共查询到20条相似文献,搜索用时 78 毫秒
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介绍了液相催化加氢反应器最重要的2点设计:搅拌器和换热。分析了各种搅拌器的特点、性能,并进行了互相对比,特别是对自吸式搅拌器结构特点、工作原理、性能做了详细介绍,认为自吸式搅拌器是所有搅拌器中气液传质效果最好的搅拌器,它的应用提高了加氢反应速率和氢气的利用率;对加氢反应器的换热盘管或夹套与传热板进行了比较,传热板的应用提高了传热效果,认为自吸式搅拌和高效率的传热板应用于液相催化加氢反应中是一种最新型的液相催化加氢反应器。 相似文献
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木质素是一种重要的生物质可再生资源,其降解后得到的酚类物质加氢后可得大量高附加值化学品,在环境治理和原料利用方面都有着十分重要的影响。本文综述了近年来国内外木质素酚类加氢反应催化剂的研究进展,总结了液相酚类催化加氢催化剂的种类、反应机理及结构敏感性因素对酚类催化加氢反应活性的影响,阐述了催化剂颗粒尺寸对液相酚类加氢反应活性影响,并以木质素液相酚类加氢反应催化剂的活性金属和载体为体系,对现有的结构敏感性反应中催化剂存在的形貌效应、晶相效应进行了讨论。提出未来可通过控制催化剂形貌和晶相来研究催化剂形态与催化活性之间的构效关系,为今后设计高活性木质素液相酚类加氢催化剂提供借鉴和参考。 相似文献
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硝基苯液相催化加氢制苯胺催化剂研究进展 总被引:2,自引:1,他引:1
介绍了苯胺生产中硝基苯液相催化加氢制苯胺工艺,着重介绍了液相加氢催化剂体系中的镍系催化剂和贵金属催化剂的研究进展。液相催化加氢多采用贵金属催化剂和高活性、制备工艺复杂的催化剂,生产成本较高,开发价廉、高效并能满足绿色化工要求的新型催化剂是今后工作的重点。 相似文献
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芳香族硝基化合物还原制芳胺生产工艺评析 总被引:1,自引:0,他引:1
本文简要叙述了芳胺用途、常用合成工艺,重点对各生产工艺进行了技术、经济评析,并对芳香族硝基化合物还原方法的选择提出了自己的看法。 相似文献
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综述了有关N—甲基邻硝基苯胺的现有合成方法,提出了以邻硝基苯胺为原料,酰化,甲基化,再水解,合成N—甲基邻硝基苯胺的工艺路线。该合成工艺条件温和,路线短,原料的转化率高,产品的纯度高(≥98%以上),易于工业化生产。 相似文献
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Electron beam irradiation effects of ten kinds of polymers containing various aromatic rings linked by functional groups in the main chain (aromatic polymer) were studied with reference to change in tensile properties. The polymers studied were polyimides ‘Kapton H’, and ‘UPILEX’, polyetherimide ‘ULTEM’, polyamides ‘A-Film’, and ‘APH-50 (nomex type paper)’, poly-ether-ether-ketone ‘PEEK’, polyarylate ‘U-Polymer’, polysulphones ‘Udel-Polysulphone’, and ‘PES’, and modified poly(phenylene oxide) ‘NORYL’. Irradiation was carried out by use of electron beam at a dose rate of 5 × 103 Gy s?1 at room temperature. The elongation at break was the most severely influenced by the irradiation and it decreased with increasing dose. The order of radiation resistivity which was evaluated from the dose required for the elongation to become 50% and 20% of the initial value was as follows:Polyimide>PEEK>polyamide>polyetherimide>polyarylate>polysulphone, poly(phenylene oxide)Based on the above experimental results, the following order was proposed as for the radiation stability of the aromatic repeating units composing the main chain: 相似文献
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Kirsi-Maarit Lehto Helge Lemmetyinen Jaakko Puhakka 《Polycyclic Aromatic Compounds》2013,33(1-4):297-309
Polycyclic aromatic hydrocarbons (PAHs), naphthalene, phenanthrene, anthracene, and pyrene were irradiated in acetonitrile (CH3CN) and in dichloromethane (CH2Cl2) on individual PAH compounds and in the presence of other compounds. The observed photodegradation of PAHs was dependent on the structure of the compound. Anthracene and pyrene were the most photoreactive in dichloromethane: with total degradation after 0.5 h irradiation for anthracene and 1.5 h for pyrene. The decomposition of PAHs was faster in dichloromethane than in acetonitrile. 相似文献
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开发了一种能有效吸附稠环芳烃的新型吸附剂 ,成功地应用在金陵石化公司化工一厂万吨级中压 ( 6 0MPa)加氢装置上 ,使凡士林产品质量符合英国药典BP 93版标准。通过新型吸附剂与活性白土比较实验后认为 :新型吸附剂吸附稠环芳烃性能及在工业装置上使用性能均好于活性白土。凡士林经新型吸附剂精制后紫外谱图峰值≤ 0 6,而经活性白土精制后紫外谱图峰值 >1 6。 相似文献
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Debora Fabbri Alessandra Bianco Prevot Edmondo Pramauro 《Journal of Applied Electrochemistry》2005,35(7-8):815-820
Photocatalytic treatment in the presence of aqueous TiO2 suspensions was applied to an aqueous percolate containing various hydrophilic aromatic pollutants, in particular naphthalene
sulfonates. A preliminary feasibility study was accomplished on standards of pure compounds, for which a degradation rate
trend inversely proportional to the sulfonation degree was found, demonstrating the important role played by the substrate
adsorption on semiconductor particles. The evolution of primary processes, the abatement of TOC and the release of sulfate
were monitored. Further experiments performed on samples of percolates taken from an abandoned industrial site demonstrated
the suitability of photocatalysis for the effective destruction and mineralization of the investigated contaminants in these
complex matrices after a few hours irradiation. 相似文献
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在优化卷烟烟气试样前处理技术的基础上,确定了6种多环芳烃分离的最佳条件和测定的最佳荧光激发、发射波长,并进行波长程序编程,采用高效液相色谱编程荧光法(HPLC-FLD)建立了一种同时测定卷烟烟气中6种多环芳烃的分析方法。各多环芳烃在所测定的含量范围内有良好的线性关系,方法的最低检出限可达到0.4 ng/mL,回收率均在87%以上。并利用该方法对国产卷烟样品进行了分析。 相似文献
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吕宋芒果中香味成分分析 总被引:1,自引:0,他引:1
用GC—MS方法分析测定了吕宋芒果提取液的香味成分,共测得51个组成成分,其主要成分为萜烯类(45.22%)、高级脂肪酸(14.94%)、醛酮类(1.11%)和少量醇、酯、内酯、烷烃类等。萜烯类中,异松油烯的含量最高,达31.84%。 相似文献
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催化CO/H2O还原芳香硝基化合物制芳胺的研究进展 总被引:3,自引:1,他引:3
CO/H2O还原芳香硝基化合物制芳胺是1978年首次被发现。所使用的催化剂为过滤金属羰基化合物有些可以在常温常压下完成反应,并具有很好的选择性,在反应完成后可将催化剂从反应产物中分离这项技术可以做为加氢还原重要补充。反应过程的常压化、催化剂的分离将成为这项技术研究重点。这项新技术将有广阔的工业前景、有24篇参考文献。 相似文献