共查询到20条相似文献,搜索用时 109 毫秒
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柔性太阳能电池具有轻便、可弯曲的优点,可用于可穿戴设备等器件的即时充电,具有广阔的应用前景,受到持续广泛的关注。柔性太阳能电池制备中的关键在于基材以及与之相关的电极材料的制备。本文综述了柔性染料敏化太阳能电池和柔性钙钛矿太阳能电池近几年的发展情况,着重介绍了柔性染料敏化太阳能电池光阳极、对电极以及柔性钙钛矿太阳能电池的底电极和电子传输层。结果发现高温烧结目前仍是制备高效染料敏化太阳能电池光阳极不可避免的方法,而对电极则不受这一限制并且已经有多种材料的效率超过了高温烧结的铂。柔性钙钛矿太阳能电池的研究重点是用其他材料代替底电极中柔性较差的ITO以及高温烧结的电子传输材料TiO2,并且都取得显著成效。在此基础上,展望了柔性染料敏化太阳能电池和柔性钙钛矿太阳能电池未来的发展方向。 相似文献
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柔性染料敏化太阳能电池(Flexible Dye-Sensitized Solar Cell,FDSSC)是以聚合物或金属等柔性材料为基底的染料敏化太阳能电池(Dye-Sensitized Solar Cell,DSSC)。相比于刚性DSSC,其具有可弯曲、低成本、易大面积加工和应用范围广等优点,越来越受到人们的关注。柔性染料敏化太阳能电池TiO2光阳极的制备方法,根据热处理温度的不同可以分为低温和高温制备方法,其中包括化学法、压力法、电泳沉积法、转移法、金属基底上的制备以及一些新的制备方法等。本文结合DSSC光阳极中电子的传输和复合的基本原理,针对电极的各制备方法进行了综述,并对电池的相关性能作了一定的介绍;最后,对FDSSC未来的发展前景和有潜力的研究方向进行了展望。 相似文献
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研究了染料敏化纳晶薄膜太阳电池由于价格低、性能好而备受关注,对电极作为染料敏化纳晶薄膜太阳电池的重要组成部分,其性能对电池性能有很大影响。综述了目前对电极的研究进展,重点分析了对镀铂电极、碳电极的研究进展,并简要介绍了导电聚合物电极和柔性对电极在染料敏化纳晶薄膜太阳电池中的应用。 相似文献
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采用增韧剂(A)对氰酸酯树脂(CE)进行了增韧改性,使用溶液浇铸成型制备了改性CE柔性膜。研究了催化剂(B)和增韧剂对CE固化速率和固化温度的影响。与纯CE相比,含有催化剂的CE固化温度大幅度降低、固化速度明显提高。增韧剂的加入降低了CE/B体系的固化温度。固化时间延长,CE/A体系固化程度提高;增韧剂用量增大,改性CE膜的拉伸强度和杨氏模量下降,柔性提高;改变CE与A预聚温度可调整改性CE膜的强度和模量。 相似文献
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In this work, the utilization of matrix-assisted laser desorption/ionization-mass spectrometric imaging (MALDI-MSI) for capillary electrophoresis (CE) analysis of peptides based on a simple and robust off-line interface has been investigated. The interface involves sliding the CE capillary distal end within a machined groove on a MALDI sample plate, which is precoated with a thin layer of matrix for continuous sample deposition. MALDI-MSI by time of flight (TOF)/TOF along the CE track enables high-resolution and high-sensitivity detection of peptides, allowing the reconstruction of a CE electropherogram while providing accurate mass measurements and structural identification of molecules. Neuropeptide standards and their H/D isotopic formaldehyde-labeled derivatives were analyzed using this new platform. Normalized intensity ratios of individual ions extracted from the CE trace were compared to MALDI-MS direct analysis and the theoretical ratios. The CE-MALDI-MSI results show potential for sensitive and quantitative analysis of peptide mixtures spanning a wide dynamic range. 相似文献
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Dong Ye Yajiang Ding Yongqing Duan Jiangtao Su Zhouping Yin Yong An Huang 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(21)
Nanofibers/nanowires usually exhibit exceptionally low flexural rigidities and remarkable tolerance against mechanical bending, showing superior advantages in flexible electronics applications. Electrospinning is regarded as a powerful process for this 1D nanostructure; however, it can only be able to produce chaotic fibers that are incompatible with the well‐patterned microstructures in flexible electronics. Electro‐hydrodynamic (EHD) direct‐writing technology enables large‐scale deposition of highly aligned nanofibers in an additive, noncontact, real‐time adjustment, and individual control manner on rigid or flexible, planar or curved substrates, making it rather attractive in the fabrication of flexible electronics. In this Review, the ground‐breaking research progress in the field of EHD direct‐writing technology is summarized, including a brief chronology of EHD direct‐writing techniques, basic principles and alignment strategies, and applications in flexible electronics. Finally, future prospects are suggested to advance flexible electronics based on orderly arranged EHD direct‐written fibers. This technology overcomes the limitations of the resolution of fabrication and viscosity of ink of conventional inkjet printing, and represents major advances in manufacturing of flexible electronics. 相似文献
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目的利用添加剂改善离子液体溶剂再生纤维素的性能。方法以离子液体为纤维素溶剂,利用柔性聚丁二酸丁二醇酯(PBS)增韧纤维素薄膜,并对复合薄膜的结构进行研究。利用拉伸实验仪和扫描电子显微镜,研究复合薄膜的力学性能及拉伸机理。结果 PBS质量分数为1%时,复合薄膜的拉伸强度和断裂伸长率由纯纤维素的45.6 MPa和7.21%提高到58 MPa和15.6%,分别提高了30.7%和48.2%。结论 PBS是以共混的形式存在于纤维素基体中,它们之间没有化学键作用,PBS的含量显著影响其颗粒的大小和分散状态。低含量下PBS微颗粒均匀分散在纤维素基体内,降低了纤维素分子间氢键的密度,有利于纤维素分子链滑移,增强复合薄膜韧性。 相似文献
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量子点敏化太阳能电池(Quantum Dot-Sensitized Solar cells, QDSCs)制备工艺简单, 制造成本低廉, 是一种有希望的新型太阳能电池。QDSCs利用量子点具有光谱吸收强、尺寸可调和多激子效应等优点, 能够提高其光电转换效率; 同时, 利用无机量子点替代染料作为敏化剂, 能够解决染料敏化太阳能电池(DSCs)的稳定性问题。但是, QDSCs光电转换效率较低是制约其应用的主要问题。近年来, 通过改变和调控对电极的材料和电子特性提高QDSCs的光电效率的方法受到了广泛关注。本文综述了QDSCs对电极材料的制备方法、微观形貌和晶体结构; 重点分析了金属化合物、复合材料、杂化材料、多元金属硫族化合物、导电聚合物和碳材料对电极对量子点敏化太阳能电池的电荷转移阻抗、光电性能等参数的影响; 并分析影响其电催化活性和电子传输性能的主要因素。最后, 提出通过表面修饰、复合和杂化等方法构筑新型对电极材料, 进而改善和提高QDSCs转换效率和稳定性, 是今后的研究重点和研究方向。 相似文献
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John Fahlteich Dr. Matthias Fahland Dr. Steffen Straach Steffen Günther Dr. Nicolas Schiller Dr. 《真空研究与实践》2011,23(4):29-37
Transparent permeation barrier layers on flexible polymer substrates This paper reviews different vacuum based technologies for manufacturing transparent permeation barrier layers and layer stacks on flexible polymer substrates. With plasma assisted reactive evaporation, a cost‐efficient, highly productive process for food packaging applications is presented. Reactive dual magnetron sputtering is a technology for the deposition of oxide layers with a very low water vapor and oxygen transmission rate at a reasonable deposition rate. Many groups suggest multilayer stacks for the encapsulation of flexible electronic devices. In this paper, an all‐in‐vacuum inline concept for manufacturing such multilayers is presented. It is based on the combination of reactively sputtered barrier layers with interlayers grown by using a magnetron based PECVD process (Magnetron‐PECVD). Both, process parameters, such as deposition rate and process pressure, and important layer properties, such as morphology and the water vapor and oxygen transmission rate are compared for the different single and multi layer technologies. 相似文献
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An improved vacuum deposition interface for coupling capillary electrophoresis with MALDI-TOF MS has been developed. Liquid samples consisting of analyte and matrix were deposited on a moving tape in the evacuated source chamber of a TOF mass spectrometer, enabling 24 h of uninterrupted analysis. The vacuum deposition procedure was compared with the dried-droplet method, and it was found that vacuum deposition generated significantly more reproducible signal intensity, eliminating the need for "sweet spot" searching. A concentration detection limit in the low-nanomolar range has been achieved with a low-attomole amount of sample consumed per spectrum. In addition, ion suppression caused by hydrophobicity differences in the analytes was reduced. To minimize ion suppression further, separation prior to MALDI MS analysis was employed. The performance of capillary electrophoresis (CE)-MALDI-TOF MS using the vacuum deposition interface was evaluated with a peptide mixture injected at low-femtomole levels. All peptides were baseline resolved with separation efficiencies in the range of 250000-400000 plates/m (2-3-s band half-width), demonstrating the high separation efficiency of the CE-MALDI MS coupling. A fast (approximately 40 s) CE separation of a mixture of angiotensins was found to reduce significantly ion suppression and enable trace level detection. It was also shown, for the analysis of an enolase digest, that sequence coverage of 65% was obtained using CE separation compared to 52% using step-elution solid-phase extraction and 44% in the control experiment using an unseparated mixture. 相似文献
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《Current Opinion in Solid State & Materials Science》1998,3(4):386-390
One of the various solar control glasses, a silver-based multilayer film formed by sputtering is becoming increasingly important because of its excellent and versatile performance. Recently major progress has been made in the sputtering process by several manufacturers, which has enabled both a stable and high rate of deposition. Efforts to improve the durability of sputter coating have been maintained seeking a flexible production process and expanded applications. 相似文献
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