共查询到19条相似文献,搜索用时 187 毫秒
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研究了橡胶共混比、硫化体系、高耐磨炭黑用量及共混工艺等对EPDM/CR共混物性能的影响,考察了共混物的力学性能、耐高温硝酸性能、热空气老化性能、耐辐射性能和相容性。试验结果表明,采用炭黑全部加入EPDM中然后与CR混合的共混工艺,所得硫化胶的力学性能超过两种橡胶硫化胶力学性能的加和值;共混胶中EPDM采用硫黄硫化才能得到比较好的力学性能。硫化动力学研究表明CR的硫化速度较EPDM的硫化速度对温度的依赖性小。DSC和DVA分析结果表明共混胶具有两个明显的玻璃化转变温度,为热力学不相容体系。研制的EPDM/CR共混物具有耐老化、耐高温硝酸、耐辐射、粘合好等优良性能。 相似文献
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用动态硫化法制备了丁腈(NBR)/酚醛树脂(PF)共混型热塑性弹性体。研究了NBR中丙烯腈含量、PF品种、橡塑并用比和硫化体系对共混物性能的影响。研究结果表明:随NBR中丙烯腈含量的增加,共混物的强度有所提高;随PF用量的增加,共混物的拉伸强度显著提高,耐油性能和老化性能均得到明显提高:硫磺硫化体系可使NBR/PF并用体系硫化胶有较好的物理机械性能。 相似文献
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稀土BR/SBR共混胶的性能 总被引:1,自引:0,他引:1
研究了4种共混比的LnBR/SBR共混生胶、混炼胶及硫化胶的性能,并与NiBR/SBR共混胶进行了对比。结果表明,共混生胶的ML均低于LnBR及SBR;当LnBR/SBR共混混炼胶的ML、剪切应力、出口膨胀及硫化速度均低于NiBR/SBR共混胶,挤出物外观优于后者;共混硫化胶的拉伸强度、热空气老化、拉伸疲劳、湿滑、耐磨等性能均明显优于后者,生热和透气率高于后者。 相似文献
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用动态硫化法制备了丁腈(NBR)/酚醛树脂(PF)共混型热塑性弹性。研究了NBR中丙烯腈含量、PF品种、橡塑并比和硫化体系对共混通用性能的影响。研究结果表明:随NBR中烯腈含量的增加,共混物的强度有所提高:随PF用量的增加,共混物的拉伸强度显著提高,耐油性能和老化性能均得到明显的提高硫磺硫人体系可使NBR/PF并用 化胶有较好的机理机械性能。 相似文献
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Yin Changjie Quiyu Zhang Gu Junwei Zhang Junping Shi Youqiang Wang Yuhang 《Journal of Polymer Research》2011,18(6):2487-2494
Composites of styrene butadiene rubber (SBR), hydrogenated acrylonitrile–butadiene rubber (HNBR) and silica were prepared.
Sulfur (S), dicumyl peroxide (DCP) and a combination of S and DCP (M) were used as curing agents, respectively. The morphology
of the composites with different blend ratio was examined to correlate with observations on mechanical properties by scanning
electron microscopy. The effects of blend ratio and curing systems on the curing characteristics and mechanical properties,
such as stress–strain behavior, tensile strength, elongation at break and hardness of SBR/HNBR/Silica composites, were studied.
Composites prepared by M curing systems showed comparatively better mechanical properties, wet traction and rolling resistance
than S and D curing systems. The tensile strength, tear strength, and elongation at break were improved by adding HNBR for
M curing systems. The wet traction of the vulcanizates containing HNBR was better than that of the vulcanizates without HNBR.
A relatively uniform dispersion of silica was observed for SBR/HNBR/silica compositions compared with SBR/silica composites. 相似文献
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The covulcanization characteristics, mechanical properties, compatibility, and hot‐air aging resistance of hydrogenated nitrile‐butadiene rubber (HNBR)/ethylene‐propylene‐diene rubber (EPDM) blends cured with either sulfur or dicumyl peroxide (DCP) were studied. The difference between MH and ML (MH ? ML), rheometer graphs, selective swelling and a dynamic mechanical analysis of HNBR/EPDM blends confirmed that the peroxide curing system gives better covulcanization characteristics than the sulfur curing system and peroxide exhibited higher crosslink efficiency on EPDM while sulfur showed larger crosslink efficiency on HNBR. Dynamic mechanical analysis and morphology indicated that the compatibility between HNBR and EPDM is limited. Tensile strength and elongation at break of the sulfur‐cured blends are greater than those obtained with peroxide and increase with the HNBR fraction. The blends crosslinked with peroxide retain their tensile strength but not their elongation at break after hot air ageing better than blends vulcanized by sulfur. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
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采用添加短纤维的不饱和聚酯(DMC)填充EPDM/基乙烯基硅橡胶(MVQ)并用胶。研究其物理性能和耐热老化性能。结果表明,添加DMC后。EPDM/MVQ并用胶的邵尔A型硬度和拉伸强度大幅提高,耐热老化性能较好,兼具EPDM,MVQ和DMC的优点。EPDM/MVQ并用胶的较优配方为:EPDM25,MVQ75,DMC80,白炭黑40,氧化锌5,防老剂D1,硫化剂DCP6,促进剂DM0.8。 相似文献
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The structure development, rheological behavior, viscoelastic, and mechanical properties of dynamically cured blend based on the ethylene–propylene–diene terpolymer (EPDM) and polypropylene (PP) with a ratio of 60/40 by weight were studied. The variation of two‐phase morphology was observed and compared as the level of curing agent was increased. Meanwhile, as the level of curing agent increased, viscosity as a function of shear stress always increased at a shear stress range of 2.2 × 104 to 3.4 × 105 Pa at the temperature of 200°C, yet viscosity of the blend approached each other at high shear stress. Dynamic mechanical spectra at different temperatures show that dynamic modulus (E′) of the blend exhibits two drastic transitions corresponding to glass transition temperature (Tg) of EPDM and Tg of PP, respectively. In the blends Tgs of EPDM increase and Tgs of PP almost remain unchangeable with an increase in curing agent level. Tensile strength increased, yet elongation at break decreased as the level of curing agent is increased. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 357–362, 2004 相似文献