Static and dynamic magnetic properties of Co<Subscript>2</Subscript>Z barium ferrite nanoparticle composites

The static, dynamic and attenuation properties of Co₂Z barium ferrites and Co₂Z composites have been studied. The results showed that both static and dynamic magnetic properties are significantly different for large particles and nanoparticles. As compared to large particles, Co₂Z nanoparticles have a small saturation magnetization M_s, large coercivity H_c, small permeability ₀ and _max, but high resonance frequency f_R. The maximum reflection loss predicted is much smaller for nanoparticles than for large particles. Therefore, Co₂Z barium ferrite with large particle is more suitable for EM materials with high attenuation and broad bandwidth at microwave frequency.     

Hydroxylapatite-zirconia composites: Thermal stability of phases and sinterability as related to the CaO-ZrO<Subscript>2</Subscript>phase diagram

Composites of hydroxylapatite (HA) with pure zirconia, and 3 and 8% Y₂O₃ in zirconia, were pressure-less sintered at temperatures from 900 to 1300C, and hot-pressed at 1200C in argon gas atmosphere for 1 h. The reactions and transformations of phases were monitored with X-ray diffraction and thermal analysis. At sintering temperatures higher than 1000,C, calcium from HA diffused into the zirconia phase, and the HA phase decomposed to tri-calcium phosphate (TCP). Above about 1200,C, CaZrO₃ was formed. These reactions and transformations were interpreted in terms of the ZrO₂-CaO phase diagram. On the other hand, zirconia and hydroxylapatite phases in hot pressed composite remained mainly stable suggesting that air in the sintering environment increased the reactivity between the phases. The highest densification was found in a composite initially containing 10% monoclinic ZrO₂ sintered at 1300,C. The densification of the composites decreased at lower sintering temperatures and higher zirconia contents upon air-sintering.     

Dielectric anomalies in monoclinic TlInS<Subscript>2</Subscript> polytypes

Comparison of room-temperature x-ray diffraction data and temperature-dependent (190–220 K) permittivity data for different polytypes of monoclinic TlInS₂ demonstrates that the anomalies in (T) at the phase transition correlate with the c cell parameter of the polytypes. The (T) curve of single-phase crystals with c 15 Å shows a single, sharp peak at about 205 K. The peaks in the of the polytypes with c 30 and 60 Å occur at other temperatures, indicating that permittivity data near the phase transition can be used to identify the polytypes present in TlInS₂ crystals.Translated from Neorganicheskie Materialy, Vol. 40, No. 12, 2004, pp. 1423–1426.Original Russian Text Copyright © 2004 by Alekperov, Nadjafov     

Spectral parameters of Nd<Superscript>3+</Superscript> ion in Sr<Subscript>6</Subscript>NdSc(BO<Subscript>3</Subscript>)<Subscript>6</Subscript> crystal

The spectroscopic study of Nd³⁺ in Sr₆NdSc(BO₃)₆ crystal had been performed. Based on the Judd-Ofelt theory to analyze the optical strengths measured in absorption spectra, the following spectral parameters were obtained: intensity parameters are ₂ = 1.108 × 10^–20 cm², ₄ = 2.884 × 10^–20 cm², ₆ = 3.085 × 10^–20 cm², the radiative lifetime is 385 s, the quantum efficiency is 12.5%. The fluorescence branch ratios were calculated: ₁ = 0.423, ₂ = 0.482, ₃ = 0.092, ₄ = 0.005.     

Electrical and photoelectric properties of electrodeposited <Emphasis Type="Italic">n</Emphasis>-Si/<Emphasis Type="Italic">n</Emphasis>-Cd<Subscript>1 - <Emphasis Type="Italic">x</Emphasis></Subscript>Zn<Subscript>x</Subscript>S heterojunctions

n-Si/n-Cd_{1 - x} Zn_xS heterojunctions are produced by electrodepositing Cd_{1 - x} Zn_xS (0 x 0.6) films on silicon substrates, and their electrical and photoelectric properties are studied. The results demonstrate that the spectral response of the heterojunctions depends strongly on the film composition and heat-treatment conditions. The highest photosensitivity is achieved at x = 0.6 by heat treatment at 350°C for 7 min: V _OC = 0.5 V and I _SC = 3.8 mA/cm² under illumination of 1500 lx at 300 K.Translated from Neorganicheskie Materialy, Vol. 41, No. 3, 2005, pp. 276–280.Original Russian Text Copyright © 2005 by Mamedov, Gasanov, Amirova.This revised version was published online in April 2005 with a corrected cover date.This revised version was published online in April 2005 with a corrected cover date.     

A model with length scales for composites with periodic structure. Steady state heat conduction problem

A new high-order model for analysing distribution of temperature in periodic composites is proposed. The original scalar elliptic problem with Y-periodic coefficients (Y is a cube) is replaced with a vectorial elliptic problem of constant coefficients. The unknown fields are: the averaged distribution of temperature and the vector field which stands for perturbation of the temperature within the cells of periodicity. The recovery of temperature in the original composite is given by the approximation: 0(x)=0(x) +h ^a (x/) _a (x) analogous with the first terms of the two-scale asymptotic expansion known from the homogenization theory. The functions h are defined as approximations of the solutions to the basic cell problems. In contrast to the two-scale expansion the expression for satisfies the boundary condition.     

Universal simulation of degenerating homogeneous turbulence

The problem of universal simulation of the dynamics of a turbulent velocity field (universal in the sense of arbitrary values of the Reynolds turbulence number) is treated on the basis of the moment model in the second approximation.Notation ¯q² _i ² double the kinetic turbulence energy - _u ² =5v¯q²/_u Taylor turbulence scale squared - _u=v1/x_k)²> kinetic-energy dissipation function - N_Re,=¯q²_u / Reynolds turbulence number Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 42, No. 1, pp. 46–52, January, 1982.     

Equations of generalized thermoelasticity of a Cosserat medium in stresses

Thermoelasticity equations in stresses are derived in this paper for a Cosserat medium taking into account the finiteness of the heat propagation velocity. A theorem is proved on the uniqueness of the solution for one of the obtained systems of such equations.Notation u displacement vector - small rotation vector - absolute temperature - ₀ initial temperature of the medium - relative deviation of the temperature from the initial value - , , , , , ,, m constants characterizing the mechanical or thermophysical properties of the medium - density - I dynamic characteristic of the medium reaction during rotation - k heat conduction coefficient - ₀ a constant characterizing the velocity of heat propagation - X external volume force vector - Y external volume moment vector - w density of the heat liberation sources distributed in the medium - E unit tensor - T force stress tensor - M moment stress tensor - nonsymmetric strain tensor - bending-torsion tensor - s entropy referred to unit volume - V volume occupied by the body - surface bounding the body - (T)_ki, (M)_ki components of the tensorsT andM - q thermal flux vector Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 40, No. 3, pp. 482–488, March, 1981.     

Thermal transport properties of helium near the superfluid transition. II. Dilute3He-4He mixtures in the superfluid phase

Measurements of the average thermal conductivity _exp hQ/T and of the thermal relaxation time to reach steady-state equilibrium conditions are reported in the superfluid phase for dilute mixtures of³He in⁴He. Hereh is the cell height,Q is the heat flux, andT is the temperature difference across the fluid layer. The measurements were made over the impurity range 2×10^–9<X(³He)<3×10^–2 and with heat fluxes 0.3<Q<160 µW/cm². Assuming the boundary resistanceR _b , measured forX<10^–5, to be independent ofX over the whole range ofX, a calculation is given for _exp. ForQ smaller than a well-defined critical heat fluxQ _c (X) X ^0.9, _exp is independent of Q and can be identified with the local conductivity _eff, which is found to be independent of the reduced temperature = (T–T)/T for –10^–2. Its extrapolated value at T is found to depart forX10^–3 from the prediction X ^–1 , tending instead to a weaker divergence X ^–a witha0.08. A finite conductivity asX tends to zero is not excluded by the data, however. ForQ >Q _c (X), a nonlinear regime is entered. ForX10^–6, the measurements with the available temperature resolution are limited to the nonlinear conditions, but can be extrapolated into the linear regime forX2×10^–7. The results for _exp(Q),Q _c (X), and _eff(XX) are found to be internally consistent, as shown by comparison with a theory by Behringer based on Khalatnikov's transport equations. Furthermore, the observed relaxation times (X) in the linear regime are found to be consistent forX>10^–5 with the hydrodynamic calculations using the measured _eff(X). ForX<10^–5, a faster relaxation mechanism than predicted seems to dominate. The transport properties in the nonlinear regimes are presented and unexplained observations are discussed.     

Tangent modulus tensor in plasticity under finite strain

Summary The tangent modulus tensor, denoted as , plays a central role in finite element simulation of nonlinear applications such as metalforming. Using Kronecker product notation, compact expressions for have been derived in Refs. [1]–[3] for hyperelastic materials with reference to the Lagrangian configuration. In the current investigation, the corresponding expression is derived for materials experiencing finite strain due to plastic flow, starting from yield and flow relations referred to the current configuration. Issues posed by the decomposition into elastic and plastic strains and by the objective stress flux are addressed. Associated and non-associated models are accommodated, as is plastic incompressibility. A constitutive inequality with uniqueness implications is formulated which extends the condition for stability in the small to finite strain. Modifications of are presented which accommodate kinematic hardening. As an illustration, is presented for finite torsion of a shaft, comprised of a steel described by a von Mises yield function with isotropic hardening.Notation B strain displacement matrix - C=F ^T F Green strain tensor - compliance matrix - D=(L+L ^T )/2 deformation rate tensor - D fourth order tangent modulus tensor - tangent modulus tensor (second order) - d VEC(D) - e VEC() - E Eulerian pseudostrain - F, F _e ,F _p Helmholtz free energy - F=x/X deformation gradient tensor - f consistent force vector - residual function - G strain displacement matrix - h history vector - h time interval - H function arising in tangent modulus tensor - I, I ₉ identity tensor - i VEC(I) - k ₀,k ₁ parameters of yield function - K _g geometric stiffness matrix - K _T tangent stiffness matrix - k _k kinematic hardening coefficient - J Jacobian matrix - L=v/x velocity gradient tensor - m unit normal vector to yield surface - M strain-displacement matrix - N shape function matrix - n unit normal vector to deformed surface - n ₀ unit normal vector to undeformed surface - n unit normal vector to potential surface - r, R, R ₀ radial coordinate - s VEC() - S deformed surface - S ₀ undeformed surface - t time - t, t ₀ traction - t VEC() - VEC( ) - t VEC() - t _r reference stress interior to the yield surface - t t–t _r - T kinematic hardening modulus matrix - u=x–X displacement vector - U permutation matrix - v=x/t particle velocity - V deformed volume - V ₀ undeformed volume - X position vector of a given particle in the undeformed configuration - x(X,t) position vector in the deformed configuration - z, Z axial coordinate - vector of nodal displacements - =(F ^T F–I)/2 Lagrangian strain tensor - history parameter scalar - , azimuthal coordinate - elastic bulk modulus - flow rule coefficient - twisting rate coefficient - elastic shear modulus - iterate - Second Piola-Kirchhoff stress - Cauchy stress - Truesdell stress flux - deviatoric Cauchy stress - Y, Y yield function - residual function - plastic potential - X, Xe, Xp second order tangent modulus tensors in current configuration - X, Xe, Xp second order tangent modulus tensors in undeformed configuration - (.) variational operator - VEC(.) vectorization operator - TEN(.) Kronecker operator - tr(.) trace - Kronecker product     

Effects of Y<Subscript>2</Subscript>O<Subscript>3</Subscript> on the microstructure and electrical properties of Pr-ZnO varistors

Effects of Y₂O₃ contents on the microstructure and electrical properties of Pr₆O₁₁-based ZnO varistor have been studied. The varistor voltage (V_1mA) and the nonlinear exponent () increased with increasing Y₂O₃ contents, whereas the dielectric constant decreased. Y-rich phase segregated at nodal points in grain boundaries. The average grain size decreased with increasing Y₂O₃ content. The specimen with 4.0 mol% Y₂O₃ sintered at 1285 C exhibited the highest nonlinear exponent ( = 77) with the dielectric constant, ~352 at 1 kHz.     

Sintering behavior and thermal property of Mg<Subscript>2</Subscript>SnO<Subscript>4</Subscript>

The sintering behavior of Magnesium Orthostannate (Mg₂SnO₄) by Magnesium oxide (MgO) and tin oxide (SnO₂) was investigated. Mg₂SnO₄ compound was formed by traditional solid state reaction (SSR) at elevated temperatures over a range of 600 C–1300 C. X-ray studies have revealed that the resulting, as-fired, compound is polycrystalline composed of an inverse spinel-structure grains separated partially by porosity. However it failed to detect any phase change as a result of annealing. Scanning electron microscope (SEM) was employed to follow-up any change in the morphology throughout the sintering and reduction processes. Thermal property Differential Scanning Calorimetry (DSC) revealed that reduction takes place at a temperature between 400 and 600 C, depending on the concentration of H₂ in the atmosphere in accordance with the X-ray studies. The technique employed has also demonstrated the stability of reduced species in typical atmospheres and working conditions.     

Photoacoustic Spectroscopic Study of Optical Band Gap of Zn<Subscript>1-x</Subscript>Be<Subscript>x</Subscript>Se Semiconductors

Using the photoacoustic spectroscopic (PAS) technique for the first time, the composition-dependent optical absorption coefficient and band gap of Zn_1-xBe_xSe semiconductors (with x = 0.0–0.25) have been measured at room temperature. The band gap ₀estimated from the PAS spectra varies nonlinearly with Be concentration. The exchange interaction of electrons in conduction and valence bands, effects of polytypes, microstructures, and the mixed crystallization (zinc-blend and wurtzite structures) effect are considered for the analysis of the data. The observed exponential edge (Urbachs edge) can be considered as an internal Franz–Keldish effect arising from the charged impurity generated and frozen-in optical phonon-generated fields. The phonon-assisted indirect transition at the band tail regions for some samples is also observed in the present studies.Paper presented at the Fifteenth Symposium on Thermophysical Properties, June 22–27, 2003, Boulder, Colorado, U.S.A.     

Some electrical characteristics of lithium and yttrium sialons

Some electrical properties of hot-pressed lithium sialons, Li _x/8Si_6–3x/4Al_5x/8O _x N_8–x havingx<5 and an yttrium sialon were measured between 291 and 775 K; the former consisted essentially of a single crystalline phase whereas the latter contained 98% glassy phase. For lithium sialons, the charging and discharging current followed al(t) t ^–nlaw withn=0.8 at room temperature. The d.c. conductivities were about 10^–13 ohm^–1 cm^–1 at 291 K and rose to 5×10^–7 ohm^–1 cm^–1 at 775 K. At high temperatures electrode polarization effects were observed in d.c. measurements. The variation of the conductivity over the frequency range 200 Hz to 9.3 GHz followed the () ⁿ law. The data also fitted the Universal dielectric law,() ^n–1 well, and approximately fitted the Kramers-Kronig relation()/()– =cot (n/2) withn decreasing from 0.95 at 291 K to 0.4 at 775 K. The temperature variations of conductivities did not fit linearly in Arrhenius plots. Very similar behaviour was observed for yttrium sialon except that no electrode polarization was observed. The results have been compared with those obtained previously for pure sialon; the most striking feature revealed being that _d.c. for lithium sialon can be at least 10³ times higher than that of pure sialon. Interpretation of the data in terms of hopping conduction suggests that very similar processes are involved in all three classes of sialon.     

Dynamic scaling and ultrasonic attenuation in 4He near the superfluid transition point

Attenuation of first sound has been measured in ⁴He under saturated vapor pressure near the lambda temperature T at frequencies /2 ranging from 10.2 to 271 MHz. The frequency dependence of the critical part of the attenuation is determined and the dynamic scaling hypothesis is examined. Above the lambda point, it is found that the critical attenuation is described by a scaling function (, ) = ^1+y F(), where = ₀^–x and = T/T – 1, with the results x = 1.02±0.05 and y = 0.33±0.03. The characteristic frequency of the order-parameter fluctuation with the wave number k equal to the inverse correlation length is then proportional to ^x , which is in an excellent agreement with the prediction of dynamic scaling. Below the lambda point, a characteristic relaxation time or times shorter than previously expected at lower frequencies appears to exist in the present frequency range.Based on a Ph.D dissertation submitted by K. Tozaki to the University of Tokyo (1977).     

Synthesis,crystal structure,and proton conductivity of KFe(H<Subscript>2</Subscript>P<Subscript>2</Subscript>O<Subscript>7</Subscript>)<Subscript>2</Subscript>

KFe H₂P₂O7)₂ is synthesized at 443 K in molten polyphosphoric acids containing K and Fe ions, and its crystal structure is determined: triclinic unit cell with a = 4.9974(6) Å, b = 7.4766(9) Å, c = 7.8185(9) Å, = 82.29(2)°, = 83.37(2)° , = 74.13(2)° ; Z = 1, sp. gr. P . The structure is made up of infinite ribbons formed by corner-shared PO₄ tetrahedra and FeO₆ octahedra, with the K atoms in between. Neighboring ribbons are linked by hydrogen bonds. The proton conductivity of potassium iron(III) dihydrogen diphosphate is rather low.Translated from Neorganicheskie Materialy, Vol. 41, No. 1, 2005, pp. 74–77. Original Russian Text Copyright © 2005 by Chudinova, Murashova, Ilyukhin, Tarnopolskii, Yaroslavtsev.     

High-field electrical conduction in m Hgl2

The electrical and dielectric properties of illuminated Hgl₂ were studied at room temperature under various a.c.-signal amplitudes in the frequency range 1 Hz to 10 kHz. Below 40 H, We real part of the dielectric constant, ,was found to vag slightly with voltege for low electric fields (E < 10³V cm^–1, above which it showed a steady increase with the applied voltage. At higher frequencies, no voltage dependence of (or the geometrical capacitance) of the crystal was observed. On the other hand, the imaginary part of the dielectric constant, or the a.c. conductivity, (=_o) was found to decrease considerably with the applied voltage forE < 10³V cm^–1 at all frequencies. For higher fields (E > 10³V cm^–1), exp [C(E/)^1/2], whereC is e constant. Above 40 Hz, this variation was in good agreement with the behaviour of the bulk, resistance of the crystal. Such behaviour is discussed in the view of Richardnon-Schottky and Poole-Frenkel conduction mechanisms, which seem to be operative in Hgl₂ at room temperature.     

Measurement of temperature in a non-steady-state gas flow

A method is described for measuring the temperature of a non-steady-state gas flow with a thermocouple which is an inertial component of the first order.Notation T*_f non-steady-state gas flow temperature - T_t thermosensor temperature - thermal inertia factor of thermosensor - time - C total heat capacity of thermosensor sensitive element - S total heat-exchange surface between sensitive element and flow - heat-liberation coefficient - temperature distribution nonuniformity coefficient in sensitive element - Re, Nu, Pr, Bi, Pd hydromechanical and thermophysical similarity numbers - P^* total flow pressure - P static flow pressure - T^* total flow temperature - d_t sensitive element diameter - w gas flow velocity - flow density - flow viscosity - _f flow thermal conductivity - k gas adiabatic constant - R universal gas constant - M Mach number - T thermodynamic flow temperature - _o, _o and values at T=288°K - A, m, n, p, r coefficients - _c heat-liberation coefficient due to colvection - _r heat-liberation coefficient due to radiation - _b emissivity of sensitive element material - Stefan-Boltzmann constant - T_e temperature of walls of environment - _c, _r, _tc thermosensor thermal inertia factors due to convective, radiant, and conductive heat exchange - L length of sensitive element within flow - a thermal diffusivity of sensitive element material - _t thermal conductivity of sensitive element material Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 47, No. 1, pp. 59–64, July, 1984.     

Phase transitions and high-temperature crystal chemistry of polymorphous modifications of Cs<Subscript>2</Subscript>(UO<Subscript>2</Subscript>)<Subscript>2</Subscript>(MoO<Subscript>4</Subscript>)

Phase transitions and thermal deformations of - and -Cs₂(UO₂)₂(MoO₄)₃ were studied by high-temperature X-ray diffraction analysis. In heating of -Cs₂(UO₂)₂(MoO₄)₃ to 625 ± 25°C, the reconstructive phase transition proceeds. -Cs₂(UO₂)₂(MoO₄)₃ is stable up to 700 ±25°C. The thermal expansion of both phases is sharply anisotropic: ₁₁ = 10 × 10^–6, ₂₂ = 33 × 10^–6, ₃₃ = 10 × 10^–6, _V = 53 × 10^–6 deg^–1 for -Cs(UO₂)₂(MoO₄)₃ and ₁₁ = 13 × 10^–6, ₃₃ = 3 × 10^–6, _V = 31 × 10^–6 deg^–1 for -Cs₂ (UO₂)₂ (MoO₄)₃. The anisotropy of thermal expansion is explained by features of the crystal structure of the compounds.Translated from Radiokhimiya, Vol. 46, No. 5, 2004, pp. 405–407.Original Russian Text Copyright © 2004 by Nazarchuk, Krivovichev, Filatov.     

Analysis of the tensile properties and fractography of as-cast and heat treated 359-SiC-20p composite

An experimental study of the heat treatment of 359-SiC 20p composite and its base alloy was made to determine the strength-ductility characteristics under varying conditions of heat treatment. Microstructural observations revealed that addition of the SiC_p reinforcement to the base alloy produced a more uniform and refined interdendritic microstructure compared to the latter. The tensile data obtained was analysed in terms of the theoretical models existing in the composite literature. Ultimate tensile strength (UTS)-log elongation relationships were obtained to test the applicability of the quality index parameter,Q, to the present composite. From this analysis, it was found that all data points in the ageing temperature range 140–210 °C could be represented by a single line (cf. two lines in the case of 359 alloy), indicating the important fact that the tensile properties of this composite can be predicted/determined over the entire temperature range. The presence of the SiC particles was seen to accelerate the Mg₂Si precipitation kinetics, but not to alter it. Fracture mechanisms were determined from both the fracture surfaces and their longitudinal sections beneath the fracture surface, employing both optical and scanning electron microscopy.Nomenclature a Particle diameter - b Burger's vector - b _ii Numerical constant relating P _ii ^E _m andP ₃₃ ^A - E _c Young's modulus of the composite - E _m Young's modulus of the matrix - E _p Young's modulus of SiC particles - El Elongation (%) - f _p SiC volume fraction - P ₃₃ ^A Applied stress - P _ii ^E Long range back stress developed by elastic misfit - P _m ^F Change in matrix flow stress - <P _ii ^P >_m Back stresses due to plastic deformation - P _c ^ps Proof strain of a composite - q _ii Plastic misfit - Q Quality index - R Statistical correlation coefficient - RE Rockwell E hardness value - S SiC particle aspect ratio - S _c Critical aspect ratio for the SiC particles - UTS Ultimate tensile strength of the alloy or composite - YS Yield strength of the alloy or composite - Critical misfit strain - Constant, 1.25 for aluminum alloys - Plastic strain - ^ps Plastic strain at whichP _c ^ps is required - Work hardening rate at a given plastic strain - Work hardening rate as a function of total strain - Shear modulus - Dislocation density - _c ^O Yield stress of the composite - _CTE Increase in yield stress due to coefficient of thermal expansion (CTE) - _m ^O Yield stress of the matrix - _p Particle strength - _i Interfacial shear strength