共查询到8条相似文献,搜索用时 15 毫秒
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Bhavdeep K. Patel 《Polymer-Plastics Technology and Engineering》2013,52(3):244-249
Bisphthalamic acids were prepared by reaction between phthalic anhydride and diamines. Flame-retardant poly(ester-amide)s (FR-PEAs) were prepared by reaction between bisphthalamic acids and brominated epoxy resin. Acrylation of FR-PEAs gives flame retardant acrylated poly(ester-amide)s (FR-APEAs). FR-PEAs and FR-APEAs were characterized by IR spectra, elemental analysis and number average molecular weight. Blending of FR-APEAs with methyl methacrylate and styrene was carried out. Curing study of these blends was monitored by Differential Scanning Calorimeter (DSC). Based on DSC data, glass and carbon reinforced composites have been laminated and characterized. The unreinforced cured samples were subjected to thermogravimetric analysis. 相似文献
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采用粘度、凝胶时间及力学性能测试以及示差扫描量热分析和扫描电镜研究了上纬环氧树脂2511-A体系的工艺性能,固化反应行为及其采用西曼树脂浸渍膜塑成型工艺(Seeman Composites Infusion Molding Process,SCRIMP)制成的环氧玻璃纤维复合材料的性能。结果表明:2511-A体系在25~35℃下粘度保持在600 mPa.s以下的时间长达120 min,满足SRCIMP成型工艺要求,其玻璃化转变温度为112℃。复合材料的孔隙率仅为0.19%,且具有良好的力学性能。 相似文献
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A review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites 总被引:1,自引:0,他引:1
Rajatendu SenguptaMithun Bhattacharya S. BandyopadhyayAnil K. Bhowmick 《Progress in Polymer Science》2011,36(5):638-670
Carbon materials particularly in the form of sparkling diamonds have held mankind spellbound for centuries, and in its other forms, like coal and coke continue to serve mankind as a fuel material, like carbon black, carbon fibers, carbon nanofibers and carbon nanotubes meet requirements of reinforcing filler in several applications. All these various forms of carbon are possible because of the element's unique hybridization ability. Graphene (a single two-dimensional layer of carbon atoms bonded together in the hexagonal graphite lattice), the basic building block of graphite, is at the epicenter of present-day materials research because of its high values of Young's modulus, fracture strength, thermal conductivity, specific surface area and fascinating transport phenomena leading to its use in multifarious applications like energy storage materials, liquid crystal devices, mechanical resonators and polymer composites. In this review, we focus on graphite and describe its various modifications for use as modified fillers in polymer matrices for creating polymer-carbon nanocomposites. 相似文献
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Nanying NingSirui Fu Wei ZhangFeng Chen Ke Wang Hua DengQin Zhang Qiang Fu 《Progress in Polymer Science》2012,37(10):1425-1455
Polymer/filler composites have been widely used in various areas. One of the keys to achieve the high performance of these composites is good interfacial interaction between polymer matrix and filler. As a relatively new approach, the possibility to enhance polymer/filler interfacial interaction via crystallization of polymer on the surface of fillers, i.e., interfacial crystallization, is summarized and discussed in this paper. Interfacial crystallization has attracted tremendous interest in the past several decades, and some unique hybrid crystalline structures have been observed, including hybrid shish-kebab and hybrid shish-calabash structures in which the filler served as the shish and crystalline polymer as the kebab/calabash. Thus, the manipulation of the interfacial crystallization architecture offers a potential highly effective route to achieve strong polymer/filler interaction. This review is based on the latest development of interfacial crystallization in polymer/filler composites and will be organized as follows. The structural/morphological features of various interfacial crystallization fashions are described first. Subsequently, various influences on the final structure/morphology of hybrid crystallization and the nucleation and/or growth mechanisms of crystallization behaviors at polymer/filler interface are reviewed. Then recent studies on interfacial crystallization induced interfacial enhancement ascertained by different research methodologies are addressed, including a comparative analysis to highlight the positive role of interfacial crystallization on the resultant mechanical reinforcement. Finally, a conclusion, including future perspectives, is presented. 相似文献
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Nabarun Roy 《Progress in Polymer Science》2012,37(6):781-819
The various forms of carbon used in composite preparation include mainly carbon-black, carbon nanotubes and nanofibers, graphite and fullerenes. This review presents a detailed literature survey on the various modifications of the carbon nanostructures for nanocomposite preparation focusing upon the works published in the last decade. The modifications of each form of carbon are considered, with a compilation of structure-property relationships of carbon-based polymer nanocomposites. Modifications in both bulk and surface modifications have been reviewed, with comparison of their mechanical, thermal, electrical and barrier properties. A synopsis of the applications of these advanced materials is presented, pointing out gaps to motivate potential research in this field. 相似文献