电磁动态塑化挤出机熔体混合性能的研究

在不同振动频率下，利用剖分式料筒电磁动态塑化挤出机，对碳酸钙填充聚乙烯体系进行了螺杆沿程混合性能的研究。通过对不同位置处物料的SEM图的分散相作粒径统计分析。发现振动力场对CaCO3在LDPE熔体中的分散有促进作用。改善了混合物料的混合程度；相同振幅下，振动频率高则分散效果越好。     

Analysis on Pulsating Flow of Melt for Reciprocating Extrusion in the Screw Channel

In the reciprocating extrusion, the vibration force field (VFF) is applied to the entire plasticating process by the axial vibration of screw and the novel concept on the polymer dynamic plasticating process being strengthened has been brought forward in the paper. The mathematical model is established that describes the plasticating process under the VFF and the approximative analytical solutions of the velocity distribution, pressure gradient in the screw channel and the plasticating capability are obtained. The theoretical results show that the axial vibration of screw can accelerate the blend capability of polymer and make melt temperature more uniform. With increase of the vibration intensity, the effect of blend and plasticating is enhanced further. The average pressure gradient drops down the channel under the VFF because of lower virtual viscosity of polymer melt and smaller flow resistance in the channel. The comparison between the theoretical analysis and the experimental results shows the plasticating capability of melt is improved with increase of vibration intensity.     

振动力场下填充聚合物挤出过程研究

研究了利用塑料电磁动态塑化挤出机加工ＰＰ／ＣａＣＯ３和ＬＤＰＥ／ＣａＣＯ３时的动态挤出过程,探讨了振动力场对聚合物填充体系挤出过程扣影响规律和作用机理。结果表明,在一定的振动条件下,振动力场的作用使挤出压力减同功率降低,混合分散效果明显提高。     

基于电磁动态塑化挤出的模头挤出特性的研究

本文以塑料电磁动态塑化挤出机上的圆截面模头为对象,研究了将振动力场引入聚合物塑化挤出全过程条件下圆截面模头的挤出特性,建立了圆截面模头脉动挤出特性的数学模型,并进行了实验研究,理论分析与实验结果趋向一致,从而揭示了振动力场引入聚合物塑化挤出全过程对圆截面模头挤出特性的影响规律。     

Effect of vibration extrusion on the structure and properties of high‐density polyethylene pipes

BACKGROUND: The axial strength of a plastic pipe is much higher than its circumferential strength due to the macromolecular orientation during extrusion. In this work, a custom‐made electromagnetic dynamic plasticating extruder was adopted to extrude high‐density polyethylene (HDPE) pipes. A vibration force field was introduced into the whole plasticating and extrusion process by axial vibration of the screw. The aim of superimposing a vibration force field was to change the crystalline structure of HDPE and improve the molecular orientation in the circumferential direction to obtain high‐circumferential‐strength pipes. RESULTS: Through vibration extrusion, the circumferential strength of HDPE pipes increased significantly, and biaxial self‐reinforcement pipes could be obtained. The maximum increase of bursting pressure and tensile yield strength was 34.2 and 5.3%, respectively. According to differential scanning calorimetry and wide‐angle X‐ray diffraction measurements, the HDPE pipes prepared by vibration extrusion had higher crystallinity, higher melting temperature, larger crystal sizes and more perfect crystals. CONCLUSION: Vibration extrusion can effectively enhance the mechanical properties of HDPE pipes, especially the circumferential strength. The improvement of mechanical properties of HDPE pipes obtained by vibration extrusion can be attributed to the higher degree of crystallinity and the improvement of the molecular orientation and of the crystalline morphology. Copyright © 2008 Society of Chemical Industry     

单螺杆挤出机中熔体混合理论的研究

综述采用不同的函数对单螺杆挤出机中熔体混合过程进行描述的研究情况和新的混沌混合的研究进展，以及近几年来利用可视化和可视化技术对矣合物材料在挤出过程中的行为所作的观测和分析研究，指出在新型电磁动态塑化挤出机中，引入挤出加工全过程的振动力场，对熔体的混合起到了较好的促进作用。     

短圆管挤出模头中熔体取向行为对螺杆轴向振动响应的光散射研究

利用光散射测量方法研究了短圆管挤出模头中聚合物熔体取向行为对螺杆轴向振动的响应。研究结果表明,螺杆轴向振动使聚合物熔体的流动状态和大分子的取向发生了显著的变化,振动力场中振幅或频率的增加都会引起熔体中大分子取向程度的增大。     

聚合物挤出成型的新方法与新设备

本文论述一种聚合物塑化挤出成型的新方法与新设备,着重分析聚合物塑化挤出新概念和动态塑化挤出过程,并介绍塑料电磁动态塑化挤出设备的原理、结构、性能及特点。     

振动力场作用下聚合物熔体单螺杆挤出过程数值模拟

根据塑料电磁动态塑化挤出过程中熔体输送的实际情况，对三维模型进行简化，利用大型有限元软件ANSYS模拟了叠加轴向振动力场作用下聚合物熔体在螺槽中的流动情况，求解出周期性变化的速度，压力场分布，结果表明，与稳态挤出过程相比，振动力场的引入在进出口压力差恒定的情况下，可以提高熔全输送流率。采用有限元模拟方法可以为确定和优化工艺参数，产品质量控制提供指导。     

An experimental study of plasticating in a reciprocating-screw injection molding machine

Experimental studies were performed with low density polyethylene, acrylonitrile-butadiene-styrene polymers and on polyvinyl chloride to elucidate the nature of the plasticating process in a reciprocating-screw injection molding machine. Melting data, obtained by use of the “cooling experiment,” and plastic temperature data reveal that the screw recharge process is a transient plasticating extrusion process which gradually approaches the equilibrium extrusion behavior as the screw rotates. If the screw rotation time is a high percentage of the total cycle time, the plasticating behavior is very similar to steady-state extrusion behavior, but if the screw rotation time is a small percentage of the total cycle time, the plasticating behavior is significantly different. Furthermore, better plasticating is obtained by use of a low RPM and high percentage rotation time than by a high RPM and low percentage rotation time.     

塑料电磁动态塑化挤出机的挤出功率研究与模拟

本文采用自行修正的Tanner本构方程研究了塑料电磁动态塑化挤出机中熔体输送挤出功率对振动力场的响应。建立了振动力场作用下熔体输送挤出功率的理论模型,以此为基础模拟塑料电磁动态塑化挤出机的挤出功率,并进行了实验研究,结果表明理论模拟能够在一定范围内反映实际情况,为塑料电磁动态塑化挤出设备的设计和生产应用提供重要的理论指导依据。     

塑料电磁动态塑化挤出机加工制品的力学性能

本文采用塑料电磁动态塑化剂出机挤出的条料和吹塑的薄膜进行制样,并对其试样进行力学性能测试分析,结果表明,由于在挤出加工的全过程中引入了周期性振动力场,经塑料电磁动态塑化挤出机加工的制品的力学性能得到了改善和提高,对于PP和LDPE挤出试样,拉伸强度分别提高4.2%和4.7%,对HDPE吹塑膜,纵模向拉伸强度分别提高19.2%和37.4%。     

动态挤出PP板材制品的结构与性能

利用电磁动态塑化挤出机挤出PP板材制品,并对其聚集态结构与力学性能进行测试分析。结果表明在挤出过程中引入振动力场,可以改变PP制品的聚集态结构,从而使其力学性能得到改善。     

振动力场作用下聚合物填充体系挤出混合特性

本文利用一种新型毛细管动态流变仪,对碳酸钙填充聚丙烯体系进行了实验性研究。发现质量百分比为８５／１５的ＰＰ／ＣａＣＯ３填充体系,在一较佳振动条件下动态挤出时,振动场的存在对ＣａＣＯ３在ＰＰ熔体中的分散有促进作用,大大改善了混合料的混合程度。     

振动挤出对HDPE管材耐慢速裂纹增长性能的影响

使用自制的电磁动态塑化挤出机挤出高密度聚乙烯(HDPE)管材。对稳态挤出和振动挤出的HDPE管材耐慢速裂纹增长性能进行了测试。采用DSC、WAXD分析研究了振动力场对HDPE管材耐慢速裂纹增长性能的影响。结果表明:振动挤出的HDPE管材结晶度提高,熔点升高,晶片变厚,晶粒尺寸变大,结晶完善,耐慢速裂纹增长性能提高。     

Increasing the efficiency of the extrusion process

The article presents constructional methods of increasing the efficiency of the polymer extrusion process. Increasing the efficiency of the polymer extrusion process consists in the increase of the flow rate of the processed polymer and the energy efficiency of polymer processing extruders and the decrease of the specific energy consumption and the pulsation of the flow rate and polymer pressure, as well as quality improvement of the received extrudate as a result of better homogenization of mechanical and thermal properties and polymer structure. Therefore, the improvement of the constructional solution of the screw and barrel of the extruder plasticating system was discussed. The improvement of the construction of the screw lies in using the active and passive grooved barrel section. Original constructional solutions of the active grooved section with both longitudinal and helical grooves were shown. The devices increasing the efficiency of the extrusion were also shown, which included a screen changer, a melt pump, and a static mixer. Appropriate conclusions were drawn. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers     

Vibrational force field effect on the melting process of a polymer solid against a sliding wall

The melting of polymers caused by friction before a solid plug is an important phenomenon in the vibration‐induced plastic extrusion process. In order to better analyze the melting process of polymers in a vibration screw type extruder, a melting model is proposed as well as a corresponding experimental apparatus to test the model. Due to the introduction of vibration force field, the viscidity of a polymer melt behaves in a strong non‐linear and time‐dependent fashion. Therefore, the effect of heat generated by viscous dissipation is very important. Through sophisticated deduction, an analytical expression of the relationship between the velocity of polymer solid element and the parameters of vibration is derived. The model is then proved by comparing a calculated sample with experimental results, which indicate that, the introduction of vibration force field can improve the melting process to a great extent. This model can serve as the theoretical basis for a polymer melting process. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers     

电磁动态挤出机螺杆轴向振动研究

简要介绍了电磁动态单螺杆挤出机的结构性能，分析了螺杆在振动力场作用下的轴向受力状况。通过将实际螺杆简化成广义螺杆的方法建立了螺杆轴向振动力学模型和振动方程，求解得到了螺杆轴向振动的规律。通过对比螺杆轴向振动的试验和理论幅频（幅值和频率）关系曲线，验证了理论分析的合理性，为电磁动态挤出机的动态挤出和优化设计提供了理论依据。     

HDPE在振动场中挤出成型时的流变行为

利用自行研制的新型液压振动挤出装置研究了高密度聚乙烯（HDPE）在振动场中挤出成型时的流变行为。研究表明,HDPE熔体在振动场中的表观粘度与振动频率、振幅、口模温度和挤出机螺杆转速均有关,随着振动频率的增加,表观粘度先降至最低值,然后回升到一定程度后基本保持不变,但始终低于未施加振动时的表观粘度;振幅越大,振动场对表观粘度的影响就越大;口模温度超过熔点时,振动场对表观粘度的影响有所增大;螺杆转速越大,振动场对表观粘度的影响就越小。