共查询到18条相似文献,搜索用时 46 毫秒
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采用共混添加法,将载银活性炭与丙烯腈偏氯乙烯共聚体共混,以二甲基甲酰胺为溶剂湿法纺丝,制成一种新型抗菌吸附多功能纤维,探讨了所制得的纤维的结构与性能。通过SEM、DSC、TG和力学性能测试对所制纤维的物理化学性能进行了表征.结果表明,适合纺丝的载银活性炭含量在15%~20%(质量分数),在此范围内制得纤维力学性能良好,载银活性炭的载银量〉0.02%,具有较好的抗菌功效。 相似文献
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采用DSC、TGA、IR及PGC等方法对AN-VDC共聚体纤维在空气中受热过程中发生的化学变化进行分析。结果表明,在250℃以下,共聚体化学结构无明显变化;在250℃,共聚体脱除HCl,该反应的温度几乎不受共聚体组成的影响,在300~320℃处,共聚体分子链中AN序列的CN基发生环化,适当提高VDC含量有利于降低环化温度,在500℃附近,共聚体完全分解,并生成大量低分子碎片。 相似文献
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腈氯纶阻燃机理的研究 总被引:2,自引:1,他引:1
本文对腈氯纶中氯元素的阻燃效果及其作用机理和三氧化二锑与氯元素的协同效应等问题作了分析。结果表明,偏二氯乙烯的阻燃效果优于氟乙烯,当丙烯腈-偏二氯乙烯共聚体中偏二氯乙烯含40%wt时,由该共聚体所纺成的腈氯纶具有显著的阻燃性;三氧化二锑与氯元素的阻燃增效效应达到最佳时(△LOI达到最大),Sb/Cl为21~25(摩尔比),与腈氯纶的化学结构无关。 相似文献
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甲醛作为室内空气的主要污染物之一,对人类的健康造成极大的危害.能否有效去除甲醛已成为人们关注的热点,而吸附法被认为是一种去除甲醛的重要方法.本研究采用低浓度的硝酸、草酸、双氧水和氢氧化钠于常温下浸渍处理竹质活性炭,利用环境扫描电子显微镜(E-SEM)、比表面积分析仪(BET)、傅里叶变换红外光谱(FTlR)和X射线光电子能谱(XPS)对改性前后的活性炭形貌、孔隙特征和表面官能团进行表征,并运用静、动态甲醛检测分析装置评价改性后的竹质活性炭对甲醛的吸附效果.结果表明,与未处理竹质活性炭相比,四种改性处理的竹质活性炭样品表面都有不同程度的蚀刻和皱缩,微孔数量均有不同程度的增加,但氢氧化钠改性竹质活性炭平均孔径为1.89 nm,小于未处理竹质活性炭孔径.改性前后竹质活性炭的FTlR特征吸收峰的峰形没有明显变化,只是峰强有所差异;XPS结果表明改性后竹质活性炭的含氧量均有所增加;改性活性炭对甲醛的去除能力明显提高了,其中硝酸改性竹质活性炭性能最好,主要原因是硝酸改性活性炭表面羰基和酯基的协同作用增强,提高了活性炭的极性,有利于对极性甲醛分子的吸附. 相似文献
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活性炭纤维的吸附特性R.C.Bansal等(印度)前言制备能消除或减小传质过程中外扩散、内扩散阻力因而具有高的吸附速率的活性炭纤维成为最近许多研究的主题。这些活性炭纤维是通过酚醛前驱体(1—2)、粘胶丝纤维(3-4)及沥青前驱体纤维(5)的碳化及随后... 相似文献
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为了解活性炭纤维对室内低浓度污染物的吸附性能及其影响因素,以甲醛为模拟污染物,通过改变污染物的初始浓度以及外界参数(温度、相对湿度、表面风速)对活性炭吸附性能进行了试验研究.实验结果显示:温度和气流速度对活性炭纤维的吸附性能有较大的影响,相对来说温度的影响要大一些;而相对湿度对其的影响则不太明显.并运用吸附动力学方程式和吸附平衡方程式对影响因素进行了分析并与试验结果进行了比较,结果表明实验结果与理论分析相吻合. 相似文献
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将纳米MnO2催化剂粉末负载到自制的含活性炭的腈氯纶纤维上,在室温下对甲醛进行吸附分解研究。借助扫描电子显微镜(SEM)进行显微结构观察,并分析了不同处理情况的负载纤维对甲醛的去除率。结果表明,研磨6h的MnO2粉末分散均匀,平均粒径可达300 nm,以平铺的形式均匀地负载于纤维上;研磨6h的MnO2粉末反应72h对甲醛的去除率达94.07%;二甲基甲酰胺(DMF)处理后的纤维对甲醛的去除率有所提高。 相似文献
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活性炭纤维(ACF)吸附二硫化碳(CS2)的研究 总被引:1,自引:0,他引:1
研究了商用活性炭纤维(Activated carbonf fiber-ACF)对二硫化碳(Carbon disulfide-CS2)的吸附件能,并与活性炭(Activated carbon-AC)、沸石吸附CS2的性能做了对比.重点考察了CS2浓度、吸附气流量、湿度和ACF含水量对CS2在ACF上吸附性能的影响.结果表明:相对于AC、沸石,ACF对CS2的吸附快、吸附率高,达46.5%;CS2浓度、吸附气流量增加,穿透点前移;湿度和含水量上升会明显降低ACF对CS2的吸附性能,当湿度升至65%时,吸附时间缩短28.6%;当含水量为质量分数45%时,穿透时间提前42.9%;当含水量增至质量分数60%时,CS2迅速穿透,ACF几乎不能再吸附CS2. 相似文献
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Shuixia Chen Ruimei Xu Huixing Huang Fenyun Yi Xin Zhou Hanmin Zeng 《Journal of Materials Science》2007,42(23):9572-9581
A number of activated carbon fibers (ACF) were prepared by activation with steam, Phosphoric acid, or Zinc Chloride. Their
reduction-adsorption behavior for Pt(IV) was studied using scanning electron microscopy, X-ray diffraction (XRD) and X-ray
photoelectron spectroscopy. The results show that Pt ions in solution can be adsorbed by ACFs and reduced to metallic platinum.
The reduction–adsorption capacity of ACF for Pt could be greater than 200 mg/g. Generally, higher specific surface area or
lower electrode potential produces a higher capacity. Most of the adsorbed platinum ions were reduced into metallic platinum,
and about 25% of platinum atoms remained as Pt(II) or Pt(IV). XRD examination showed that the Pt particles on the ACF surface
were crystallized when heated to 673 K. 相似文献
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炭纤维和活性炭甲醇气相吸附动力学和等温线 总被引:3,自引:0,他引:3
C.Vagner G.Finqueneisel T.Zimny J.V.Weber 《新型炭材料》2003,18(2):133-136
采用不同原料、不同活化过程的两种活性炭和两种炭纤维(PAN、Rayon基)进行了甲醇气相静态吸附,结合其吸附动力学和等温线的数据研究了有关扩散问题,发现温度与所用样品表面化学性质、中孔率、孔隙(形态与大小)微织构对其吸附动力学有影响。 相似文献
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Mercury adsorption on granular activated carbon in aqueous solutions containing nitrates and chlorides 总被引:1,自引:0,他引:1
Adsorption is an effective process to remove mercury from polluted waters. In spite of the great number of experiments on this subject, the assessment of the optimal working conditions for industrial processes is suffering the lack of reliable models to describe the main adsorption mechanisms. This paper presents a critical analysis of mercury adsorption on an activated carbon, based on the use of chemical speciation analysis to find out correlations between mercury adsorption and concentration of dissolved species. To support this analysis, a comprehensive experimental study on mercury adsorption at different mercury concentrations, temperatures and pH was carried out in model aqueous solutions. This study pointed out that mercury capture occurs mainly through adsorption of cationic species, the adsorption of anions being significant only for basic pH. Furthermore, it was shown that HgOH(+) and Hg(2+) are captured to a higher extent than HgCl(+), but their adsorption is more sensitive to solution pH. Tests on the effect of temperature in a range from 10 to 55 °C showed a peculiar non-monotonic trend for mercury solution containing chlorides. The chemical speciation and the assumption of adsorption exothermicity allow describing this experimental finding without considering the occurrence of different adsorption mechanisms at different temperature. 相似文献
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Study on adsorption refrigeration cycle utilizing activated carbon fibers. Part 1. Adsorption characteristics 总被引:1,自引:0,他引:1
Y. Hamamoto K.C.A. Alam B.B. Saha S. Koyama A. Akisawa T. Kashiwagi 《International Journal of Refrigeration》2006,29(2):305-314
Thermal heat driven adsorption systems using natural refrigerants have been focused on the recent energy utilization trend. However, the drawbacks of these adsorption systems are their poor performance in terms of system cooling capacity and coefficient of performance (COP). The objective of this paper is to improve the performance of thermally powered adsorption cooling system by selecting new adsorbent–refrigerant pair. Adsorption capacity of adsorbent–refrigerant pair depends on the thermophysical properties (pore size, pore volume and pore diameter) of adsorbent and isothermal characteristics of the pair. In this paper, the thermophysical properties of two PAN types of activated carbon fibers (FX-400 and KF-1000) are determined from the nitrogen adsorption isotherms. The standard nitrogen gas adsorption/desorption measurements on various adsorbents at liquid nitrogen of temperature 77.3 K were performed. Surface area of each adsorbent was determined by the Brunauer, Emmett and Teller (BET) plot of nitrogen adsorption data. Pore size distribution was measured by the Horvath and Kawazoe (HK) method. As of the adsorption/desorption isotherms, FX-400 shows very small hysteresis when the value of P/Po exceeds 0.4, while KF-1000 has no hysteresis in the whole range of P/Po. The adsorption capacity of FX-400 is about 30% higher than that of KF-1000. The adsorption equilibrium data of activated carbon fiber (ACF)-methanol are presented and correlated with simple equations. The adsorption equilibrium data of ACF (KF-1000)-water also presented in order to facilitate comparison with those of ACFs-methanol pair. The results will contribute significantly in designing the adsorber/desorber heat exchanger for thermally driven adsorption cooling system. 相似文献
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Energetic heterogeneities of the oxidized cellulose-, pitch-, and poly-acrylonitrile-based activated carbon fibers are characterized by means of the adsorption potential distribution functions. These distributions are calculated from the low-temperature nitrogen adsorption isotherms by using the condensation approximation method. It is shown that the distribution functions obtained for the carbon fibers studied are composed of two peaks, which reflect the bi-microporous structure of these solids. 相似文献