A systematic technique for cost-effective CO<Subscript>2</Subscript> emission reduction in process plants

There has been growing interests to reduce the environmental impact caused by greenhouse gas emissions from process plants through various energy conservation strategies. CO₂ emissions are closely linked to energy generation, conversion, transmission and utilisation. Various studies on the design of energy-efficient processes, optimal mix of renewable energy and hybrid power system are driven to reduce reliance on fossil fuel as well as CO₂ emissions reduction. This paper presents a systematic technique in the form of graphical visualisation tool for cost-effective CO₂ emission reduction strategies in industry. The methodology is performed in four steps. The first step involves calculating the energy consumption of a process plant. This is followed by identification of potential strategies to reduce CO₂ emissions using the CO₂ management hierarchy as a guide. In the third step, the development of “Investment” versus “CO₂ Reduction” (ICO₂) plot is constructed to measure the optimal CO₂ emission reductions achieved from the implementation of possible CO₂ reduction strategies. The Systematic Hierarchical Approach for Resilient Process Screening (Wan Alwi and Manan in AIChE J 11:3981–3988, 2006) method is used in the fourth step via substitution or partial implementation of the various CO₂ reduction options in order to meet the cost-effective emission reduction within the desired investment limit or payback period (PP). An illustrative case study on a palm oil refinery plant has been used to demonstrate the implementation of the method in reduction of CO₂ emissions. The developed graphical tool provides an insight-based approach for systematic CO₂ emission reduction in the palm oil refinery considering both heat and power energy sources. Result shows that 31.2 % reduction in CO₂ emissions can be achieved with an investment of USD 38,212 and PP of 10 months based on the present energy prices in Malaysia.     

CO2‐neutrale Mobilität als Herausforderung und Chance

CO₂‐neutral Mobility as a Challenge and an Opportunity – From the powertrain to the electrolyzer: Plasma surface technology along the energy chain Three concepts are suitable for CO₂‐neutral and sustainable mobility: First, the direct use of electrical energy for battery electric vehicles (BEV). Secondly, the conversion of regeneratively generated electricity into green hydrogen as an energy carrier for fuel cell electric vehicles (FCEV) and thirdly, the generation of synthetic fuels from green hydrogen. The technologies will complement each other in terms of vehicle weight, distance and required propulsion power. Regardless of the powertrain concept, plasma surface technology offers outstanding opportunities for the optimization of highly stressed tribological systems. For example, Triondur PVD and PACVD coating systems in the automotive industry, where they were initially used to prevent wear, have become an extremely valuable design element for increasing energy efficiency and CO₂ savings through friction reduction. As a result, more than 150 million components coated with Triondur were delivered worldwide in 2018. Defossilization of the energy chain requires increased industrialization of components for electrolyzers and fuel cells, such as the metallic bipolar plates of galvanic cells. Here, as well, plasma surface technology will play a key role in meeting the high demands for the required electrochemical properties and quality standards. For CO₂‐neutral and sustainable mobility, plasma surface technology will always be and remain an important key technology, regardless of the powertrain concept.     

Long-term effects of structural changes in the Brazilian electricity matrix

The Brazilian 2015 Intended Nationally Determined Contribution proposes a reduction of 43% in its greenhouse gas emissions by 2030, compared to its 2005 emissions. In terms of the contribution of the Brazilian electrical sector to achieve this target, it commits to increase the use of renewable energy sources, other than hydroelectricity, and an efficiency gain of 10% by 2030. Considering these targets, this paper estimates the economic and CO₂ emissions effects of such propositions using input–output analysis. The estimates are based on eight different future electricity matrices scenarios (2030 and 2050) developed by specialists within the Energy Scenarios Platform. On the one hand, achieving cleaner electrical production requires large investments. On the other hand, a reorganization of the sector leading to increased use of renewable energy sources produces GDP and employment growth. The results show that the net effects are positive in the medium and long run. Brazilian GDP growth may range from 0.61 to 1.24% per year by 2030 and from 0.66 to 1.26% per year by 2050, and total labor demand may reach 630 thousand new employees in 2030 and 685 thousand jobs in 2050. Regarding the reduction of CO\(_2\) emissions, a maximum saving of 4 million tons by 2030 and 1 million tons by 2050 is expected. Therefore, according to the scenarios analyzed, although investing in renewable electrical sources demands more investment, their operational costs are lower, such that the extra expending is more than offset. Hence, the economic benefits from such changes more than compensate the costs of investing in such efforts.     

Prozessberechnungen für eine CO<Subscript>2</Subscript>-Anlage zur Kälte- und Wärmeerzeugung für Supermärkte. Teil 2: Begrenzte bzw. keine CO<Subscript>2</Subscript>-Abkühlung durch Umgebungsluft

CO₂ processes are used in supermarkets for medium- and low-temperature refrigeration and by now even for room heating and hot tap-water preparation via heat recovery. Through systematic thermodynamic process calculations, the limits of the heat recovery and it’s influence on the refrigeration process as well as the complete system are investigated for a supermarket with 100 kW medium-temperature refrigeration capacity. This investigation focuses on the energy efficiency of the heat supply by the extended CO₂ plant. By using the medium-temperature refrigeration capacity as reference, the results for ambient temperatures between ??15?°C and +?10?°C are applicable for other supermarket sizes as well.In part 2, a plant is investigated with a ratio between low- and medium-temperature refrigeration capacity of 0.2 and of 0.4, and limited or no CO₂ cooling the ambient air. The contributions of refrigeration and heat supply are specified for a range of high-pressure values for sub-critical and for trans-critical operation of the CO₂ plant. Relevant data for design and operation of the CO₂ plant are made available: the supplied heating capacity (relative to the medium-temperature refrigeration capacity), the coefficients of performance and the exergy efficiencies of refrigeration (medium-temperature, low-temperature and total), of heating, and of combined refrigeration and heating. With this knowledge, optimal operation parameters for the CO₂ process can be chosen depending on the ambient temperature. Moreover, the decision is prepared, whether an additional heating system is required or the heat recovery from the refrigeration plant is sufficient.     

A technical and economic evaluation of CO<Subscript>2</Subscript> separation from power plant flue gases with reclaimed Mg(OH)<Subscript>2</Subscript>

A method of inexpensively and reliably separating CO₂ from flue gases by means of using magnesium hydroxide (Mg(OH)₂) has been studied. Mg(OH)₂ may be easily reclaimed from power plants using magnesium enhanced flue gas desulfurization systems (ME-FGD). The CO₂ scrubbing system may be operated as either a once-through system which produces magnesium carbonate for sequestration of carbon, or as a regenerable system where a concentrated CO₂ gas stream is created for further processing.The experimental results indicate that CO₂ is absorbed into solutions containing reclaimed Mg(OH)₂ by mean of a first order reaction, where the activation energy of this reaction was measured to be 7.7 kcal/mol. Continuous flow experiments were performed in a bubble reactor with simulated flue gas containing 15%_V CO₂ in contact with a solution of Mg(OH)₂. Experiments have shown that up to 70% of CO₂ separation may be achieved in this system. For a system based on a typical 500 MW power plant and reclaiming the magnesium hydroxide from a ME-FGD, experiments have shown that from 7–17% of the CO₂ from the gas stream may be continuously removed through the regenerable system.The energy requirements for CO₂ separation were also evaluated for a regenerable system based on equilibrium data in the liquid phase. A liquid solution equilibrium solver, MINEQL+, was used to determine the equilibrium values. The economic evaluation is based on a 500-MW power plant burning a high sulfur coal. The calculation considered up to a 22 °C temperature difference between the absorption step and the regeneration system. These calculations show that approximately 40 to 68 MW of energy are required to separate 7% of the CO₂ from the flue gas stream. The energy required depends on the temperature and pH difference between the absorption and desorption step, and the liquid-to-gas ratio in the absorber. The details of the energy calculations are given in the paper.     

Modern and appropriate technologies for the reduction of gaseous pollutants and their effects on the environment

Harmful effects on environment such as global warming and climate change may result from the gases emanating from fossil fuel combustion. Jordan and most Middle East countries use fossil fuels exclusively. Therefore, new technologies which could accommodate the demand for cleaner effluents, such as: combined cycles, fluidized bed combustion, magneto hydrodynamics, fuel cells, nuclear power, natural gas, renewable energy, and energy conservation have been considered. CO₂ being the most produced gas, many technical methods of reducing and reusing CO₂ have been suggested such as: Injection in oceans, storage in caverns, injection in depleted oil and gas fields, pumping during oil recovery, storage as CO₂ ice, elimination by fixation using water algae, and increasing plantation especially forestation. These methods are being used at different degrees in the Middle East countries. Reduction of formation and harmful effects of other gaseous pollutants is also discussed, with some concentration on the transportation sector, energy efficiency and fuel cells, which have special importance for the developing countries.     

Electrochemical CO2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design

The electrochemical reduction of CO₂ is a promising route to convert intermittent renewable energy to storable fuels and valuable chemical feedstocks. To scale this technology for industrial implementation, a deepened understanding of how the CO₂ reduction reaction (CO₂RR) proceeds will help converge on optimal operating parameters. Here, a techno‐economic analysis is presented with the goal of identifying maximally profitable products and the performance targets that must be met to ensure economic viability—metrics that include current density, Faradaic efficiency, energy efficiency, and stability. The latest computational understanding of the CO₂RR is discussed along with how this can contribute to the rational design of efficient, selective, and stable electrocatalysts. Catalyst materials are classified according to their selectivity for products of interest and their potential to achieve performance targets is assessed. The recent progress and opportunities in system design for CO₂ electroreduction are described. To conclude, the remaining technological challenges are highlighted, suggesting full‐cell energy efficiency as a guiding performance metric for industrial impact.     

Co-production of power and urea from coal with CO<Subscript>2</Subscript> capture: performance assessment

Coal-based power plants are largest emitter of CO₂ as a single sector. To use fossil fuels (including coal), CO₂ capture and storage is a visible option. But large energy requirement for this process and risk associated with storage of CO₂ demand alternative solutions including recycling of captured CO₂. In this paper, a co-production of power and urea is proposed using coal with captured CO₂. Detailed ASPEN Plus^® model is developed for this plant. As shift reaction for producing H₂ has significant effect on output parameters, analysis is done for two different values of shift reaction, i.e., 90 and 95 % conversion. Plant consumes substantial auxiliary power (~19 % for the base case). Auxiliary power becomes a minimum for about 25 % captured CO₂ utilization for 95 % shift conversion. An economy factor is also defined to estimate the economic advantage of utilizing captured CO₂. Results show that economic advantage is obtained for CO₂ utilization beyond ~5 % for 95 % water gas shift reaction and it is beyond ~10 % for a 90 % shift reaction.     

Photocatalytic CO<Subscript>2</Subscript> conversion over Au/TiO<Subscript>2</Subscript> nanostructures for dynamic production of clean fuels in a monolith photoreactor

Global economic development intensifies the consumption of fossil fuels which results in increase of carbon dioxide (CO₂) concentration in the atmosphere. The technologies for carbon capture and utilization to produce cleaner fuels are of great significance. However, phototechnology provides one perspective for economical CO₂ conversion to cleaner fuels. In this study, CO₂ conversion with H₂ to selective fuels over Au/TiO₂ nanostructures using environment friendly continuous monolith photoreactor has been investigated. Crystalline nanoparticles of anatase TiO₂ were obtained in the Au-doped TiO₂ samples. The Au deposited over TiO₂ in metal state produced plasmonic resonance. CO₂ was efficiently converted to CO as the main product over Au/TiO₂ with a maximum yield rate of 4144 µmol g-catal.^?1 h^?1, 345 fold-higher than using un-doped TiO₂ catalyst. The significantly enhanced photoactivity of Au/TiO₂ catalyst was due to hindered charges recombination rate and Au metallic-interband transition. The photon energy in the UV range was high enough to excite the d-band electronic transition in the Au to produce CO, CH₄, and C₂H₆. The quantum efficiency over Au/TiO₂ catalyst for CO was considerably improved in the continuous monolith photoreactor. At higher space velocity, the yield rates of CO gradually reduced, but the initial rates of hydrocarbon yields increased. The stability of the recycled Au/TiO₂ catalyst was sustained in cyclic runs. Thus, Au-doped TiO₂ supported over monolith channels is promising for enhanced CO₂ photoreduction to high energy products. This provides pathway that phototechnology to be explored further for cleaner and economical fuels production.     

Ni-doped ZnCo<Subscript>2</Subscript>O<Subscript>4</Subscript> atomic layers to boost the selectivity in solar-driven reduction of CO<Subscript>2</Subscript>

Regulating the selectivity of CO₂ photoreduction is particularly challenging. Herein, we propose ideal models of atomic layers with/without element doping to investigate the effect of doping engineering to tune the selectivity of CO₂ photoreduction. Prototypical ZnCo₂O₄ atomic layers with/without Ni-doping were first synthesized. Density functional theory calculations reveal that introducing Ni atoms creates several new energy levels and increases the density-of-states at the conduction band minimum. Synchrotron radiation photoemission spectroscopy demonstrates that the band structures are suitable for CO₂ photoreduction, while the surface photovoltage spectra demonstrate that Ni doping increases the carrier separation efficiency. In situ diffuse reflectance Fourier transform infrared spectra disclose that the CO₂^·? radical is the main intermediate, while temperature-programed desorption curves reveal that the ZnCo₂O₄ atomic layers with/without Ni doping favor the respective CO and CH₄ desorption. The Ni-doped ZnCo₂O₄ atomic layers exhibit a 3.5-time higher CO selectivity than the ZnCo₂O₄ atomic layers. This work establishes a clear correlation between elemental doping and selectivity regulation for CO₂ photoreduction, opening new possibilities for tailoring solar-driven photocatalytic behaviors.

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A non-autonomous optimal control model of renewable energy production under the aspect of fluctuating supply and learning by doing

Given the constantly raising world-wide energy demand and the accompanying increase in greenhouse gas emissions that pushes the progression of climate change, the possibly most important task in future is to find a carbon-low energy supply that finds the right balance between sustainability and energy security. For renewable energy generation, however, especially the second aspect turns out to be difficult as the supply of renewable sources underlies strong volatility. Further on, investment costs for new technologies are so high that competitiveness with conventional energy forms is hard to achieve. To address this issue, we analyze in this paper a non-autonomous optimal control model considering the optimal composition of a portfolio that consists of fossil and renewable energy and which is used to cover the energy demand of a small country. While fossil energy is assumed to be constantly available, the supply of the renewable resource fluctuates seasonally. We further on include learning effects for the renewable energy technology, which will underline the importance of considering the whole life span of such a technology for long-term energy planning decisions.     

Energie- und CO2-Bilanzen von Solarkollektoranlagen

Energy systems based on solar collectors or other renewable energy sources are normally regarded as CO₂ zero-emission systems because nearly no fossil fuels are used to operate the systems. But the complete evaluation of an energy system concerning its CO₂ reduction potential must not be restricted to the emissions during the operation of the system. The cumulative energy demand and the cumulative CO₂ emissions during the life cycle have to be considered. In case of a solar collector system, in particular the production-determined emissions and emissions due to the requirement of auxiliary electric power for the collector pump are important. An energy analysis is this kind was performed for solar domestic hot water systems. It is shown that the consideration of the life cycle emissions reduces significantly the CO₂ reduction potential of solar collector systems whereby the design of the system has a major influence.     

<Emphasis Type="Italic">Ab initio</Emphasis> studies on [bmim][PF<Subscript>6</Subscript>]-CO<Subscript>2</Subscript> mixture and CO<Subscript>2</Subscript> clusters

Ab initio molecular dynamics studies have been carried out on the room temperature ionic liquid, 1,n-butyl,3-methylimidazolium hexafluorophosphate ([bmim][PF₆]) and supercritical carbon dioxide mixture at room temperature and experimental density. Partial radial distribution functions (RDF) for different sites have been computed to see the organization of CO₂ molecules around the ionic liquid. Several partial RDFs around the carbon atom of CO₂ molecule are compared to find out that the CO₂ has specific interaction with a carbon atom present in the imidazolium ring. The CO₂ is also found to be very well organized around the terminal carbon atom of the butyl chain. The partial RDFs for the oxygen atoms around oxygen and carbon atoms of the CO₂ suggests that there is very good organization of CO₂ molecules around themselves even in the [bmim][PF₆]-CO₂ mixture. The instantaneous quadrupole moment tensor has been calculated for the anion and the cation. The ensemble average of diagonal components of quadrupole moment tensor of the cation have finite values, whereas the off-diagonal components of the cation and both the diagonal and off-diagonal components of the anion have the value of zero with a large standard deviation. The CPMD studies performed on CO₂ clusters reveals the greater tendency of the clusters with more CO₂ units, to deviate from the linear geometry.     

Surface Immobilization of Transition Metal Ions on Nitrogen‐Doped Graphene Realizing High‐Efficient and Selective CO2 Reduction

Electrochemical conversion of CO₂ to value‐added chemicals using renewable electricity provides a promising way to mitigate both global warming and the energy crisis. Here, a facile ion‐adsorption strategy is reported to construct highly active graphene‐based catalysts for CO₂ reduction to CO. The isolated transition metal cyclam‐like moieties formed upon ion adsorption are found to contribute to the observed improvements. Free from the conventional harsh pyrolysis and acid‐leaching procedures, this solution‐chemistry strategy is easy to scale up and of general applicability, thus paving a rational avenue for the design of high‐efficiency catalysts for CO₂ reduction and beyond.     

High‐Temperature CO2 Electrolysis in Solid Oxide Electrolysis Cells: Developments,Challenges, and Prospects

High‐temperature CO₂ electrolysis in solid‐oxide electrolysis cells (SOECs) could greatly assist in the reduction of CO₂ emissions by electrochemically converting CO₂ to valuable fuels through effective electrothermal activation of the stable C?O bond. If powered by renewable energy resources, it could also provide an advanced energy‐storage method for their intermittent output. Compared to low‐temperature electrochemical CO₂ reduction, CO₂ electrolysis in SOECs at high temperature exhibits higher current density and energy efficiency and has thus attracted much recent attention. The history of its development and its fundamental mechanisms, cathode materials, oxygen‐ion‐conducting electrolyte materials, and anode materials are highlighted. Electrode, electrolyte, and electrode–electrolyte interface degradation issues are comprehensively summarized. Fuel‐assisted SOECs with low‐cost fuels applied to the anode to decrease the overpotential and electricity consumption are introduced. Furthermore, the challenges and prospects for future research into high‐temperature CO₂ electrolysis in SOECs are included.     

Sustainable multi-period electricity planning for Iskandar Malaysia

This paper presents the current situation and projected planning of the electricity generation sector for Iskandar Malaysia by implementing a model to optimise the cost, utilise the usage of available renewable energy sources, and achieve carbon dioxide reduction targets. This Mixed Integer Linear Programming model was developed with the main objective of minimising the total cost of electricity generation, taking into consideration energy demand, reserve margin, electricity generation, peak and base generation, resource availability, and CO₂ emission. Data for the year 2013 were forecasted until 2025 to illustrate the analysis for this study, and are represented via four scenarios. This optimal model is capable of balancing types of fuel and switching coal plants to natural gas power plants. It also enhances the use of renewable energy (RE) to meet CO₂ emission targets. The model is further integrated with several other considerations related to energy systems, such as suitability of power plants as peak or base plants, RE resource availability, intermittency of solar power, losses during transmission, fuel selection for biomass, decision to retrofit existing coal power plant to NG power plant, and construction lead time of power plants. The results for this study determined that the optimal scenario is Scenario 3 (CS3). This research proves that Iskandar Malaysia can reduce CO₂ emission by 2025 via utilisation of RE. This model is generic and can be applied to any case study, which would be useful for assisting government policy-making.     

Synthesis and characterization of magnetic and microwave absorbing properties in polycrystalline cobalt zinc ferrite (Co<Subscript>0.5</Subscript>Zn<Subscript>0.5</Subscript>Fe<Subscript>2</Subscript>O<Subscript>4</Subscript>) composite

In this research work, magnetic and microwave absorption loss and other response characteristics in cobalt zinc ferrite composite has been studied. Cobalt zinc ferrite with the composition of Co_0.5Zn_0.5Fe₂O₄ was prepared via high energy ball milling followed by sintering. Phase characteristics of the as-prepared sample by using XRD analysis shows evidently that a high crystalline ferrite has been formed with the assists of thermal energy by sintering at 1250 °C which subsequently changes the magnetic properties of the ferrite. A high magnetic permeability and losses was obtained from ferrite with zinc content. Zn substitution into cobalt ferrite has altered the cation distribution between A and B sites in spinel ferrite which contributed to higher magnetic properties. Specifically, Co_0.5Zn_0.5Fe₂O₄ provides electromagnetic wave absorption characteristics. It was found that cobalt zinc ferrite sample is highly potential for microwave absorber which showed the highest reflection loss (RL) value of ??24.5 dB at 8.6 GHz. This material can potentially minimize EMI interferences in the measured frequency range, and was therefore used as fillers in the prepared composite that is applied for microwave absorbing material.     

Growth and properties of LiCu<Subscript>2</Subscript>O<Subscript>2</Subscript>-NaCu<Subscript>2</Subscript>O<Subscript>2</Subscript> crystals

Platelike Li_{1 ? x} Na _x Cu₂O₂ single crystals up to 2 × 10 × 10 mm in dimensions have been grown by slowly cooling (1 ? x)Li₂CO₃·xNa₂O₂·4CuO melts in alundum crucibles in air. Li_{1 ? x} Na _x Cu₂O₂ solid solutions in the LiCu₂O₂-NaCu₂O₂ system have been shown to exist in the composition range 0.78 < x < 1. The temperature stability ranges of NaCu₂O₂ and LiCu₂O₂ are 780–930 and 890–1050°C, respectively. The Mössbauer spectra and electrical conductivity of the crystals have been measured.     

Nanostructure of CaMgSi<Subscript>2</Subscript>O<Subscript>6</Subscript> (Diopside) and CaTiO<Subscript>3</Subscript> (Perovskite) mechanically activated in carbon dioxide

The micro- and nanostructure of materials resulting from mechanochemical interactions of natural diopside (CaMgSi₂O₆) and synthetic perovskite (CaTiO₃) with CO₂ have been studied by transmission electron microscopy (TEM) and high-resolution TEM. The results indicate that CO₂ absorption is accompanied by CO₂ “dissolution” in the form of CO ₃ ^2? ions in the structurally disordered silicate or titanate matrix. The diopside activation product is a quasi-homogeneous amorphous carbonate-silicate phase. The mechanically activated perovskite is a nanocomposite consisting of CaTiO₃ nanocrystals embedded in a carbonated amorphous titanate matrix.     

Electrical conductivity of nanostructured fluorite-like Sc<Subscript>4</Subscript>Ti<Subscript>3</Subscript>O<Subscript>12</Subscript>

Single-crystal and polycrystalline samples of Sc₄Ti₃O₁₂ have been shown to contain nanodomains (10–50 nm) with different degrees of ordering, coherent with the fluorite-like matrix. The oxygen-ion conductivity of this compound has been determined in the range 300–1000°C in air using impedance spectroscopy. The nanostructured single-crystal and polycrystalline samples are close in the activation energy for bulk conduction at both low and high temperatures: ?1.26 and 1.29 eV in the range 300–775°C, ?1.98 and 2.07 eV in the range 775–1000°C.