewable hydrogen production from biomass via anaerobic digestion & dry reformation

There is a growing interest in the usage of hydrogen as an environmentally cleaner form of energy for end users. However, hydrogen does not occur naturally and needs to be produced through energy intensive processes, such as steam reformation. In order to be truly renewable, hydrogen must be produced through processes that do not lead to direct or indirect carbon dioxide emissions. Dry reformation of methane is a route that consumes carbon dioxide to produce hydrogen. This work describes the production of hydrogen from biomass via anaerobic digestion of waste biomass and dry reformation of biogas. This process consumes carbon dioxide instead of releasing it and uses only renewable feed materials for hydrogen production. An end-to-end simulation of this process is developed primarily using Aspen HYSYS® and consists of steady state models for anaerobic digestion of biomass, dry reformation of biogas in a fixed-bed catalytic reactor containing Ni–Co/Al₂O₃ catalyst, and a custom-model for hydrogen separation using a hollow fibre membrane separator. A mixture-process variable design is used to simultaneously optimize feed composition and process conditions for the process. It is identified that if biogas containing 52 mol% methane, 38 mol% carbon dioxide, and 10 mol% water (or steam) is used for hydrogen production by dry reformation at a temperature of 837.5 °C and a pressure of 101.3 kPa; optimal values of 89.9% methane conversion, 99.99% carbon dioxide conversion and hydrogen selectivity 1.21 can be obtained.     

A comprehensive review on pretreatment of microalgae for biogas production

Use of microalgal biomass for renewable energy production has gained considerable attention in the world due to increasing global energy demand and negative environmental impacts of nonrenewable fossil fuels. Anaerobic digestion is one of the renewable technologies that microalgal biomass is converted into biogas by anaerobic archea. One of the main drawbacks of using microalgal biomass for biogas production is that certain types of microalgae has rigid cell wall characteristics, which limits accessibility of anaerobic archea to microalgal intracellular organic matter during hydrolysis phase. This limitation lowers efficiency of biogas production from microalgal biomass. However, introducing pretreatment methods prior to anaerobic digestion provides disruption of rigid microalgal cell wall and improve biogas yields from microalgal biomass. The objective of this paper was to review current knowledge related to pretreatment methods applied prior to anaerobic digestion of microalgal biomass. Efficiency and applicability of pretreatment methods mainly depend on type of microalgae, cell wall characteristics, and cost and energy requirements during pretreatment process. In this review, various type of pretreatment methods applied to microalgal biomass was discussed in detail with background knowledge and literature studies in their potential on maximization of biogas yields and their cost effectiveness, which is important for large‐scale applications. In the view of current knowledge, it was concluded that each pretreatment method has a relative contribution to improvement in biogas production depending on the type of microalgae. However, energy and cost requirements are the main limitations for pretreatment. So, further studies should focus on reduction of cost and energy demand by introducing combined methods, novel chemicals, and on‐site or immobilized enzymes in pretreatment to increase feasibility of pretreatment prior to anaerobic digestion in industrial scale.     

Performance evaluation of biogas upgrading systems from swine farm to biomethane production for renewable hydrogen source

Biogas upgrading to biomethane is a necessary process for biohydrogen production from renewable source. In this work, absorption processes using water and diethanolamine (DEA) as absorbent were modeled in Aspen Plus software. The purpose was to find the optimal operating condition for sustainable production of biomethane using multi-criteria perspective considering technical, environmental and economic aspects. The absorption system was modified by including one additional absorber unit for improving biogas upgrading efficiency. The performance of the biogas upgrading system was evaluated and compared in terms of methane recovery, methane content in biomethane, and energy consumption. Effects of operating conditions such as operating pressure in absorber, concentration, and total flow rate of absorbents were investigated. The results revealed that the performance of the modified absorption system was superior to the conventional system. The methane content in biomethane, methane recovery, and energy consumption increased with the increase of operating pressure in the absorbers. Increasing concentration and total flow rate of absorbents increased the methane content in biomethane and the energy consumption but decreased the methane recovery. The optimal operating condition could achieve 96%v/v of methane content in biomethane with methane recovery of higher than 95%v/v in the modified water absorption system. The optimum operating pressures of absorber Units 1 and 2, and total absorbent flow rates were at 13 and 5 bar and 16,000 kmol/h, respectively.     

Bio-fuels from Agricutural Residues

Abstract

Bio-fuels, such as bio-oil, bio-char, and bio-gas, can be obtained from agricultural residues. Agricultural residues are potential renewable energy resources such as biogas from anaerobic digestion, bio-oil from pyrolysis, and bio-char from carbonization and slow pyrolysis processes. Pyrolysis process of agricultural residues are the most common and convenient methods for conversion into bio-oil and bio-char. When the pyrolysis temperature increased, the bio-char yield decreased. The bio-char yield increased with increasing particle size of the sample. The yield of bio-oil from pyrolysis of the samples increased with temperature. Anaerobic biogas production is an effective process for conversion of a broad variety of agricultural biomass to methane to substitute natural gas and medium calorific value gases.     

Potential for biofuels from the biomass of prickly pear cladodes: Challenges for bioethanol and biogas production in dry areas

Prickly pear is a term used to refer to several species of cactus belonging primarily to the genus Opuntia. In general, these species present an exceptional ability to produce biomass in soil and climate conditions unfavorable for most plant species, in part due to their high water use efficiency. Given the current increase demand for renewable energy and the future prospect of more limited water resources, the potential use of prickly pear cladodes for biofuel production deserves to be investigated. The objectives of this study were to gather information on the chemical composition of prickly pear biomass from the most cultivated varieties in NE Brazil, discuss the potential of processing biomass for ethanol and biogas production and to point out gaps in know-how and priorities for research on this topic. We quantified in the tree varieties studied significant amounts of uronic acids (10.7%) and oxalic acid (10.3%), confirming the reports of high amounts of pectin and calcium oxalate in cladodes of prickly pear. The estimated potential of ethanol production for prickly pear (1490–1875 L ha⁻¹ yr⁻¹) was low when compared to traditional biomass sources (sugarcane and sugar beet, for example). However, it appears that prickly pear stands out as a biomass with potential for high production rates of methane (3717 m³ ha⁻¹ yr⁻¹), being comparable to traditional energy crops. Further studies are needed to assess more consistently both the sustainability of biomass production as the potential for ethanol, and biogas production, specially for newly released varieties of prickly pear.     

Optimization of biogas production by anaerobic digestion for sustainable energy development in Zimbabwe

There is increasing international interest in developing low carbon renewable energy technologies. Biomass is increasingly being utilized as an energy source throughout the world. Several modern technologies have been developed that convert biomass to bioenergy. Anaerobic digestion is a mature energy technology for converting biomass to biogas, which is a renewable primary energy source. Biogas is a robust fuel that can be used to supply heat, electricity, process steam and methanol. There are vast biomass resources in Zimbabwe that have good potential for biogas production by anaerobic digestion. However, anaerobic digestion is not being optimally used as a biomass conversion technology in the country. This paper presents an overview of biogas production in Zimbabwe and outlines technical options that can be utilized to optimize biogas production by anaerobic digestion in the country.     

Technoeconomic analysis of a methanol plant based on gasification of biomass and electrolysis of water

Methanol production process configurations based on renewable energy sources have been designed. The processes were analyzed in the thermodynamic process simulation tool DNA. The syngas used for the catalytic methanol production was produced by gasification of biomass, electrolysis of water, CO₂ from post-combustion capture and autothermal reforming of natural gas or biogas. Underground gas storage of hydrogen and oxygen was used in connection with the electrolysis to enable the electrolyser to follow the variations in the power produced by renewables. Six plant configurations, each with a different syngas production method, were compared. The plants achieve methanol exergy efficiencies of 59–72%, the best from a configuration incorporating autothermal reforming of biogas and electrolysis of water for syngas production. The different processes in the plants are highly heat integrated, and the low-temperature waste heat is used for district heat production. This results in high total energy efficiencies (∼90%) for the plants. The specific methanol costs for the six plants are in the range 11.8–25.3 €/GJ_exergy. The lowest cost is obtained by a plant using electrolysis of water, gasification of biomass and autothermal reforming of natural gas for syngas production.     

Waste-to-energy: A way from renewable energy sources to sustainable development

Nowadays, energy is key consideration in discussions of sustainable development. So, sustainable development requires a sustainable supply of clean and affordable renewable energy sources that do not cause negative societal impacts. Energy sources such as solar radiation, the winds, waves and tides are generally considered renewable and, therefore, sustainable over the relatively long term. Wastes and biomass fuels are usually viewed as sustainable energy sources. Wastes are convertible to useful energy forms like hydrogen (biohydrogen), biogas, bioalcohol, etc., through waste-to-energy technologies.In this article, possible future energy utilization patterns and related environmental impacts, potential solutions to current environmental problems and renewable energy technologies and their relation to sustainable development are discussed with great emphasis on waste-to-energy routes (WTERs).     

Evaluation of biogas production from different biomass wastes with/without hydrothermal pretreatment

Municipal biomass waste is regarded as new available energy source, although it could cause serious environmental pollution. Generally, biogas recovery by anaerobic digestion was seen as an ideal way to treat biomass waste. Different types of biomass waste have different biogas production potential. In this paper, cow manure, pig manure, municipal sewage sludge, fruit/vegetable waste, and food waste were chosen as typical municipal biomass waste. In addition, hydrothermal pretreatment was used to accelerate digestion and increase biogas production. Biochemical methane potential (BMP) test was used to evaluate biogas production for raw biomass and hydrothermal treated waste. Raw materials of fruit/vegetable and food waste show higher methane production than that of cow manure, pig manure, and municipal sewage sludge. After hydrothermal pretreatment at typical condition (170 °C at 1 h), the biogas production of pig manure, cow manure, fruit/vegetable waste, and municipal sewage sludge increased by 7.8, 13.3, 18.5, and 67.8% respectively. While, for treated food waste, the biogas decrease by 3.4%. The methane yield of pig manure, fruit/vegetable waste, and municipal sewage sludge increased by 14.6, 16.1, and 65.8%, respectively. While, for treated cow manure and food waste, the methane decrease by 6.9% and 7.5%.     

Biogas production and its application in compressed gas

Nowadays, the world is facing critical problem of energy deficit, global warming, and deterioration of the environment. Under the current scenario, the biogas energy source is the most challenging one to cope up with the scarcity of energy. Biogas is a renewable energy source which can be obtained by fermentation of organic matter also known as biomass. The biomass includes livestock waste (cow dung, manure, and uneaten food), food waste, and residues from meat, fish and dairy processing. The present study is to explore the potential of biogas production from cow dung and its usage through compressed form in a cylinder. This stored biogas can be put in use to the extent where it is required and it also reduces transportation costs, which is a major hurdle in the biogas usage. This paper summarizes an idea that can be carried out for effective biogas production, scrubbing, compression, and bottling process.     

Biogas derived from municipal solid waste to generate electrical power through solid oxide fuel cells

Depleting fossil fuels and the pollution resulting from their consumption indicate an urgent need for clean and dependable alternatives such as renewable energies. Biomass is a free and abundant source of renewable energy. Municipal solid waste (MSW) as one of the main categories of biomass has always been an issue for metropolitan cities. It has, however, a high potential for biogas production. In this study, the technical and economic aspects of generating electrical power through solid oxide fuel cells (SOFCs) powered by injecting biogas derived from Tehran's MSW, as a case study, are investigated. The main objectives of the current study are to identify the power generation capability of the process and find out if it can result in a competitive energy resource. The total amount of obtainable methane through anaerobic digestion of MSW and then the achievable power generation capacity by using the obtained biogas are computed using the electrochemical relations inside the SOFC. The economic calculations are carried out to estimate the final price of the generated electricity, taking into account the major capital and ongoing costs of the required equipment. The effect of variations of MSW composition on the power generation capability and final electricity price is also studied. Moreover, the application of a gas turbine (GT) with the SOFC as a hybrid SOFC–GT system to recover the produced heat by SOFC and its effect on the power generation capability and the final electricity price are investigated. Results indicate that around 997.3 tons day^?1 biomethane can be generated using Tehran's MSW. By using the SOFC, the produced biogas can generate 300 MW_AC electrical power with a final cost of Depleting fossil fuels and the pollution resulting from their consumption indicate an urgent need for clean and dependable alternatives such as renewable energies. Biomass is a free and abundant source of renewable energy. Municipal solid waste (MSW) as one of the main categories of biomass has always been an issue for metropolitan cities. It has, however, a high potential for biogas production. In this study, the technical and economic aspects of generating electrical power through solid oxide fuel cells (SOFCs) powered by injecting biogas derived from Tehran's MSW, as a case study, are investigated. The main objectives of the current study are to identify the power generation capability of the process and find out if it can result in a competitive energy resource. The total amount of obtainable methane through anaerobic digestion of MSW and then the achievable power generation capacity by using the obtained biogas are computed using the electrochemical relations inside the SOFC. The economic calculations are carried out to estimate the final price of the generated electricity, taking into account the major capital and ongoing costs of the required equipment. The effect of variations of MSW composition on the power generation capability and final electricity price is also studied. Moreover, the application of a gas turbine (GT) with the SOFC as a hybrid SOFC–GT system to recover the produced heat by SOFC and its effect on the power generation capability and the final electricity price are investigated. Results indicate that around 997.3 tons day^?1 biomethane can be generated using Tehran's MSW. By using the SOFC, the produced biogas can generate 300 MW_AC electrical power with a final cost of $0.178 kWh^?1. By using the hybrid SOFC–GT, the electrical power capacity is increased to 525 MW_AC, and the final electricity cost drops to $0.11 kWh^?1, which indicates its competitiveness with other common energy resources in the near future, especially by considering different governmental subsidy policies that support renewable energy resources. The considerable environmental benefits of the proposed procedure, from both MSW management and CO₂ emission reduction points of view, make it a promising sustainable energy resource for the future. Copyright © 2016 John Wiley & Sons, Ltd.     

Biogas generation potential by anaerobic digestion for sustainable energy development in India

The potential of biogas generation from anaerobic digestion of different waste biomass in India has been studied. Renewable energy from biomass is one of the most efficient and effective options among the various other alternative sources of energy currently available. The anaerobic digestion of biomass requires less capital investment and per unit production cost as compared to other renewable energy sources such as hydro, solar and wind. Further, renewable energy from biomass is available as a domestic resource in the rural areas, which is not subject to world price fluctuations or the supply uncertainties as of imported and conventional fuels. In India, energy demand from various sectors is increased substantially and the energy supply is not in pace with the demand which resulted in a deficit of 11,436 MW which is equivalent to 12.6% of peak demand in 2006. The total installed capacity of bioenergy generation till 2007 from solid biomass and waste to energy is about 1227 MW against a potential of 25,700 MW. The bioenergy potential from municipal solid waste, crop residue and agricultural waste, wastewater sludge, animal manure, industrial waste which includes distilleries, dairy plants, pulp and paper, poultry, slaughter houses, sugar industries is estimated. The total potential of biogas from all the above sources excluding wastewater has been estimated to be 40,734 Mm³/year.     

Two-stage anaerobic dry digestion of blue mussel and reed

Blue mussels and reeds were explored as a new biomass type in the Kalmar County of Sweden to improve renewable transport fuel production in the form of biogas. Anaerobic digestion of blue mussels and reeds was performed at a laboratory-scale to evaluate biogas production in a two-stage dry digestion system. The two-stage system consisted of a leach bed reactor and an upflow anaerobic sludge blanket (UASB) reactor. The two-stage system was efficient for the digestion of blue mussels, including shells, and a methane yield of 0.33 m³/kg volatile solids (VS) was obtained. The meat fraction of blue mussels was easily solubilised in the leach bed reactor and the soluble organic materials were rapidly converted in the UASB reactor from which 68% of the methane was produced. However, the digestion of mussels including shells gave low production capacity, which may result in a less economically viable biogas process. A low methane potential, 0.22 m³/kg VS, was obtained in the anaerobic two-stage digestion of reeds after 107 days; however, it was comparable to similar types of biomass, such as straw. About 80% of the methane was produced in the leach bed reactor. Hence, only a leach bed reactor (dry digestion) may be needed to digest reed. The two-stage anaerobic digestion of blue mussels and reeds resulted in an energy potential of 16.6 and 10.7 GWh/year, respectively, from the estimated harvest amounts. Two-stage anaerobic digestion of new organic materials such as blue mussels and reeds can be a promising biomass resource as land-based biomass start to be limited and conflict with food resources can be avoided.     

Biogas: A promising renewable technology and its impact on rural households in Nepal

Nepal, one of the least developed countries, is characterized by very low per capita energy consumption. Because of a lack of other commercial sources of energy, the country relies heavily on traditional fuel source, especially firewood. In order to solve the energy problem in rural areas, the country initiated production and distribution of several renewable energy technologies. Among several technologies, biogas has been proved to be viable and emerged as a promising technology. It has been one of the most successful models for the production of clean, environmental friendly, cost effective source of energy and has multiple benefits. In this paper we present the current state and discuss benefits of the biogas technology in Nepal. Improved health, increased crop productivity, saved time for women are some of the major benefits to the users. It provides economic benefit to the country through reduced deforestation and carbon trading. In addition, by reducing green house gas emission, the technology helps in mitigating global warming and climate change. Thus biogas is a renewable, sustainable and clean source of energy that provides multiple benefits; locally and globally. With some exception, cattle dung has been used primarily as an input and the technology is limited to households only. More systematic and comprehensive study supported by research and development is required to use other degradable waste such as municipal waste to produce biogas on a large scale.     

Hydrogen and methane production from lipid-extracted microalgal biomass residues

A two-stage process to produce hydrogen and methane from lipid-extracted microalgal biomass residues (LMBRs) was developed. The biogas production and energy efficiency were compared between one- and two-stage processes. The two-stage process generated 46 ± 2.4 mL H₂/g-volatile solid (VS), and 393.6 ± 19.5 mL CH₄/g-VS. The methane yield was 22% higher than the one in the one-stage process. Energy efficiency increased from 51% in the one-stage process to 65% in the two-stage process. Additionally, it was found that repeated batch cultivation was a useful method to cultivate the cultures to improve the methane production rate and reduce the fermentation time. In the repeated batch cultivation, the methane yield slightly decreased if the ammonia levels rose, suggesting that the accumulation of ammonia could affect methane production.     

Effect of thermal, chemical and thermo-chemical pre-treatments to enhance methane production

The rise in oil price triggered the exploration and enhancement of various renewable energy sources. Producing biogas from organic waste is not only providing a clean sustainable indigenous fuel to the number of on-farm digesters in Europe, but also reducing the ecological and environmental deterioration. The lignocellulosic substrates are not completely biodegraded in anaerobic digesters operating at commercial scale due to their complex physical and chemical structure, which result in meager energy recovery in terms of methane yield. The focus of this study is to investigate the effect of pre-treatments: thermal, thermo-chemical and chemical pre-treatments on the biogas and methane potential of dewatered pig manure. A laboratory scale batch digester is used for these pre-treatments at different temperature range (25 °C-150 °C). Results showed that thermo-chemical pretreatment has high effect on biogas and methane potential in the temperature range (25–100 °C). Maximum enhancement is observed at 70 °C with increase of 78% biogas and 60% methane production. Thermal pretreatment also showed enhancement in the temperature range (50–10 °C), with maximum enhancement at 100 °C having 28% biogas and 25% methane increase.     

Challenges in biogas production from anaerobic membrane bioreactors

Spectacular applications of anaerobic membrane bioreactors (AnMBRs) are emerging due to the membrane enhanced biogas production in the form of renewable bioresources. They produce similar energy derived from the world's depleting natural fossil energy sources while minimizing greenhouse gas (GHG) emissions. During the last decade, many types of AnMBRs have been developed and applied so as to make biogas technology practical and economically viable. Referring to both conventional and advanced configurations, this review presents a comprehensive summary of AnMBRs for biogas production in recent years. The potential of biogas production from AnMBRs cannot be fully exploited, since certain constraints still remain and these cause low methane yield. This paper addresses a detailed assessment on the potential challenges that AnMBRs are encountering, with a major focus on many inhibitory substances and operational dilemmas. The aim is to provide a solid platform for advances in novel AnMBRs applications for optimized biogas production.     

Renewable energy market conditions and barriers in Turkey

Decentralized wind, hydropower, biogas and biomass, geothermal, solar thermal and solar electricity energy systems are the most commonly found renewable energy technologies promoted for rural energy supply within sustainable developments programs. They are, therefore, seen to have a central place in the practice of sustainable development and in allowing less development countries to bypass the environmentally damaging fossil fuel intensive paths made by industrialized countries. On the political front, many less development countries are critical of pressure on them to adopt environmental energy technologies.Turkey is situated the meeting point of three continents (Asia, Europe and Africa) and stands as a bridge between Asia and Europe. The country is located in southeastern Europe and southwestern Asia. As Turkey’s economy has expanded in recent years, the consumption of primary energy has increased. Presently in order to increase the energy production from domestic energy resources, decrease the use of fossil fuels as well as reduce of green house gas emissions different renewable energy sources are used for energy production in Turkey. The share of energy production from renewable energy sources has increased during the last 10 years. Turkey must import most of the energy to meet her needs. Turkey also has a large potential for renewable energies. The lack of knowledge about renewable energy technologies by most policy-makers, potential consumers, and energy firm managers has played against renewable energy developments. The paper presents renewable energy used in Turkey and Europe Union and evaluation of the market conditions and barriers of renewable energy use in Turkey.     

Simulation of a solar‐biogas hybrid energy system for heating,fuel supply,and power generation

Biogas production from organic wastes has been widely utilized for several decades, but maintaining right temperature for anaerobic bacteria is a challenge. In order to overcome the inhibition of the bacteria growth and biogas production due to the low temperature, a solar‐biogas hybrid energy system for heating, fuel supply, and power generation has been proposed for converting domestic garbage into biogas in a rural area of China. In this system, the solar energy has been included as one of the heating sources during an anaerobic digestion process. A mathematical model has been developed to evaluate the influence of system operating characteristics. Based on the simulation results, the biogas production rate, thermal efficiency, temperature of the digester, energy distributions in the system, optimal operating parameters, economic efficiency, and thermodynamic characteristics of the system were analyzed. The impact of solar irradiation on the efficiency of the system was also studied. According to the results, in cloudy days, the reactor volume and solar collector area greatly influenced the steady energy supply. In winter, the produced biogas is mostly utilized by the aided boiler to maintain the proper organic mixture temperature in the bioreactor. Heat loss from bioreactor dramatically increases the organic mixture volume. Per simulation, the longest return on the investment of this type of the biogas system is about 5.54 years, and the shortest return on the investment is less than 4 years if the battery is removed and the electric grid can be used. Therefore, in this study, the feasibility of a hybrid energy system for converting domestic garbage into energy has been validated. Copyright © 2017 John Wiley & Sons, Ltd.