共查询到20条相似文献,搜索用时 187 毫秒
1.
《精细化工原料及中间体》2014,(9)
正紫外线吸收剂是光稳定剂中一类重要品种。其中,苯并三唑类紫外线吸收剂具有性能稳定,毒性低,吸收紫外线能力强,能够抑制或减弱光降解作用,提高合成材料的耐光性能,与高分子材料相容性好,广泛地应用于聚烯烃、聚酯树脂、涂料、食品包装、感光材料等各种合成材料制品中。苯并三唑类紫外线吸收剂的合成方法是:重氮化、偶合、还原。前两步是较成熟的工艺,而还原方法有很多种。还原剂有:锌粉、氢气、葡萄糖、醇类、甲醛、聚甲醛、 相似文献
2.
《精细化工原料及中间体》2010,(3)
紫外线吸收剂是光稳定剂中一类重要品种。其中,苯并三唑类紫外线吸收剂具有性能稳定,毒性低,吸收紫外线能力强,能够抑制或减弱光降解作用,提高合成材料的耐光性能,与高分子材料相容性好,广泛地应用于聚烯烃、聚酯树脂、涂料、食品包装、感光材料等各种合成材料制品中。 相似文献
3.
苯并三唑类紫外线吸收剂的研究进展 总被引:3,自引:0,他引:3
论述了应用最广泛的紫外线吸收剂苯并三唑类化合物在提高消光系数、引入可聚合基团以及和其它光稳定剂如受阻胺光稳定剂的协同作用等方面的研究进展。 相似文献
4.
5.
通过考察老化前后色差的变化,研究了耐候剂、色粉、橡胶种类对ASA树脂耐候性的影响。结果表明,受阻胺光稳定剂的加入明显提高了ASA树脂的耐候性,复配苯并三唑类紫外线吸收剂,耐候性可进一步提升。黑色和白色ASA耐候性相对更好,而红色的ASA则由于有机色粉的迁移析出,耐候性较差。AES高胶粉的加入对ASA改性材料的耐候性影响很小,ABS高胶粉的加入在短期内对ASA改性材料的耐候性影响不大,但对其中长期耐候性影响较明显。通过对比表面显微IR谱图,发现ASA树脂老化变色主要是由于生成了含羰基的芳酮等有色基团所致。 相似文献
6.
以阻燃聚碳酸酯材料为研究对象,探讨了不同种类抗冲击改性剂、不同种类阻燃剂、不同种类紫外线吸收剂、不同种类抗水解助剂对阻燃聚碳酸酯材料耐候性能的影响。结果表明:添加以硅橡胶为核的MSiA抗冲击改性剂的阻燃聚碳酸酯材料耐光性能和耐水性能均最好;添加磷腈类阻燃剂SPB-100的阻燃聚碳酸酯材料耐光性能与耐水性能均最好;添加氰基丙烯酸酯类紫外线吸收剂Uvinul 3030的阻燃聚碳酸酯材料耐光性能最好;添加聚合碳化二亚胺抗水解剂Stabaxol P100的阻燃聚碳酸酯材料耐水性能最好。 相似文献
7.
介绍苯并三唑类紫外线吸收剂当前发展概况及其改性品种,指出该领域正向着高分子质量、多功能化和反应性化方面发展,其中一些品种已工业化并且用于塑料工业.同时,还详细介绍了苯并三唑类紫外线吸收剂的合成方法. 相似文献
8.
9.
10.
11.
Warren B. Blumenthal 《Polymer Engineering and Science》1974,14(11):754-759
Zirconium compounds dispersed in polymers often bond the polymer molecules together, increasing their stability. This can generally be attributed to the formation of covalent bonds between zirconium atoms and small atoms of high electronegativity of the polymer molecule, to overlapping of pi orbitals of unsaturated moieties of the organic compound with sigma orbitals of the zirconium atoms, to fractional bond formation between zirconium and organic hydrogen, and to combinations of these. Bonding and its effects on physical properties have been achieved by molecular dispersions of zirconium compounds in the polymer, by dispersion of insoluble particles of zirconium compounds, and through residues from zirconium catalysts used in polymer preparation. Coatings and plastic components have been improved in strength and in durability by the dispersions. Compounds of other metals often perform similarly. The totality of relevant properties of zirconium compounds often leads to their preferential use. 相似文献
12.
Synthesis of some symmetrically substituted stilbene‐triazine derivatives containing tetramethylenepiperidine fragments and their application to make self‐whitening polyacrylonitrile
下载免费PDF全文
![点击此处可从《Coloration Technology》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Polya Miladinova 《Coloration Technology》2015,131(4):272-278
This study reports the synthesis of nine new fluorescent stilbene‐triazine whitening agents containing a tetramethylpiperidine fragment. These products were isolated and characterised by spectroscopic techniques, i.e. infrared, ultraviolet, and fluorescent spectra, and confirmed by proton nuclear magnetic resonance spectroscopy. The photostability of the new compounds and two optical brighteners containing an unsaturated group without a stabiliser fragment was studied. It was found that the compounds containing tetramethylpiperidine have better photostability. The possibility of the copolymerisation of the unsaturated compounds with acrylonitrile was investigated, and self‐whitening polymers with an intense blue fluorescence were obtained. It was established that 85–86% of the fluorophores are chemically bound to the polymer chain. 相似文献
13.
In polymeric composites, reactive functional groups on the fiber surface are assumed to enhance the mechanical strength of the fiber-matrix interface greatly by forming covalent bonds with the matrix. To test this assumption, we sought to promote covalent bonding at the aramid fiber-epoxy matrix interface by attaching flexible reactive pendent groups to the fiber surface. Other factors that could affect interfacial adhesion were kept constant, i.e., surface energy and surface topography. Quantitative analysis showed a pendent group attachment level of 1.5 to 4.5 groups per 100 Å2 of fiber surface, a level that agrees well with the theoretical amount. Surprisingly, in adhesive performance tests, the presence of these reactive pendent groups did not improve the fiber-matrix interface strength. Specific chemical tests for covalent bond formation between the terminal amine of the pendent group and the epoxy molecule showed that covalent bonding did not occur, thus explaining the unexpected lack of improvement in adhesive performance. 相似文献
14.
15.
Bingtao Tang Shufen Zhang Jinzong Yang Yanfeng Tang Jian Huang 《Coloration Technology》2004,120(4):180-183
A polymeric dye was synthesised via the reaction of 2,4-dinitrochlorobenzene and polyallylamine prepared from the homopolymerisation of monoallylammonium chloride. The polymeric dye was fixed to cotton and silk via a crosslinking agent [2-chloro-4,6-di(aminobenzene-4'-β-sulphatoethylsulphone)-1,3,5- s -triazine]. The fixation of this polymeric dye reached 99% and the dyeing was fast to dimethylformamide at the boil, indicating that the dye fixation was through covalent bonding with the crosslinking agent, which acted as a bridge between the fibre polymer and the dye molecule. The dyed samples showed excellent fastness to washing and rubbing. 相似文献
16.
Summary Polymerizable 2(2-hydroxyphenyl)2H-benzotriazole ultraviolet absorbers have the normal hydrogen bonded maximum at 340 nm. When more than one ortho-hydroxy group capable of hygen bonding is present in the molecule the extinction coefficient increases dramatically; the fluorescence spectra are also affected. It is expected that these compounds are very effective ultraviolet stabilizers.Functional Polymers. LIV., G.S. Dai, S.K. Wu, A. Sustic, F. Xi, and O. Vogl, Polymer Bulletin 20, 67 (1988) 相似文献
17.
The mechanical force to polymeric materials in vacuum at 77 K produces mechano radicals, mechano anions and mechano cations due to homogeneous and heterogeneous scissions of the covalent bonds comprising polymer main chain. The ionic degree of the covalent bond was estimated by calculating the “absolute ΔMulliken atomic charge,” which was defined as the difference between the Mulliken atomic charges of the two adjacent atoms comprising the covalent bond of the polymer main chain. The ionic yield of the covalent bond increased with increasing the absolute ΔMulliken atomic charge. The empirical formula for the ionic yield was obtained with the absolute ΔMulliken atomic charge, and indicates that the ionic yield could be estimated from its chemical structure. 相似文献
18.
Aurore Olivier Franck MeyerJean-Marie Raquez Pascal DammanPhilippe Dubois 《Progress in Polymer Science》2012,37(1):157-181
Surface-functionalization mediated through “grafting from” methods is of considerable interest as means to tailor the chemical and physical properties of functional substrates in a reliable way. The resulting polymer brushes, obtained by a “grafting from” strategy, are composed of grafted polymer chains tethered from one of their extremities to a surface by a covalent bond. Tuning the molecular parameters of these polymeric brushes such as the nature of monomer, the grafting density, and the chain length as well as the design of micropatterned structures enables delicate modification of the properties of these substrates, paving the way to the development of functional surfaces. In this review, we highlight recent and most important approaches to form monolayers and to subsequently elaborate homogeneous and heterogeneous coatings of polymer brushes by surface-initiated polymerization. The control of initiator molecule assembly is particularly important for the final configuration of polymer brushes. We report the creation of homopolymers and block copolymers using major controlled polymerization techniques as well as lithographic techniques aiming at the design of polymeric (micro- or nano-) patterns. 相似文献
19.
以酯基间有2~6个碳原子的聚酯二元醇(CMA-24、CMA-44、CMA-254、CMA-66)、甲苯二异氰酸酯和扩链剂3,5-二甲硫基甲苯二胺(DMTDA)为原材料,通过预聚体法制备了一种耐水解聚酯型聚氨酯弹性体。探讨了水解稳定剂、防酶剂、紫外线吸收剂和抗氧剂等助剂对聚氨酯弹性体性能的影响,测定了耐水解聚酯型聚氨酯弹性体的耐湿热老化和耐海水性能。结果表明,通过添加适量的水解稳定剂、防霉剂、紫外线吸收剂和抗氧剂可大幅度提高聚酯型聚氨酯弹性体的耐湿热老化和耐紫外线老化性能,特别是耐海水性能较传统的聚酯型聚氨酯弹性体提高了5倍以上。 相似文献
20.
Solvatochromic merocyanine dyes were immobilized onto polymer surfaces and copolymerized with acrylic resins, yielding novel reversibly solvatochromic polymers, which were used as solvent polarity indicators that exhibited different colors in water and alcohols. To generate solvatochromic polymer for solvent polarity indication, two solvatochromic merocyanine dyes containing moieties, which allow their immobilization onto polymer surfaces, or copolymerization with acrylic and vinyl monomers, were sequentially synthesized in four and six steps. Merocyanine dye (E)‐2‐(2‐(1‐(6‐aminohexyl)pyridinium‐4‐yl)vinyl)‐4,6‐dichlorophenolate (AHPVD) was prepared with a terminal aminohexyl group which allowed covalent bonding to activated carboxylated or sulfonated polymeric materials. The dyes were covalently bonded to the polymer surfaces, such as, nylon, polycarbonate, polyethylene terephthalate, and silicone. Solvatochromic merocyanine dye (E)‐2‐(2‐(1‐(6‐acrylamidohexyl)pyridinium‐4‐yl)vinyl)‐4,6‐dichlorophenolate (AAPVD) was synthesized for radical copolymerization with acrylate and vinyl monomers and oligomers. Side‐chain solvatochromic merocyanine‐containing hydrophilic polymers with differential water and alcohol absorption were obtained upon photoinitiated radical copolymerization with specially formulated acrylated resins. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44451. 相似文献