Reducing life cycle greenhouse gas emissions of corn ethanol by integrating biomass to produce heat and power at ethanol plants

A life-cycle assessment (LCA) of corn ethanol was conducted to determine the reduction in the life-cycle greenhouse gas (GHG) emissions for corn ethanol compared to gasoline by integrating biomass fuels to replace fossil fuels (natural gas and grid electricity) in a U.S. Midwest dry-grind corn ethanol plant producing 0.19 hm³ y⁻¹ of denatured ethanol. The biomass fuels studied are corn stover and ethanol co-products [dried distillers grains with solubles (DDGS), and syrup (solubles portion of DDGS)]. The biomass conversion technologies/systems considered are process heat (PH) only systems, combined heat and power (CHP) systems, and biomass integrated gasification combined cycle (BIGCC) systems. The life-cycle GHG emission reduction for corn ethanol compared to gasoline is 38.9% for PH with natural gas, 57.7% for PH with corn stover, 79.1% for CHP with corn stover, 78.2% for IGCC with natural gas, 119.0% for BIGCC with corn stover, and 111.4% for BIGCC with syrup and stover. These GHG emission estimates do not include indirect land use change effects. GHG emission reductions for CHP, IGCC, and BIGCC include power sent to the grid which replaces electricity from coal. BIGCC results in greater reductions in GHG emissions than IGCC with natural gas because biomass is substituted for fossil fuels. In addition, underground sequestration of CO₂ gas from the ethanol plant’s fermentation tank could further reduce the life-cycle GHG emission for corn ethanol by 32% compared to gasoline.     

Techno-economic analysis of using corn stover to supply heat and power to a corn ethanol plant – Part 2: Cost of heat and power generation systems

This paper presents a techno-economic analysis of corn stover fired process heating (PH) and the combined heat and power (CHP) generation systems for a typical corn ethanol plant (ethanol production capacity of 170 dam³). Discounted cash flow method was used to estimate both the capital and operating costs of each system and compared with the existing natural gas fired heating system. Environmental impact assessment of using corn stover, coal and natural gas in the heat and/or power generation systems was also evaluated. Coal fired process heating (PH) system had the lowest annual operating cost due to the low fuel cost, but had the highest environmental and human toxicity impacts. The proposed combined heat and power (CHP) generation system required about 137 Gg of corn stover to generate 9.5 MW of electricity and 52.3 MW of process heat with an overall CHP efficiency of 83.3%. Stover fired CHP system would generate an annual savings of 3.6 M$ with an payback period of 6 y. Economics of the coal fired CHP system was very attractive compared to the stover fired CHP system due to lower fuel cost. But the greenhouse gas emissions per Mg of fuel for the coal fired CHP system was 32 times higher than that of stover fired CHP system. Corn stover fired heat and power generation system for a corn ethanol plant can improve the net energy balance and add environmental benefits to the corn to ethanol biorefinery.     

Thermal gasification or direct combustion? Comparison of advanced cogeneration systems in the sugarcane industry

We compare different cogeneration system scenarios for efficient energy production from bagasse fuel in an Indonesian sugar and ethanol factory. These scenarios include the use of condensing-extraction steam turbines, variable speed electric drives for process equipment, measures to reduce low pressure steam demand for process needs, and two advanced cogeneration systems. One advanced system includes an 80 bar high pressure direct combustion steam Rankine cycle (advanced SRC), while the other uses a biomass integrated gasifier combined cycle (BIGCC); both utilize fuel dryers. Using steady-state thermodynamic models, we estimate that the net electricity generation potentials of the BIGCC and advanced SRC systems are approximately seven and five times the potential of the existing factory, respectively. The maximum net electricity generation potentials for the respective systems are 170 kWh/tc (BIGCC) and 140 kWh/tc (advanced SRC). However, the BIGCC system needs a bagasse feed rate that is 50 percent higher than the advanced SRC system to satisfy the factory low pressure steam demand for sugar and ethanol processing, which may affect its ability to provide steam and electricity during the off-season. For the Indonesian sugar factory, the annual revenue potential of the BIGCC system is US$14 million per year, approximately 50 percent higher than that of the advanced SRC system (electricity sale rate: US$45/MsWh; carbon credit price: US$13.60). BIGCC technology is still in an early stage of development and there are no commercial systems in sugar factories, so an advanced SRC system may be a more suitable option in the near future.     

Performance and cost assessment of Integrated Solar Combined Cycle Systems (ISCCSs) using CO2 as heat transfer fluid

In this paper, a performance and cost assessment of Integrated Solar Combined Cycle Systems (ISCCSs) based on parabolic troughs using CO₂ as heat transfer fluid is reported on. The use of CO₂ instead of the more conventional thermal oil as heat transfer fluid allows an increase in the temperature of the heat transfer fluid and thus in solar energy conversion efficiency. In particular, the ISCCS plant considered here was developed on the basis of a triple-pressure, reheated combined cycle power plant rated about 250 MW. Two different solutions for the solar steam generator are considered and compared.The results of the performance assessment show that the solar energy conversion efficiency ranges from 23% to 25% for a CO₂ maximum temperature of 550 °C. For a CO₂ temperature of 450 °C, solar efficiency decreases by about 1.5–2.0% points. The use of a solar steam generator including only the evaporation section instead of the preheating, evaporation and superheating sections allows the achievement of slightly better conversion efficiencies. However, the adoption of this solution leads to a maximum value of the solar share of around 10% on the ISCCS power output. The solar conversion efficiencies of the ISCCS systems considered here are slightly greater than those of the more conventional Concentrating Solar Power (CSP) systems based on steam cycles (20–23%) and are very similar to the predicted conversion efficiencies of the more advanced direct steam generation solar plants (22–27%).The results of a preliminary cost analysis show that due to the installation of the solar field, the electrical energy production cost for ISCCS power plants increases in comparison to the natural gas combined cycle (NGCC). In particular, the specific cost of electrical energy produced from solar energy is much greater (about two-fold) than that of electrical energy produced from natural gas.     

A criterion for selecting renewable energy processes

We propose that minimum incremental cost per unit of greenhouse gas (GHG) reduction, in essence the carbon credit required to economically sustain a renewable energy plant, is the most appropriate social criterion for choosing from a myriad of alternatives. The application of this criterion is illustrated for four processing alternatives for straw/corn stover: production of power by direct combustion and biomass integrated gasification and combined cycle (BIGCC), and production of transportation fuel via lignocellulosic ethanol and Fischer Tropsch (FT) syndiesel. Ethanol requires a lower carbon credit than FT, and direct combustion a lower credit than BIGCC. For comparing processes that make a different form of end use energy, in this study ethanol vs. electrical power via direct combustion, the lowest carbon credit depends on the relative values of the two energy forms. When power is 70$ MW h^?1, ethanol production has a lower required carbon credit at oil prices greater than 600$ t^?1 (80$ bbl^?1).     

Improving bioethanol production from sugarcane: evaluation of distillation, thermal integration and cogeneration systems

Demand for bioethanol has grown considerably over the last years. Even though Brazil has been producing ethanol from sugarcane on a large scale for decades, this industry is characterized by low energy efficiency, using a large fraction of the bagasse produced as fuel in the cogeneration system to supply the process energy requirements. The possibility of selling surplus electricity to the grid or using surplus bagasse as raw material of other processes has motivated investments on more efficient cogeneration systems and process thermal integration. In this work simulations of an autonomous distillery were carried out, along with utilities demand optimization using Pinch Analysis concepts. Different cogeneration systems were analyzed: a traditional Rankine Cycle, with steam of high temperature and pressure (80 bar, 510 °C) and back pressure and condensing steam turbines configuration, and a BIGCC (Biomass Integrated Gasification Combined Cycle), comprised by a gas turbine set operating with biomass gas produced in a gasifier that uses sugarcane bagasse as raw material. Thermoeconomic analyses determining exergy-based costs of electricity and ethanol for both cases were carried out. The main objective is to show the impact that these process improvements can produce in industrial systems, compared to the current situation.     

Fuel-cycle analysis of early market applications of fuel cells: Forklift propulsion systems and distributed power generation

Forklift propulsion systems and distributed power generation are identified as potential fuel cell applications for near-term markets. This analysis examines fuel cell forklifts and distributed power generators, and addresses the potential energy and environmental implications of substituting fuel-cell systems for existing technologies based on fossil fuels and grid electricity. Performance data and the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model are used to estimate full fuel-cycle emissions and use of primary energy sources. The greenhouse gas (GHG) impacts of fuel-cell forklifts using hydrogen from steam reforming of natural gas are considerably lower than those using electricity from the average U.S. grid. Fuel cell generators produce lower GHG emissions than those associated with the U.S. grid electricity and alternative distributed combustion technologies. If fuel-cell generation technologies approach or exceed the target efficiency of 40%, they offer significant reduction in energy use and GHG emissions compared to alternative combustion technologies.     

Techno-economic and environmental assessment of integrating SOFC with a conventional steam and power system in a natural gas processing plant

Solid oxide fuel cell (SOFC) technology has been proven to be a highly efficient electrochemical device that directly converts chemical energy into electrical energy with a potential to increase system efficiencies and to significantly reduce emissions in oil and gas operations. Enabling an effective integration and smarter utilization of SOFC systems at different scales and point-of-use can lead to an overall system efficiency improvement. In this research paper, two case studies, including the steam and power system in a gas plant, are considered for comparative analysis purposes. The first case study, base case, is a traditional steam and power system in a natural gas processing plant and the proposed case is the combined steam and power system with SOFC unit. Techno-economic and environmental analyses are performed for both cases. To carry out a comparative analysis, the power output of both cases is fixed at 20 MW. The results of this study show that a reduction of almost 35% in the emissions is possible and the cost of electricity becomes about 25% less for the proposed case.     

The role of policy instruments for promoting combined heat and power production with low CO2 emissions in district heating systems

Policy instruments clearly influence the choice of production technologies and fuels in large energy systems, including district heating networks. Current Swedish policy instruments aim at promoting the use of biofuel in district heating systems, and at promoting electric power generation from renewable energy sources. However, there is increasing pressure to harmonize energy policy instruments within the EU. In addition, natural gas based combined cycle technology has emerged as the technology of choice in the power generation sector in the EU. This study aims at exploring the role of policy instruments for promoting the use of low CO₂ emissions fuels in high performance combined heat and power systems in the district heating sector. The paper presents the results of a case study for a Swedish district heating network where new large size natural gas combined cycle (NGCC) combined heat and power (CHP) is being built. Given the aim of current Swedish energy policy, it is assumed that it could be of interest in the future to integrate a biofuel gasifier to the CHP plant and co‐fire the gasified biofuel in the gas turbine unit, thereby reducing usage of fossil fuel. The goals of the study are to evaluate which policy instruments promote construction of the planned NGCC CHP unit, the technical performance of an integrated biofuelled pressurized gasifier with or without dryer on plant site, and which combination of policy instruments promote integration of a biofuel gasifier to the planned CHP unit. The power plant simulation program GateCycle was used for plant performance evaluation. The results show that current Swedish energy policy instruments favour investing in the NGCC CHP unit. The corresponding cost of electricity (COE) from the NGCC CHP unit is estimated at 253 SEK MWh^?1, which is lower than the reference power price of 284 SEK MWh^?1. Investing in the NGCC CHP unit is also shown to be attractive if a CO₂ trading system is implemented. If the value of tradable emission permits (TEP) in such as system is 250 SEK tonne^?1, COE is 353 SEK MWh^?1 compared to the reference power price of 384 SEK MWh^?1. It is possible to integrate a pressurized biofuel gasifier to the NGCC CHP plant without any major re‐design of the combined cycle provided that the maximum degree of co‐firing is limited to 27–38% (energy basis) product gas, depending on the design of the gasifier system. There are many parameters that affect the economic performance of an integrated biofuel gasifier for product gas co‐firing of a NGCC CHP plant. The premium value of the co‐generated renewable electricity and the value of TEPs are very important parameters. Assuming a future CO₂ trading system with a TEP value of 250 SEK tonne^?1 and a premium value of renewable electricity of 200 SEK MWh^?1 COE from a CHP plant with an integrated biofuelled gasifier could be 336 SEK MWh^?1, which is lower than both the reference market electric power price and COE for the plant operating on natural gas alone. Copyright © 2005 John Wiley & Sons, Ltd.     

Monetary value of the environmental and health externalities associated with production of ethanol from biomass feedstocks

This research is aimed at monetizing the life cycle environmental and health externalities associated with production of ethanol from corn, corn stover, switchgrass, and forest residue. The results of this study reveal current average external costs for the production of 1 l of ethanol ranged from $0.07 for forest residue to $0.57 for ethanol production from corn. Among the various feedstocks, the external costs of PM₁₀, NO_X, and PM_2.5 are among the greatest contributors to these costs. The combustion of fossil fuels in upstream fertilizer and energy production processes is the primary source of these emissions and their costs, especially for corn ethanol. The combined costs of emissions associated with the production and use of nitrogen fertilizer also contribute substantially to the net external costs. For cellulosic ethanol production, the combustion of waste lignin to generate heat and power helps to keep the external costs lower than corn ethanol. Credits both for the biogenic carbon combustion and displacement of grid electricity by exporting excess electricity substantially negate many of the emissions and external costs. External costs associated with greenhouse gas emissions were not significant. However, adding estimates of indirect GHG emissions from land use changes would nearly double corn ethanol cost estimates.     

Baseload electricity from wind via compressed air energy storage (CAES)

This study investigates two methods of transforming intermittent wind electricity into firm baseload capacity: (1) using electricity from natural gas combined-cycle (NGCC) power plants and (2) using electricity from compressed air energy storage (CAES) power plants. The two wind models are compared in terms of capital and electricity costs, CO₂ emissions, and fuel consumption rates. The findings indicate that the combination of wind and NGCC power plants is the lowest-cost method of transforming wind electricity into firm baseload capacity power supply at current natural gas prices (∼$6/GJ). However, the electricity supplied by wind and CAES power plants becomes economically competitive when the cost of natural gas for electric producers is $10.55/GJ or greater. In addition, the Wind-CAES system has the lowest CO₂ emissions (93% and 71% lower than pulverized coal power plants and Wind-NGCC, respectively) and the lowest fuel consumption rates (9 and 4 times lower than pulverized coal power plants and Wind-NGCC, respectively). As such, the large-scale introduction of Wind-CAES systems in the U.S. appears to be the prudent long-term choice once natural gas price volatility, costs, and climate impacts are all considered.     

Conversion of fossil and biomass fuels to electric power and transportation fuels by high efficiency integrated plasma fuel cell (IPFC) energy cycle

The IPFC is a high efficiency energy cycle, which converts fossil and biomass fuel to electricity and co-product hydrogen and liquid transportation fuels (gasoline and diesel). The cycle consists of two basic units, a hydrogen plasma black reactor (HPBR) which converts the carbonaceous fuel feedstock to elemental carbon and hydrogen and CO gas. The carbon is used as fuel in a direct carbon fuel cell (DCFC), which generates electricity, a small part of which is used to power the plasma reactor. The gases are cleaned and water gas shifted for either hydrogen or syngas formation. The hydrogen is separated for production or the syngas is catalytically converted in a Fischer–Tropsch (F–T) reactor to gasoline and/or diesel fuel. Based on the demonstrated efficiencies of each of the component reactors, the overall IPFC thermal efficiency for electricity and hydrogen or transportation fuel is estimated to vary from 70 to 90% depending on the feedstock and the co-product gas or liquid fuel produced. The CO₂ emissions are proportionately reduced and are in concentrated streams directly ready for sequestration. Preliminary cost estimates indicate that IPFC is highly competitive with respect to conventional integrated combined cycle plants (NGCC and IGCC) for production of electricity and hydrogen and transportation fuels.     

Evaluating fuel ethanol feedstocks from energy policy perspectives: A comparative energy assessment of corn and corn stover

Concerns surrounding the continued, un-checked use of petroleum-based fuels in the transportation sector, the search for more sustainable, renewable alternatives, and the constraints of the existing supply infrastructure in the United States have placed a spotlight on biomass-derived fuels. The central question of the ethanol debate has changed from “Should we make ethanol?” to “From what should we make ethanol?” emphasizing the importance of understanding the differences between specific biomass supply systems for fuel ethanol. When presented with numerous options, the priorities of an individual decision maker will define which feedstock alternative is the most appropriate choice for development from their perspective. This paper demonstrates how energy data can be successfully used to quantify assessment metrics beyond a standard net energy value calculation, thus quantifying the relative “value” of ethanol supply systems. This value is defined based on decision-maker priorities that were adopted from national energy policy priorities: increased national energy security and increased conservation of energy resources. Nine energy assessment metrics that quantify detailed system energy data are calculated and a straightforward comparative assessment is performed between corn and corn stover feedstocks produced under the same farm scenario. Corn stover is shown to be more compatible with the national energy policy priorities and it is recommended that additional research be performed on utilizing this feedstock from the corn farm.     

Hydrogen production from fossil fuels with carbon capture and storage based on chemical looping systems

This paper analyzes innovative processes for producing hydrogen from fossil fuels conversion (natural gas, coal, lignite) based on chemical looping techniques, allowing intrinsic CO₂ capture. This paper evaluates in details the iron-based chemical looping system used for hydrogen production in conjunction with natural gas and syngas produced from coal and lignite gasification. The paper assesses the potential applications of natural gas and syngas chemical looping combustion systems to generate hydrogen. Investigated plant concepts with natural gas and syngas-based chemical looping method produce 500 MW hydrogen (based on lower heating value) covering ancillary power consumption with an almost total decarbonisation rate of the fossil fuels used.The paper presents in details the plant concepts and the methodology used to evaluate the performances using critical design factors like: gasifier feeding system (various fuel transport gases), heat and power integration analysis, potential ways to increase the overall energy efficiency (e.g. steam integration of chemical looping unit into the combined cycle), hydrogen and carbon dioxide quality specifications considering the use of hydrogen in transport (fuel cells) and carbon dioxide storage in geological formation or used for EOR.     

Exploring impacts of process technology development and regional factors on life cycle greenhouse gas emissions of corn stover ethanol

This paper examines impacts of regional factors affecting biomass and process input supply chains and ongoing technology development on the life cycle greenhouse gas (GHG) emissions of ethanol production from corn stover in the U.S. Corn stover supply results in GHG emissions from −6 gCO₂eq./MJ ethanol (Macon County, Missouri) to 13 gCO₂eq./MJ ethanol (Hardin County, Iowa), reflecting location-specific soil carbon and N₂O emissions responses to stover removal. Biorefinery emissions based on the 2011 National Renewable Energy Laboratory (NREL) process model are the single greatest emissions source (18 gCO₂eq./MJ ethanol) and are approximately double those assessed for the 2002 NREL design model, due primarily to the inclusion of GHG-intensive inputs (caustic, ammonia, glucose). Energy demands of on-site enzyme production included in the 2011 design contribute to reducing the electricity co-product and associated emissions credit, which is also dependent on the GHG-intensity of regional electricity supply. Life cycle emissions vary between 1.5 and 22 gCO₂eq./MJ ethanol (2011 design) depending on production location (98%–77% reduction vs. gasoline). Using system expansion for co-product allocation, ethanol production in studied locations meet the Energy Independence and Security Act emissions requirements for cellulosic biofuels; however, regional factors and on-going technology developments significantly influence these results.     

Onboard fuel processor for PEM fuel cell vehicles

To lower vehicle greenhouse gas emissions, many automotive companies are exploring fuel cell technologies, which combine hydrogen and oxygen to produce electricity and water. While hydrogen storage and infrastructure remain issues, Renault and Nuvera Fuel Cells are developing an onboard fuel processor, which can convert a variety of fuels into hydrogen to power these fuel cell vehicles.The fuel processor is now small enough and powerful enough for use on a vehicle. The catalysts and heat exchangers occupy 80 l and can be packaged with balance of plant controls components in a 150-l volume designed to fit under the vehicle. Recent systems can operate on gasoline, ethanol, and methanol with fuel inputs up to 200 kWth and hydrogen efficiencies above 77%. The startup time is now less than 4 min to lower the CO in the hydrogen stream to the target value for the fuel cell.     

Calculation of bright roof-tops for solar PV applications in Dhaka Megacity,Bangladesh

Bangladesh has already been known as the country of power crisis. Although the country's electricity generation capacity is 4275 MW, around 3000–3500 MW of electricity can be generated against the demand of more than 5000 MW. The country's power is being generated mostly with conventional fuel (82% indigenous natural gas, 9% imported oil, 5% coal) and renewable sources (4% hydropower and solar). But recently a remarkable decline of the indigenous gas takes place, which rapidly aggravates electricity generation. Dhaka, the capital as well as prime city of the country with its nearly 14 million populations faces the worst situation due to the shortfall of electricity. Around 1000–1200 MW of electricity is supplied to Dhaka Megacity, while the existing demand is nearly 2000 MW. As a result frequent load shedding takes place and most of the service sectors in the city are interrupted, which has recently created immense dissatisfaction among the city-dwellers. Given the city's power crisis and geophysical situations, applications of either stand-alone or grid connected PV systems would be very effective and pragmatic for power supplement. The conservative calculation of bright roof-tops from the Quickbird Scene 2006 of Dhaka city indicates that the city offers 10.554 km² of bright roof-tops within the Dhaka City Corporation (DCC) ward area (134.282 km²). The application of stand-alone PV systems with 75 Wp solar modules can generate nearly 1000 MW of electrical power, which can substantially meet the city's power demand.     

Electricity generation from corn cob char though a direct carbon solid oxide fuel cell

Solid oxide fuel cell (SOFC) is a potential technology for utilizing biomass to generate electricity with high conversion efficiency and low pollution. Investigations on biomass integrated gasification SOFC system show that gasifier is one of the high cost factors which impede the practical application of such systems. Direct carbon solid oxide fuel cell (DC-SOFC) may provide a cost effective option for electricity generation from biomass because it can operate directly using biochar as the fuel so that the gasification process can be avoided. In this paper, the feasibility of using corn cob char as the fuel of a DC-SOFC to generate electricity is investigated. Electrolyte-supported SOFCs, with yttrium stabilized zirconia (YSZ) as the electrolyte, cermet of silver and gadolinium-doped ceria (GDC) as the anode and the cathode, are prepared and tested with fixed bed corn cob char as fuel and static ambient air as oxidant. The maximum power output of a DC-SOFC operated on pure corn cob char is 204 mW cm⁻² at 800 °C and it achieves 270 mW cm⁻² when Fe of 5% mass fraction, as a catalyst of the Boudouard reaction, is loaded on the corn cob char. The discharging time of the cell with 0.5 g corn cob char operated at a constant current of 0.1 A lasts 17 h, representing a fuel conversion of 38%. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometer (EDS) and Raman spectroscopy have been applied to characterize the char-based fuels.     

Life cycle energy and environmental analysis of a microgrid power pavilion

Microgrids—generating systems incorporating multiple distributed generator sets linked together to provide local electricity and heat—are one possible alterative to the existing centralized energy system. Potential advantages of microgrids include flexibility in fuel supply options, the ability to limit emissions of greenhouse gases, and energy efficiency improvements through combined heat and power (CHP) applications. As a case study in microgrid performance, this analysis uses a life cycle assessment approach to evaluate the energy and emissions performance of the NextEnergy microgrid Power Pavilion in Detroit, Michigan and a reference conventional system. The microgrid includes generator sets fueled by solar energy, hydrogen, and natural gas. Hydrogen fuel is sourced from both a natural gas steam reforming operation and as a by‐product of a chlorine production operation. The chlorine plant receives electricity exclusively from a hydropower generating station. Results indicate that the use of this microgrid offers a total energy reduction potential of up to 38%, while reductions in non‐renewable energy use could reach 51%. Similarly, emissions of CO₂, a key global warming gas, can be reduced by as much as 60% relative to conventional heat and power systems. Hydrogen fuels are shown to provide a net energy and emissions benefit relative to natural gas only when sourced primarily from the chlorine plant. Copyright © 2006 John Wiley & Sons, Ltd.     

Reforming options for hydrogen production from fossil fuels for PEM fuel cells

PEM fuel cell systems are considered as a sustainable option for the future transport sector in the future. There is great interest in converting current hydrocarbon based transportation fuels into hydrogen rich gases acceptable by PEM fuel cells on-board of vehicles. In this paper, we compare the results of our simulation studies for 100 kW PEM fuel cell systems utilizing three different major reforming technologies, namely steam reforming (SREF), partial oxidation (POX) and autothermal reforming (ATR). Natural gas, gasoline and diesel are the selected hydrocarbon fuels. It is desired to investigate the effect of the selected fuel reforming options on the overall fuel cell system efficiency, which depends on the fuel processing, PEM fuel cell and auxiliary system efficiencies. The Aspen-HYSYS 3.1 code has been used for simulation purposes. Process parameters of fuel preparation steps have been determined considering the limitations set by the catalysts and hydrocarbons involved. Results indicate that fuel properties, fuel processing system and its operation parameters, and PEM fuel cell characteristics all affect the overall system efficiencies. Steam reforming appears as the most efficient fuel preparation option for all investigated fuels. Natural gas with steam reforming shows the highest fuel cell system efficiency. Good heat integration within the fuel cell system is absolutely necessary to achieve acceptable overall system efficiencies.