胆甾醇润滑添加剂的摩擦噪声与胶合分析

在N15机械油中添加胆甾醇,用标准的立式万能摩擦磨损试验台实验分析了N15机械油、N15油机械 胆甾醇的摩擦磨损性能。针对磨合阶段、稳定磨损阶段、胶合失效与摩擦噪声进行分析。结果表明,在磨合阶段摩擦因数有较大变化,随后的稳定磨损阶段中摩擦因数变化减小;在摩擦副出现胶合失效前,摩擦副的摩擦因数急剧上升;N15机械油 1.7%胆甾醇的抗胶合性能较好,但N15机械油 0.106%胆甾醇的摩擦噪声特性较好;胆甾醇添加剂可以显著改善N15号机械油的抗胶合能力。     

纳米碳酸钙与液晶添加剂的摩擦磨损分析

在15^#机械油中添加纳米碳酸钙或纳米液晶，用标准的立式万能摩擦磨损实验台实验分析了15^#机械油、15^#机械油＋纳米碳酸钙、15^#机械油＋5CB液晶的摩擦磨损性能。针对磨合阶段、稳定磨损阶段、胶合失效与摩擦噪声进行分析。结果表明，在磨合阶段摩擦因数有较大变化，随后的稳定磨损阶段中摩擦因数变化减小，在摩擦副出现胶合失效前，摩擦副的摩擦因数急剧上升；在摩擦因数变化幅度达到5％左右时出现嗡嗡声，在摩擦因数变化幅度达到10％左右时，在摩擦因数上升阶段出现摩擦啸叫声，而在摩擦因数下降阶段不出现摩擦噪声。提出了用能量耗散原理来解释上述现象。     

不同润滑介质下钢-钢摩擦副的摩擦磨损性能

研究了钢-钢摩擦副在干摩擦、水润滑、酒精润滑和60 N油润滑等条件下的摩擦磨损行为。结果表明:润滑介质可以显著降低钢-钢摩擦副的摩擦系数,在干摩擦、水润滑、酒精润滑和60N油润滑,摩擦载荷为(50～200)g(钢球半径为2 mm)时摩擦系数的平均值分别为0.75～0.81,0.45～0.33,0.22～0.15,0.13～0.09;在高载荷下酒精润滑与油润滑磨损速率相差甚小,并且在摩擦磨损初期阶段(500 s之内)摩擦系数相差甚少;同时,酒精润滑条件下的磨损表面形貌与油润滑下的磨损表面形貌极为相似,无明显粘着现象。分析表明,酒精润滑是一种绿色润滑介质,在压延、拉伸工业中有良好的应用前景。     

润滑条件与缸套材料对活塞环-缸套摩擦磨损特性的影响

在润滑油中未添加和添加质量分数0.1％MoS2润滑条件下,对YH31合金铸铁活塞环和不同材料(高硼铜铸铁和铬钼铝铸铁)缸套进行摩擦磨损试验,研究了润滑条件和缸套材料对摩擦因数、体积磨损量和磨损表面形貌的影响,分析了磨损机制.结果表明:Mo S 2的添加可以缩短活塞环与高硼铜铸铁缸套的磨合时间,延长稳定磨损时间,降低摩擦因数,减小体积磨损量;摩擦副表面磨痕较未添加MoS2润滑条件下细而浅,且未出现裂纹.在未添加MoS2润滑条件下,活塞环与铬钼铝铸铁缸套对磨比与高硼铜铸铁缸套对磨更早进入稳定磨损阶段,但稳定磨损持续时间较短,平均摩擦因数有所增大,体积磨损量大幅增加;活塞环的磨损机制均为抛光磨损,高硼铜铸铁缸套和铬钼铝铸铁缸套的磨损机制分别为磨粒磨损+疲劳磨损和磨粒磨损.     

摩擦副磨合过程摩擦因数时间序列分形行为研究

为探究在油润滑条件下,涡旋压缩机端面摩擦副接触面在磨合初期与稳定磨损阶段摩擦因数局部时间序列曲线的分形行为,在TRB多功能摩擦磨损试验机上采用球墨铸铁分别与不同表面粗糙度的铜合金和铝合金进行摩擦磨损试验,采集磨合过程中摩擦因数的时间序列信号曲线并对其进行分形表征。结果显示:摩擦因数时间序列曲线具有明显的分形特征,可以根据摩擦过程中摩擦因数时间序列信号的分形维数来判断磨合过程的复杂程度;摩擦副在油润滑时表面粗糙度越大则磨合过程的平均摩擦因数越大,但摩擦因数曲线的分形维数越小,且磨合初期摩擦因数局部时间序列曲线的分形维数不规则波动越大;软质材料表面粗糙度的改变对摩擦因数及其局部分形维数的影响较大。     

溅射沉积MoS_2/Sb_2O_3复合润滑膜的摩擦磨损过程与失效分析

采用UMT-2型球-盘摩擦磨损试验机研究溅射沉积MoS2/Sb2O3复合固体润滑膜的滑动摩擦磨损寿命,采用显微镜分析球-盘摩擦副在不同磨损阶段的磨损形貌与磨损状况,并对磨痕位置S、Mo元素进行XPS分析。结果表明:在摩擦磨损寿命试验过程中,摩擦副的接触方式最开始的点接触逐步过渡到面接触;MoS2固体润滑膜对滑动摩擦副的延寿作用是基底材料表面的有效厚度润滑膜及MoS2对摩擦偶件(钢球)的转移;机械磨损的剪切剥离效应是润滑失效的主要原因,MoS2的氧化在一定程度上加剧了润滑失效的进程。     

润滑介质对摩擦性能影响差异分析

L-CKD150润滑油和复合锂基润滑脂广泛运用于石油装备润滑减磨。为研究2种润滑介质对摩擦副摩擦磨损性能及磨损机制的影响差异,采用MMW-1型微机控制立式万能摩擦磨损试验机,开展不同接触压力和线速度及不同润滑环境下摩擦学实验研究。结果表明:实验工况下,销-盘摩擦副表面以磨粒磨损为主,同时存在黏着磨损;相比于L-CKD150润滑工况,复合锂基润滑脂润滑时销-盘表面黏着磨损更为严重,进而加大摩擦因数的波动幅度,最大波动幅度为L-CKD150润滑下的3.7倍;盘试样表面磨粒磨损与接触压力有关,0.5 MPa接触压力下,L-CKD150润滑时磨粒磨损较严重,1.5 MPa下则复合锂基润滑脂润滑时更严重,磨粒磨损是影响盘试样磨损量差异的主要因素。     

润滑脂粘度与机械性能的相关性研究

利用润滑脂性能检测仪器,分别对润滑脂的流变性能和摩擦磨损性能进行研究。首先理论分析它们之间的相关性,然后对比实验结果,最后根据润滑脂的流变性,估算其摩擦磨损性能并进行数值模拟,与实际实验结果进行对比。结果表明:润滑脂在相同的润滑条件下,其测得的摩擦磨损中的转矩值、摩擦系数值均随着润滑脂的表观粘度的变化而变化。     

双金属轴承材料表面黏结润滑涂层摩擦学性能研究

在HDM-10型端面摩擦磨损试验机上进行油润滑及规律变载条件下的摩擦磨损试验,考察了石墨﹑MoS2及其复合黏结润滑涂层的摩擦磨损性能.结果表明:固体润滑涂层显示了较好的减摩耐磨性能,摩擦副正常阶段的摩擦系数在0.09以下,摩擦温升小,涂层的承载载荷都超过了2 800 N,最高达到4 800N;石墨与MoS2有较好的协同效应,当石墨、MoS2与胶黏剂的比例为3∶ 2∶ 10时,涂层的摩擦学性能最佳.     

等离子喷涂陶瓷涂层在高温（450℃）下的摩擦磨损机理分析

本文用SEM观察分析了等离子喷涂陶瓷涂层（Metco136F,Metco80NS,Metco102,Metco105,Metco202NS,国产Al 2O 3）在高温无油和有油润滑下的摩擦磨损机理。发现陶瓷涂层仍会象金属摩擦副那样出现疲劳脱落、塑性形变、粘着撕裂。450℃时的干摩擦系数比有油润滑的摩擦系数高得多,且磨损表面形貌和磨损机理与有油润滑时大为不同。干磨擦是较易出现粘着磨损,而有润滑时则较难出现。     

Rheological and Tribological Characterization of a New Acylated Chitosan–Based Biodegradable Lubricating Grease: A Comparative Study with Traditional Lithium and Calcium Greases

This work compares the thermal, rheological, and tribological properties of a new gel-like biodegradable formulation, prepared using an acylated chitosan thickener and castor oil, with properties exhibited by two conventional greases thickened with lithium and calcium soaps, respectively, taken as benchmarks. Thermogravimetric (TGA), rheological (small-amplitude oscillatory shear [SAOS], rheodestruction, and viscous flow) and tribological (friction and wear analysis) tests, as well as roll-stability measurements were carried out to characterize the three grease samples. In addition, infrared spectroscopy and differential scanning calorimetry (DSC) were used to chemically characterize the acylated chitosan thickener agent. From a thermogravimetric point of view, the new formulation displayed better thermal resistance than the calcium and lithium lubricating greases. The evolution of the linear viscoelasticity functions with frequency and viscosity values in the shear rate and temperature ranges studied were similar to those obtained with the commercial lubricating greases. However, the linear viscoelasticity functions of the biodegradable formulation were slightly more affected by temperature. The mechanical stability behavior and recovery of the rheological functions found in the biodegradable formulation were also better than that exhibited by the calcium-based grease. However, the friction coefficient measured at low rotational speed is slightly higher than that obtained with the benchmarks, with similar or lower values obtained at a high rotational speed. Resulting wear marks obtained after the frictional tests using the acylated chitosan–based grease were larger than those obtained with the commercial greases.     

Effect of Graphite on Friction and Wear Characteristics of Molybdenum Dithiocarbamate

The effects of graphite powder on the friction and wear characteristics of molybdenum dithiocarbamate MoDTC were studied in reciprocated sliding contact using a ball-on-plate type tester. The oil used was squalane, a pure hydrocarbon. The addition of MoDTC alone to the oil showed a high coefficient of friction at an early stage of a rubbing test, since the extent of the formation of a surface film containing MoS₂ was insufficient to decrease the coefficient of friction. The high friction at the early stage brought about noticeable wear. On the other hand, the addition of graphite powder together with succinimide-type dispersant to the oil containing MoDTC considerably improved the friction and wear performance not only at the early stage but also at the steady stage. The added graphite powder seems to cover the part of rubbing surfaces without a film containing MoS₂ to reduce the friction and wear, not only at the steady stage after the running-in process, but also in the running-in process or at the early stage.     

The effect of space irradiation on the lubricating performance of perfluoropolyether greases in simulated space environment

In this paper, 2 kinds of commercial perfluoropolyether (PFPE) greases were coated on the polyimide (PI) blocks, which were placed within simulated space environment including atomic oxygen (AO), proton (Pr), ultraviolet (UV), and electron (El) irradiations, and then the tribological performance has been investigated with a ball‐on‐disc tribometer. Results indicated that the MoS₂‐grease showed better lubrication performance than the PTFE‐grease. The changes in infrared spectroscopy induced by Pr and El irradiations were more obvious than that by AO and UV irradiations. Results of energy dispersive X‐ray spectroscopy indicated that Pr and El irradiations caused carbonation of greases, and AO and UV irradiations induced oxidation of greases. Referred to the tribological properties of PI coated with PFPE oil, PI coated with PFPE greases showed minor changes in friction coefficient and wear rate, and the MoS₂ additives could significantly improve the lubrication properties of PFPE greases in simulated space environment.     

Correlation Studies of WS 2 Fullerene-Like Nanoparticles Enhanced Tribofilms: A Scanning Electron Microscopy Analysis

The beneficiary effects of tungsten disulphide (WS₂) inorganic fullerene-like nanoparticles (IFLNPs) in the lubrication industry were shown in recent years. However, their successful incorporation into lubricants (oils, greases) is not straightforward. In practice, the lubricant contains several components for different purposes, e.g. reducing the oxidization of the oil (antioxidant), minimizing the wear rate (anti-wear additive), dispersants, etc. These additives can contain chemically active compounds, which under the lubrication process (where locally extreme conditions can develop: high pressure and flash temperatures) can change the chemistry in the contact zone and block the beneficial effects of the inorganic nanoparticles. In this investigation, poly-alpha-olefin (PAO) is being used as base oil in which the WS₂ nanoparticles and different additives are mixed. A ball-on-disc sliding test revealed that certain additives inhibit the nanoparticles to reduce friction (less than 5 % decrease in friction coefficient), while in other cases, the friction reduction was above 50 %. The comparison is being made between PAO + additive and PAO + additive + IFLNPs. Scanning electron microscope and energy dispersive X-ray spectroscopy were used to investigate the elemental composition of the tribofilms formed on the wear marks. Further analysis was made in order to reveal correlations between elemental compositions of the tribofilms and external parameters such as the friction coefficient and wear rate. For instance, a strong correlation between tungsten content of the tribofilm and the friction coefficient was found.     

Friction torque in grease lubricated thrust ball bearings

Thrust ball bearings lubricated with several different greases were tested on a modified Four-Ball Machine, where the Four-Ball arrangement was replaced by a bearing assembly. The friction torque and operating temperatures in a thrust ball bearing were measured during the tests. At the end of each test a grease sample was analyzed through ferrographic techniques in order to quantify and evaluate bearing wear.A rolling bearing friction torque model was used and the coefficient of friction in full film lubrication was determined for each grease, depending on the operating conditions.The experimental results obtained showed that grease formulation had a very significant influence on friction torque and operating temperature. The friction torque depends on the viscosity of the grease base oil, on its nature (mineral, ester, PAO, etc.), on the coefficient of friction in full film conditions, but also on the interaction between grease thickener and base oil, which affected contact replenishment and contact starvation, and thus influenced the friction torque.     

脂肪醇对Ti6Al4V/钢摩擦副摩擦磨损性能的影响

采用SRV型摩擦磨损试验机分别考察了Ti6Al4V/钢摩擦副在多种脂肪醇润滑下的摩擦磨损性能。结果表明,与液体石蜡相比,碳链长度小于碳8的脂肪醇作为Ti6Al4V/钢摩擦副的润滑剂表现出良好的润滑性能,其润滑机制是在Ti6Al4V磨损表面形成吸附膜。载荷和频率明显影响Ti6Al4V/钢摩擦副在脂肪醇润滑下的摩擦磨损行为和摩擦磨损机制:当载荷较小时,Ti6Al4V磨损表面主要发生轻微的擦伤;随着载荷增加,Ti6Al4V磨损表面擦伤严重并在更高载荷下发生较为严重犁沟和塑性变形。     

Improvement of Lubrication for Cam and Follower

In order to improve the lubrication between cam and follower of internal combustion engines, the influences of materials or oil viscosity and additives on the friction and scuffing characteristics have been examined with a test rig by increasing the contact load at a constant revolution speed. Also the effects of oil supply through the oil-hole of the camshaft on the reduction of friction and the prevention of scuffing have been examined. From the experiments the following results were made obvious.

Firstly, the effect of the material on the reduction of friction or the prevention of scuffing is dependent upon the combination of cam and follower materials. The follower material of hard sintered metal or silicon nitride ceramics is superior in both effects to chilled cast iron when mating with the cam material of hardened S48C steel cam.

Secondly, as the viscosity of base-oil becomes low, the friction increases or decreases depending on oil additives, but the scuffing resistance always becomes small. The organo-molybdenum compounds, MoDTP and MoDTC, decrease the friction and the zinc dialkyl-dithiophosphates are effective in preventing scuffing. In the case of mixed additive with such Molybdenum friction modifiers, primary ZnDTP and secondary ZnDTP enhance the effect to modif' the friction. when mixed with MoDTP, however primary ZnDTP becomes inferior in scuffing resistance to secondary ZnDTP. Specifically the mixed additive of MoDTC and primary ZnDTP improves the lubrication in both respects of the friction and the anti-scuffing.

Lastly, the oil supply from cam surface oil-hole is an effective means of improving the lubrication. The effect becomes largest when the oil-hole is arranged between the flank and shoulder of the cam-lobe corresponding to the valve opening.     

硅油润滑对莫来石基陶瓷摩擦磨损性能的影响研究

莫来石基陶瓷具有一系列优异的性能,其在摩擦学领域中的应用越来越广泛。本文研究了硅油润滑对该类陶瓷摩擦磨损性能的影响规律。研究结果表明,硅油可明显地降低莫来石基陶瓷的摩擦系数和磨损率,但却使摩擦系数在稳定阶段的波动幅度增加。硅油润滑条件下,莫来石基陶瓷的磨损机理主要是微观断裂和磨料磨损。