磁性钙钛矿型氧化物的研究进展

综述了研究钙钛矿型氧化物的一些成果,通过介绍钙钛矿型氧化物的结构、磁电性质,归纳了该系列材料共同遵循的一些特征.分别对研究钙钛矿型氧化物的掺杂方法、主要的合成方法进行了对比,期望阐明研究出该类型材料的有益方法,以获得性能更优异的材料.     

磁性双钙钛矿材料的研究进展

室温下标准双钙钛矿型氧化物Sr2FeMoO6中,10％的隧穿型磁电阻现象的发现,使得这类A2B′B″O6氧化物在磁电阻效应实用化研究的众多候选对象中脱颖而出,引起了人们相当大的关注。本文通过它们与钙钛矿型ABO3氧化物材料的类比,初步回顾了已有A2B′B″O6材料的研究成果,归纳了该系列材料共同遵循的一些特征,并试图阐明对这一大类既有丰富物理内涵,又兼备重要应用前景的双钙钛矿型氧化物材料进行研究的有益方法,以及更深一步进行探索的实验方向和可行的研究途径。     

钙钛矿材料La0.65Ca0.35Mn1-xFexO3的低场磁电阻特性探讨

我们制备了氧化物材料科La0.65Ca0.35Mn1-xFexO3(x=0,0.01,0.02,0.03),研究了材料在低场0.57T下的磁电阻效应,我们发现氧化物材料La0.65Ca0.35Mn1-xFexO3据里温度Tc及电阻峰位温度Tp均值铁含量的增加而下降,这主要是因为Fe离子不参加双交换作用,且阻挡了双交换作用的进行,材料的铁磁作用随铁含量增加而减弱。利用迪尼模型计算了La0.65Ca0.35Mn1-xFexO3材料在零场及磁场为0.57T下电阻随温度的变化关系,理论计算结果与实验数据吻合得较好。     

庞磁电阻材料的研究进展

20世纪自旋电子学的高速发展以及对强关联电子材料的进一步研究使得具有庞磁电阻效应的稀土掺杂锰氧化物成为凝聚态物理和功能材料研究的重要领域。锰氧化物的载流子自旋极化率高，在居里度附近有很大的磁电阻效应，因此在自旋电子学中有潜在应用前景。锰氧化物是典型的强关联电子材料，它对目前有关强关联体系的认识提出了很大挑战。本文介绍了锰氧化物所具有的包括庞磁电阻效应在内的各种效应及其可能的应用。     

NiFe／Co／Cu／Co结构自旋阀GMR效应及Co夹层的影响研究

用射频磁控溅射发射法成功制备了ＮｉＦｅ／Ｃｕ／Ｃｏ自旋阀多层膜材料,改变Ｃｕ层的厚度,研究材料的ＧＭＲ效应与Ｃｕ层厚度的关系,结果表明Ｃｕ为２．５ｎｍ时样品的ＭＲ值最大,其磁电阻效应ＭＲ可达１．６％,在ＮｉＦｅ和Ｃｕ之间插入一Ｃｏ薄夹层,通过对不同温度厚度Ｃｏ夹层的样品的ＭＲ曲线及磁滞回线的研究,讨论了Ｃｏ夹层对样品磁电阻的影响并分析了原因,结果表明插入适当的Ｃｏ层将提高材料的磁电阻效应,可达２．     

自旋电子学的研究现状

自旋电子学主要研究电子自旋在固体物理中的作用,是一门结合磁学与微电子学的新兴交叉学科。本文简单介绍了自旋电子学的概念及其内容,综述了自旋电子学目前的研究,尤其是半导体自旋电子学。最后对自旋电子器件的应用进行了展望。     

半导体自旋电子学功能材料的研究进展

巨磁电阻效应的发现开拓了磁电子学的新领域，20世纪90年代，磁电子学到了迅速的发展，并在实际应用方面取得了显著的经济效益与巨大的社会效益，本世纪初，研究重点已转移到新的半导体自旋电子学方向，并取得了重要进展。本文结合作者率领的科研组的研究工作，阐述了从磁电子学材料到半导体自旋电子学材料的发展概况，其中，重点介绍了稀磁半导体材料的研究进展。     

自旋Seebeck效应实验研究进展

自旋Seebeck效应是自旋热电子学(Spin caloritronics)领域中反映自旋流和热流之间相互作用关系的重要物理现象。它具有重要的科学研究价值和深远的应用前景,得到了国内外相关研究组织的广泛关注。通过对自旋Seebeck效应的研究意义进行简单介绍,重点分析了由热流激发自旋波(自旋流)引起的自旋Seebeck效应的物理机制,并对其探测方法以及现阶段存在的问题进行了着重阐述。     

钙钛矿型锰氧化物相分离研究进展

相分离作为一种物理现象,在钙钛矿结构锰氧化物中普遍存在,成为近年来此领域重要的研究课题之一.介绍了相分离的发展历史、分类,总结了相分离在钙钛矿结构锰氧化物中的实验和理论研究进展,并给出了该领域的发展趋势.     

掺Ag磁性氧化物的庞磁电阻效应

本文重点介绍了掺Ag的钙钛矿锰氧化物和磁铁矿的磁电阻增强效应。结构分析表明，这些材料是由铁磁性的钙钛矿锰氧化物相或亚铁磁性的磁铁矿相与非磁性的金属Ag相所组成的两相复合物。由于金属Ag相的存在，它们的低场磁电阻效应明显增强。这可归因于传导电子在磁性相和非磁性相界面处的自旋相关散射的增强。     

钙钛矿型复合氧化物催化剂中过渡金属离子的状态及其间的相互作用

讨论了Ｂ位二元复下钛矿型复合氧化物ＬａＭｙＭ＇１－ｙＯ３（Ｍ，Ｍ＇＝Ｍｎ，Ｆｅ，Ｃｏ；ｙ＝０．０￣１．０）中过渡金属离子的状态及其间的相互作用。在Ｍｎ－Ｃｏ复合体系中，富锰区（ｙ〉０．５）Ｍｎ＾３＋－Ｏ＾２－－Ｍｎ＾４＋的铁磁超交换作用对样品的磁性起决定作用。富钴区（ｙ〉０．５）Ｃｏ＾２＋和Ｃｏ＾ＩＩＩ离子的存在及其浓度是影响磁性和电导性的主要因素。ｙ＝０．５时样品的结构决定了样品的强铁磁性质。在     

Tailoring Spin State of Perovskite Oxides by Fluorine Atom Doping for Efficient Oxygen Electrocatalysis

Promoting the initially deficient but economical catalysts to high-performing competitors is important for developing superior catalysts. Unlike traditional nano-morphology construction methods, this work focuses on intrinsic catalytic activity enhancement via heteroatom doping strategies to induce lattice distortion and optimize spin-dependent orbital interaction to alter charge transfer between catalysts and reactants. Experimentally, a series of different concentrations of fluorine-doped lanthanum cobaltate (F_x-LaCoO₃) exhibiting excellent electrocatalytic activity is synthesized, including a low overpotential of 390 mV at j = 10 mA cm⁻² for OER and a large half-wave potential of 0.68 V for ORR. Meanwhile, the assembled rechargeable Zn–air batteries deliver an excellent performance with a large specific capacity of 811 mAh/g_Zn under 10 mA cm⁻² and stability of charge/recharge (120 h). Theoretically, taking advantage of density functional theory calculations, it is found that the prominent OER/ORR performance arises from the spin state transition of Co³⁺ (Low spin state (LS, t_2g⁶e_g⁰) → Intermediate spin state (IS, t_2g⁵e_g¹) and the mediated d-band center upshift by F atom incorporation. This work establishes a novel avenue for designing superior electrocatalysts in perovskite-based oxides by regulating spin states.     

Spin Injection and Transport in Magnetic-Superconducting Oxide Heterostructures

Advances in thin film deposition techniques, in particular molecular beam epitaxy, have made it possible to produce bilayer heterostructures of high-temperature superconductors and manganite perovskites. The latter exhibit the phenomenon of colossal magnetoresistance (CMR). The half-metallic character of CMR compounds results in their carriers being spin polarized. The geometry of the structures that have been fabricated is such that it is possible to measure the interface conductance–voltage characteristic G(V) as well as the current–voltage characteristic of the superconducting half of the bilayer. Injection of carriers suppresses superconductivity in the latter, with a current gain of order unity. The data exhibit qualitative features of equilibrium theories of spin-polarized transport across an interface between a ferromagnet and an anisotropic superconductor, although a detailed understanding requires generalization of the theory to include out of equilibrium effects.     

Electron Spin Resonance in Pr0.65Ca0.35MnO3

The magnetic behavior of the distorted perovskite manganese, Pr_0.65Ca_0.35MnO₃ was studied by X-band electron spin resonance for powder samples. We observed the onset of the charge-ordered state at T _CO215 K, the antiferromagnetic transition with the peak of the ESR linewidth, H _p–p at T _AF180 K and the canted antiferromagnetic transition at T _CAF125 K associated with the abrupt increase of both the effective magnetization and H _p–p . Below 90 K, the absorption intensity profile becomes weakened with decreasing temperature suggesting the existence of some kind of magnetic disorder below 90 K, which is responsible for a part of evidence of the existence of the spin-glass state as has been proposed by Yoshizawa et al., Phys. Rev. B 52, 1689 (1996).     

锂空气电池用碳纳米管/钴锰氧化物复合电极材料的制备及电化学性能

采用沉淀法合成了不同钴锰含量的碳纳米管(CNTs)/钴锰氧化物纳米复合材料. 利用XRD、SEM、TEM、BET和FT-IR等方法对材料进行了表征, 考察了不同复合材料对锂空气电池放电及充电过程的影响, 同时对循环性能进行了研究. 结果表明: 钴锰比例为4:0与0:4时, 产物为CNTs/Co₃O₄与CNTs/Mn₃O₄, 钴锰比例为3:1、2:2、1:3时, 产物为CNTs/(Co, Mn)(Co, Mn)₂O₄。产物具有良好的分散性能, 氧化物负载在碳管表面, 其中CNTs/Mn₃O₄的分散性能最好。随着锰含量的增加, 电池的放电性能提高, CNTs/Mn₃O₄的放电电压达到2.92 V。随着钴含量的增加, 电池的充电性能提高, 充电电压最低为3.80 V。钴锰比为3:1时的产物充放电过电势(△V)仅为1.05 V, 5次循环后依然保持着良好的放电性能。     

The In Situ Optimization of Spinterface in Polymer Spin Valve by Electronic Phase Separated Oxides

Tailoring the interface between organic semiconductor (OSC) and ferromagnetic (FM) electrodes, that is, the spinterface, offers a promising way to manipulate and optimize the magnetoresistance (MR) ratio of the organic spin valve (OSV) devices. However, the non-destructive in situ regulation method of spinterface is seldom reported, limiting its theoretical research and further application in organic spintronics. (La_2/3Pr_1/3)_5/8Ca_3/8MnO₃ (LPCMO), a recently developed FM material, exhibits a strong electronic phase separation (EPS) property, and can be employed as an effective in situ spinterface adjuster. Herein, we fabricated a LPCMO-based polymer spin valve with a vertical configuration of LPCMO/poly(3-hexylthiophene-2,5-diyl) (P3HT)/Co, and emphasized the important role of LPCMO/P3HT spinterface in MR regulation. A unique competitive spin-scattering mechanism generated by the EPS characteristics of LPCMO inside the polymer spin valve was discovered by abstracting the anomalous non-monotonic MR value as a function of pre-set magnetic field (B_pre) and temperature (T). Particularly, a record-high MR ratio of 93% was achieved in polymer spin valves under optimal conditions. These findings highlight the importance of interdisciplinary research between organic spintronics and EPS oxides and offer a novel scenario for multi-level storage via spinterface manipulation.     

Magnetocaloric and Colossal Magnetoresistance Effect in Layered Perovskite La1:4Sr 1:6Mn2O7

Magnetocaloric and colossal magnetoresistance effects of the layered perovskite La_1:4Sr_1:6Mn₂O₇ compound have been studied. A broad peak of magnetic entropy change (-ΔS_M) is found above the Curie temperature (T_C=120 K), which can be associated with the existence of two-dimensional short range ferromagnetic order. Additionally, the curvilinear shape of -ΔS_M for layered perovskite is quite different from that of the Ln_1-xA_xMnO₃ probably arising from magnetocrystalline anisotropy. At the same time, a wide peak of colossal magnetoresitance effect near T_C is found in the layered provskite La_1:4Sr_1:6Mn₂O₇.     

La—Na—Mn—O纳米颗粒的磁卡效应

用溶胶－凝胶法制备了Ｌａ１－ｘＮａｘＭｎＯｚ多晶纳米颗粒。用结构分析,程序升温还原及磁性测量等方法研究限样品的结构和磁卡效应。结果表明,样品的居里温度ＴＣｎ－Ｏ键长有密切的联系,这些材料在低磁场下在室温附近较大的温度范围内具有相当大的磁熵变,是较为理想的室温磁致冷工作物质。     

复合相结构钙钛矿锰氧化物低场磁电阻效应

阐述了低场磁电阻及其产生的物理机制,综述了国内外近年来在复合相钙钛矿锰氧化物低场磁电阻增强这一研究领域的进展及其存在的问题.在母相中添加第二相物质形成复合相结构是低场增强磁电阻最简单和有效的方法.结合实践需要和自身研究结果提出制备复合相钙钛矿锰氧化物的新方法,即粘接法,用此方法制备出的复相材料具有很好的应用潜力.