共查询到20条相似文献,搜索用时 156 毫秒
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通过氢化物发生-原子荧光光谱法(HG-AFS)对地质样品中的硒进行测定,对测定结果的不确定度来源进行分析,评定不确定度的分量。结果表明,该方法测量不确定度引入的最主要来源有两项:硒标准溶液配制过程和重复性测量样品。因此在实际分析过程中,应提高分析人员检测技能和规范操作,保证测定结果的准确性和可靠性。当测试样品中硒的含量为0.1631μg/g时,其扩展不确定度(k=2)为0.0081μg/g。 相似文献
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参照我国计量技术规范JJF1059—1999《测量不确定度的评定与表示》及有关方法,对玩具重金属分析不确定度进行了评定,获得玩具中可溶性汞、锑、砷、硒、铅、铬、镉、钡八种有害元素分析相对扩展不确定度在4.5%~23.5%之间。证明该方法能满足实验认证认可对测量不确定度的要求。 相似文献
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范华 《现代测量与实验室管理》2014,(6):30-32
本文以测量误差与测量不确定度的定义解析,了解两者的区别,在概念上加深对测量不确定度的理解;通过介绍测量不确定度A类和B类评定方法的异同点,使检测人员初步认知测量不确定度的评定方法,为今后开展测量不确定度的评定工作打下基础。 相似文献
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采样计数法测量信号频率的不确定度 总被引:1,自引:0,他引:1
介绍了用数字化采样计数法评价周期信号频率时,测量结果的不确定度分析和评定过程,讨论了影响测量不确定度的几个主要误差来源;给出了减小测量不确定度的主要措施;在一组实际评价例子上,给出了其不确定度分析和评定结果,该过程及结论可应用信号频率的测量不确定度评定。 相似文献
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本文以测量误差与测量不确定度的定义解析,了解两者的区别,在概念上加深对测量不确定度的理解;通过介绍测量不确定度A类和B类评定方法的异同点,使检测人员初步认知测量不确定度的评定方法,为今后开展测量不确定度的评定工作打下基础。 相似文献
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采用石墨炉原子吸收法,使用热解涂层石墨管,加上硝酸镁作基体改进剂,直接测定水中的铍。 相似文献
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研究了超高纯试剂异丙醇中痕量钙的石墨炉原子吸收光谱测定法。制定了石墨炉原子吸收光谱法测定痕量钙的分析程序,试样经挥发浓缩,采用标准曲线法测定;还确定了仪器最佳工作条件,原子化条件等,研究了共存离子的干扰,回收试验及实测样品等。同时将石墨管用氯氧化锆进行适当的处理,并控制合适的仪器操作条件及升温程序,即可提高石墨炉原子吸收法测钙的灵敏度,获得了较满意的结果。 相似文献
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Haji Shabani AM Dadfarnia S Motavaselian F Ahmadi SH 《Journal of hazardous materials》2009,162(1):373-377
A simple and selective method for the determination of cadmium in water samples by FAAS after solid phase extraction has been developed. The method is based on the sorption of cadmium as CdI(4)(2-) on octadecyl silica membrane disks modified by cationic surfactant of methyltrioctylammonium chloride in the pH range of 1-8. The sorbed cadmium is then eluted with 10ml of 1moll(-1) nitric acid in ethanol and is measured by flame atomic absorption spectrometry. The influence of flow rates of eluent and sample solution, iodide concentration and amount of surfactant in retention and elution of cadmium from disks was also investigated. A preconcentration factor of 100 was achieved by passing 1000ml of sample through the membrane disk. The limit of detection (LOD) of cadmium was found to be 0.014ngml(-1). Precision at 2.5mugl(-1) was 1.2% (n=8). The method was successfully applied to the determination of cadmium in some natural water samples. The accuracy was assessed through recovery experiment, independent analysis by graphite furnace atomic absorption spectrometry, and analysis of certified reference waters. 相似文献
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石墨炉原子吸收光谱法测定水样消解研究 总被引:1,自引:0,他引:1
本文采用硝酸-过氧化氢的消解体系,对石墨炉原子吸收法测定水样中痕量重金属含量过程中样品消解环节进行研究,认为通过严格控制使用的试剂和消解过程,能够提高样品分析的准确度和精密度,同时样品加标回收率结果也比较满意。 相似文献
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Evaluation of various digestion procedures for trace element contents of some food materials 总被引:2,自引:0,他引:2
The levels of trace elements in different types of food material consumed in Turkey were determined by flame and graphite furnace atomic absorption spectrometry. Food samples were digested with dry ashing, wet ashing and microwave digestion procedures in this study. The microwave digestion procedure was chosen for the digestion of all the food samples because it required shorter time and made higher recovery (specially for Se). Fe, Cu, Mn, Zn, Al and Se were determined by flame and graphite furnace atomic absorption spectrometry, respectively. Relative standard deviations (RSD) were found below 10%. The accuracy of the procedure was confirmed by certified reference materials. Moreover, this procedure was easier to use when compared with dry and wet digestions. 相似文献
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A solid phase extraction and graphite furnace atomic absorption spectrometry (GFAAS) for the determination of nickel, silver, cobalt, copper, cadmium and lead with MCI GEL CHP 20Y as sorbent was studied. Trace amounts of chromium, nickel, silver, cobalt, copper, cadmium and lead were reacted with 2-(2-quinolinil-azo)-4-methyl-1,3-dihydroxidobenzene (QAMDHB) followed by adsorption onto MCI GEL CHP 20Y solid phase extraction column, and 1.0molL(-1) HNO(3) was used as eluent. The metal ions in 300mL solution can be concentrated to 1.0mL, representing an enrichment factor of 300 was achieved. The recoveries of analytes at pH 8.0 with 1.0g of resin were greater than 95% without interference from alkaline, earth alkaline and some metal ions. When detected with graphite furnace atomic absorption spectrometry, the detection limits in the original samples were 1.4ngL(-1) for Cr(III), 1.0ngL(-1) for Ni(II), 0.85ngL(-1) for Ag(I), 1.2ngL(-1) for Co(II), 1.0ngL(-1) for Cu(II), 1.2ngL(-1) for Cd(II) and 1.3ngL(-1) for Pb(II). The validation of the procedure was performed by the analysis of the certified standard reference materials, and the presented procedure was applied to the determination of analytes in biological, water and soil samples with good results (recoveries range from 89 to 104%, and R.S.D.% lower than 3.2%. The results agreed with the standard value or reference method). 相似文献
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采用石墨炉原子吸收法,使用热解涂层石墨管,加上硝酸镁作基体改进剂,直接测定水中的痕量铍、镍、钡。测定钡时采用原子化阶段不停气,通以10mL/min的流量;测定完成后,再使用“清除温度”空烧1~2次处理,可消除记忆效应的影响。 相似文献