Ti-1100高温钛合金铸造过程中与CaO坩埚的界面反应

研究了Ti-1100高温钛合金和CaO坩埚在可控气氛下感应熔炼时的相互作用,并对合金组织、化学成分、显观硬度以及与坩埚的界面反应进行分析。结果表明：合金的铸态组织是典型的魏氏组织。熔融金属和CaO坩埚的界面反应是由坩埚轻微的化学溶解和微弱的物理侵蚀引起的。根据线扫描分析,合金在坩埚底部和侧部界面反应区的α层厚度分别为18和17μm,这比采用硬度测试所获得的实验数据要小。α反应层的形成机制是间隙氧原子。还对Ti-1100合金CaO（s）=Ca＋O反应的标准吉布斯自由能进行了测定,得到Ca和O的平衡常数和相互作用参数分别为lg K=-3.14和eCa O=-3.54。     

Ti-17钛合金扩散连接界面特征及接头剪切强度(英文)

研究不同连接时间下Ti-17钛合金扩散连接界面特征及接头剪切强度。结果表明,随着连接时间的延长,连接界面平均空洞尺寸逐渐减小,空洞数量增加至最大值后逐渐减少。具有锯齿状边缘的不规则空洞逐渐转变为具有平滑表面的椭圆形空洞以及细小的圆形空洞。当连接时间为60 min时连接界面上形成了跨连接界面的晶粒。接头剪切强度随着连接时间的延长而增大,当连接时间为60 min时,接头剪切强度达到最大值,为887.4 MPa。尽管塑性变形的作用时间很短,但是对促进空洞闭合以及提高接头剪切强度的作用显著。     

Ti-6Al-4V钛合金与氮化硼基复合型壳精铸时的界面反应

主要研究了一种新型钛合金精铸用型壳--氮化硼基复合型壳与铸造钛合金Ti-6Al-4V之间的界面反应.研究中,氮化硼基复合型壳的面层是由经过预处理的六方氮化硼,少量氧化钇和钇熔胶粘结剂构成.试验中使用了水冷铜坩埚来熔炼Ti-6Al-4V合金,合金的浇注温度为1 750℃;通过使用电子探针(EPMA)等仪器对铸件表面进行检测,以便研究型壳与钛合金TC4之间的反应.研究发现,这种型壳与1 750℃铸造钛合金Ti-6Al-4V的反应层大约为30～50 μm,铸件表面"沾污层"大约为180～200μm.最后还对氮化硼基复合型壳与钛合金Ti-6Al-4V反应的机理进行了研究.     

基于ABAQUS的近α型Ti-1100合金热变形有限元分析

以氢化钛粉为原料,采用粉末冶金–热等静压法制备近α型Ti-1100合金,并基于ABAQUS对φ12 mm×8 mm试样的热压缩试验进行有限元分析。结果表明：Ti-1100合金试样中心区域受到较大压应力的作用,变形最大;鼓形区域受拉应力作用,和顶部区域的变形程度均相对较小。在低温高应变速率下,试样中心区域的温升最大,出现动态软化特征,不均匀变形程度较大,且中心区域与鼓形区域的应力差值较大,内部变形剧烈;鼓形区域显微组织以倾斜的层状α晶粒为主,有局部塑性流动现象出现。在高温低应变速率下,内部变形相对均匀,显微组织以等轴α晶+β转变组织为主。此外,在所有变形条件下,中心区域均以层状α晶粒为主,并发生了动态再结晶,顶部区域与中心区域的组织相似。     

Ti-Al合金熔体与氧化物陶瓷界面反应的热力学分析(英文)

研究CaO、MgO、Al2O3和Y2O3与熔融Ti及Ti合金之间的界面反应热力学。根据氧化物在Ti合金熔体中的溶解反应机制建立热力学模型,通过热力学分析预测各氧化物相对于Ti-Al(0≤x(Al)≤0.5)合金的热力学稳定性。根据氧化物坩埚熔炼实验结果来研究氧化物与Ti-xAl合金熔体的界面反应,对熔炼效果进行定量分析,发现随着合金中Al含量的提高和熔体温度的降低,合金中杂质元素含量成比例的减少,这与氧化物稳定性计算结果一致。     

高温钛合金Ti-60热处理窗口与性能的关系

研究了高温钛合金Ti-60的热处理工艺窗口大小、组织和性能的关系.结果表明Ti-60合金的α+β热处理工艺窗口在士10℃之间,初生α控制在4%-15%,合金组织保持细小的晶粒.随着α稳定元素Al的增加,具有缩小两相区范围的趋势.在热处理工艺窗口内热处理,合金力学性能良好.     

SiC/Ti-6Al-4V复合材料界面反应的扫描电镜分析

采用扫描电镜分析了国产SiC纤维增强Ti-6Al-4V复合材料的界面反应,发现不带C涂层的SiC纤维与Ti-6Al-4V反应形成TiC和钛的硅化物,带有C涂层的SiC纤维与Ti-6Al-4V反应仅形成TiC。观察表明C涂层的厚度差别较大。     

Ti-15-3钛合金橡皮成形的摩擦因数(英文)

用网格应变自动测量分析系统测量Ti-15-3钛合金板料刚模胀形试验的极限应变,并进行拟合以获取Ti-15-3钛合金的成形极限图。通过分析刚模胀形、橡皮胀形、液压胀形等试验的"拉拉"区极限应变,可知橡皮胀形的极限应变最大,接近等双拉时的,橡皮硬度对胀形极限应变的影响很小。用平板摩擦试验初步确定Ti-15-3钛合金与刚模间无润滑无变形条件下的摩擦因数。将试验与有限元模拟结合,分别分析Ti-15-3钛合金刚模胀形及橡皮胀形的应变,确定润滑条件下双拉变形时的Ti-15-3板料刚模间的摩擦因数以及Ti-15-3板料橡皮间的摩擦因数。Ti-15-3板料刚模间的摩擦对成形影响很大,而Ti-15-3板料橡皮间的摩擦对成形的影响则很小。     

离心熔模精铸TiAl合金与ZrO2型壳的界面反应

选用CaO增强的ZrO2作为TiAl熔模精密铸造用陶瓷型壳的面层材料,通过OM、SEM、EDS和XRD对TiAl合金界面反应处进行形貌分析和元素线扫描分析,研究离心熔模铸造TiAl合金与ZrO2型壳的界面反应.结果表明:在较低的转速(200 r/min)条件下,ZrO2陶瓷与TiAl合金的反应层厚度较小,大约为5 μm;而在较高的转速(400 r/min)情况下,ZrO2陶瓷与TiAl合金的反应层厚度约为20 μm,界面有轻微粘砂.     

TiH2基粉末冶金近α钛合金Ti-1100的热变形行为

通过热压缩试验,研究了TiH2基粉末冶金近α钛合金Ti-1100在973-1173K温度范围和0.01-1.0s-1应变速率范围内的热变形行为。建立了Arrhenius本构方程,计算出的热形变活化能为334.76 kJ / mol。通过修改函数计算了温度灵敏度（θ）,确定了应变率灵敏度（m）。根据温度灵敏度、应变率灵敏度和应变率为0.5时的显微组织分析结果,对热加工条件进行了分析。结果表明,在应变率为0.01s-1和1s-1,在整个温度范围内,出现了失稳区,而在1135K&0.29s-1至1173K&0.76s-1、1040&0.33s-1至1096K&0.6s-1的范围内获得了最佳的热加工条件。此外,微观结构分析表明,在0.01-0.1s-1的应变速率条件下发生了动态再结晶（DRX）,而应变率为1s-1时微孔的形成为流动软化的主要机制。     

SnCu钎料镀层与Cu/Ni镀层钎焊接头的界面反应

观察了不同焊接工艺条件下钎焊接头界面的微观结构，并对钎焊过程中的界面反应进行分析。探讨了钎缝界面处IMC的生长机制，通过对不同钎焊温度和保温时间下的IMC生长规律的分析建立铜锡化合物厚度与温度和时间的关系方程。结果表明：钎焊过程中SnCu钎料合金镀层与可焊性Cu层的界面处生成金属间化合物Cu6Sn5和Cu3Sn；化合物的生长厚度与焊接时间之间满足抛物线关系，表明化合物的生长为扩散反应控制过程，并随焊接时间的延长化合物的生长速率逐渐下降。     

Effect of boron on microstructure and mechanical properties of thermomechanically processed near alpha titanium alloy Ti-1100

The effect of 0.2 wt.% of boron on the mechanical properties of Ti-1100, a near α titanium alloy, was evaluated at room temperature and at 600 °C in the as cast and thermomechanically processed (α-β rolled) condition after subjecting it to different heat treatments. Boron addition in Ti-1100 significantly refined the microstructure in the as cast condition but the mechanical properties did not show any improvement. However, in the thermomechanically processed (α-β rolled) and standard heat treatment condition, the yield strength (YS) and ultimate tensile strength (UTS) of the boron containing alloy increased significantly without any drop in elongation-to-failure as compared to the base alloy at both room temperature and 600 °C. No discernible trend was seen in YS and UTS in boron containing alloy with change in solution treatment temperature either at room temperature or at 600 °C.     

Characterization of zirconia-based slurries with different binders for titanium investment casting

The materials and physical properties of primary slurry are crucial to the surface quality of the finished castings,especially for high reactivity titanium alloys.The aim of this study is to investigat...     

Interfacial heat-transfer between A356-aluminium alloy and metal mould

The interracial heat-transfer coefficient at casting/mould interface is a key factor that impacts the simulation accuracy of solidification progress. At present, the simulation result of using available data is comparatively different from the practice. In the current study, the methods of radial heating and electricity measurement under steady-state condition were employed to study the nature of interfacial heat-transfer between A356 Aluminum alloy and metal mould. The experimental results show that the interracial heat-transfer between A356 Aluminum alloy and the outer mould drops linearly with time while that of A356 aluminum alloy and the inner mould increases with time during cooling. The interracial heat-transfer coefficient between A356 aluminum alloy and mould is inversely proportional to the electrical resistance.     

Molecular simulation of interfacial reaction between TiAl alloy melts and different coatings

The effect of coatings (Y2O3, ZrO2 and Al2O3) on the interfacial reaction of TiAl alloys was studied with molecular dynamics. The binding energy of coatings and the diffusion process of oxygen in the melt were simulated, and then the simulation results were compared with the experimental results. The simulation results indicate that for each of the three simulated coatings, inordinate interfacial reactions have occurred between the coating and the melt. The binding energy results show that Y2O3 has the best stability and is the most difficult to break down. ZrO2 has the greatest decomposition energy and is the easiest to break down in the melt. Besides,the molecular dynamics indicate that the diffusion coefficient of the oxygen atom in Al2O3 is larger than that in the other two coatings, indicating that oxygen diffusion in Al2O3 is the fastest at a given temperature. The experimental results show that the oxygen concentration of the melt with Al2O3 coating is the highest, and the oxygen diffusion is of similar magnitude to the simulation values, from which the conclusion can be obtained that the oxygen concentration is significantly influenced by the coating materials.     

Improvement in collapsibility of ZrO2 ceramic mould for investment casting of TiAl alloys

Investment casting has been widely recognized as the best option in producing TiAl components with key benefits of accuracy,versatility and integrity.The collapsibility of ceramic moulds for investment casting is critical in the manufacturing process of TiAl components due to TiAl’s intrinsic brittleness at room temperature.The aim of the present research is to provide a method for production of TiAl components by investment casting in ZrO2 ceramic moulds with improved collapsibility.Slurries prepared with high polymer additions were utilized during the preparation of ceramic moulds.The stress/strain curves obtained from green and baked ceramic moulds demonstrate that the green strength was increased with the application of high polymer,while baked strength decreased,thus the collapsibility of ceramic moulds was improved.It is suggested that this result is related to the burn-out of high polymer which left a lot of cavities.The experimental findings were also verified by the investment casting of "I"-shaped TiAl components.     

Reaction between Ti and boron nitride based investment shell molds used for casting titanium alloys

The aim of this paper was to study the reaction between a Ti-6Al-4V alloy and boron nitride based investment shell molds used for invest- ment casting titanium. In BN based investment shell molds, the face coatings are made of pretreated hexagonal boron nitride (hBN) with a few yttria (Y2O3) and colloidal yttria as binder. The Ti-6Al-4V alloy was melted in a controlled atmosphere induction furnace with a segment water-cooled copper crucible. The cross-section of reaction interface between Ti alloys and shell mold was investigated by electron probe micro-analyzer (EPMA) and microhardness tester. The results show that the reaction is not serious, the thickness of the reacting layer is about 30-50 μm, and the thickness of α-case is about 180-200 μm. Moreover the α-case formation mechanism was also discussed.     

粉料的粒度分布对TiAl合金熔模精密铸造用氧化锆陶瓷型壳性能的影响(英文)

研究粉料的粒度分布对TiAl合金熔模精密铸造用氧化锆陶瓷性能的影响。对粉料粒度分布、粉末形貌、浆料黏度、型壳抗弯强度和断裂形貌之间的关系进行研究;通过测量氧化锆粉末和粘结剂构成的浆料的黏度来考察粉末粒度分布对浆料黏的影响;对不同粒度分布氧化锆陶瓷型壳断口形貌进行观察。结果表明:粉料粒度分布对未焙烧和焙烧后氧化锆陶瓷型壳的强度影响行为相似;粉料粒度分布对氧化锆陶瓷型壳的质量能产生很大的影响并进而影响到熔模精密铸造制备TiAl合金构件的质量。