共查询到19条相似文献,搜索用时 140 毫秒
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基于电子传输的扩散理论建立了染料敏化太阳能电池(DSSC)的连续性方程,使用适合于二氧化钛(TiO2)作为光阳极的内部参数,对DSSC电子注入和传输的内在机理进行研究。分别考查温度、TiO2膜厚、电子寿命、电子扩散系数、光照强度、吸收系数等因素对DSSC光电性能的影响,为DSSC性能的改进及光电转换效率的提高提供理论指导。 相似文献
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太阳能电池的研究现状与发展趋势 总被引:2,自引:2,他引:2
针对目前太阳能电池中占重要地位的硅太阳能电池、化舍物半导体和染料敏化太阳能电池的研究现状进行了调研,对研究热点、存在问题及发展方向进行了总结,同时讨论了三类太阳能电池各自的优势和不足. 相似文献
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《可再生能源》2013,(12):1-6
以CdS量子点敏化TiO2纳米颗粒多孔薄膜为光阳极,与多硫电解液和Pt对电极组装太阳能电池,研究了光阳极厚度和敏化周期对光伏性能的影响。结果表明,TiO2纳米颗粒多孔薄膜的最佳厚度为14μm,最佳CdS量子点敏化周期为20,由此得到的太阳能电池的短路电流密度J sc、光电转换效率η和量子效率分别为4.51 mA/cm2、0.76%和69%。在光阳极中采用TiO2纳米颗粒/TiO2纳米线多孔薄膜双层工作电极,TiO2纳米线散射层增加了对入射光的利用率,使电池在可见光波段的量子效率增加,从而使电池的短路电流密度J sc和光电转换效率分别比原来提高了11.6%和10.5%。 相似文献
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报道了用四探针法及阳极氧化法测试云南半导体器件帮生产的φ(100)绒面硅太阳能电池扩散层薄层电阻(Rs)及结深(X1)的情况,从中可检测适合于硅太阳能电池p-n结需要的Rs和x1对提高太阳能电池产品质量有较重要的指导作用。 相似文献
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Monishka Rita Narayan 《Renewable & Sustainable Energy Reviews》2012,16(1):208-215
The performance of dye sensitized solar cells is mainly based on the dye as a sensitizer. Natural dyes have become a viable alternative to expensive and rare organic sensitizers because of its low cost, easy attainability, abundance in supply of raw materials and no environment threat. Various components of a plant such as the flower petals, leaves and bark have been tested as sensitizers. The nature of these pigments together with other parameters has resulted in varying performance. This review briefly discusses the emergence, operation and components of dye sensitized solar cells together with the work done on natural dye based dye sensitized solar cells over the years. 相似文献
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We have explored the application of natural dyes extracted from beetroot in Dye sensitized solar cell (DSSC). The main pigment is betacyanin which was obtained by separation and purification from the extract. The photo electrochemical performance of the DSSC based on these dyes showed that the photo voltage and photocurrent 435 mV, 9.86 mA, respectively. The overall conversion efficiency of nano WO3 coated TiO2 dye-sensitized solar cells exhibits a higher conversion efficiency of 2.2%. The photo electrochemical performance of beetroot extract demonstrate that betacyanin dye was the most effectual component of the sensitizer for DSSC because of the simple preparation technique, widely available and low cheap cost. 相似文献
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Aycan Atli Abdullah Atilgan Cesur Altinkaya Kenan Ozel Abdullah Yildiz 《国际能源研究杂志》2019,43(8):3914-3922
Natural dyes extracted from fruits, vegetables, flowers, and leaves are considered as promising alternative sensitizers to replace synthetic dyes for dye‐sensitized solar cells (DSSCs). Generally, solar activity of natural dyes stem from anthocyanin pigment. Carbonyl, carboxyl, and hydroxyl groups present in the anthocyanin molecule improve the adsorption ability of dye on TiO2 and therefore facilitate charge transfer. Here, for the first time, novel natural dyes extracted from St. Lucie cherry, yellow jasmine, and madder berries are reported to act as sensitizer in DSSCs. These novel natural dye extracts are prepared by dissolving related fruits in ethanol. The ingredient of the dyes is identified by FT‐IR spectroscopy. Accordingly, FT‐IR spectrum reveals that novel natural dye extracts exhibit all the characteristic peaks of anthocyanin pigment. Specifically, St. Lucie cherry consists of more distinct carbonyl group than other sources. Also, photoanodes composed of three TiO2 layers are prepared by using a spin‐coating method. Then, they are immersed into natural dyes and analyzed by conducting UV‐Vis spectroscopy. Compared with bare TiO2, natural dye–loaded photoanodes demonstrate far higher absorption ability in the visible region. After fabrication of devices with different novel natural dye sensitizers, current‐voltage characteristics and electrochemical impedance spectroscopy measurements are performed. The best power conversion efficiency (PCE) of 0.19% is obtained by sensitization of St. Lucie cherry with an open‐circuit voltage (Voc) of 0.56 V, short‐circuit current density (Jsc) of 181 μA cm?2, and fill factor (FF) of 0.55. Furthermore, St. Lucie cherry–sensitized devices show the lowest charge transfer and highest recombination resistances. This result can be attributed to the obvious carbonyl group exhibited by St. Lucie cherry. 相似文献
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Nofrijon Sofyan Aga Ridhova Akhmad H. Yuwono Arief Udhiarto Jeffrey W. Fergus 《国际能源研究杂志》2019,43(11):5959-5968
Efficiency of a dye‐sensitized solar cell (DSSC) device depends on its semiconductor layer and the sensitizing dye to absorb the light. This work seeks to obtain the best solvent for the natural dye extraction from Melastoma malabathricum L. seeds. The extracted dye is used as sensitizer on TiO2 nanoparticles produced via hydrothermal but optimized at relatively low temperature. Infrared characterization of the extracted dyes showed differences in functional groups using different solvents, whereas ultraviolet visible examination of the dyes showed differences in intensity along the spectrum ranges of 600 to 400 nm with maximum absorption around 550 to 500 nm. Thermal analysis revealed that the natural dye should be stable around room temperature. Analysis on the synthesized TiO2 nanoparticles showed that the average crystallite size reported in the previous work is consistent with crystallite sizes observed in the transmission electron microscope images. Photoactivity examination showed that the DSSC sensitized using natural dye extracted with ethanol containing 20% distilled water on TiO2 synthesized at 150°C has an efficiency of 5.7%, whereas the one on commercial TiO2 P25 Degussa has an efficiency of 3.0%. The DSSC device sensitized using commercial dye on TiO2 synthesized at 150°C has an efficiency of 4.4%, whereas the one on TiO2 P25 Degussa has an efficiency of 4.0%. This result is promising for further development of the DSSC device using TiO2 nanoparticles synthesized at low hydrothermal temperature and sensitized with the natural dye. 相似文献
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Enhancement in the photostability of natural dyes for dye‐sensitized solar cell (DSSC) applications: a review
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N. Prabavathy S. Shalini R. Balasundaraprabhu Dhayalan Velauthapillai S. Prasanna N. Muthukumarasamy 《国际能源研究杂志》2017,41(10):1372-1396
The advancements in the generation of solar cells have created a landmark to design a cost‐effective, less weight, biocompatible, and environmental‐friendly solar cell. Dye‐sensitized solar cells (DSSCs) have become a topic of significant research in the recent years because of their imperative role in the zone of harvesting energy from the renewable source, and it appears to be a promising candidate for the triumph because of its low cost and ease of preparation. The use of synthetic dyes as a sensitizer for DSSC provides better efficiency and high durability. Unfortunately, they suffer from several margins such as higher cost and usage of toxic materials. These downsides have opened up for alternative sensitizer such as biocompatible natural dyes. Natural dyes contain plant pigments such as carotenoid, flavonoid, betalains, and chlorophyll that act as sensitizers (dye) for DSSC. But, the efficiency of natural dyes is not up to the mark mainly due to photoinstability of natural dye in the presence of sunlight that leads to photodegradation. The stability issues are mainly due to interaction of natural dyes with photoelectrode. The photoelectrodes in DSSC are semiconductor materials with superior characteristic of photocatalytic activity (PCA). The PCA of titanium dioxide (TiO2) generates high energetic free electrons on the surface of film that produce free radical ions in contact with moisture. These free radical ions readily degrade the organic matter present nearby (natural dye in DSSC). Thus, the PCA of photoelectrode is responsible for the photodegradation of dyes causing photoinstability. The main objective of this review is to study the photoinstability of natural dyes in DSSC. In this regard, the DSSC is concentrated into sections, and the stability issues due to PCA of photoelectrode are studied individually in the view of considering the DSSC operating with iodide‐based electrolytes and platinum as counter electrode only. Various algae groups are featured as a study tool to overview the dye interaction with photoelectrode. It highlights the application of Z‐scheme of photosynthesis to DSSC to have a broader perception on the working of DSSC and also shows some of the ways for improving the stability of dyes by suppressing or reducing the PCA of photoelectrode. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
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Dye sensitized solar cells employing natural plant dyes as phosensitizers can be effectively used to train students in the science and technology of solar cells. This is especially relevant to developing countries where facilities for silicon cell fabrication are non-existent. The cross-disciplinary nature of this device makes it very attractive for student projects. The present work describes such a project where anthocyanin dye from hibiscus flowers has been used as the electron harvester. 相似文献
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Investigation of novel anthracene‐bridged carbazoles as sensitizers and Co‐sensitizers for dye‐sensitized solar cells
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Novel anthracene‐bridged carbazole organic dyes (designated ML4 and ML5) were synthesized using the Suzuki coupling reaction. These dyes were designed to be donor‐π‐conjugation‐acceptor sensitizers for dye‐sensitized solar cells, where the carbazole moiety acts as the donor, the anthracene moiety provides the π‐conjugation, and the cyano acrylic acid acts as the acceptor. Solar cells were fabricated with ML4 and ML5 alone with low power conversion efficiencies, but they were also used as co‐sensitizers with N719, improving the efficiency of the dye‐sensitized solar cells produced by ~3% and ~10%, respectively. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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S. Shalini R. Balasundaraprabhu T. Satish Kumar N. Prabavathy S. Senthilarasu S. Prasanna 《国际能源研究杂志》2016,40(10):1303-1320
Dye‐sensitized solar cells (DSSCs) have become a topic of significant research in the last two decades because of their scientific importance in the area of energy conversion. Currently, DSSC is using inorganic ruthenium (Ru)‐based, metal‐free organic dyes, quantum‐dot sensitizer, perovskite‐based sensitizer, and natural dyes as sensitizer. The use of metal‐free, quantum‐dot sensitizer, perovskite‐based sensitizer, and natural dyes has become a viable alternative to expensive and rare Ru‐based dyes because of low cost, ease of preparation, easy attainability, and environmental friendliness. Most of the alternatives to Ru‐based dyes have so far proved inferior to the Ru‐based dyes because of their narrow absorption bands (Δλ ≈ 100–250 nm), adverse dye aggregation, and instability. This review highlights the recent research on sensitizers for DSSC, including ruthenium complexes, metal‐free organic dyes, quantum‐dot sensitizer, perovskite‐based sensitizer, mordant dyes, and natural dyes. It also details and tabulates all types of sensitizer with their corresponding efficiencies. Plot of progress in efficiency (η) of DSSC till date based on different types of sensitizers is also presented. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
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The synthesis and characterization of carbon dots and their application in dye sensitized solar cell
《International Journal of Hydrogen Energy》2019,44(29):14580-14587
Carbon dots (CDOTs) are increasingly becoming popular in the areas ranging from sensing and bioimaging to electronics. The interesting optical properties of CDOTs make it vital to explore its potential in the development of sustainable energy. In this work, one-step hydrothermally synthesized CDOTs were used as sensitizing agent in the fabrication of dye sensitized solar cell. The fabrication of the CDOT-based dye sensitized solar cell and its performance characteristics are explored in depth. The fabricated dye sensitized solar cell performance in terms of efficiency, voltage, and current was evaluated using a standard illumination of air-mass 1.5 global (AM 1.5 G) having an irradiance of 100 mW/cm [2]. The photon-to-current conversion efficiency (η) of only the carbon dot sensitized solar cell was 0.10% whereas the efficiency of the solar cell fabricated with a sensitizing dye made up of CDOT and N719 was 0.19%. As compared with the performance DSSCs fabricated with only 719 dye, it was observed that when CDOT was used in combination with N719 as sensitizing dye, the open circuit voltage increases yet the overall efficiency of the resulting solar cells decreases. It is clear from the result that CDOT could be used as a sensitizing dye in DSSCs. However, it is not very useful when used in combination with other sensitizing dyes due to energy transfer. 相似文献