TL电刷镀Ni-Cu-P非晶态合金工艺研究

采用电刷镀技术,利用扫描电镜、能谱分析仪、X光衍射仪等测试手段,对三元Ni-Cr-P合金刷镀溶液的配方组成、施镀工艺、镀层组织结构及成份进行了分析研究,确定了三元Ni-Cu-P镀液的组成及刷镀工艺。研究结果表明：该镀层具有良好的综合性能,并可镀厚,且镀层表观 光泽平整。     

化学镀Ni-Cr-P合金镀层在NaCl溶液中的耐蚀性

用电化学方法研究了化学镀Ni-Cr-P合金镀层在3.5%NaCl 溶液中的耐蚀性.结果表明Ni-Cr-P镀层与Ni-P镀层的阳极极化曲线形状相似,自腐蚀电位正移150 mV以上,自腐蚀电流降低近3倍,在钝化区的阳极电流降低约1个数量级,镀层的耐蚀性提高.     

化学镀Ni-P合金在铝合金剑杆头上的应用

采用化学镀工艺方法在铝合金剑杆头表面镀一层Ni-P合金，代替进口的剑杆头。对铝合金剑杆头的预处理工艺、镀液的配方、施镀工艺以及镀后热处理工艺进行了研究，确定了简便易行的施镀工艺及镀后热处理工艺。所确定的镀液配方，性能稳定，可获得40μm以上厚度的镀层，且镀层与基体的结合力较好，其硬度可达1100HV以上，其 综合性能与进口件相当。     

次亚磷酸盐在化学镀液中的应用研究

简要地介绍次亚磷酸盐化学镀液的应用历史,探讨次亚磷酸盐的还原机制,提出了次亚磷酸盐在化学镀镍、化学镀铜、化学镀钴、化学镀锡、化学镀铅锡、化学镀金、化学镀铁、化学镀砷、化学镀铬的应用方法。在此基础上,还归纳了18种配方。文章提供的配方及其工艺参数。具有一定的参考价值。     

TL—5化学镀Ni—P合金在Nd—Fe—B永磁体上的工艺研究

粘结型Nd-Fe-B永磁体具有组织疏松，孔隙率高，强度低，耐热性差等特点，试验了孔隙封闭，除毛刺去边角滚光及活化除去基体氧化膜等前处理技术。研究化学镀Ni-P工艺选择一次性化学镀Ni-P合金工艺，成功地解决了Nd-Fe-B永磁体的耐蚀问题，既简化了工艺流程，缩短了施镀时间，又降低了成本，亦适合烧结型Nd-Fe-B永磁体。     

Ni-Cr-P化学镀层的制备与电化学腐蚀行为

通过化学镀技术制备Ni-Cr-P三元合金镀层。利用称重法,SEM,EDS,XRD和电化学测试等方法,研究镀液中CrCl_3,C_3H_6O_3,C_2H_5NO_2和K_2C_2O_4浓度对Ni-Cr-P镀层的沉积速率、Cr含量及其在模拟燃料电池环境中电化学腐蚀行为的影响。结果表明,CrCl_3浓度增加,沉积速率提高;随着C_3H_6O_3,C_2H_5NO_2和K_2C_2O_4浓度的增加,沉积速率不断降低。Ni-Cr-P镀层的表面形貌呈胞状结构,镀层为非晶和微晶混合结构。Ni-Cr-P镀层的自腐蚀电位远高于Ni-P二元合金镀层的,向正移动约0.25 V;其电荷转移电阻增大,腐蚀电流密度降低了约两个数量级,Ni-Cr-P三元合金镀层的耐蚀性明显优于Ni-P二元合金镀层的。     

热处理对Ni—Cu—P化学镀层性能的影响

研究了热处理工艺对Ｎｉ－Ｃｕ－Ｐ化学镀层性能的影响,试验结果表明,Ｎｉ－Ｃｕ－Ｐ化学镀层具有较好的热稳定性,在３００℃以下加热时,其硬度变化并不明显。     

镀铜石墨粉的制备研究

表面镀铜的非金属材料是当前功能材料开发的一个热点.利用化学镀的方法在石墨粉的表面进行化学镀铜,通过对化学镀铜沉积速度和镀层表面形貌进行分析,探讨了如何获得表面包覆良好的镀层.石墨粉表面化学镀铜工艺可以分为表面预处理、化学镀和性能测试三大步骤.研究重点放在化学镀施镀步骤上,对化学镀铜的影响因素进行了研究,得出最佳的镀铜工艺配方,并将此配方应用于实际,得到了色泽光亮、分散性好的石墨镀铜粉.     

热处理对化学镀镀层性能影响的研究进展

热处理可以使镀层稳定,改善力学性能。分别叙述了随温度的升高和保温时间的延长,热处理对化学镀Ni-P二元合金、Ni-W-P、Ni-Cr-P等三元合金、Ni-W-Mo-P四元合金镀层性能的影响,分析了热处理对合金镀层耐蚀性、耐磨性的影响,并提出了热处理改善化学镀镀层性能的研究方向。     

碱性化学镀Ni-P/CeO2复合镀层及其耐蚀性研究

对碱性化学镀Ni-P/CeO2复合镀层的工艺参数进行了研究,并与化学镀Ni-P镀层的耐水溶液腐蚀和耐高温腐蚀性能进行了比较研究。通过对镀层表面形貌、结合力以及CeO2复合量的测量,确定出最佳镀液配方和施镀参数。实验结果表明,Ni-P/CeO2复合镀层具有良好的耐蚀性能。其原因主要是由于弥散分布的稀土CeO2颗粒改善了镀层的微观结构,并在腐蚀过程中表现出稀土元素所起的效应。     

The structure and properties of electroless Ni–Mo–Cr–P coatings on copper alloy

In the present study, the quaternary Ni–Mo–Cr–P alloy coatings were deposited on copper alloy by an electroless deposition process. Crystallization behavior and the effect of heat‐treatment on hardness and corrosion resistance of Ni–Mo–Cr–P deposits were detailedly investigated. X‐ray diffraction (XRD) analysis shows that as‐deposited Ni–Mo–Cr–P coatings are Ni–Mo–Cr–P solid solution and mixed crystal structure; the trend of microcrystallinity increases with the introduction of additional types of metal element; Ni–Mo–Cr–P alloy coatings start to occur in the crystallization with the heat‐treatment temperature increasing. With an increase in the annealing temperature, the hardness improves and reaches the maximum value at 500 °C. Further, it is found that Ni–Mo–Cr–P coatings have superior corrosion resistance than Ni–P and Ni–Mo–P deposits after the analysis of electrochemical measurements. Moreover, corrosion resistance increases before annealed at 400 °C, but heat‐treatment at higher temperatures has a negative effect on the corrosion resistance of Ni–Mo–Cr–P alloy coatings.     

化学镀Ni—Cr—P合金镀层在NaCli溶液中的耐蚀性

用电化学方法研究了化学镀Ｎｉ－Ｃｒ－Ｐ合金镀层在３．５％ＮａＣｌ溶液中的耐蚀性,结果表明Ｎｉ－Ｃｒ－Ｐ镀层与Ｎｉ－Ｐ镀层的阳极极化曲线形状相似,自腐蚀电位正移１５０ｍＶ以上,自腐蚀电流降低近３倍,在钝化区的阳极是约１个数量级,镀层的耐蚀性提高。     

热处理对不锈钢表面化学镀Ni-Cr-P合金镀层结构及性能的影响

采用化学镀工艺在不锈钢表面获得了Ni-Cr-P合金镀层。研究了Ni-Cr-P非晶态合金膜随热处理温度升高,其结构以及显微硬度和耐蚀性的变化规律,并对变化的原因进行了分析。结果表明,镀态Ni-Cr-P为非晶态镀层,200℃热处理开始晶化,到400℃时Ni3P晶化比较完全,800℃时Ni3P完全分解,生成含Ni、Cr、Fe的合金膜的Cr2Ni3和FeNi2P相。其显微硬度随热处理温度升高而升高,500～600℃之间显微硬度略有下降,600～700℃又随着热处理温度的升高而略有升高,700℃后显微硬度略有下降;合金膜的耐腐性在热处理温度200～400℃间变化较小,500℃热处理后其耐腐蚀性下降厉害,600～700℃随着热处理温度的升高其耐腐蚀性又略有升高,800℃后由于Ni3P的分解其耐腐蚀性又急剧下降。     

Fe70Cr10P13C7合金激光非晶化研究

Fe70Cr10P13C7是一种可形成非晶态的合金,它除具有比一般结构钢高得多的断裂强度外,还具有特别突出的耐腐蚀性能。用2～5kw连续波CO2激光在40Cr钢基体上首先获得晶态的Fe70Cr10P13C7宽带熔覆层,而后获得多道搭接的厚约0.2mm的非晶层。该非晶层动电位极化曲线表明,非晶态Fe70Cr10P13C7的耐腐蚀性高于1Cr18Ni9Ti不锈钢和加Cr的Ni-Nb非晶合金。     

SURFACE OXIDATION OF THE AMORPHOUS ALLOY Ni_(68)P_(18)Cr_(14)

The surface layer of Ni_(68)P_(18)Cr_(14) amorphous alloy was studied by AES and XPS associated with ion beam sputtering. It was found that great differences existed between the surface layer and the bulk both in composition and chemical states. The dominant component elements Ni and P were of lower content in the surface laver, while Cr was enriched. Cr was drastically oxidized in the surface layer, but Ni underwent no oxidation. There was a P enriched region just helow the surface oxide layer, which was supposed to enhance the surface segregation of Cr. Ni underwent no oxidation in Ni_(68)P_(18)Cr_(14) amorphous alloy.     

典型Fe-Cr-Al及Ni-Cr-(Fe)系电热合金丝的显微组织与织构

选取了两类典型电热合金丝材成品进行了检测,对比分析了合金丝的显微组织及织构,包括Fe-Cr-Al系的国产0Cr25Al5合金与进口0Cr22Al5合金和Ni-Cr-(Fe)系的国产Cr20Ni80合金与Cr20Ni30合金。结果表明:进口Fe-Cr-Al合金的平均晶粒尺寸相对较大,晶粒尺寸分布较为均匀,而织构较弱;国产0Cr25Al5合金的平均晶粒尺寸均匀程度较差,而较粗的样品平均晶粒尺寸较大且织构稍弱,接近于进口Fe-Cr-Al合金,表明较粗的丝材制备形变量较小。Ni-Cr-(Fe)系的合金均表现为不均匀的晶粒组织,而Cr20Ni80合金相较于Cr20Ni30合金的大尺寸晶粒更多;减小合金丝材的直径有细化组织作用,同时还能增强两种Ni-Cr合金丝中均存在的<111>丝织构。     

HIP diffusion bonding of P/M titanium alloy Ti-6Al-4V and stainless steel 1Cr18Ni9Ti

The HIP diffusion bonding of P/M titanium alloy Ti-6A1-4V and stainless steel 1Cr18Ni9Ti using pure Ni as intermediate layer was studied. Bonding joint with complex bonding interface was obtained by HIPing pre-alloyed Ti-6Al-4V powders and stainless steel 1Crl 8Ni9Ti in a vacuum canning. The joint strengths were examined and the characteristics of bonding joint were observed. The result shows that the maximized strength of HIP diffusion bonding between P/M titanium alloy Ti-6Al-4V and stainless steel 1Cr18Ni9Ti can be up to 388 MPa and the microstructure of bonding joint is acceptable.     

Ni—Cr—Mo—Nb合金的阴极溅射行为

研究了双层辉光放电条件下镍基合金Inconel625的阴极溅射行为,结果表明：多组元镍基合金由于各组元溅射率不同,产生择优溅射现象。Mo,Nb等低溅射率元素在阴极表面富集,Ni,Cr等高溅射率元素在阴极表面贫化,使阴极表面发生相变,形成含Mo,Nb奋斗高的金属间化合物析出相P相和Laves相,随着阴极溅射电压的增加,阴极合金元素溅射率增加;并且随着阴极温度升高,阴极溅射率也随之增加。     

高温自蔓延过程中的挤压工艺对合成Ni_3Al-B-Cr合金的组织及力学性能的影响(英文)

采用高温自蔓延及挤压工艺制备Ni3Al-0.5B-5Cr合金,研究挤压工艺对合成合金的微观组织及力学性能的影响。结果表明:合成后的挤压工艺可使合成合金进一步致密并能有效地细化其组织。X射线衍射及透射电镜观察发现除了Ni3Al基体外,合金中还含有Al2O3、Ni3B及Cr3Ni2析出相。与无挤压合成的合金有所不同,合金在高温自蔓延合成及挤压过程中经历了大变形和再结晶过程,其促进了组织的细化并降低了晶粒的取向差。此外,合成后的挤压工艺促使Al2O3颗粒重新分布且减少了γ-Ni相。与无挤压合成的合金相比,高温自蔓延合成及挤压工艺制备的合金具有更好的室温力学性能。     

Influence of Al Addition on Oxidation Behavior of Cu–Ni–Cr Alloys at 973–1073 K in 1.01 × 10<Superscript>2</Superscript> kPa Pure Oxygen

The oxidation behavior of Cu–20Ni–15Cr–2.5Al and Cu–20Ni–20Cr–2.5Al alloys was studied at 973–1073 K in 1.01 × 10² kPa pure oxygen. The oxidation kinetics exhibited large deviations from the parabolic rate law and were comprised of three or four quasi-parabolic stages. Oxidation rates of the present alloys were much lower than those previously reported for a Cu–20Ni–20Cr alloy. Cu–20Ni–15Cr–2.5Al alloy formed a continuous scale of chromia in contact with the alloy, while at other locations, the scale formed deep protrusions into alloy along β phases. Cu–20Ni–20Cr–2.5Al alloy formed a continuous scale of chromia with a small quantity of light and unoxidized precipitates of α phase, especially at 1073 K. There was a thin layer depleted in Cr beneath the continuous scales of chromia. The addition of 2.5 at.% Al to Cu–Ni–Cr alloy made the diffusion of reactive component Cr become much faster and facilitated the formation of a continuous external scale of chromia for a lower Cr content.