Proficiency test for effective area determination of a pneumatic pressure balance in Mexico

A pneumatic pressure proficiency test for effective area determination of a pressure balance was performed among 4 accredited calibration laboratories in Mexico. CENAM provided the reference values (making initial and final calibrations) and was the pilot laboratory. The Mexican Accreditation Entity (ema) collaborated. The participants calibrated, by cross floating, a Wika pressure balance model CPB 5000 with accuracy class 0.015% of the reading in the range 0.7–7 MPa. The calibration pressures were 0.7, 1.4, 2.1 3.5, 4.2, 5.6 and 7.0 MPa. For A₀ and A_e, the normalized error equation was used to compare the results of the laboratories with CENAM’s reference values. The results obtained were satisfactory (E_n did not exceed the compatibility limit, −1 ⩽ E_n ⩽ 1).     

Uncertainty evaluation of the 20 kN m deadweight torque standard machine

A deadweight-type torque standard machine of 20 kN m rated capacity (20 kN m-DWTSM) has been designed and developed by the National Metrology Institute of Japan (NMIJ) at the National Institute of Advanced Industrial Science and Technology (AIST). Each uncertainty contribution comes mainly from the performance of each mechanical part of the 20 kN m-DWTSM. Authors evaluated the uncertainty of the mass of the linkage weights, local acceleration of gravity, influence of air buoyancy on deadweight loading, initial moment-arm length (including CMM measurement and temperature compensation), and sensitivity of the fulcrum. This report deals especially with evaluation of the remaining contributions, namely the influence of arm flexure and reference line variation at the end of the moment-arm on best measurement capability (BMC). Estimation of BMC in the 20 kN m-DWTSM gave a relative expanded uncertainty of less than 7.0 · 10⁻⁵ (k = 2) for the calibration range from 200 N m to 20 kN m.     

Calibration of a 3D-ball plate

The presented 3D-ball plate is used for testing machine tools with a workspace of 500 mm × 500 mm × 320 mm. The artefact consists of a 2D-ball plate which is either located by a kinematic correct coupling on a base plate or on a spacer. The spacers are placed between the base plate and the ball plate and are also kinematic coupled to the other elements of the artefact. The kinematic couplings provide a high repeatability of the measurement setup. Because of the specific application the known calibration procedures for 2D-ball plates are not applicable.A calibration method for the pseudo-3D-artefact on a coordinate measuring machine (CMM) is presented, with the aim to minimise the influence of geometric CMM errors. Therefore a computer simulation is used to analyse the effects of these disturbing errors on the calibration of the ball plate and the spacers. Using a reversal method, the plate is measured at four different horizontal positions after rotating the ball plate around its vertical axis. A couple of the CMM errors, e.g., a squareness error C0Y between the X- and Y-axis of the CMM, can be eliminated by that method—others have to be determined with additional measurements, e.g., the positioning errors EXX or EYY of the X- and Y-axis, respectively. The paper also contains a measurement uncertainty estimation for the calibration by use of experiments, tolerances and Monte Carlo-simulations. The achieved uncertainty for ball positions in the working volume is less than 2.1 μm (coverage factor k = 2).     

On-site calibration system for trace humidity sensors

A portable device for calibration of trace humidity sensors and an adopted calibration procedure have been developed. The calibration device is based on humidity generation by permeating water through polymeric membrane tubes. Water vapour transmission rates for various polymers were experimentally determined in order to select the most suitable polymeric material. The developed trace humidity generator consists of a gas-flow polymeric hose immersed in a water reservoir thermostated by a sensor-controlled heater. Mole fractions of water vapour between 1 μmol mol⁻¹ and 350 μmol mol⁻¹ (equivalent to frost-point temperatures from −76 °C to −31 °C) were generated by varying either the operating temperature or gas flow. The operating temperature can be varied from 20 °C to 60 °C and kept stable within 0.1 K. Uncertainty analysis indicated that the trace humidity generator produces gas flows of constant humidity amounts with a relative expanded uncertainty less than 3.4% (k = 2) of the generated value.     

Uncertainty evaluation of a 10N·m dead weight torque standard machine and comparison with a 1kN·m dead weight torque standard machine

A 10N·m dead weight torque standard machine (10-N·m-DWTSM) has been developed and evaluated since 2006 at the National Metrology Institute of Japan (NMIJ), a part of the National Institute of Advanced Industrial Science and Technology (AIST). Previously, the lengths of a moment arm, made of a low-thermal-expansion alloy (Super Invar), and the sensitivity limit of the fulcrum were evaluated. However, it is known that mechanical parts made of Super Invar vary in size with time. Therefore, the sensitivity limit of the fulcrum should be investigated under real calibration conditions. In this study, the moment arm lengths and the sensitivity limit of the fulcrum were re-evaluated. The moment arm lengths were found to have increased by an average of 6.3 μm in five years. The relative combined standard uncertainty of the moment arm length, w_arm, was re-evaluated in consideration of the uncertainty of the secular length change and was found to be 1.8 × 10⁻⁵. The sensitivity limit of the fulcrum was investigated by using a highly accurate, small-rated-capacity torque measuring device. The relative combined standard uncertainty due to the sensitivity limit of the fulcrum was 2.5 × 10⁻⁵ in the 0.1–10N·m torque range. The uncertainty budget table of the 10-N·m-DWTSM was completed. The relative expanded uncertainty of torque realized by the 10-N·m-DWTSM, W_tsm, was evaluated in the 0.1–10N·m torque range and was found to be 6.6 × 10⁻⁵, with a coverage factor, k, being equal to 2. In addition, the 10-N·m-DWTSM was compared with the existing 1-kN·m-DWTSM at NMIJ by using small-rated-capacity torque measuring devices at 5N·m and 10N·m torque steps. Two loading conditions were adopted in this comparison. The comparison results showed good agreement within the uncertainties in all cases. Thus, the torque realized by the 10-N·m-DWTSM was shown to be equivalent to that achieved by the 1-kN·m-DWTSM.     

Preparation,characterization, electrical conductivity and dielectric studies of Na2SO4 and V2O5 composite solid electrolytes

Composite solid electrolytes (1 − x) Na₂SO₄–(x) V₂O₅ were prepared and characterized by various techniques such as XRD, FT-IR, DTA and SEM. AC impedance spectroscopy revealed that the contribution of grain is strong enough over the grain boundary. Arrhenius plot of the Na₂SO₄ shows a sharp increase in conductivity at 523 K due to the structural phase transition (phase V → I). Composites show the enhanced ionic conductivity than the pristine Na₂SO₄ over the entire temperature range. The maximum conductivity σ = 0.003 S cm⁻¹ at 773 K with the lowest activation energy of 0.28 eV was observed for the x = 0.4 sample. The enhanced value of dielectric constant and dielectric loss in the case of composites was obtained because of increase of conductivity, resulted from the increase of space charge polarization and charge motion.     

A motorized 5 m tape comparator for traceable measurements of tapes and rules

A motorized 5 m tape comparator was constructed in TUBITAK UME for calibration of tapes and rules up to 5 m length in one set-up and further lengths in multiple set-ups. The system is a practical development and provides a cost effective solution for calibration of tapes in which the highest grade’s accuracy requirement in OIML R35-1 e.g. is 600 μm for 5 m length and 1100 μm for 10 m length. It is mainly composed of 6 m rail system, mechanical parts, optical units and an integrated 6 m incremental linear encoder as a reference measurement axis for traceable measurements. The rails are kinematically located on a heavy marble construction and a motorized carriage, which employs a camera for probing of the scales on the tapes, is moved along the rails during the measurement. The image of the scale taken by the camera is viewed on the monitor screen together with the running software. The operator can perform the probing process by simply moving the carriage over the measured scales (tapes or rules) using a joystick. The carriage movement is measured by the incremental linear encoder previously calibrated by a laser interferometer and the software automatically takes the measurement results from the incremental linear encoder, applies correction values previously defined and determines the length of the tapes and rules as well as deviations from nominal lengths. The estimated expanded uncertainty of the steel tape measurement is U = 54 μm in one set-up (for 5 m length) and U = 77 μm in two set-ups (for 10 m length) at the confidence level of approximately 95%. Uncertainty budget for calibration of the device itself and for calibration of the test tapes are explained in detail. The results of extensive experimental work and analysis are provided by demonstrating application of science and technology of measurement and instrumentation. Investigations for long term stability of the system are given with the reported test results for the years of 2003-2011 and participated intercomparison results to validate the device scientifically are illustrated.     

Improved wear resistance in alumina-PTFE nanocomposites with irregular shaped nanoparticles

Past studies with PTFE nanocomposites showed up to 600× improvements in wear resistance over unfilled PTFE with the addition of Al₂O₃ nanoparticles. Irregular shaped nanoparticles are used in this study to increase the mechanical entanglement of PTFE fibrils with the filler. The tribological properties of 1, 2, 5 and 10 wt.% filled samples are evaluated under a normal pressure and sliding speed of 6.3 MPa and 50.8 mm/s, respectively. The wear resistance was found to improve 3000× over unfilled PTFE with the addition of 1 wt.% nanoparticles. The 5 wt.% sample had the lowest steady state wear rate of K = 1.3 × 10⁻⁷ mm³/N m and the lowest steady friction coefficient with μ = 0.21.     

1-N-alkyl -3-methylimidazolium ionic liquids as neat lubricants and lubricant additives in steel–aluminium contacts

The influence of the alkyl chain length and of the anion on the lubricating ability has been studied for the room-temperature ionic liquids (IL) 1-n-alkyl-3-methylimidazolium X⁻ [X = PF₆; n = 6 (L-P106). X = BF₄; n = 2 (L102), 6 (L106), 8 (L108). X = CF₃SO₃; n = 2 (L-T102). X = (4-CH3C6H4SO3); n = 2 (L-To102)]. Neat IL have been used for AISI 52100 steel-ASTM 2011 aluminium contacts in pin-on-disk tests under variable sliding speed. While all IL give initial friction values lower than 0.15, real-time sharp friction increments related to tribochemical processes have been observed for L102 and L-P106, at room-temperature and at 100 °C. Electronic microscopy (SEM), energy dispersive (EDS) and X-ray photoelectron (XPS) spectroscopies show that wear scar surfaces are oxidized to Al₂O₃ and wear debris contain aluminium and iron (for L102) fluorides. For L-P106, the steel surface is covered with a P-containing tribolayer. A change of anion (L-T102; L-To102) reduces friction and wear, but the lowest values are obtained by increasing the alkyl chain length (L106; L108). When the more reactive L102 and L-P106 are used as 1 wt.% base oil additives at 25 °C, tribocorrosion processes are not observed and a friction reduction (69–75% for 1 wt.% L102) and a change from severe (10⁻³ mm³ m⁻¹) to mild wear (10⁻⁴ to 10⁻⁶ mm³ m⁻¹) is obtained with respect to the neat IL. 1 wt.% IL additives also show good lubricating performance at 100 °C.     

Thermopower detection of single nanowire using a MEMS device

We present a MEMS-based device on a silicon nitride membrane in order to measure the thermoelectric properties of a single nanowire. A temperature gradient along a nanowire was generated by a nanoheater, and the temperature was measured by Pt thermometers. A thermal simulation using a finite element method was conducted to analyze the temperature distribution over the MEMS device. The validity of the MEMS device was established by testing the Pt nanowires which had different symmetry configurations. From the test results of Pt nanowires, a convincing temperature calibration method was proposed and applied to an actual case of Bi₂Te₃ nanowire. We measured a Seebeck coefficient of −53 μV/K and electrical conductivity of 2.23 × 10⁵ S/m for a single Bi₂Te₃ nanowire with a diameter of 70 nm at 300 K. Our solid design for thermoelectric measurements based on a membrane structure enables the fast and high-yield characterization of one-dimensional nanostructures.     

An ultra high-pressure test rig for measurements of small flow rates with different viscosities

Within the framework of a research project regarding investigations on a high-pressure Coriolis mass flow meter (CMF) a portable flow test rig for traceable calibration measurements of the flow rate (mass - and volume flow) in a range of 5 g min⁻¹ to 500 g min⁻¹ and in a pressure range of 0.1 MPa to 85 MPa was developed. The measurement principle of the flow test rig is based on the gravimetrical measuring procedure with flying-start-and-stop operating mode. Particular attention has been paid to the challenges of temperature stability during the measurements since the temperature has a direct influence on the viscosity and flow rate of the test medium. For that reason the pipes on the high-pressure side are double-walled and insulated and the device under test (DUT) has an enclosure with a separate temperature control. From the analysis of the first measurement with tap water at a temperature of 20 °C and a pressure of 82.7 MPa an extensive uncertainty analysis has been carried out. It was found that the diverter (mainly due to its asymmetric behaviour) is the largest influence factor on the total uncertainty budget. After a number of improvements, especially concerning the diverter, the flow test rig has currently an expanded measurement uncertainty of around 1.0% in the lower flow rate range (25 g min⁻¹) and 0.25% in the higher flow rate range (400 g min⁻¹) for the measurement of mass flow. Additional calibration measurements with the new, redesigned flow test rig and highly viscous base oils also indicated a good agreement with the theoretical behaviour of the flow meter according to the manufacturers׳ specifications with water as test medium. Further improvements are envisaged in the future in order to focus also on other areas of interest.     

On the film thickness dependence of shear strengths in sliding,boundary-layer friction

The density functional theory calculated pressure-dependent shear strength S of a four-layer slab of KCl on a Fe(1 0 0) substrate is compared to previous calculations for a bilayer slab to gauge the effect of film thickness on the shear properties of the film. It is found that the shear strength varies with pressure as S = S₀ + αP, where P is the contact pressure. The resulting calculated values for the four-layer slab are S₀〈1 0〉 = 62 ± 15 and S₀〈1 1〉 = 65 ± 11 MPa while α〈1 0〉 and α〈1 1〉 are 0.06 ± 0.01. The values are very close to those calculated for the bilayer slab of S₀〈1 0〉 = 64 ± 9 and S₀〈1 1〉 =69 ± 8 MPa and α〈1 0〉 and α〈1 1〉 of 0.05 ± 0.01, and in reasonable agreement with the experiment values. These results suggest that the thickness of the film does not have a profound effect on the shear properties.     

Development and evaluation of the calibration facility for high-pressure hydrogen gas flow meters

The calibration facility with the multi-nozzle calibrator was developed for the calibration of flow meters to be used with high-pressure, high-flow-rate hydrogen gas. The critical nozzles installed in the multi-nozzle calibrator were calibrated with traceability to the national standard. The relative standard uncertainty of the mass flow rates produced from the calibration facility is 0.09% when the flow rate is between 150 g/min and 550 g/min. In this study, the Coriolis flow meter was calibrated for a pressure range of 15–35 MPa. The relative standard uncertainty of the flow rates obtained from the Coriolis flow meter was 0.44% for the case of the worst fluctuations in the output of the flow meter; based on the calibration curve, this is 0.91%. The present result shows that there is a maximum 3% difference between the output of the Coriolis flow meter and the mass flow rates of the multi-nozzle calibrator, even though the Coriolis flow meter was calibrated using water. Therefore, for the development of a calibration facility that can calibrate a flow meter under the same conditions as those encountered in actual use, it will be important to develop a new flow meter.     

Reaffirmation of measurement uncertainty in pressure sensitivity determination of LS2P microphones by reciprocity method

The paper presents the accuracy and precision associated with realization of primary standard of sound using the reciprocity method. An experimental determination of the front cavity volume on Universal Measuring Machine has lead to reaffirmation of measurement uncertainty in pressure sensitivity determination to 0.04–0.15 dB in frequency range 31.5 Hz to 25 kHz. The reduced measurement uncertainty has also been validated from the results of the recent APMP Key comparison and also by comparison to the manufacturer’s value for LS2P microphones. The use of optical method for measuring the front cavity volume has refined the measurement methodology followed with adaptation of a self reliant, traceable and systematic measurement procedure in comparison to the earlier use of nominal values for sensitivity fitting exercise conducted on MP.EXE program. Consequently, the measurement uncertainty associated with the calibration of working standard microphones, multifunction acoustic calibrator and A-weighted sound pressure level measurements is also reduced.     

Non-contact temperature measurement of silicon wafers based on the combined use of transmittance and radiance

We propose a non-contact temperature measurement method that combines the temperature dependence of transmittance below 600 °C and radiation thermometry above 600 °C. The combined method uses a polarization technique and the Brewster angle between air and a dielectric film such as SiO₂ or Si₃N₄ grown on silicon wafers. A prominent feature of this method is that both measurements of transmittance and radiance are performed with the same geometrical arrangement.For a semitransparent wafer, the measurement of p-polarized transmittance at the wavelengths of 1.1, 1.2 and 1.3 μm enables temperature measurement in the range from room temperature to 600 °C. For an opaque wafer above 600 °C, the p-polarized radiation thermometry at the wavelength of 4.5 μm allows the temperature measurement without the emissivity problem. The combined method with the use of transmittance and radiance is valid in the entire temperature range irrespective of variations of film thickness and resistivity.     

Synthesis of multiple degrees-of-freedom spatial-motion compliant parallel mechanisms with desired stiffness and dynamics characteristics

This paper presents a new design method to synthesize multiple degrees-of-freedom (DOF) spatial-motion compliant parallel mechanisms (CPMs). Termed as the beam-based structural optimization approach, a novel curved-and-twisted (C-T) beam configuration is used as the basic design module to optimize the design parameters of the CPMs so as to achieve the targeted stiffness and dynamic characteristics. To derive well-defined fitness (objective) functions for the optimization algorithm, a new analytical approach is introduced to normalize the differences in the units, e.g., N/m or N m/rad, etc., for every component within the stiffness matrix. To evaluate the effectiveness of this design method, it was used to synthesize a 3-DOF spatial-motion (θ_x − θ_y − Z) CPM that delivers an optimized stiffness characteristics with a desired natural frequency of 100 Hz. A working prototype was developed and the experimental investigations show that the synthesized 3-DOF CPM can achieved a large workspace of 8°×8°×5.5 mm, high stiffness ratios, i.e., >200 for non-actuating over actuating stiffness, and a measured natural frequency of 84.4 Hz.     

Performance evaluation of a cheap,open source,digital environmental monitor based on the Raspberry Pi

We report on the design, construction and evaluation of a low-cost digital environmental monitoring system based on a popular micro-computer board and mass market digital sensors. The system is based around the use of open source software and readily available digital sensors, providing key parameters required for environmentally-controlled calibration laboratories: air temperature, pressure and humidity. Each system logs data at set intervals with front-panel display, web page graphical display and email alerting when exceeding set tolerances. The sensors have been calibrated at the National Physical Laboratory using standards traceable to the SI. Long term stability of the system is estimated and in addition to monitoring of laboratory environments for regulatory purposes, the systems can also be used to provide on-demand values for local refractive index with an expanded (k = 2) uncertainty of 1.1 × 10⁻⁷ as required for many optical-based measuring systems.     

Specific energy and surface roughness of minimum quantity lubrication grinding Ni-based alloy with mixed vegetable oil-based nanofluids

Vegetable oil is a low toxic, excellent biodegradable and renewable energy source used as an ideal lubricating base oil in machining. Castor oil exhibits good lubrication performance but poor mobility, which limits its application especially in precision grinding. The main objective of the work presented to obtain optimal mixed vegetable based-oil and optimal nanoparticles adding concentration in grinding Ni-based alloy with minimum quantity lubrication. An experimental investigation is carried out first to study the different vegetable oils with excellent mobility mixed with castor oil. The lubrication property of the oil was evaluated in terms of grinding force, force ratio, specific grinding energy, and surface roughness. Based on the test conditions, it is found that soybean/castor mixed oil obtained the optimal results (μ= 0.379, U = 83.27 J/mm³ and Ra = 0.325 μm) and lubricating effect compared with castor oil and other mixed base oils. To further explore the lubricating capability of soybean/castor mixed oil, MoS₂ nanoparticles which have excellent lubricating property were added into the soybean/castor mixed oil to prepare different concentrations nanofluids. From the present study, it can be concluded that 8% mass fraction of the oil mixture should be added to obtain the optimal machining results, with the lowest force ratio (0.329), specific energy (58.60 J/mm³), and average grinding temperature (182.6 °C). Meanwhile, better surface microtopography of ground parts and grinding debris morphologies were also observed for the machining conditions.     

Improved critical flow factors and representative equations for four calibration gases

The critical flow nozzle is widely used to calibrate flowmeters in gas flow measurement. Its use requires the critical flow factor, C*, a parameter dependent upon the thermophysical properties of the gas at the nozzle throat, and the upstream temperature and pressure. This paper presents C* values for four calibration gases (air, argon, nitrogen and methane), calculated from the most recent reference quality equations of state, over a wider range of temperature and pressure than previously available, 200–600 K and up to 20 MPa. In addition, a new empirical equation has been developed to represent the calculated values accurately, thus eliminating the need for complex calculations or interpolations from tables.