首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 500 毫秒
1.
In this study, artificial neural networks (ANNs) and a nonlinear autoregressive exogenous (NARX) neural network model were employed in order to model a fixed bed downdraft gasification. The relation between the feature group and the regression performance was investigated. First, feature group consists of the equivalence ratio (ER), air flow rate (AF), and temperature distribution (T0‐T5) obtained from the fixed bed downdraft gasifiers, while the second group includes ultimate and proximate values of biomasses, ER, AF, and the reduction temperature (T0). Models constructed to predict the syngas composition (H2, CO2, CO, CH4) and calorific value. Experimental gasification data that involve 3831 data samples that belong to pinecone and wood pellet were used for training the ANNs. Different ANN architecture and NARX time series model have been constructed to examine the prediction accuracy of the models. The results of the ANN models were consistent with the experimental data (R2 > 0.99). The overall score of NARX time series networks is found to be higher than other architecture types. A successful method is proposed to reduce the number of features, and the effect of the features on the prediction capability was examined by calculating the relative importance index using the Garson's equation.  相似文献   

2.
To develop a model for biomass gasification in fluidized bed gasifiers with high accuracy and generality that could be used under various operating conditions, the equilibrium model (EM) is chosen as a general and case-independent modeling method. However, EM lacks sufficient accuracy in predicting the content (volume fraction) of four major components (H2, CO, CO2 and CH4) in product gas. In this paper, three approaches—MODEL I, which restricts equilibrium to a specific temperature (QET method); MODEL II, which uses empirical correlations for carbon, CH4, C2H2, C2H4, C2H6 and NH3 conversion; and MODEL III, which includes kinetic and hydrodynamic equations—have been studied and compared to map the barriers and complexities involved in developing an accurate and generic model for the gasification of biomass.This study indicates that existing empirical correlations can be further improved by considering more experimental data. The updated model features better accuracy in the prediction of product gas composition in a larger range of operating conditions. Additionally, combining the QET method with a kinetic and hydrodynamic approach results in a model that features less overall error than the original model based on a kinetic and hydrodynamic approach.  相似文献   

3.
This work investigates the opportunity of retrofitting existing small-scale gasifiers shifting from combined heat and power (CHP) to hydrogen and biofuels production, using steam and biomass residues (woodchips, vineyard pruning and bark). The experiments were carried out in a batch reactor at 700 °C and 800 °C and at different steam flow (SF) rates (0.04 g/min and 0.20 g/min). The composition of the producer gas is in the range of 46–70 % H2, 9–29 % CO, 12–27 % CO2, and 2–6 % CH4. A producer gas specific production factor of approx. 10 NLpg/gchar can be achieved when the lower SFs are used, which allows to provide 80 % of the hydrogen concentration required for biomethanation and MeOH synthesis. As for FT synthesis, an optimal H2/CO ratio of approx. 2 can be achieved. The results of this work provide further evidence towards the feasibility of hydrogen and biofuels generation from residual biomass through steam gasification.  相似文献   

4.
Biomass as a renewable fuel compared to fossil fuels usually contains high moisture content and volatile release. Hydrogen production by large particle biomass gasification is a promising technology for utilizing high moisture content biomass particle in the high temperature fluidized bed reactor. In the present work, simulation of large particles biomass gasification investigated at high temperature by using the discrete phase model (DPM). Combustible gases with homogeneous gas phase reactions, drying process with a heterogeneous reaction, primary and secondary pyrolysis with independent parallel-reaction by using two-competing-rate model to control a high and low temperature were used. During the thermochemical process of biomass, gaseous products containing of H2, H2O, CH4, CO and CO2 was obtained. The effects of concentration, mole and mass fraction and hydrodynamics effects on gaseous production during gasification were studied. The results showed that hydrodynamic effect of hot bed is different from cold bed. Concentration and molar fraction of CO and H2 production by continually and stably state and small amount of CO2, H2O, and CH4 was obtained. The hydrodynamic of bed plays the significant role on the rate of gaseous products.  相似文献   

5.
The depletion of fossil fuels and the increasing environmental problems, make biomass energy a serious alternative resource of energy. Biomass gasification is one of the major biomass utilization technologies to produce high quality gas. In this paper, biomass gasification was performed in a self-designed fluidized bed. The main factors (equivalence ratio, bed temperature, added catalyst, steam) influenced the gasification process were studied in detail. The results showed that the combustible gas content and the heating value increased with the increase of the temperature, while the CO2 content decreased. The combustible gas content decreased with the increase of the equivalence ratio (ER), but CO2 content increased. At the same temperature and at different ratios of CaO (from 0 to 20%), H2 content was increased significantly, CO content was also increased, CH4 content increased slightly, but CO2 content was decreased. With the addition of steam at different temperature, the gas in combustible components increased, the content of H2 increased obviously. The growth rate was 50% increased. As the bed temperature increased, gas reforming reaction increased, the CO and CH4 content decreased, but CO2 and H2 content increased.  相似文献   

6.
Process simulation and modeling works are very important to determine novel design and operation conditions. In this study; hydrogen production from synthesis gas obtained by gasification of lignocellulosic biomass is investigated. The main motivation of this work is to understand how biomass is converted to hydrogen rich synthesis gas and its environmentally friendly impact. Hydrogen market development in several energy production units such as fuel cells is another motivation to realize these kinds of activities. The initial results can help to contribute to the literature and widen our experience on utilization of the CO2 neutral biomass sources and gasification technology which can develop the design of hydrogen production processes. The raw syngas is obtained via staged gasification of biomass, using bubbling fluidized bed technology with secondary agents; then it is cleaned, its hydrocarbon content is reformed, CO content is shifted (WGS) and finally H2 content is separated by the PSA (Pressure Swing Adsorption) unit. According to the preliminary results of the ASPEN HYSYS conceptual process simulation model; the composition of hydrogen rich gas (0.62% H2O, 38.83% H2, 1.65% CO, 26.13% CO2, 0.08% CH4, and 32.69% N2) has been determined. The first simulation results show that the hydrogen purity of the product gas after PSA unit is 99.999% approximately. The mass lower heating value (LHVmass) of the product gas before PSA unit is expected to be about 4500 kJ/kg and the overall fuel processor efficiency has been calculated as ~93%.  相似文献   

7.
In this work, air gasification of sewage sludge was conducted in a lab-scale bubbling fluidized bed gasifier. Further, the gasification process was modeled using artificial neural networks for the product gas composition with varying temperatures and equivalence ratios. Neural network-based prediction will help to predict the hydrogen production from product gas composition at various temperatures and equivalence ratios. The gasification efficiency and lower heating values were also established as a function of temperatures and equivalence ratios. The maximum H2 and CO was recorded as 16.26 vol% and 33.55 vol%. Intraileally at ER 0.2 gas composition H2, CO, and CH4 show high concentrations of 20.56 vol%, 45.91 vol%, and 13.32 vol%, respectively. At the same time, CO2 was lower as 20.20 vol% at ER 0.2. Therefore, optimum values are suggested for maximum H2 and CO yield and lower concentration of CO2 at ER 0.25 and temperature of 850 °C. A predictive model based on an Artificial Neural network is also developed to predict the hydrogen production from product gas composition at various temperatures and equivalence ratios. The network has been trained with different topologies to find the optimal structure for temperature and equivalence ratio. The obtained results showed that the regression coefficients for training, validation, and testing are 0.99999, 0.99998, and 0.99992, respectively, which clearly identifies the training efficiency of the trained model.  相似文献   

8.
A semi-batch fluidized-bed gasifier was used to investigate the experimental gasification process of olive bagasse particles, an olive oil industry residue. The effect of bed temperature was studied, in the range of 750 to 900 °C. The oxidant agent was air, fed at constant flowrate, and sand particles were used as bed material. The bagasse particles used had diameters within 1.25–2 mm and the biomass was characterized in terms of its higher heating value and ultimate analysis. During each run, several gaseous samples were collected to be further analysed by gas chromatography allowing the quantification of CO, CO2, H2, CH4, O2 and N2. The reaction mechanism of the gasification process is determinant on the composition of the producer gas. Experimental results showed that higher bed temperatures favoured gas production as well as other gasification performance parameters. Best results were obtained for a bed temperature of 850 °C.  相似文献   

9.
Plasma methods are given significant attention in the context of conditioning the producer gas derived from biomass gasification. The goal of this work is to present the impact of hydrogen on the other producer gas compounds during microwave plasma valorization. These compounds include main producer gas components (CO, CO2, CH4, N2) and minor impurities (tar compounds, H2S and NH3). The results prove a beneficial impact of hydrogen addition on the conversion of CH4 and toluene, increasing it from ca. 68%–95% and ca. 97%–100%, respectively. Additionally, the presence of hydrogen changes the distribution of the products, inhibiting soot and aromatics production and promoting C2 compounds. In the case of CO2, the conversion increases from ca. 18%–63% when compared to nitrogen plasma, with CO being the resulting product. The presence of hydrogen inhibits H2S conversion and does not affect CO and NH3  相似文献   

10.
This work presents a method for modeling the gas composition in a Reformed Methanol Fuel Cell system. The method is based on Adaptive Neuro-Fuzzy-Inference-Systems which are trained on experimental data. The developed models are of the H2, CO2, CO and CH3OH mass flows of the reformed gas. The ANFIS models are able to predict the mass flows with mean absolute errors for the H2 and CO2 models of less than 1% and 6.37% for the CO model and 4.56% for the CH3OH model.  相似文献   

11.
Experiments were carried out to study the characteristics of biomass gasification in a fluidized bed using industrial sand and porous medium as bed materials. Analysis was conducted to investigate the effects of different operation parameters, including bed material, gasification temperature (600 °C–900 °C), oxygen enrichment in the gasifying agent (21 vol.% to 50 vol.%), and steam flow rate (1.08 kg/h to 2.10 kg/h), on product yields and gas composition. The results of gas chromatography show that the main generated gas species were H2, CO, CO2, CH4, and C2H4. Compared with industrial sand as bed material, porous medium as bed material was more suitable for gasifying biomass to hydrogen-rich gas. The physical characteristics of porous structure are more favorable to heat transfer, producing the secondary crack of heavy hydrocarbons and generating more hydrogen and other permanent gases. The product yields of hydrogen-rich gas increased with increasing gasification temperature. The hydrogen concentration improved from 22.52 vol.% to 36.06 vol.%, but the CO concentration decreased from 37.53 vol.% to 28.37 vol.% with increasing temperature from 600 °C to 900 °C under the operation parameters of porous bed material at a steam flow rate of 1.56 kg/h. With increasing oxygen concentration, H2 concentration increased from 12.36% to 20.21%. Over the ranges of the examined experimental conditions, the actual steam flux value (e.g., 1.56 kg/h) was found to be the optimum value for gasification.  相似文献   

12.
The syngas composition characteristic was investigated in the real slurry-feed gasifier using a detailed gas phase reaction mechanism. The results show that the time for syngas to reach equilibrium is much shorter than the residence time for slurry feed entrained-flow gasifiers, indicating a gas phase species partial equilibrium state. Further calculation shows that the four major species, CO, CO2, H2, and H2O, are in equilibrium via the reaction CO + H2O ⇔ CO2+H2. Suggestions are provided for future modeling and model validation.  相似文献   

13.
A comprehensive coarse grain model (CGM) is applied to simulation of biomass steam gasification in bubbling fluidized bed reactor. The CGM was evaluated by comparing the hydrodynamic behavior and heat transfer prediction with the results predicted using the discrete element method (DEM) and experimental data in a lab-scale fluidized bed furnace. CGM shows good performance and the computational time is significantly shorter than the DEM approach. The CGM is used to study the effects of different operating temperature and steam/biomass (S/B) ratio on the gasification process and product gas composition. The results show that higher temperature enhances the production of CO, and higher S/B ratio improves the production of H2, while it suppresses the production of CO. For the main product H2, the minimum relative error of CGM in comparison with experiment is 1%, the maximum relative error is less than 4%. For the total gas yield and H2 gas yield, the maximum relative errors are less than 7%. The predicted concentration of different product gases is in good agreement with experimental data. CGM is shown to provide reliable prediction of the gasification process in fluidized bed furnace with considerably reduced computational time.  相似文献   

14.
This study investigated the effects of calcium based catalyst (calcium oxide) on variation of gas composition in catalytic gasification reaction stages by controlling the gasification temperature between 600 °C and 900 °C whilst varying a catalyst/biomass ratio from 0 to 0.2 w/w. The tested biomass generated from used bamboo chopsticks were used as the feedstock. To assess the gas composition variation, the ratio of H2/CO, H2/CO2, CO/CO2, and 3H2/CH4 are four important factors that affect the performance of catalytic gasification process. The maximum ratio of H2/CO increased from 0.23 to 0.72 in the gasification temperature range between 600 °C and 900 °C and 0%–20% calcium based catalyst addition ratio. This is due to enhanced H2 production as a result of the facilitated water–gas shift reaction. The ratios of CO/CO2 and 3H2/CH4 increased significantly from 0.9 to 2.1 and from 2.6 to 4.1, respectively, when the gasification temperature increased from 600 °C to 900 °C and 20% catalyst addition ratio. Obviously, the high temperature and catalyst addition are favorable for production of CO and H2 during gasification of tested biomass. In conclusion, the tested mineral calcium based catalyst (CaO) can help facilitating the reaction rate of partial oxidation and water–gas shift reaction, enhancing the quality of synthesis gas, and reduction of the gasification reaction time. This catalyst has potential application in gasification of waste bamboo chopsticks in the future.  相似文献   

15.
Subbituminous coal, activated carbon, coke and a mixture of coal and biomass were gasified using direct solar irradiation in a 23-kW solar furnace located at the U.S. Army White Sands Missile Range, White Sands, New Mexico. The sunlight was focused directly on the coal (or alternate fuel) bed being gasified through a window in the reactor. Steam or CO2 (in different experiments) was passed through the solar-heated coal bed where it reacted with the coal and thus formed a combustible product gas that contained the energy content of both the coal and the sunlight. More than 40 per cent of the sunlight arriving at the focus external to the reactor was chemically stored as fuel value in the product gas. Since there were considerable solar losses because of the reflectivity of the window and the window aperture being smaller than the focal-spot size, it is estimated that in excess of 60 per cent of the solar energy that entered the reactor was chemically stored. The product-gas production rate increased with increased solar power, and when steam was used for gasification, the product-gas composition and thus heating value were almost independent of solar power. A typical moisture-free gas composition was 54 per cent H2, 25 per cent CO, 16 per cent CO2, 4 per cent CH4 and 1 per cent higher hydrocarbons. Activated carbon and a uniform mixture of coal and biomass were also gasified with similar efficiencies but slightly different product-gas compositions. Coke showed a lower solar conversion efficiency. Solar gasification offers several advantages over conventional oxygen-blown gasifiers: (1) commercial grade oxygen is not required, (2) almost twice as much gas per ton of coal can be achieved because no coal is burned to provide process heat and because the gas contains energy from both coal and the sun, and (3) the system has very low thermal inertia and is insensitive to thermal shock, making it very adaptable to rapidly changing solar conditions such as passing clouds.  相似文献   

16.
Computational Fluid Dynamics-Discrete Element Method (CFD-DEM) is employed to describe the co-gasification of biomass and coal in bubbling fluidized bed coupled with chemical reaction kinetic model. Six sets of simulations are set up to study the effect of blend ratio on the amount of gasification products compared with experiments. The calorific value of syngas, carbon conversion efficiency, hydrogen conversion efficiency and cold gas efficiency are calculated. Compared with the separate gasification, the hydrogen efficiency and cold gas efficiency in the co-gasification are enhanced. When biomass accounts for 75%, the contents of CO gas and CO2 gas are the lowest, while the contents of H2 gas and CH4 gas are the highest. The high calorific value, carbon conversion efficiency and hydrogen conversion efficiency reach the maximum under this blend ratio. The cold gas efficiency is not obviously affected by the blend ratio, and reaches the maximum when the biomass content is 50%.  相似文献   

17.
This work presents an experimental study of the gasification of a wood biomass in a moving bed downdraft reactor with two-air supply stages. This configuration is considered as primary method to improve the quality of the producer gas, regarding its tar reduction. By varying the air flow fed to the gasifier and the distribution of gasification air between stages (AR), being the controllable and measurable variables for this type of gasifiers, measuring the CO, CH4 and H2 gas concentrations and through a mass and energy balance, the gas yield and its power, the cold efficiency of the process and the equivalence ratio (ER), as well as other performance variables were calculated. The gasifier produces a combustible gas with a CO, CH4 and H2 concentrations of 19.04, 0.89 and 16.78% v respectively, at a total flow of air of 20 Nm3 h−1 and an AR of 80%. For these conditions, the low heating value of the gas was 4539 kJ Nm−3. Results from the calculation model show a useful gas power and cold efficiency around 40 kW and 68%, respectively. The resulting ER under the referred operation condition is around 0.40. The results suggested a considerable effect of the secondary stage over the reduction of the CH4 concentration which is associated with the decreases of the tar content in the produced gas. Under these conditions the biomass devolatilization in the pyrolysis zone gives much lighter compounds which are more easily cracked when the gas stream passes through the combustion zone.  相似文献   

18.
A literature review on gasification of lignocellulosic biomass in various types of fluidized bed gasifiers is presented. The effect of several process parameters such as catalytic bed material, bed temperature and gasifying agent on the performance of the gasifier and quality of the producer gas is discussed. Based on the priorities of researchers, the optimum values of various desired outputs in the gasification process including improved producer gas composition, enhanced LHV, less tar and char content, high gas yield and enhanced carbon conversion and cold gas efficiency have been reported. The characteristics and performance of different fluidized bed gasifiers were assessed and the obtained results from the literature have been extensively reviewed. Survey of literature revealed that several industrial biomass gasification plants using fluidized beds are currently conducting in various countries. However, more research and development of technology should be devoted to this field to enhance the economical feasibility of this process for future exploitations.  相似文献   

19.
Catalytic performance of Cu and Zn catalysts was investigated during rice husk (RH) high-temperature pyrolysis under isothermal conditions in a micro-fluidized bed reactor. The results showed that the presence of Cu and Zn evidently influenced the release characteristics and conversion of the gas components. The impregnated Cu promoted the conversion of H2, CH4, CO and CO2, while Zn showed positive catalytic effect on the conversion of H2, CH4 and CO2 and negative effect on the conversion of CO. The X-ray diffraction patterns of the residue chars revealed that metallic copper nanoparticles (Cu0) were formed during Cu impregnated biomass pyrolysis. Textural characterization and SEM images showed that the impregnation of Cu and Zn, particularly Zn, promoted the generation of micropores and mesopores, with the pore sizes predominantly at around 1.3 nm and 3.9 nm. Reaction kinetics for generating these gases was studied based on model fitting method, and the most probable reaction mechanism was obtained based on the relative error between experimental and calculated conversion data. The resulting apparent activation energies were 85.08, 12.56, 49.72 and 38.37 kJ/mol for the formation of H2, CO, CH4 and CO2 from pure RH pyrolysis. The presence of Cu decreased the forming activation energies of the four gases, and Zn decrease the forming activation energies of H2, CH4 and CO2 while increased the value for the formation of CO.  相似文献   

20.
A kinetic model of algae gasification for hydrogen production with air and steam as gasification agent and was developed. The developed model was based on kinetic parameters available in the literature. The objective was to study the effect of critical parameters such as reaction temperature, stoichiometric ratio (SR) and steam flow rate (SFR) on H2/CO ratio in the syngas, hydrogen yield, and lower heating value (LHV) of the produced syngas. Model formulation was validated with experimental results on air-steam gasification of biomass conducted in an atmospheric fluidized bed gasifier. The results showed that higher temperature contributed to lower H2/CO, while higher SFR resulted in higher H2/CO. The LHV of producer gas increased with SFR and gasification temperature.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号