共查询到18条相似文献,搜索用时 62 毫秒
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前言 1925年6月,柏林物理工艺试验局分析化学家诺达克(Noddack.W.)和塔科女士(Tacke.I.)分析挪威产的铌铁矿石时,从中提取出周期表第75号元素的氧化物。在观测其X射线光谱时,显示出75号元素的特征谱线。他们把75号元素命名为Rhenium,符号Re(中译名铼),是取莱茵河之意。尽管元素铼发现很晚,但由于其独一无二的性能,特别是它有异常低的蒸汽压,被广泛用在电子、无线电技术和电真空工业中,为了保护电真 相似文献
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从辉钼精矿中提取钼,铼的研究 总被引:3,自引:0,他引:3
本文阐述全湿法(氧气压煮法)从辉钼精矿中制取仲钼酸铵和高铼酸铵的新工艺流程,具有收率高(钼95.08%、铼96.28%)、原材料单耗低、产品质量好、技术经济指标先进的优点。 相似文献
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加入过氧化氢溶解钨铼合金试样,经电感耦合等离子体原子发射光谱法对钨铼合金中铼元素的含量进行测定,铼元素分析谱线为221.426 nm,基体匹配法将基体钨带来的干扰影响加以消除,铼质量分数在0%~3%时光谱强度线性关系良好,线性系数超过0.999,定量下限0.0040%。测定结果相对标准偏差低于2%(n=11),样品加标回收率96.0%~102.0%。该方法优势较为突出,主要体现在样品处理过程简单方便、测量结果准确快速,工厂生产钨铼合金样品测定需求可得到很好的满足。 相似文献
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通过单因素实验考察了黑钨渣硫酸浸钪规律. 结果表明,在温度90℃、酸渣质量比1.2:1、硫酸浓度29%(w)、反应2.5 h条件下,钪浸出率达88%,铁浸出率为98%. 在上述最佳浸出条件下通过调整反应过程料浆的酸度,探究了钪浸出和铁的草黄铁矾法抑制浸出规律. 结果表明,在温度90℃、硫酸浓度29%(w)、总硫酸加入量为1.0倍渣量(质量比)、一段加入0.8倍渣量的硫酸、反应2.0 h后加入剩余硫酸再反应0.5 h条件下,钪浸出率为87%,铁浸出率由98%降至57%,实现了铁抑制浸出. 相似文献
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在硫酸体系中,采用熔融雾化制粉、硫酸体系双氧水氧化酸浸工艺浸出铼,钨钽等稀有金属富集在渣中,研究了酸度、双氧水用量、温度、粒度、液固体积/质量比、时间对浸出的影响. 结果表明,最佳浸出条件为:在硫酸体系中,废合金雾化粉20 g,粉末粒度71~100 mm,温度75℃,液固比8 mL/g,硫酸浓度3.5 mol/L,滴加30%双氧水65 mL,反应6 h. 该条件下铼、镍和钴的浸出率均超过99%,钨钽浸出率均低于1%,钼浸出率为28%,实现了铼浸出与稀有金属在渣中富集. 相似文献
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《分离科学与技术》2012,47(5):1120-1143
Abstract Rhenium-188 is a radionuclide with favorable physical characteristics suitable for radiotherapeutic purposes (T1/2 16.9 h, Eβmax 2.12 MeV; Eγ 155 keV (15%)) for radiotherapeutic purposes and can be continually obtained from 188W/188Re generator systems. The preparation conditions of an alumina based 188W/188Re generator are reported. Initially, the W and Re sorption behavior on alumina in NaCl and HCl medium was performed evaluating the following parameters: medium pH, alumina size particle, sorption capacity, and kinetic. Re-188 is not adsorbed in HCl and NaCl medium whereas W-188 is strongly adsorbed in both media at pH < 5. The strongest sorption of W was obtained in alumina with a particle size of 0.075–0.048 mm. The weight capacity of alumina is approximately 0.337 meq/g and the sorption equilibrium in static conditions is attained after 18 hours. This data was used to construct and evaluate alumina 188W/188Re-generators for a period of six months. 相似文献
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Minghui Zhang Henry H. Hwu Mark T. Buelow Jingguang G. Chen Todd H. Ballinger Paul J. Andersen 《Catalysis Letters》2001,77(1-3):29-34
The decomposition of 15NO on C/W(111), C/W(110), and on monolayer and bulk C/Mo/W(111) surfaces is compared based on temperature-programmed desorption (TPD) and Auger electron spectroscopy (AES) measurements. Our results indicate that the decomposition of 15NO occurs readily over all surfaces, and the only 15N-containing reaction products are 15N2 and 15N2O under our experimental conditions. Much higher surface reactivity for 15NO decomposition was observed over the more open-structured C/W(111) surface, with a value of 0.68 15NO/W, in contrast to the surface reactivity of 0.24 15NO/W over the close-packed C/W(110) surface. The selectivity of these two 15N-containing reaction products depends on the structure of the substrates as well. The more open-structured C/W(111) surface favors the production of 15N2, with a product selectivity of 15N2 being approximately 87%. In contrast, the selectivity to 15N2 is only about 52% on C/W(110). In addition, we have investigated the decomposition of 15NO on C/Mo surfaces that were epitaxially grown on W(111). The selectivity of 15N2 on C/Mo/W(111) surfaces is 88%, which is very similar to that observed on C/W(111). Finally, the general similarity between the DeNOx chemistry on carbides and on Pt-group metals will also be discussed. 相似文献
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本文利用循环伏安法在铂电极上研究了三核钼钨簇合物(〔Mo3L〕2+ ,〔W 3L〕2+其中L= 〔(μ3- O)2(μ- CH3COO)6(H2O)3〕的电化学性质及其对电化学性质的影响因素。 相似文献
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Vickers hardness of WO3 , W18 O49 , and MoO2 is reported for temperatures up to 800°C. Polycrystalline samples of the oxides were prepared by hot-pressing, and hardness was determined using a Vickers hardness tester modified for high-temperature applications. The hardness of a heavily deformed tungsten rod was also measured as a reference. 相似文献
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Michael Kmetz Steven L. Suib Francis S. Galasso 《Journal of the American Ceramic Society》1989,72(8):1523-1524
The strength and toughness of fibrous composites depend on the interface properties which control the bonding between the fibers and matrices. One method of controlling the interface involves coating the fiber with an appropriate material. In a previous study, it was found that there is a definite advantage in using low coating temperatures to prevent fibers from degrading. We therefore were interested in a report that Mo2 C could be deposited from Mo(CO)6 at temperatures as low as 300° to 475°C. Our studies indicated that the material was not Mo2 C, but an oxycarbide, which, with an analogous tungsten oxycarbide coating, was applied to SiC yarns. Both oxycarbides could be converted to the metals by heat-treating in N2 . 相似文献
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