首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.

In-situ high-energy X-ray diffraction experiments with high temporal resolution during rapid cooling (280 °C s−1) and isothermal heat treatments (at 450 °C, 500 °C, and 550 °C for 30 minutes) were performed to study austenite decomposition in two commercial high-strength low-alloy steels. The rapid phase transformations occurring in these types of steels are investigated for the first time in-situ, aiding a detailed analysis of the austenite decomposition kinetics. For the low hardenability steel with main composition Fe-0.08C-1.7Mn-0.403Si-0.303Cr in weight percent, austenite decomposition to polygonal ferrite and bainite occurs already during the initial cooling. However, for the high hardenability steel with main composition Fe-0.08C-1.79Mn-0.182Si-0.757Cr-0.094Mo in weight percent, the austenite decomposition kinetics is retarded, chiefly by the Mo addition, and therefore mainly bainitic transformation occurs during isothermal holding; the bainitic transformation rate at the isothermal holding is clearly enhanced by lowered temperature from 550 °C to 500 °C and 450 °C. During prolonged isothermal holding, carbide formation leads to decreased austenite carbon content and promotes continued bainitic ferrite formation. Moreover, at prolonged isothermal holding at higher temperatures some degenerate pearlite form.

  相似文献   

2.
The influence of weld thermal simulation on the transformation kinetics and heat-affected zone (HAZ) microstructure of two high-strength low-alloy (HSLA) steels, HSLA-80 and HSLA-100, has been investigated. Heat inputs of 10 kJ/cm (fast cooling) and 40 kJ/cm (slow cooling) were used to generate single-pass thermal cycles with peak temperatures in the range of 750 °C to 1400 °C. The prior-austenite grain size is found to grow rapidly beyond 1100 °C in both the steels, primarily with the dissolution of niobium carbonitride (Nb(CN)) precipitates. Dilatation studies on HSLA-80 steel indicate transformation start temperatures (T s ) of 550 °C to 560 °C while cooling from a peak temperature (T p ) of 1000 °C. Transmission electron microscopy studies show here the presence of accicular ferrite in the HAZ. The T s value is lowered to 470 °C and below when cooled from a peak temperature of 1200 °C and beyond, with almost complete transformation to lath martensite. In HSLA-100 steel, the T s value for accicular ferrite is found to be 470 °C to 490 °C when cooled from a peak temperature of 1000 °C, but is lowered below 450 °C when cooled from 1200 °C and beyond, with correspondingly higher austenite grain sizes. The transformation kinetics appears to be relatively faster in the fine-grained austenite than in the coarse-grained austenite, where the niobium is in complete solid solution. A mixed microstructure consisting of accicular ferrite and lath martensite is observed for practically all HAZ treatments. The coarse-grained HAZ (CGHAZ) of HSLA-80 steel shows a higher volume fraction of lath martensite in the final microstructure and is harder than the CGHAZ of HSLA-100 steel.  相似文献   

3.
The influence of weld thermal simulation on the transformation kinetics and heat-affected zone (HAZ) microstructure of two high-strength low-alloy (HSLA) steels, HSLA-80 and HSLA-100, has been investigated. Heat inputs of 10 kJ/cm (fast cooling) and 40 kJ/cm (slow cooling) were used to generate single-pass thermal cycles with peak temperatures in the range of 750 °C to 1400 °C. The prior-austenite grain size is found to grow rapidly beyond 1100 °C in both the steels, primarily with the dissolution of niobium carbonitride (Nb(CN)) precipitates. Dilatation studies on HSLA-80 steel indicate transformation start temperatures (T s ) of 550 °C to 560 °C while cooling from a peak temperature (T p ) of 1000 °C. Transmission electron microscopy studies show here the presence of accicular ferrite in the HAZ. The T s value is lowered to 470 °C and below when cooled from a peak temperature of 1200 °C and beyond, with almost complete transformation to lath martensite. In HSLA-100 steel, the T s value for accicular ferrite is found to be 470 °C to 490 °C when cooled from a peak temperature of 1000 °C, but is lowered below 450 °C when cooled from 1200 °C and beyond, with correspondingly higher austenite grain sizes. The transformation kinetics appears to be relatively faster in the fine-grained austenite than in the coarse-grained austenite, where the niobium is in complete solid solution. A mixed microstructure consisting of accicular ferrite and lath martensite is observed for practically all HAZ treatments. The coarse-grained HAZ (CGHAZ) of HSLA-80 steel shows a higher volume fraction of lath martensite in the final microstructure and is harder than the CGHAZ of HSLA-100 steel.  相似文献   

4.
Laboratory thermomechanical processing (TMP) experiments have been carried out to study the austenite transformation characteristics, precipitation behavior, and recrystallization of deformed ferrite for an interstitial-free (IF) steel in the temperature range just below Ar 3. For cooling rates in the range 0.1 °C s−1 to 130 °C s−1, austenite transforms to either polygonal ferrite (PF) or massive ferrite (MF). The transformation temperatures vary systematically with cooling rate and austenite condition. There is indirect evidence that the transformation rates for both PF and MF are decreased by the presence of substitutional solute atoms and precipitate particles. When unstable austenite is deformed at 850 °C, it transforms to an extremely fine strain-induced MF. Under conditions of high supersaturation of Ti, Nb, and S, (Ti,Nb) x S y precipitates form at 850 °C as coprecipitates on pre-existing (Ti,Nb)N particles and as discrete precipitates within PF grains. Pre-existing intragranular (Ti,Nb) x S y precipitates retard recrystallization and grain coarsening of PF deformed at 850 °C and result in a stable, recovered subgrain structure. The results are relevant to the design of TMP schedules for warm rolling of IF steels.  相似文献   

5.
Phase evolution in a 0.36 wt% C steel has been studied by thermodynamic calculation and dilatometric analysis with an aim to achieve high strength TRIP‐assisted steel with bainitic microstructure. The equilibrium phase fraction calculated as the function of temperature indicated the formation of δ‐ferrite (≈98%) at 1417°C. In contrast, similar calculation under para‐equilibrium condition exhibited transformation of δ‐ferrite to austenite at the temperature below 1300°C. During further cooling two‐phase (α+γ) microstructure has been found to be stable at the intercritical temperature range. The experimentally determined CCT diagram has revealed that adequate hardenability is achievable in the steel under continuous cooling condition at cooling rate >5°C s?1. In view of the aforesaid results, the steel has been hot rolled and subjected to different process schedule conducive to the evolution of bainitic microstructure. The hot rolled steel has exhibited reasonably good tensile properties. However, cold deformation of the hot rolled sample followed by intercritical annealing and subsequent isothermal bainitic transformation has resulted in high strength (>1000 MPa) with attractive elongation due to the favorable work hardening condition during plastic deformation offered by the multiphase microstructure.  相似文献   

6.
Hot ductility tests were used to determine the hot-cracking susceptibility of two low-carbon, low Mn/S ratio steels and compared with a higher-carbon plain C-Mn steel and a low C, high Mn/S ratio steel. Specimens were solution treated at 1623 K (1350 °C) or in situ melted before cooling at 100 K/min to various testing temperatures and strained at 7.5 × 10?4 s?1, using a Gleeble 3500 Thermomechanical Simulator. The low C, low Mn/S steels showed embrittlement from 1073 K to 1323 K (800 °C to 1050 °C) because of precipitation of MnS at the austenite grain boundaries combined with large grain size. Isothermal holding for 10 minutes at 1273 K (1000 °C) coarsened the MnS leading to significant improvement in hot ductility. The higher-carbon plain C-Mn steel only displayed a narrow trough less than the Ae3 temperature because of intergranular failure occurring along thin films of ferrite at prior austenite boundaries. The low C, high Mn/S steel had improved ductility for solution treatment conditions over that of in situ melt conditions because of the grain-refining influence of Ti. The higher Mn/S ratio steel yielded significantly better ductility than the low Mn/S ratio steels. The low hot ductility of the two low Mn/S grades was in disagreement with commercial findings where no cracking susceptibility has been reported. This discrepancy was due to the oversimplification of the thermal history of the hot ductility testing in comparison with commercial production leading to a marked difference in precipitation behavior, whereas laboratory conditions promoted fine sulfide precipitation along the austenite grain boundaries and hence, low ductility.  相似文献   

7.

This study is to comprehensively clarify the effect of Nb addition on the particles, austenite grain growth, microstructure evolution, and toughness in the heat-affected zone after high heat input welding at 400 kJ cm−1 for shipbuilding steel plates with Mg deoxidation containing 0.002 and 0.016 wt pct Nb. The Nb addition enhances the dissolution of small particles (< 20 nm) and the coarsening of large particles (> 20 nm) during welding period of T > 1300 °C, because the stability of (Ti, Nb)(C, N) particles is reduced caused by the weaker bonding of Ti–C, Nb–N, and Nb–C. With the temperature above 1300 °C during welding, the austenite grain growth rate increases with Nb addition because the particle pinning force reduces by the small-sized particle dissolution and large-size particle coarsening. Nb addition hinders the ferrite transformation with the transformation temperature decreasing from 700–535 °C to 670–520 °C, due to the increased PAG size. Thus, with Nb addition, the microstructures change from high-temperature fine polygonal ferrite in small prior austenite grains (PAGs) to low-temperature coarse intragranular bainite ferrite in large PAGs, reducing the high-angled grain boundary density from 1.3 to 0.5 μm−1 and increasing the effective grain size from 10.4 to 17.6 μm. Thus, the toughness at − 40 °C decreases from 127 to 58 J.

  相似文献   

8.
Ferrite formation from the ultra-fine dynamically recrystallized austenite (dγ < 5 μm) was investigated on a microalloyed steel with 0.11%C. Hot rolling conditions were simulated by the hot deformation simulator Wumsi. Due to accelerated cooling a corresponding fine homogeneous ferrite grain of dα < 2 μm was achieved with a pearlite free acicular microstructure after a cooling rate of more than 20 K/s. Excellent mechanical properties (2.0% proof stress of over 700 MPa and impact transition temperature of -180°C) were obtained, superior to those after thermomechanical processing of the same steel without dynamic recrystallization of the low-temperature austenite.  相似文献   

9.
It has been generally believed that pearlite transformation in hypoeutectoid steels starts when the average carbon concentration in untransformed austenite reaches the Acm line after the formation of proeutectoid ferrite. To test this concept experimentally, volume fractions of proeutectoid ferrite/pearlite and carbon contents in the austenite being transformed into pearlite were measured for the Fe-2Mn-0.3C alloy isothermally transformed in the temperature range 848 K to 898 K (575 °C to 625 °C). It was found that lamellar pearlite can form even when the average carbon content in untransformed austenite is much lower than the Acm line. This peculiar observation is probably due to the two-dimensional diffusion of carbon, i.e., parallel to and normal to the austenite/pearlite interface, which enables lamellar cementite to grow continuously by supplying carbon atoms to its growth front. This results in proeutectoid ferrite fractions with respect to pearlite being much lower than those predicted by the lever rule. With decreasing prior austenite grain size, proeutectoid ferrite fractions with respect to pearlite were found to increase, but the thickness of proeutectoid ferrite was constant within the range of grain size investigated. This is due to the existence of the critical α/γ interface velocity only below which pearlite (actually cementite) can be nucleated at the migrating α/γ interface. Furthermore, the upper limit temperatures for pearlite formation in the Fe-1Mn-0.33C and Fe-2Mn-0.3C alloys were found to be well between the PLE/NPLE and PE Ae1 temperatures.  相似文献   

10.
An ultralightweight Fe–30Mn–13.2Al–1.6C–5Cr steel, which contains more than 13 wt% of Al and thereby reduces the density by 20%, is developed. The ultralightweight steel, which is very brittle due to high Al content, is fabricated by optimizing hot rolling and heat treatment conditions. Hot rolling is conducted after soaking at the temperature range of 1100–1200 °C for 2 h. The ultralightweight steel is hot-rolled successfully after soaking at 1100 °C, whereas specimens soaked at 1150 and 1200 °C are intergranularly cracked after hot rolling, resulting from coarse grain and a large fraction and size of ferrite, which is transformed to ordered DO3 phase during cooling, at the grain boundaries. In homogenization heat treatment, water quenching and air cooling are performed, respectively, after holding at 1050 °C for 2 h. The air-cooled steel has inferior tensile property due to the formation of brittle ordered DO3 phase at grain boundaries. Meanwhile, the water-quenched steel shows an excellent tensile property, which is attributed to a uniform microstructure comprising austenite, fine κ-carbide in austenite, and a very small fraction of the ordered DO3 phase.  相似文献   

11.
To research the effect of Mg on the austenite grain growth of the heat-affected zone (HAZ) in low-carbon high-strength steels, two steels with different Mg contents were prepared using a laboratory vacuum. It was observed through optical microscope (OM) that the HAZ austenite grain size decreased from 385 to 86 μm after Mg treatment. In-situ observation by a confocal scanning laser microscope showed that the HAZ austenite grain size of the steel with Mg treatment could hold fine-grained structure after 1673 K (1400 °C) heating for 300 seconds, which was mainly attributed to the formation of pinning particles after the addition of Mg. Analysis showed that the number of pinning particles was much increased and the mean size was much decreased by the Mg treatment. It also can be found that more particles occurred with the MgO as the nucleating center. The HAZ toughness was improved from 33 to 185 J by refinement of austenite grains in the simulated HAZ due to the Mg treatment. The results presented in this article point to a potential method for improving HAZ toughness of low-carbon high-strength steels.  相似文献   

12.
Steels with compositions that are hot rolled and cooled to exhibit high strength and good toughness often require a bainitic microstructure. This is especially true for plate steels for linepipe applications where strengths in excess of 690 MPa (100 ksi) are needed in thicknesses between approximately 6 and 30 mm. To ensure adequate strength and toughness, the steels should have adequate hardenability (C. E. >0.50 and Pcm >0.20), and are thermomechanically controlled processed, i.e., controlled rolled, followed by interrupted direct quenching to below the Bs temperature of the pancaked austenite. Bainite formed in this way can be defined as a polyphase mixture comprised a matrix phase of bainitic ferrite plus a higher carbon second phase or micro-constituent which can be martensite, retained austenite, or cementite, depending on circumstances. This second feature is predominately martensite in IDQ steels. Unlike pearlite, where the ferrite and cementite form cooperatively at the same moving interface, the bainitic ferrite and MA form in sequence with falling temperature below the Bs temperature or with increasing isothermal holding time. Several studies have found that the mechanical properties may vary strongly for different types of bainite, i.e., different forms of bainitic ferrite and/or MA. Thermomechanical controlled processing (TMCP) has been shown to be an important way to control the microstructure and mechanical properties in low carbon, high strength steel. This is especially true in the case of bainite formation, where the complexity of the austenite-bainite transformation makes its control through disciplined processing especially important. In this study, a low carbon, high manganese steel containing niobium was investigated to better understand the effects of austenite conditioning and cooling rates on the bainitic phase transformation, i.e., the formation of bainitic ferrite plus MA. Specimens were compared after transformation from recrystallized, equiaxed austenite to deformed, pancaked austenite, which were followed by seven different cooling rates ranging between 0.5 K/s (0.5 °C/s) and 40 K/s (40 °C/s). The CCT curves showed that the transformation behaviors and temperatures varied with starting austenite microstructure and cooling rate, resulting in different final microstructures. The EBSD results and the thermodynamics and kinetics analyses show that in low carbon bainite, the nucleation rate is the key factor that affects the bainitic ferrite morphology, size, and orientation. However, the growth of bainite is also quite important since the bainitic ferrite laths apparently can coalesce or coarsen into larger units with slower cooling rates or longer isothermal holding time, causing a deterioration in toughness. This paper reviews the formation of bainite in this steel and describes and rationalizes the final microstructures observed, both in terms of not only formation but also for the expected influence on mechanical properties.  相似文献   

13.
Continuous cooling transformation (CCT) diagrams for HSLA-80 and HSLA-100 steels pertaining to fusion welding with heat inputs of 10 to 40 kJ/cm, and peak temperatures of 1000 °C to 1400 °C have been developed. The corresponding nonlinear cooling profiles and related γ → α phase transformation start and finish temperatures for various peak temperature conditions have been taken into account. The martensite start (M s ) temperature for each of the grades and ambient temperature microstructures were considered for mapping the CCT diagrams. The austenite condition and cooling rate are found to influence the phase transformation temperatures, transformation kinetics, and morphology of the transformed products. In the fine-grain heat-affected zone (FGHAZ) of HSLA-80 steel, the transformation during cooling begins at temperatures of 550 °C to 560 °C, and in the HSLA-100 steel at 470 °C to 490 °C. In comparison, the transformation temperature is lower by 120 °C and 30 °C in the coarse-grain heat-affected zone (CGHAZ) of HSLA-80 steel and HSLA-100 steel, respectively. At these temperatures, acicular ferrite (AF) and lath martensite (LM) phases are formed. While the FGHAZ contains a greater proportion of acicular ferrite, the CGHAZ has a higher volume fraction of LM. Cooling profiles from the same peak temperature influence the transformation kinetics with slower cooling rates producing a higher volume fraction of acicular ferrite at the expense of LM. The CCT diagrams produced can predict the microstructure of the entire HAZ and have overcome the limitations of the conventional CCT diagrams, primarily with respect to the CGHAZ.  相似文献   

14.
Herein, the effect of molybdenum (Mo) and postrolling cooling processes on the mechanical properties and microstructure transformation characteristics of an X80 thick-wall high-strength pipeline steel are deeply investigated. The results reveal that the yield strength and tensile strength of the steel are enhanced with Mo addition at the equalization temperature of 480 °C at a cooling rate of 25 °C s−1, accompanied by the improvement in the yield ratio. However, when the postrolling cooling temperature is reduced to 380 °C, the mechanical properties of steels with Mo-free and 0.29 wt% Mo are comparable. The mechanistic study indicates that the Mo addition would inhibit the transformation from deformed austenite to polygonal ferrite, and promote the transformation of acicular ferrite/granular bainite at medium–low temperatures, as well as significant differences in the volume fraction, size, and morphology of martensite/austenite (M/A) in the matrix. Notably, the volume fraction of M/A decreases from 7.2% to less than 1.0% with Mo content increasing, while its average size also reduces from 1.5 to less than 1.0 μm. And the fine, spheroidal, and dispersed M/A is found to play a vital role in the high-strength and excellent low-temperature toughness of the steel.  相似文献   

15.
The hot ductility and malleability of a vanadium‐microalloyed steel is investigated by means of tensile and compression tests at temperatures ranging from 700 to 850°C and strain rates of 3 × 10?4 to 0.3 s?1. The deformation tests are performed after austenitization and cooling to test temperature. The so‐called second ductility minimum is located around 750°C for all strain rates except for the highest one, where no ductility trough is observed. Ductility steadily increases with strain rate at a given temperature, and the fracture mode progressively changes from intergranular to transgranular. In the region of minimum ductility, intergranular cracking occurs at low strain rates by void nucleation, growth and coalescence within thin layers of deformation induced ferrite covering the austenite grain boundaries. Cracking is favoured by V(C,N) precipitation associated with the γ/α phase transformation. Ductility remains low above the temperature of minimum ductility, where no apparent ferrite formation is observed (790 °C). Void formation takes place as a result of grain boundary sliding in combination with matrix and grain boundary precipitation. These voids are able to grow and link up forming intergranular cracks. Ductility increases with strain rate mainly due to the short time available for precipitation as well as for intergranular void growth and coalescence.  相似文献   

16.
17.
Isothermal transformation from austenite in an Fe-9.14 pct Ni alloy has been studied by optical metallography and examination by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). In the temperature range 565 °C and 545 °C, massive ferrite (α q ) forms first at prior austenite grain boundaries, followed by Widmanst?tten ferrite (α W ) growing from this grain boundary ferrite. Between 495 °C and 535 °C, Widmanst?tten ferrite is thought to grow directly from the austenite grain boundaries. Both these transformations do not go to completion and reasons for this are discussed. These composition invariant transformations occur below T 0 in the two-phase field (α+γ). Previous work on the same alloy showed that transformation occurred to α q > and α W on furnace cooling, while analytical TEM showed an increase of Ni at the massive ferrite grain boundaries, indicating local partitioning of Ni at the transformation interface. An Fe-3.47 pct Ni alloy transformed to equiaxed ferrite at 707 °C ±5 °C inside the single-phase field on air cooling. This is in agreement with data from other sources, although equiaxed ferrite in Fe-C alloys forms in the two-phase region. The application of theories of growth of two types of massive transformation by Hillert and his colleagues are discussed. This article is based on a presentation made at the symposium entitled “The Mechanisms of the Massive Transformation,” a part of the Fall 2000 TMS Meeting held October 16–19, 2000, in St. Louis, Missouri, under the auspices of the ASM Phase Transformations Committee.  相似文献   

18.
The plastic-flow behavior of ferrite + pearlite, pearlite + cementite, and austenite + cementite mixtures in plain carbon steels has been examined over the temperature range 500 to 1050 °C, strain-rate range 6 x l0−6 to 2 x l0−2 s−1, and carbon range 0.005C to 1.89C. Up to the eutectoid temperature the strength of the ferrite + pearlite mixture more than doubles as the carbon content increases from 0.005C to 0.7C, so that whereas in low-carbon steels the ferrite is weaker than the higher temperature austenite phase, in eutectoid steels the fully pearlitic structure is stronger than the fully austenitic structure. Manganese and silicon strengthen ferrite more effectively than they do austenite. A 0.17 pct phosphorus addition strengthens the ferrite + pearlite mixture across the range of microstructures from fully ferritic to fully pearlitic. Beyond the eutectoid composition, the amount of proeutectoid cementite does not significantly affect the strength of the pearlite, but above the eutectoid temperature it appreciably strengthens the austenite and cementite mixture at the strain rate of 2 X 10-2 s-1.  相似文献   

19.
Deformation dilatometry is used to simulate the hot rolling of 0.20 pct C-1.10 pct Mn steels over a product thickness range of 6 to 170 mm. In addition to a base steel, steels with additions of 0.02 pct Ti, 0.06 pct V, or 0.02 pct Nb are included in the study. The transformation behavior of each steel is explored for three different austenite grain sizes, nominally 30, 55, and 100 μm. In general, the volume fraction of Widmanst?tten ferrite increases in all four steels with increasing austenite grain size and cooling rate, with austenite grain size having the more significant effect. The Nb steel has the lowest transformation temperature range and the greatest propensity for Widmanst?tten ferrite formation, while the amount of Widmanst?tten ferrite is minimized in the Ti steel (as a result of intragranular nucleation of polygonal ferrite on coarse TiN particles). The data emphasize the importance of a refined austenite grain size in minimizing the formation of a coarse Widmanst?tten structure. With a sufficiently fine prior austenite grain size (e.g., ≤30 μm), significant amounts of Widmanst?tten structure can be avoided, even in a Nb-alloyed steel.  相似文献   

20.
C. Du  J. Zhang  J. Wen  Y. Li  P. Lan 《钢铁冶炼》2016,43(5):331-339
Surface transverse cracking, especially corner cracking, is prone to generate in continuously cast slabs of microalloyed steels. The method of surface structure control (SSC) was supposed to the best way to avoid the detrimental defects. However, the mechanism of improving hot ductility by SSC and the specific parameters to control the process are still unclear for the reasonable adoption in production. In the present work, the impact of cooling rate, holding temperature and holding time on austenite decomposition, and the austenite grain size before and after intense cooling were investigated by thermal simulation method. With the increase of cooling rate, it is observed that the phase is transformed from austenite?→?grain boundary film-like alltromorph ferrite?→?Widmanstätten ferrite plates (or intragranular ferrite plates)?→?bainite+martensite. Mostly important, the film-like ferrite can be eliminated through intense cooling and the following reheating, but the austenite grain size is not observed to be refined through the single γ?→?α?→?γ cycle. Even though, the reduction of area (RA) is improved drastically to over 70% in the third ductility trough, whereas the RA value is just 相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号