三氯乙酰氯的合成与应用

综述了三氯乙酰氯的合成方法及其在农药、医药等领域中的应用。     

三氯甲基碳酸酯的合成与应用

介绍了三氯甲基碳酸脂的合成及在医药、农药等领域中的应用，三氯甲基碳酸脂是一种新型的光气替代品，开发前景广阔，应加快开发步伐。     

高效甜味剂三氯蔗糖的应用与合成

介绍了高效甜味剂三氯蔗糖的合成工艺与应用,对各种工艺进行综合评价并提出较好的生产工艺,着重介绍三氯蔗糖的开发前景。     

三氯乙腈的合成、应用与市场

介绍了三氯乙腈的合成方法及应用,分析了其产销现状及前景。     

三氯蔗糖的合成与应用研究进展

三氯蔗糖是一种新型强力甜味剂，其热量值为零，不会引起人体肥胖和血糖波动，性／价比高。其作为专用甜味剂前景广阔。本介绍了其性质、合成方法等。     

双三氯甲基碳酯的合成与应用

本文主要介绍了双三氯甲基碳酸酯的性能，制备和应用。     

三氯新在锶盐牙膏中的应用

本文通过三氯新在锶盐牙膏中的应用与测试分析,取得了所研究牙膏的满意结果和最佳配方。     

三氯乙酰氯的简便合成及其应用

硝酸加入三氯乙醛(其物质的量比为2．1：1)，50℃反应6h得三氯乙酸结晶。三氯化磷加入三氯乙酸(其物质的量比为0．4：1)，在70℃回流反应4h，得三氯乙酰氯液体，收率为90％。本文还叙述了三氯乙酰氯在杀虫剂，除草剂和其他精细化工产品中的应用。     

高效甜味剂三氯蔗糖应用与合成

介绍了高效甜味剂三氯蔗糖的合成工艺与应用。对各种工艺进行综合评价，并着重介绍了三氯蔗糖的开发前景。     

双三氯甲基碳酸酯的合成与应用

介绍了双三氯甲基碳酸酯的性能,制备和应用。     

玉洁纯在牙膏和漱口水中的作用机理与应用

玉洁纯（2，4，4′-trichloro-2′-hydroxydiphenyl ether)是一种非离子的高效广谱抗微生物剂，对于一般常见的细菌、真菌及酵母等病原菌，玉洁纯都具有杀灭功效及抑制作用。国外学者长期的临床观察证实含有玉洁纯的牙膏和漱口水能有效地控制菌斑和缓解牙龈炎症状。玉洁纯的毒性极低，并无异味、无刺激感。从玉洁纯的理化性质和药理作用、玉洁纯控制菌斑的机理、玉洁纯在牙膏和漱口水中的应用等3个方面论述了国外学者对玉洁纯在牙膏和漱口水中的作用机理和应用的研究现况，为我国牙膏工业口腔卫生用品的技术革新提供了有益的参考。玉洁纯在我国口腔卫生用品中的应用正在迅速崛起，其发展趋势预计将会带动整个行业。     

Synthesis and characterization of novel antimicrobial polymers containing pendent triclosan moieties

Novel antimicrobial copolymers were produced by first converting the commodity biocide, triclosan (TCS), to an epoxy-functional derivative, 2-((5-chloro-2-(2,4-dichlorophenoxy)phenoxy) methyl)oxirane (ETCS), and then reacting ETCS with polyethylenimine (PEI). While neither ETCS or PEI showed high antimicrobial activity toward either the Gram-positive bacterium, Staphylococcus epidermidis, or the Gram-negative bacterium, Escherichia coli, some the copolymers showed very high activity toward both bacteria. Antimicrobial activity for these copolymers was found to be highly dependent on both the molecular weight of the PEI utilized and the concentration of pendent groups derived from ETCS. In general, decreasing PEI molecular weight and increasing TCS pendent group concentration increased antimicrobial activity. Surface tension measurements showed that the molecular parameters affecting antimicrobial activity also affected surface activity in a similar fashion. Thus, it was speculated that the mechanism of antimicrobial activity associated with these copolymers involves interaction of the copolymers with the bacterial cell wall. A comparison of the antimicrobial activity of the most effective copolymers to TCS showed that the copolymers were more effective toward E. coli than pure TCS when compared using an equivalent TCS content (i.e. TCS pendent group content for the copolymers). This characteristic coupled with the fact that the TCS-containing copolymers are highly aqueous soluble liquids as opposed to a crystalline solid of limited solubility may afford utility of these copolymers for a variety of applications.     

三氯新的生产及应用

介绍了三氯新的主要生产方法即以 2 ,4 二氯苯酚为主要原料的工艺路线及以邻甲氧基苯酚为主要原料的工艺路线。三氯新在日用化工方面有着广阔的应用领域 ,并呈快速增长的势头 ,具有较高的实用价值和良好应用前景     

Electro-Fenton degradation of antimicrobials triclosan and triclocarban

The antimicrobials triclosan (2,4,4′-trichloro-2′-hydroxydiphenyl ether) and triclocarban (N-(4-chlorophenyl)-N′-(3,4-dichlorophenyl)urea) have been degraded by four electro-Fenton systems using undivided electrolytic cells with a Pt or boron-doped diamond (BDD) anode and a carbon felt or O₂ diffusion cathode. The main oxidant is hydroxyl radical (OH) produced both on the anode surface from water oxidation and in the medium by Fenton's reaction, which takes place between electrogenerated H₂O₂ and Fe²⁺ coming from cathodic reduction of O₂ and Fe³⁺, respectively. Triclosan from saturated aqueous solutions of pH 3.0 is completely removed in all cells, decreasing its decay rate in the order: Pt/carbon felt > BDD/carbon felt > Pt/O₂ diffusion > BDD/O₂ diffusion, in agreement with their OH generation ability from Fenton's reaction. Glyoxylic, maleic and oxalic acids are identified as aliphatic intermediates. Complexes between oxalic acid and iron ions persist largely in solution, although Fe²⁺-oxalato complexes are mineralized by OH in the medium and Fe³⁺-oxalato complexes are destroyed by OH on BDD. Analogous treatments of more concentrated triclosan solutions using a 20:80 (v/v) acetonitrile/water mixture as solvent evidence the role of hydroxyl radicals along the degradation. In this hydroorganic medium hydroxylated derivatives such as 2,4-dichlorophenol, 4-chlorocatechol, chlorohydroquinone and chloro-p-benzoquinone, and carboxylic acids such as maleic, oxalic, formic and acetic acids are detected as products. Complete destruction of iron-oxalato complexes and released Cl⁻ ion involves some oxidizing species coming from parallel acetonitrile oxidation. The same electro-Fenton systems also yield the overall removal of triclocarban in acetonitrile/water mixtures, giving rise to urea, hydroquinone, chlorohydroquinone, 1-chloro-4-nitrobenzene and 1,2-dichloro-4-nitrobenzene as primary intermediates.     

烷醇酰胺的合成及应用

烷醇酰胺属非离子型表面活性刑，本文主要介绍了烷醇酰胺的二步合成法及它的一些应用，并对合成它的一些影响因素；反应温度、投料物质的量比、催化剂的选择等进行了全面论述。     

合成辣素的制备与应用

以香兰素和正-壬酸为原料制备了合成辣素，其化学结构经红外光谱、紫外光谱、质谱、核磁共振氢谱验证，把合成辣素作为塑料添加剂加入PVC塑料样品，进行初步的药效测试，结果表明该化合物对老鼠具有显著的驱避作用。     

间溴苯甲醚的合成与应用

介绍了间溴苯甲醚的合成方法，生产现状及应用情况，并对其发展提出了一些建议。     

聚乙烯胺的合成与应用

聚乙烯胺是一种氨基直接连接在碳氢骨架上的具有多种用途的高分子材料 ,尤为重要的是由于氨基的活性较高 ,为功能性高分子材料的制备提供了便利条件。介绍了聚乙烯胺的两类制备方法 ,即聚丙烯酰胺的Hofmann降级反应和聚 (N 酰基 )乙烯胺的水解。综述了聚乙烯胺在现代分离技术、生物医学、催化以及造纸、表面改性、污水处理等领域的应用。指出由N 乙烯基甲 /乙酰胺经聚合、水解制备聚乙烯胺是制备高纯度聚乙烯胺的比较现实的方法 ,对于那些对纯度要求并不很高的应用领域 ,聚丙烯酰胺的Hofmann降级反应则是一种经济可行的办法 ;对于前者应着重提高裂解催化剂的催化活性 ,对于后者则应注重具体生产工艺的改进 ,其中更为重要的是后处理工艺的改进。     

香兰素的合成及其应用

本文介绍了香兰素合成方法及其在精细化工领域中的应用。     

间苯二甲胺的合成与应用

综述了间苯二甲胺的合成方法,分析了以间苯二甲腈为原料、经Co和Ni为主催化剂催化加氢制备间苯二甲胺的工艺。对间苯二甲胺在环氧树脂固化剂、聚氨酯等产品生产中的应用进行了阐述。