共查询到19条相似文献,搜索用时 187 毫秒
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以国内具有代表性的卷烟为研究对象,分别对卷烟样品的非挥发性有机酸含量和卷烟主流烟气粒相物pH进行了测定,通过数学分析研究了非挥发性有机酸含量对烟气粒相物pH的影响.主流烟气粒相物pH值评价指标与有机酸的关联分析结果表明,苹果酸、十五酸、油酸对主流烟气粒相物pH值相对影响较大.对影响主流烟气粒相物pH值的11种非挥发性有机酸的主成分分析结果表明,亚油酸,油酸,苹果酸,棕榈酸,草酸和亚麻酸对主流烟气粒相物pH值相对影响较大.综上可得,苹果酸和油酸对主流烟气粒相物pH值具有较大影响. 相似文献
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将不同茶叶直接添加于卷烟烟丝中,收集萃取烟气中的烟碱和咖啡碱,用紫外分光光度法定量分析主流烟气中烟碱以及咖啡碱的变化。结果表明,茶叶能够有效的影响烟气烟碱含量,其中当绿茶添加量为20%时烟气的咖啡碱含量达到最大,同时烟碱含量降到最小。 相似文献
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氧化镁湿法烟气脱硫废水与皂化废水混合处理时造成悬浮物过高,影响混合废水的生化处理。对造成混合废水悬浮物过高的原因进行了分析,考察了提高混合废水的pH值和投加絮凝剂去除悬浮物的效果。试验结果表明,氧化镁湿法烟气脱硫废水中的Mg2+与高pH值的皂化废水混合后产生氢氧化镁晶体,在pH值较低时,氢氧化镁晶体的成核速率大于晶体成长速率,大量细小晶核团聚,不利于沉降,造成混合废水的悬浮物较高。提高混合废水的pH值可提高对悬浮物的去除效果,同时投加JYM絮凝剂可加速悬浮物的沉降速率。当pH值大于11,JYM絮凝剂投加量为200 mg/L时,混合废水的浊度可在30 min内降至5 NTU以下。 相似文献
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探讨TPEG6000/(NH4)2SO4双水相直接提取烟草中的烟碱和茄尼醇。研究烟草在不同的提取时间、不同温度、不同pH值等条件下双水相体系对烟叶中烟碱和茄尼醇的提取率。研究发现,烟草的加入量0.8g,(NH4)2SO4的质量分数为16.7%,提取时间3h,提取温度40℃,pH为7时,烟碱的提取率为3.65%,茄尼醇的提取率为2.11%。 相似文献
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二次萃取蒸馏法从烟草中提取天然烟碱 总被引:13,自引:1,他引:12
烟草中的烟碱用石灰水浸提。在pH=11的条件下,经三氯乙烯二次萃取,常压蒸馏获得烟碱粗品。再在压力为40~65kPa,温度为160~170℃条件下,减压蒸馏获得天然烟碱,产品含量可达98%以上,收率达687%。 相似文献
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二次萃取蒸馏法提取废次烟叶中烟碱的研究 总被引:4,自引:0,他引:4
采用二次萃取蒸馏法,提取废次烟叶中的烟碱。废次烟叶经过浸提、萃取、硫酸反萃、二次萃取和减压蒸馏等处理以提取烟碱,用紫外分光光度法分析了烟碱含量。结果表明,较佳的工艺条件为:以4.5 g/L的NaOH溶液浸泡粉碎后的烟叶,置于60℃水浴中振荡3.5 h,过滤得浸提液;滤渣再次浸提,并将两次浸提液合并。调节浸提液pH≥13,用正己烷按照体积比1∶2萃取浸提液3次。有机相用20%硫酸溶液反萃,调节pH≥13后,用正己烷二次萃取,合并有机相,减压蒸馏,以回收有机溶剂,残液即为含量40%的烟碱产品,提取率达75%。 相似文献
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Bradley J. Ingebrethsen Cynthia S. Lyman Charles H. Risner Patricia Martin Bert M. Gordon 《Aerosol science and technology》2013,47(5):874-886
The particle-gas equilibria of ammonia and nicotine in mainstream cigarette smoke have been studied by diffusion denuder collection. The surface deposition rate of nicotine is observed to decrease as the smoke traverses the denuder, and this effect is attributed to a changing particle nicotine vapor pressure driven by the measured rapid loss of volatile ammonia from the particles, an interpretation that differs from that of prior studies. The rapid ammonia deposition is observed to be complete at a length-to-flow rate ratio of 28 s/cm 2 for an American blended cigarette, and ~38% of the total ammonia analyzed in the collected smoke appears to be nonvolatile in the aerosol, possibly bound in the particles by reaction with acids. Fitting of a theoretical model that predicts the rapid ammonia loss and changing nicotine vapor pressure to the measurements predicts that the nicotine vapor pressure over the particles in fresh smoke is about 6% of the pure component nicotine value, and the ammonia vapor pressure over the smoke particulate is considerably less than that predicted by its aqueous Henry's law coefficient. Dilution of mainstream smoke enhanced the fractional deposition of both ammonia and nicotine in the denuder tubes and provided a means to estimate the nonvolatile ammonia fraction, which varied considerably in cigarettes made with different tobacco types. Among the different tobacco type cigarettes, smoke ammonia concentration, "smoke pH," and smoke nicotine-to-particulate ratio varied with ammonia and nicotine deposition from diluted smoke when extreme values for an all burley tobacco cigarette were included in the analysis, but no trends were apparent when only the more typical range of the other cigarettes was considered. 相似文献
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流动注射电位法测定烟草中尼古丁的研究 总被引:12,自引:0,他引:12
以聚苯胺修饰的石墨管电极为基体电极,管内涂渍以硅钨酸为活性物质的聚氯乙烯(PVC)膜,构成双膜流通式尼古丁电极,建立了流动注射电位法测定尼古丁的新方法,探讨了实验的最佳条件,用磷酸二氢钠-磷酸氢二钠缓冲溶液合并1.0×10-5mol·L-1的尼古丁标准溶液作载液,对1.0×10-4~1.0×10-1mol·L-1的尼古丁溶液有良好线性响应,相关系数0.9985。本方法简便、选择性好,进样频率80次·h-1,适合大批量样品的快速测定,可用于检测烟草中的尼古丁。 相似文献
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The significance of nicotine in the three trophic level interaction involving tobacco (Nicotiana tabacum), the tobacco hornworm (Manduca sexta), and the parasitoidCotesia congregata was investigated in field plots of two varieties of tobacco which had about a 10-fold difference in their nicotine content. WhileM. sexta mortality, rates of parasitism byC. congregata, and the total number ofC. congregata larvae produced per host were similar on each of the two varieties, the number of parasitoids reaching adult-hood on the low nicotine treatment was nearly twice that on the high nicotine treatment. This difference was due to the significantly greater proportion of parasitoid larvae which failed to emerge from the host or that died prior to pupation after emerging from hosts which fed on the high nicotine variety. A greater proportion of larvae from hosts which fed on the low nicotine tobacco died as pupae. No treatment differences occurred for either sex of the parasitoid in individual dry weight, longevity, or pupal development time, except that female pupal duration was prolonged in the high nicotine treatment. These results support the suggestion that plant allelochemicals, which may function to provide plant resistance against pest herbivores, can be detrimental to natural enemies of the pest.Scientific article No. A4148 of the Maryland Agricultural Experiment Station, Department of Entomology. Research supported by NSF grant BSR-84-00614. 相似文献
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烟碱提取新方法研究 总被引:18,自引:0,他引:18
调节低、次烟叶的含水率,使w(H2O)=12%~13%。在密闭容器中,控制温度540~550℃,使低、次烟叶碳化脱羧。产生的气体和液体用w(H2SO4)=70%的硫酸吸收,可得到w(C10H14N2)=4%左右的硫酸烟碱稀溶液。负压下,将该溶液浓缩至w(C10H14N2)≥20%、用80~100℃的饱和Na2CO3水溶液碱化至无气泡冒出为止,再加入稍过量的Na2SO4·10H2O,使水相形成饱和溶液,密闭、静置24h,即可把烟碱从水相中盐析出来。分出烟碱,在氮气保护下,负压进行两次蒸馏,收集140~148℃/4 0×103Pa馏分,可得w(C10H14N2)=98%以上的烟碱产品,产率在83%以上。提取过程中基本没有三废排放。 相似文献