CaO-SiO2-FeOx及CaO-SiO2-P2O5-FeOx渣系热力学性质的研究

CaO-SiO2-FeOx三元渣系和CaO-SiO2-P2O5-FeOx四元渣系是转炉脱磷用渣的主要子渣系,研究这两种渣系的热力学性质可为脱磷渣的高效利用提供理论依据。利于相图软件FactSage分别绘制了这两种渣系的相图,并分析了温度和氧分压对体系相平衡关系和液相线的影响规律。分析结果表明:升高温度会使这两种渣系的液相区扩大,初晶相稳定区域显著减小;降低氧分压会导致尖晶石固溶体相的初晶区消失,磷石英(SiO2)、伪硅灰石(CaSiO3)、α’-Ca2SiO4固溶体相减小。     

温度和气氛分压对CaO-SiO2-Al2O3-MgO-FetO渣系硫容量的影响

采用气-渣平衡法,用铂坩埚作反应容器,CO-CO2-SO2-N2混合气体提供体系的氧分压和硫分压,测定了一定炉渣成分,不同温度和气氛条件下CaO-SiO2一A12O3一MgO-FetO五元渣系的硫容量.研究得出,对于一定成分组成的CaO-SiO2-A12O3-MgO-FetO五元渣系,当气体流量不变时,硫容量随炉渣温度的升高而减小;当温度一定时,硫容量随体系氧分压增大而增大.     

CaO-SiO2-Al2O3-Fe2O3渣系脱磷行为

利用Factsage软件计算了Al2O3含量对CaO-SiO2-Al2O3-Fe2O3四元渣系熔点和黏度的影响,并通过实验研究了在1 400℃时,CaO-SiO2-Al2O3-Fe2O3四元渣系对高磷铁水脱磷行为的影响.结果表明:渣中Al2O3的质量分数在3％～6％之间时,随着A12O3含量的增加,渣系的熔化温度迅速降低,进一步增加渣中的A12O3含量,渣系的熔化温度逐渐增加;Al2O3对CaO-SiO2-Al2O3-Fe2O3渣系的黏度影响不大;渣中Al2O3的质量分数在3％～6％之间变化时,渣系脱磷能力变化不是很大,脱磷率维持在91％左右,进一步增加渣系中A12O3的量,脱磷率逐渐下降;Al2O3对脱磷率产生影响可能是其改变了炉渣中液相所占比例,进而影响磷从铁水中向液相渣的传质过程.     

基于修正的(NBO/T)比值的黏度模型

针对传统的(NBO/T)比值计算方法在熔渣黏度预报上的不足,研究氧化物对熔渣聚合度的影响规律,修正了(NBO/T)比值的计算方法,计算结果反映了黏度随(NBO/T)比值变化的基本趋势.提出了一个基于修正的(NBO/T)比值的黏度预报模型.利用该模型预报了CaO-SiO2-Al2O3三元系、高炉渣CaO-SiO2-MgO-Al2O3四元系和CaO-SiO2-Al2O3-RO(R2O)体系的黏度值,预报效果比传统的Urbain模型和修改后的Iida模型要好.该模型能有效预报CaO-SiO2-MgO-Al2O3-R2O(K2O或Na2O)体系黏度值.     

帘线钢生产过程中氧化物夹杂的演变规律

 使用ASPEX PSEM explorer研究了帘线钢中氧化物夹杂的成分及形态在炼钢与轧制过程的变化。结果表明,连铸坯夹杂物中SiO2质量分数较中间包有增加趋势,并在铸坯中发现MnO-SiO2-Al2O3和SiO2构成的复合夹杂物,轧制盘条中出现未很好变形的SiO2夹杂物。热力学分析表明：由于连铸过程钢液和夹杂物间的传质作用,导致铸坯夹杂物中SiO2质量分数增加,MnO-SiO2-Al2O3系夹杂在浇铸过程较CaO-SiO2-MnO-Al2O3系夹杂物更易析出SiO2相,形成MnO-SiO2-Al2O3为基体的复合夹杂物。CaO-SiO2-Al2O3-MnO和MnO-SiO2-Al2O3夹杂物在盘条中呈长条状,MnO-SiO2-Al2O3和SiO2析出相构成的复合夹杂在轧制过程将发生相分离,形成“眼睛状”或单颗粒状夹杂。     

Al2O3对铁矿粉烧结液相生成的影响

采用FactSage对不同Al2O3质量分数下CaO-SiO2-FeOx-MgO-Al2O3体系液相区进行热力学分析,并通过液相生成特性试验,研究高岭土型Al2O3和三水铝型Al2O3对CaO-SiO2-FeOx-MgO-Al2O3体系液相生成特性的影响。结果表明,高岭土型Al2O3和三水铝型Al2O3对液相生成特征温度的影响无明显差异,Al2O3质量分数增加,均使液相开始生成温度升高,液相生成温度区间缩小,高熔点黏结相比例增加。液相生成量与Al2O3类型质量分数相关,w(Al2O3)=1.0%时,含三水铝型Al2O3混合料液相生成量较少;w(Al2O3)=2.0%~3.5%时,含高岭土型Al2O3混合料液相生成量较少。     

铝土矿低钙石灰烧结过程热力学分析

通过对CaO-Al2O3、CaO-Al2O3-SiO2、CaO-SiO2、Al2O3-SiO2系的热力学分析,探讨铝土矿低钙石灰烧结过程中的热力学反应规律。结果表明,在烧结温度范围内(1 200～1 400℃),生成CaO.Al2O3和2CaO.Al2O3.SiO2的反应能发生,Al2O3可与SiO2生成Al2O3.SiO2。     

MgO和Al2O3对铁矿粉烧结液相生成的影响

为阐述烧结过程熔融机制和成矿机制,明确MgO、Al2O3质量分数对烧结液相生成和矿物组成的影响是至关重要的。利用Factsage软件计算Fe2O3 SiO2 CaO Al2O3 MgO体系的液相生成,计算氧分压在500Pa时,不同温度,不同MgO、Al2O3质量分数下体系液相生成和液相区分布的影响。通过烧结试验,分析烧结矿的矿相和矿物成分,结合软件计算得出烧结矿中MgO质量分数为2.0%、Al2O3质量分数为3.0%时其液相量、矿相、矿物成分达到最优适合烧结冶炼的标准。     

Zr-Nb-O三元系的热力学优化

综合评估了文献报道的Zr-Nb-O三元系及其子二元系的相图及热力学信息。液相的Gibbs自由能采用离子亚晶格模型描述,固溶体相(α,β)和所有化合物(αZrO2,βZrO2,γZrO2,NbO,NbO2和Nb2O5)的Gibbs自由能都采用双亚晶格模型描述。用CALPHAD(CALculation ofPHAse Diagrams)技术,使用Pandat软件中的PanOptimizer优化模块,对Zr-O二元系进行了热力学优化,计算得到的相图和热力学性质与实验结果相吻合。应用优化的Zr-O二元系模型参数,结合Zr-Nb、Nb-O已有的热力学评估结果,对Zr-Nb-O三元系进行了热力学优化,得到了该体系的一套热力学模型参数。计算了Zr-Nb-O三元系在1273,1473和1773 K温度下的等温截面,与实验数据符合得较好。计算了若干该体系在富Zr区α+ββ的相转变温度,结果和实验测量也能较好地吻合。研究结果对建立多元锆合金热力学数据库,以及指导新型锆基合金材料的成分设计具有重要意义。     

MgO和MnO对CaO-SiO2-Fe2O3-P2O5渣的物相影响

转炉渣中的磷主要存在于n2CaO·SiO2-3CaO·P2O5（以下简记为nC2S-C3P）固溶体的富磷相中。为了深入理解转炉渣的物相,便于有效富集钢渣中的磷,研究MgO和MnO含量的变化对CaO-SiO2-Fe2O3-P2O5渣中nC2S-C3P固溶体的磷含量及渣结晶物相的影响,并对其进行热力学分析。结果表明：在CaO-SiO2-Fe2O3-P2O5四元渣系中加入少量MgO或MnO,可以在一定程度上提高nC2S-C3P固溶体中的磷含量;继续提高MgO或MnO含量,固溶体中的磷含量不再发生变化。随着MgO或MnO的加入,富铁相增多,有利于钢渣的磁选分离。     

低氧分压条件下CaO-SiO_2-P_2O_5(10%)-FeO体系热力学性质的研究

以促进2CaO·SiO_2-3CaO·P_2O_5固溶体生成的非均相脱磷工艺被视为未来实现转炉少渣冶炼的重要手段,但目前相关渣系热力学性质的研究较少,不能为合理解释非均相渣脱磷的机理提供理论依据.为此,本文利用FactSage热力学软件绘制了低氧分压(1mPa)条件下CaO-SiO_2-P_2O_5(10%)-FeO体系及其子体系的热力学相图,分析了不同温度下相平衡关系及液相线的变化规律.研究结果表明:升高温度可使体系中液相区及Ca_3(PO_4)_2初晶区的范围扩大,但会导致α'-Ca_2SiO_4的初晶区缩小以及Ca_2Fe_2O_5等物相的消失;降低氧分压可使体系的液相区缩小,并向高FeO的方向收缩;CaO-SiO_2-P_2O_5(10%)-FeO体系中存在较大的α'-Ca_2SiO_4与Ca_3(PO_4)_2共存区,尤其是α'-Ca_2SiO_4,Ca_3(PO_4)_2与Ca_2Fe_2O_5的三相共存区可极大地促进2CaO·SiO_2-3CaO·P_2O_5固溶体的生成.     

不同碱度低氧化铝精炼渣对弹簧钢夹杂物成分的影响

为了优化55SiCrA弹簧钢中夹杂物的组成和形态,采用热力学软件Factsage分别研究了CaO、SiO_2含量对CaO-SiO_2-Al_2O_3-MgO与CaO-SiO_2-Al_2O_3-MnO系相图低熔点区域面积的影响,研究结果表明:随着CaO和SiO_2含量的增加,CaO-SiO_2-Al_2O_3-MnO系相图低熔点区域面积分数逐步增大;在CaO-SiO_2-Al_2O_3-MgO系中,当CaO的质量分数为40%,SiO_2的质量分数为50%时,对应相图的低熔点区域面积最大。同时,研究了不同碱度的精炼渣对钢样中夹杂物的影响,结果表明:当精炼渣的Al_2O_3含量相同时,随着精炼渣碱度的增大,夹杂物中Al_2O_3的含量不断增加,其成分逐渐偏离低熔点区域。当精炼渣中Al_2O_3的质量分数为8%,碱度为1.2时,可得到低熔点的塑性夹杂物,形貌多为球形,尺寸在5μm以下。     

帘线钢中CaO-SiO2-Al2O3类夹杂物成分的控制

对帘线钢中CaO-SiO2-Al2O3类夹杂物CaO与SiO2的比值和Al2O3含量进行了研究,并且通过热力学计算对CaO-SiO2-Al2O3系塑性夹杂物的生成条件进行了讨论。结果表明：生产帘线钢时,为了得到塑性良好的夹杂物,钢液的氧活度应控制在0．0056～0．0113,而酸溶铝含量应控制在0．00010％～0．00025％范围内。     

Phase Equilibrium for the CaO-SiO₂-FeO-P₂O₅ System at 1673K for Dephosphorization With Multi Phase Flux

Development of the efficient hot metal dephosphorization processes during steelmaking process is one of the most essential topics for the production of high grade clean steels. Since the formation of solid solution composed of tricalcium phosphate and dicalcium silicate could obtain a considerable mass transfer of phosphorus from liquid slag into solid phase during hot metal dephosphorization, itcould obviously sustain a high phosphatecapacityof theliquid slag without huge consumption of lime or addition of fluxes, such as fluorite. The above outlines are the main idea of multi phase flux dephosphorization. For the last few decades, many studies have been done towards the scientific principles and the commercial utilization of this technique. However, the reaction mechanism by using multi phase fluxes remains unclear even by now due tolack of evidence. Based on those previous works, providing a reliable and available phase diagram for the fundamental understanding of the reaction mechanism of multi phase flux dephosphorization has become the main purpose of present research. As well known, the CaO-SiO2-FeO-P2O5 slag is the main component of current steelmaking process. Hence the CaO-SiO2-FeO-P2O5 system at equilibrium has been studied at 1673K with low oxygen partial pressure. The solid phase coexisting with liquid flux is approved to be the solid solution composed of CaO, SiO2 and P2O5. Phosphorus distributes mainly in solid solution rather than liquid phase.     

Viscosity and Structure Changes of CaO-SiO2-Al2 O3-CaF2 Melts with Substituting Al2 O3 for SiO2

During the smelting process of the high Al steels,the reaction between SiO_2 in molten slag and dissolved aluminum in liquid steel always takes place.This aluminathermic reduction reaction will lead to the substitution of 1mol SiO_2 for 2/3mol Al_2O_3.Therefore,the investigations about the influence of the ratio of Al_2O_3 to SiO_2on viscosity and structure changes of mould flux during this process are very necessary.The viscosity variation of CaO-SiO_2-Al_2O_3-CaFv2 melts was studied by changing compositions considering the aluminathermic reduction reaction.It was found that viscosity increased monotonously with gradually increasing the substitution extent.According to the Raman analysis,the substitution of Al_2O_3 for SiO_2 leads to the decrease of non-bridging oxygen but the increase of bridging oxygen.Therefore,degree of polymerization and viscosity increase as the substitution extent increases.By comparing the measured viscosities with the model calculated values,it was found that both the recently developed Zhang′s model and Roboud model could describe the viscosity variation behavior of CaO-SiO_2-Al_2O_3-CaF_2 melts very well.     

Experimental Study on Phosphorus Partitions Between Liquid Iron and Liquid Slags Based on DRI

Metallurgical and Materials Transactions B - Phosphorus partition between liquid iron and CaO-SiO2-MgO-FeOx slags have been investigated experimentally. Fe doped with Fe3P was equilibrated, at 1873...