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卤水-氨法碱式氯化镁晶须的制备及影响因素的研究 总被引:1,自引:0,他引:1
在常压下用液相反应法制备了碱式氯化镁晶须,研究了氯化镁浓度、氯化镁与氨水的摩尔比、反应温度、陈化温度、陈化时间对碱式氯化镁晶须制备的影响.根据XRD和SEM测试结果,提出了制备碱式氯化镁晶须的最佳工艺条件:(1)氯化镁浓度为3mol/l;(2)氯化镁与氨水的摩尔比为4:1~6:1;(3)最佳反应温度为30℃;(4)氨水的加料速度为10ml/min~20ml/min;(5)最佳陈化温度为50℃~60℃,最佳陈化时间为48h~72h.制备得到了长径比≥100碱式氯化镁晶须. 相似文献
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为探讨魔芋葡甘聚糖吸附香兰素的基本特征,以魔芋葡甘聚糖溶液浓度、pH值、温度和时间为试验因素,进行单因素试验,对结果进行方差分析。结果表明,随着魔芋葡甘聚糖浓度增大,香兰素吸附量呈增大趋势;随pH值升高,吸附量增加;温度越高,吸附量越低;随时间的延长,吸附量逐渐减少;魔芋葡甘聚糖吸附香兰素的工艺条件为:合适的魔芋葡甘聚糖与香兰素配比,魔芋葡甘聚糖溶液pH=9.0-11.0,常温下吸附,吸附时间10min。 相似文献
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利用酿酒后废弃葡萄皮渣(WGP)作为吸附剂,对溶液中六价铬离子Cr(Ⅵ)进行吸附试验,研究了吸附时间、粒径、用量、溶液pH、Cr离子浓度对吸附率的影响。结果如下:WGP对Cr(Ⅵ)的吸附4 h就基本达到平衡,吸附率为87.97%;粒径小于60目的WGP表现出更强的吸附能力;吸附率与WGP用量正相关,用量1 g以上吸附率趋于稳定在88%左右;WGP对Cr(VI)的吸附率随着pH值增加而下降,直至pH为3时,吸附率趋于平衡;溶液中Cr浓度越高,葡萄皮渣对Cr(Ⅵ)的吸附率越高。研究表明:酿酒后葡萄皮渣具有较强吸附铬Cr(Ⅵ)的能力,可作为铬吸附剂,用于废水治理。 相似文献
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以废弃甘薯渣为原料,经化学修饰处理得到了改性甘薯废渣生物吸附剂,并将用于对水溶液中印染物质碱性品红的吸附。针对改性甘薯渣加入量、粒径、碱性品红溶液初始浓度、溶液pH、吸附温度、吸附时间各因素对吸附率的影响进行实验,对影响显著的碱性品红初始浓度、改性甘薯渣加入量、吸附时间采用二次正交旋转组合设计优化,得碱性品红初始浓度200mg/L、改性甘薯渣加入量0.8 g、吸附时间140 min时模拟预测最大吸附率97.66%,同条件下实测97.38%,二者吻合。吸附平衡试验表明甘薯渣吸附剂对碱性品红吸附符合Langmuir和Frundlich模型,其最大吸附量为37.17mg/g。吸附动力学可用准二级动力学方程描述。BET及SEM表征分析可知改性甘薯渣优化后表面疏松多孔,且褶皱增多,有利于吸附过程进行。经FT-IR与EDS得知,羟基(-OH)、羧基(-COOH)在吸附过程中起到主要作用。 相似文献
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采用硫酸(1+19)溶液对香芋皮粉末进行改性制备吸附剂,利用静态吸附法,研究吸附剂粒径、投加量、吸附温度、吸附时间和初始废水的p H、Cr(Ⅵ)初始质量浓度对Cr(Ⅵ)吸附效果的影响。结果表明,吸附剂吸附Cr(Ⅵ)的最佳工艺条件为:改性香芋皮粉末的粒径200目,投加量1.0 g、吸附温度30℃、吸附时间360 min,初始废水p H 3以及Cr(Ⅵ)初始质量浓度150 mg/L。在此工艺条件下,改性香芋皮粉末吸附剂对Cr(Ⅵ)具有良好的吸附性能,对Cr(Ⅵ)的吸附量可达到7.491 mg/g,Cr(Ⅵ)的吸附率可达99.88%。用HCl溶液(1+5)对吸附饱和的吸附剂可解吸再生。 相似文献
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为了提高苹果汁的色值,采用活性炭吸附.分别考察了活性炭目数,活性炭添加量,吸附温度对色值的影响.得出最佳的吸附目数和添加量组合是:80目,添加量为0.015g/mL.吸附温度对果汁色值的影响是温度越高,果汁色值越低. 相似文献
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采用二次回归正交旋转组合设计方法对莴笋叶渣吸附Cu2+条件进行优化,建立加入量(X1)、质量浓度(X2)、时间(X3)、pH值(X4)、温度(X5)5个因素与吸附率(Y)的回归模型为:Y=85.45862+11.80098X1-6.85546X2+0.24918X3+2.14203X4+1.12124X5-4.75315X12-2.40953X22-2.23141X32-1.49228X42-3.40533X52+3.84570X1X2+0.61717X1X3-3.15888X1X4-0.26948X1X5-0.29760X2X3+0.77899X2X4-0.01867X2X5-0.23965X3X4-1.45840X3X5+0.94533X4X5。各因素对莴笋叶渣吸附Cu2+影响顺序为:加入量>质量浓度>pH值>温度>时间,在加入量0.9g、Cu2+质量浓度30mg/L、时间5h、pH3、温度40℃条件下,莴笋叶渣对Cu2+吸附率最高可达98.40%。验证值为97.96%,与理论值基本一致。对于60mg/L Pb2+溶液,莴笋叶渣为吸附剂时的最佳固液比为12g/L;莴笋叶渣对中低质量浓度Pb2+溶液的吸附效果好于活性炭。 相似文献
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研究软锰矿脱硫尾渣(PDS)对刚果红的吸附性能。用软锰矿脱硫尾渣对刚果红模拟染料废水进行吸附实验,研究了PDS投加量、吸附时间、染料初始质量浓度和温度对吸附效果的影响。对于初始质量浓度为100 mg/L的刚果红溶液,尾渣的最佳投加量为2.4 g/L,去除率达98%;尾渣对刚果红的吸附在前5 min达到60%~70%,并在360 min后达到平衡;随着染料初始质量浓度的增大,单位吸附量上升,但去除率有所下降;温度升高有利于吸附。吸附过程符合伪二级动力学模型,红外光谱分析说明尾渣对刚果红存在化学吸附作用。 相似文献
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以饱和ATP吸附材料为硅源,用四丙基溴化铵(TPABr)为微孔模板剂和聚乙二醇1000(PEG-1000)为介孔模板剂合成多级孔ZSM-5分子筛.通过X射线衍射分析(XRD)、傅里叶红外分析(FT-IR)、扫描电子显微镜(SEM)和比表面积及孔径分析仪等表征合成产物的形貌、结构及孔道特征;再利用亚甲基蓝溶液测试其吸附性能.结果表明PEG-1000投加量对合成产物的晶型影响不明显,皆为多级孔ZSM-5分子筛,均具有较大的比表面积(约300m~2/g).随着PEG-1000投加量提高,分子筛晶体逐渐粗糙并呈近球状,介孔量和平均孔径均有所增加;当PEG-1000投加量为0.30g时,比表面积为274.230 2m~2/g,介孔所占比例47.92%,平均孔径2.68nm.在亚甲蓝溶液质量浓度为10mg/L,pH为11,吸附150min时,所合成ZSM-5分子筛对亚甲基蓝吸附率达98.2%. 相似文献
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通过静置吸附试验,研究了胡萝卜渣对铜离子吸附效果的影响因素及有关吸附机理。结果显示:吸附率随胡萝卜渣粒径的减小而增大,100目时胡萝卜渣对铜离子的吸附率可达76.35%;铜离子溶液初始浓度相同时,吸附率随胡萝卜渣加入量的增加而增大,而胡萝卜渣加入量相同时,对不同浓度的铜离子溶液吸附率均出现一次最小值;在铜离子的初始浓度为10mg/L和胡萝卜渣用量为0.5g时,对pH值、温度和浸泡时间3种因素,在6水平上进行了正交试验,最佳吸附条件为废水的pH值为2、温度为40℃、浸泡的时间为3h;20℃和40℃时铜离子的吸附等温线结果表明,胡萝卜渣对铜离子的吸附以单分子层吸附占优势,吸附等温线较好地符合Freundlich吸附等温式;铜离子的吸附动力曲线结果表明,胡萝卜渣对铜离子的吸附动力学行为比较符合二级动力学模型。 相似文献
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徐天宇崔君君孙浩伟苏有勇 《中国油脂》2020,45(1):76-81
以商用HZSM-5分子筛为母体,采用NaOH溶液对其进行预处理,在添加铝源和Y导向剂的作用下合成了HZSM-5/Y复合分子筛,并对其进行XRD、SEM和BET表征。考察了NaOH溶液浓度对复合分子筛结构和形貌的影响。进一步考察了该复合分子筛催化剂在油酸裂化反应中的催化特性,并与商用HZSM-5分子筛的催化特性作了比对。结果表明:当NaOH溶液浓度为1. 5mol/L时制备的HZSM-5/Y复合分子筛具有良好的分子筛结构,并且在催化裂化反应中表现出良好的性能。当使用该分子筛时,在反应温度475℃、质量空速6. 99 h-1条件下,液体产物产率达到了54. 2%,油酸脱氧率为38. 5%,液体产物酸价(KOH)为2. 6 mg/g;与使用商用HZSM-5分子筛相比,该复合分子筛对5~12个碳原子的链烃类的选择性更高,其裂化液体产物酸价更低,但重复使用效果较差。 相似文献
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Effect of spices, different concentration of sodium chloride and other salts on retention of ascorbic acid during storage period (21 days in case of spices and eight days for salts) was studied. The retention of ascorbic acid with the addition of 24% NaCl was 55%, followed by 37% with red chillies, fenugreek, turmeric; 32% with the addition of pepper, sugar and 26% with mustard and asafoetida. When all the spices and salt were added together, the retention was much higher (73%) than those with individual spices. Sodium chloride over a wide range of concentrations was found to have higher retention of ascorbic acid. The retention being 80%, when stored with 24.0% sodium chloride solution for eight days. Sulfates of sodium, potassium, magnesium and manganese or chlorides of magnesium or manganese did not have a significant effect on the retention of ascorbic acid. The retention with potassium chloride was close to that observed with sodium chloride. 相似文献
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Pyrene and phenanthrene sorption to model and natural geosorbents in single- and binary-solute systems 总被引:1,自引:0,他引:1
Zhang J Séquaris JM Narres HD Vereecken H Klumpp E 《Environmental science & technology》2010,44(21):8102-8107
Sorption of pyrene and phenanthrene to model (illite and charcoal) and natural (Yangtze sediment) geosorbents were investigated by batch techniques using fluorescence spectroscopy. A higher adsorption of phenanthrene was observed with all sorbents, which is related to the better accessibility of smaller molecules to micropores in the molecular sieve sorbents. In addition, pyrene sorption in binary-solute systems with a constant initial concentration of phenanthrene (0.1 μmol L(-1) or 2 μmol L(-1)) was studied. A 0.1 μmol L(-1) concentration of phenanthrene causes no competitive effect on the pyrene sorption. A 2 μmol L(-1) concentration of phenanthrene significantly suppresses the sorption of pyrene, especially in the low concentration range; nonlinearity of the pyrene sorption isotherms thus decreases. The competitive effect of 2 μmol L(-1) phenanthrene on the pyrene sorption is overestimated by the ideal adsorbed solution theory (IAST) using the fitted single sorption results of both solutes. An adjustment of the IAST application by taking into account the molecular sieve effect is proposed, which notably improves the IAST prediction for the competitive effect. 相似文献
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Potassium chloride, magnesium chloride, calcium chloride and magnesium sulfate were used to replace 50% of the ionic strength of the sodium chloride in a luncheon meat product. The magnesium chloride treatment had a higher cook yield while all four treatments resulted in lower (P ≥ 0.05) thiobarbituric acid (TBA) values than the control. Samples from the calcium chloride and magnesium chloride treatments were lighter (P ≥ 0.05) in color than the control, suggesting that these two adjuncts were detrimental to product color. Total lipid content of the magnesium chloride treatment, which had a correspondingly higher cook yield, was greater (P > 0.05) than the other treatments. Cholesterol content of the magnesium chloride, calcium chloride, and magnesium sulfate treatments was higher (P ≥ 0.05) than the control. These results suggest that potassium chloride is a viable replacement for up to 50% of the ionic strength of sodium chloride in luncheon meat without any deleterious effects on product quality. 相似文献
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ABSTRACT: Mushrooms were packaged in polypropylene, low-density polyethylene, linear low-density polyethylene (LLDPE) packages after washing with 0.5% calcium chloride and 0.5% citric acid (CA), and based on off-color and off-odor development, suitable packaging material and washing solution were selected. Effectiveness of magnesium oxide in modifying the in-package gaseous atmosphere and thereby extending the postharvest life was tested by monitoring the physicochemical properties. Oxygen concentration was 5.5% and 9.9% and carbon dioxide concentration was 8.1% and 4.5%, in the control and packages containing 3 g of magnesium oxide, respectively, on day 12 in storage. Packaging mushroom in 0.015 mm LLDPE packages with 3g of magnesium oxide after washing with 0.5% calcium chloride and 0.5% CA was successful in extending the postharvest life at 8°C and 70% RH from 6 d in commercial samples to 12 d. 相似文献